Atmospheric monitoring of CO2 geological storage has developed from a concept to reality over less than a decade. Measurements of atmospheric composition and surface to air fluxes are now being made at onshore test sites, pilot projects, operational projects and likely future storage regions around the world. The motivation for atmospheric monitoring is usually to detect potential leakage from CO2 storage activities that might affect health and safety or to test the efficacy of carbon capture and storage (CCS) as a climate mitigation option. We have focused on the mitigation requirement, which involves determining whether potential leakage is below a maximum acceptable rate. Climatic considerations suggest that the maximum leakage rate of stored CO2 should be very small, of the order of 0.01% of that stored per year, globally averaged. Monitoring operational CO2 storage sites to confirm that potential leakage to the atmosphere is below this rate and to locate and quantify the any leakage flux can be a challenge, mainly because of the large and variable CO2 concentrations and fluxes in ecosystems and urban environments. We have developed and assessed atmospheric techniques during field experiments, during 4 years of monitoring the CO2CRC Otway Project, and by using model simulations. From this experience we are able to make recommendations about suitable technologies and strategies to optimise the capability of atmospheric monitoring of CCS in different environments. Abstract for paper to be presented at CO2CRC Research Symposium 2010, 1-3 December 2010, Melbourne

This project aims to address the question: Under what geological circumstances are faults (and fractures) in mudstone seal rocks likely to impact on bulk permeability and the flow of CO₂ through these rocks and are there other geomechanical processes that might result in loss of containment?

In mid 2011 the Australian Government announced funding of a new four year National CO2 Infrastructure Plan (NCIP) to accelerate the identification and development of sites suitable for the long term storage of CO2 in Australia that are within reasonable distances of major energy and industrial CO2 emission sources. The NCIP program promotes pre-competitive storage exploration and provides a basis for the development of transport and storage infrastructure. The Plan follows on from recommendations from the Carbon Storage Taskforce and the National CCS Council (formerly, the National Low Emissions Coal Council). It builds on the work funded under the National Low Emissions Coal Initiative and the need for adequate storage to be identified as a national priority. Geoscience Australia is providing strategic advice in delivering the plan and will lead in the acquisition of pre-competitive data. Four offshore sedimentary basins (Bonaparte, Browse, Perth and Gippsland basins) and several onshore basins have been identified for pre-competitive data acquisition and study. The offshore Petrel Sub-basin is located in Bonaparte Basin, in NW Australia, has been identified as a potential carbon storage hub for CO2 produced as a by-product from future LNG processing associated with the development of major gas accumulations on the NW Shelf. The aim of the project is to determine if the sub-basin is suitable for long-term storage, and has the potential capacity to be a major storage site. The project began in June 2011 and will be completed by July 2013. As part of the project, new 2D seismic data will be acquired in an area of poor existing seismic coverage along the boundary of the two Greenhouse Gas Assessment Areas, which were released in 2009.

There remains considerable uncertainty regarding the location, timing and availability of CO2 storage sites in both southeast Queensland and New South Wales. In New South Wales, the main issues relate to the lack of recent or reliable valid geological information that would permit a complete and comprehensive evaluation. Some sedimentary basins appear to contain potential storage reservoirs although they have low permeabilities, and are therefore likely to have low injection rates. In southeast Queensland, recent work has indicated that in some parts of the Bowen and Surat basins CO2 storage is likely to compete with other resources such as groundwater and hydrocarbons. However, current research on the potential storage in deeper saline formations in the southern and western Bowen Basin has provided encouraging results. Storage in deeper stratigraphic units in the central western part of the basin will rely on injection in low permeability formations, and more correlation work is required to define generally narrow storage targets. The Wunger Ridge, in the southern Bowen Basin, however, has promise with both significant storage potential and relatively low geological risk. One area in which there is some potential in both New South Wales and southeast Queensland is CO2 storage in coal seams, as close technical and economic relationships exist between coal bed methane (CBM) field development and operations and CO2 storage. Substantial collaborative research is still required in this area and is currently a focus of the CO2CRC activities

Geological storage of CO₂ requires fundamental knowledge and predictive capabilities on the transport and reactions of injected CO₂ and associated gases to assess the short and long term consequences. CO₂ can be stored in the subsurface through various mechanisms including structural trapping, solubility trapping and by precipitation of carbonate minerals. While mineral strapping is considered to be the safest storage mechanism as it permanently immobilizes the CO₂, the reaction rates and the likely importance for geosequestration is poorly understood. This project has five objectives, which aim to make CO₂ storage more predictable and safer. A range of approaches will be used including desk top studies, laboratory and field experiments and geochemical modelling.

Initial 2D seismic survey using mini-vibroseis with high frequency band 10 - 150Hz. This seismic survey is part of the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC) projects.

Cool-water carbonate environments may be responsible for up to one third of the carbonate sediment produced on continental shelves, and are useful modern analogues for many geologically ancient deposits. The extensive southern margin of the Australian continent is recognised as the world's largest modern example of a high energy, cool-water carbonate depositional realm. A number of studies have suggested that Quaternary sediment production here is largely influenced by oceanography, and that wave abrasion strongly limits sediment accumulation. Therefore, in this region the outer-shelf, below the storm wave base, is thought to be the focus of sediment accumulation. The inner shelf is considered a zone of active sediment production due to the proliferation of carbonate secreting organisms, although few studies have investigated sediment production or accumulation in this energetic and dynamic environment. The Recherche Archipelago, which sits at the western margin of the Great Australian Bight (GAB), was examined to better understand Quaternary shelf evolution and the importance of this type of inner shelf as a carbonate 'factory'. Surficial sediments, video, multibeam sonar data, cores and shallow seismics were collected. The present seabed of the archipelago features extensive areas where flat-lying limestones sit over the often irregular granite basement. The Pleistocene erosional surface is overlain by a coarse bivalve and rhodolith dominated gravel lag. Significantly, there are extensive Holocene deposits, up to 7 m thick, throughout the archipelago, particularly in association with granite islands. These deposits comprise cross-bedded gravelly carbonate sands dominated by fragments of calcareous algae (rhodoliths), molluscs and bryozoans. In contrast, the inshore and coast is dominated by terrigenous sediment. Seismic profiles and preserved palaeo-shoreline features suggest that slow but episodic aggradation of marine sediment has occurred on the inner shelf over successive Quaternary sea level cycles, although there are also extensive areas of non-deposition. This accumulation is partly attributable to the sheltering effect of high-relief granitic outcrops and cementation of subaerially exposed carbonate sediments.

The submarine Kenn Plateau has an area of about 140,000 km² and lies 500 km east of central Queensland beyond the Marion Plateau. It is one of several thinned continental fragments lying east of Australia that were once part of Australia, and it originally fitted south of the Marion Plateau as far south as Brisbane. It is cut into smaller blocks by east and northeast trending faults, with thinly sedimented basement highs separated by basins containing several kilometres of sediment. In the Cretaceous, it was probably underlain by rocks of the New England Fold Belt on which were stacked Late Triassic to Late Cretaceous basins. Late Cretaceous stretching and breakup was followed by Paleocene drifting, and the Kenn Plateau moved away to the northeast, rotating 45 degrees clockwise and leaving the Tasman Basin oceanic basalts behind. During these processes, siliciclastic sediments poured into the basins from the mainland and from locally eroding highs, but this sequence was terminated by a regional Late Paleocene to Early Eocene unconformity. Rift volcanics are common on the northern plateau. Radiolarian chalks were widely deposited until biosiliceous sedimentation ended with the regional Late Eocene to Early Oligocene unconformity, and warming surface waters led to younger chalk deposition. Some seismic profiles show the Middle to Late Eocene compression so well exemplified in the New Caledonian obduction to the east. Hotspots formed two volcanic chains as the plateau moved northward: the Oligocene Tasmantid chain in the west, and the Neogene Lord Howe chain in the east. As the volcanoes subsided they were fringed by reefs, some of which have persisted until the present day, whereas other reefs have not kept up with subsidence so guyots formed. The plateau has subsided 2000 m or more since breakup and is now subject solely to pelagic carbonate sedimentation.

Dolomite is a magnesium rich carbonate mineral abundant in ancient coral reef formations [1-3] yet very little is found forming in modern sedimentary environments. For over 150 years this conundrum has led to various theories being put forward about dolomite formation, however none have solved the so called `Dolomite Problem'[1]. It has generally been considered a post-depositional diagenetic process [2, 3], despite little experimental success at replicating dolomite formation in normal sea water conditions [4]. Here we show dolomite is in fact forming with living crustose coralline algae Hydrolithon onkodes, a species growing prolifically in coral reefs globally. Chemical micro-analysis of the coralline skeleton reveals that not only are the cell walls calcitised, but that the cell spaces are typically filled with magnesite, rimmed by dolomite, or both. Thus there are at least three mineral phases present (magnesium calcite, dolomite and magnesite) rather than one or two (magnesium calcite and brucite) as previously thought[5-7]. Both the magnesium calcite and dolomite phases comprise a continuum of magnesium to calcium compositions, whereas magnesite is near ideal composition. Using a mass balance approach we quantify potential dolomitisation of the coralline algae and can account for the total amount of dolomite found in a raised Pleistocene reef [2]. Our results are consistent with observed dolomites in coralline-algal rich environments in fossil reefs. This is the first time the presence of dolomite in living coralline algae has been confirmed.

In the 2011/12 Budget, the Australian Government announced funding of a four year National CO2 Infrastructure Plan (NCIP) to accelerate the identification and development of suitable long term CO2 storage sites, within reasonable distances of major energy and industrial emission sources. The NCIP funding follows on from funding announced earlier in 2011 from the Carbon Storage Taskforce through the National Carbon Mapping and Infrastructure Plan and previous funding recommended by the former National Low Emissions Coal Council. Four offshore sedimentary basins and several onshore basins have been identified for study and pre-competitive data acquisition.