We collected 38 groundwater and two surface water samples in the semi-arid Lake Woods region of the Northern Territory to better understand the hydrogeochemistry of this system, which straddles the Wiso, Tennant Creek and Georgina geological regions. Lake Woods is presently a losing waterbody feeding the underlying groundwater system. The main aquifers comprise mainly carbonate (limestone and dolostone), siliciclastic (sandstone and siltstone) and evaporitic units. The water composition was determined in terms of bulk properties (pH, electrical conductivity, temperature, dissolved oxygen, redox potential), 40 major, minor and trace elements as well as six isotopes (δ18Owater, δ2Hwater, δ13CDIC, δ34SSO4=, δ18OSO4=, 87Sr/86Sr). The groundwater is recharged through infiltration in the catchment from monsoonal rainfall (annual average rainfall ~600 mm) and runoff. It evolves geochemically mainly through evapotranspiration and water–mineral interaction (dissolution of carbonates, silicates, and to a lesser extent sulfates). The two surface waters (one from the main creek feeding the lake, the other from the lake itself) are extraordinarily enriched in 18O and 2H isotopes (δ18O of +10.9 and +16.4 ‰ VSMOW, and δ2H of +41 and +93 ‰ VSMOW, respectively), which is interpreted to reflect evaporation during the dry season (annual average evaporation ~3000 mm) under low humidity conditions (annual average relative humidity ~40 %). This interpretation is supported by modelling results. The potassium (K) relative enrichment (K/Cl mass ratio over 50 times that of sea water) is similar to that observed in salt-lake systems worldwide that are prospective for potash resources. Potassium enrichment is believed to derive partly from dust during atmospheric transport/deposition, but mostly from weathering of K-silicates in the aquifer materials (and possibly underlying formations). Further studies of Australian salt-lake systems are required to reach evidence-based conclusions on their mineral potential for potash, lithium, boron and other low-temperature mineral system commodities such as uranium. <b>Citation:</b> P. de Caritat, E. N. Bastrakov, S. Jaireth, P. M. English, J. D. A. Clarke, T. P. Mernagh, A. S. Wygralak, H. E. Dulfer & J. Trafford (2019) Groundwater geochemistry, hydrogeology and potash mineral potential of the Lake Woods region, Northern Territory, Australia, <i>Australian Journal of Earth Sciences</i>, 66:3, 411-430, DOI: 10.1080/08120099.2018.1543208

Describes the Western Water Study (Wiluraratja kapi), a 3-year AGSO project to assess groundwater resources and identify regional water issues in remote Aboriginal Communities in the Northern Territory.

The potential for geochemical reactions to cause aquifer clogging or detrimental water quality changes was assessed for a managed aquifer recharge (MAR) target in the Darling River floodplain. The assessment used ambient groundwater quality from the target Calivil Formation aquifer, as well as from the shallow unconfined aquifers; Darling River source water quality; and mineralogy and geochemistry of sonic-cored aquifer samples. PHREEQC was used to examine the impact of mixing and interaction between these end-members. There is considerable variability in the redox state within the Calivil aquifer, with groundwater pe values ranging from -6 to 8. PHREEQC simulations using the median pe value of 3 resulted in super-saturation with respect to Fe(OH)3 . Hence, injection of an oxygenated source water into anoxic zones within the target aquifer can result in iron clogging due to precipitation of any source water dissolved iron and any Fe(II) oxidation in the sediments (in pyrite or displaced from exchange sites). The amount of Fe(II) within the storage zone available to be oxidised is unknown and may be limited given that Fe(III) oxides were present in the core material. The aquifer material contains species that may be released during MAR, including aluminium, arsenic, fluoride, iron, manganese, molybdenum, nickel, selenium and uranium. Injection of source water with elevated dissolved organic carbon (DOC) could enhance metal and metalloid release through reductive dissolution of iron oxides within the storage zone. The fate of any mobilised trace species would be dictated by storage zone redox conditions. Arsenic and molybdenum are likely to be adsorbed to any iron oxide surfaces under oxic conditions. Uranium and selenium are likely to reprecipitate in anoxic zones. This provides the opportunity for natural treatment within the storage zone to control mobilised trace metal species.

Groundwater monitoring around the CO2CRC Otway Project CO2 injection site aims to (1) establish baseline aquifer conditions prior to CO2 injection, and (2) enable detection monitoring for CO2 leakage, in the unlikely event any should occur in the future. The groundwater composition was monitored at 24 bores around the site for nearly 2 years before injection started. The water samples were analysed for standard bulk properties, and inorganic chemical and isotopic compositions. In addition to sampling, standing water levels were monitored continuously in 6 of the bores using barometric loggers. The shallow groundwaters have compositions typical of carbonate aquifer-hosted waters, being fresh (EC 800-4000 S/cm), dominated by Ca2+, Na+, HCO3- and Cl-, cool (T 12-23°C), and near-neutral (pH 6.6-7.5). Most of the deep groundwater samples are fresher (EC 400-1600 S/cm), also dominated by Ca2+, Na+, HCO3- and Cl-, cool (T 15-21°C), but are more alkaline (pH 7.5-9.5). Time-series reveal that most parameters measured have been relatively stable over the sampling period, although some bores display changes that appear to be non-seasonal. Groundwater levels in some of the shallow bores show a seasonal variation with longer term trends evident in both aquifers.

One of the primary requirements of managing our water resources sustainably is an understanding of the water balance. Key components of a water balance model are inputs of recharge and outputs or discharge. Rates of recharge and discharge change in response to climate, landscape morphology, geology, soil/regolith, native vegetation and landuse (including landuse history). The variable nature of these parameters results in a high degree of local variability when determining recharge and discharge fluxes both spatially and temporally. Water managers deal with this complexity in a variety of ways. Where detailed information on key parameters influencing recharge and discharge are available, comprehensive, fully distributed groundwater models are used. However, in most cases this information is not available (e.g. data poor areas) and typically a crude estimation of recharge (2-10% of average annual rainfall) is given. In these cases, discharge is often assumed to be zero. A collaborative project, funded by NWC and involving CSIRO Land and Water and Geoscience Australia, has developed a new national framework for estimating recharge and discharge in data poor areas. The approach consists of excel-based models that allow the user to populate key input fields (e.g. rainfall, soil and regolith texture, bedrock type, vegetation) to generate estimates of recharge and discharge. These excel models have been coupled with a complementary national-scale GIS dataset to assist the user in populating model input fields. In combination, the models and the GIS datasets allow the user to rapidly estimate recharge and/or discharge anywhere in Australia. The national-scale GIS datasets are available through a WEB-based interface. This presentation will focus on the development of the input datasets and will provide a brief demonstration of the WEB-based interface.

Legacy product - no abstract available

Legacy product - no abstract available

Legacy product - no abstract available

The use of airborne electromagnetics (AEM) for hydrogeological investigations often requires high resolution data. Optimisation of AEM data therefore requires careful consideration of AEM system suitability, calibration, validation and inversion methods. In the Broken Hill managed Aquifer Recharge (BHMAR) project, the helicopter-borne SkyTEM transient EM system was selected after forward modeling of system responses and assessment of test line data over potential targets. The survey involved acquisition of 31,834 line km of data over an area of 7,500 km2 of the River Darling Floodplain, and was acquired by two systems over a 9-week period.. Initial Fast Approximate Inversions (FAI) provided within 48 hours of acquisition were used to target 100 sonic and rotary mud holes for calibration and validation. A number of different (Laterally and Spatially Constrained) inversions of the AEM data were carried out, with refinements made as additional information on vertical and lateral constraints became available. Finally, a Wave Number Domain Approximate Inversion procedure with a 1D multi-layer model and constraints in 3D, was used to produce a 3D conductivity model. This inversion procedure only takes days to run, enabling the rapid trialing to select the most appropriate vertical and horizontal constraints. Comparison of borehole induction logs with adjacent AEM fiduciary points confirms high confidence levels in the final inversion. Using this approach has produced quantitative estimates of the 3D conductivity structure that provide a reliable platform for identifying new groundwater resources and a range of MAR options, and developing new geological and hydrogeological conceptual models. Integration of the AEM data with borehole lithology, textural, mineralogical, groundwater and pore fluid hydrochemical and borehole NMR data has enabled maps of hydrostratigraphy, hydraulic conductivity, groundwater salinity, salt store and neotectonics to be produced.

In this study, 3D mapping using airborne electromagnetics (AEM) was used to site a monitoring bore network in the Darling River floodplain corridor. Pressure loggers were installed in over 40 bores to monitor groundwater levels primarily in the shallow unconfined Coonambidgal Formation aquifer, deeper (semi)confined Calivil Formation and confined Renmark Group aquifers. In 2010-11, the network provided the opportunity to monitor the groundwater response to flooding of the Darling River and the replenishment of the Menindee Lakes storages, following a period of prolonged drought. In this event, the Darling River at Menindee (Weir 32) rose from 1.59m in October 2010 and peaked at 7.16m in March 2011. A synchronous rise in groundwater levels varying between 0.5-3.4m was observed in the shallow unconfined aquifer near the river. Shallow groundwater levels also declined following the flood peak. Near-river groundwater levels in the Calivil aquifer rose between 0.2-1.3m and also by 4.0 m at a site near Lake Menindee. The latter confirms lake leakage into the aquifer at this particular site, as previously inferred by the AEM data. There was also a pressure response of 0.1-0.9m evident in certain Renmark aquifer bores near the river. The monitoring confirms the importance of episodic flood events to the recharge of the alluvial aquifers, as supported by groundwater chemistry and stable isotope data. Although some of the confined aquifer response may relate to transient hydraulic loading associated with the flood, the inference is that in places there is a degree of hydraulic connectivity between the aquifers.