High-CO2 gas fields serve as important analogues for understanding various processes related to CO2 injection and storage. The chemical signatures, both within the fluids and the solid phases, are especially useful for elucidating preferred gas migration pathways and also for assessing the relative importance of mineral dissolution and/or solution trapping efficiency. In this paper, we present a high resolution study focussed on the Gorgon gas field and associated Rankin trend gases on Australia's Northwest Shelf of Australia. The Gorgon field is characterized by a series of stacked reservoirs (Figure 1), and is therefore well placed to characterize CO2 migration, dissolution and reaction by looking at geochemical signatures in the different reservoirs. Hydrological data at the Gorgon field also suggests that many of the major faults possess very low transmissivities, which should prevent or limit mixing of reservoir fluids with different chemical imprints. The gas data we present here reveal correlatable trends for mole %-CO2 and --C CO2 both areally and vertically as observed by Edwards et al. (2007). We suggest that the observed relationships are imparted due to mineral carbonation reactions that occurred along the CO2 migration pathway. These results have important implications for carbon storage operations and suggest that under certain conditions mineral sequestration might occur over longer migration distances and on shorter timescales than previously thought.

Multibeam sonar mapping, drill cores and underwater video data have confirmed the existence of a previously unknown reef province in the Gulf of Carpentaria, Australia. Seven reefs, comprised of coral limestone that support living corals have been mapped so far and as many as 50 other reefs may exist in the region. U/Th ages show that reef growth commenced shortly after limestone pedestals were submerged by rising sea level around 10.5 kyr BP, making them the oldest reefs known in Australia. Reef growth persisted for ~2.0 kyr but it had ceased at most locations by ~8.0 kyr BP. Measurements of reef growth rates (0.95 to 4 m kyr-1), indicate that the reefs were unable to keep pace with contemporaneous rapid sea level rise (>10 m kyr-1), which is consistent with a 'give up' reef growth history. Core samples from reef platforms demonstrate that Pleistocene limestone is exposed in depths of 27 and 30 m below present mean sea level. These depths represent regionally significant phases of reef growth during a prolonged sea level still stand. We conclude that the reefs are therefore mostly relict features, whose major phase of growth and development relates to an earlier, pre-Holocene sea level stillstand.

<div>The bulk rock stable isotopes database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the stable isotopic composition of sedimentary rocks with an emphasis on calcareous rocks and minerals sampled from boreholes and field sites. The stable isotopes of carbon, oxygen, strontium, hydrogen, nitrogen, and sulfur are measured by various laboratories in service and exploration companies, Australian government institutions, and universities, using a range of instruments. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and the stable isotopes ratios. The carbon (¹³C/¹²C) and oxygen (¹⁸O/¹⁶O) isotope ratios of calcareous rocks are expressed in delta notation (i.e., &delta;¹³C and &delta;¹⁸O) in parts per mil (‰) relative to the Vienna Peedee Belemnite (VPDB) standard, with the &delta;¹⁸O values also reported relative to the Vienna Standard Mean Ocean Water (VSMOW) standard. Likewise, the stable isotope ratio of hydrogen (²H/¹H) is presented in delta notation (&delta;²H) in parts per mil (‰) relative to the VSMOW standard, the stable isotope ratio of nitrogen (¹⁵N/¹⁴N) is presented in delta notation (&delta;¹⁵N) in parts per mil (‰) relative to the atmospheric air (AIR) standard, and the stable isotope ratio of sulfur (³⁴S/³²S) is presented in delta notation (&delta;³⁴S) relative to the Vienna Canyon Diablo Troilite (VCDT) standard. For carbonates, the strontium (⁸⁷Sr/⁸⁶Sr) isotope ratios are also provided.</div><div><br></div><div>These data are used to determine the isotopic compositions of sedimentary rock with emphasis on the carbonate within rocks, either as minerals, the mineral matrix or cements. The results for the carbonate rocks are used to determine paleotemperature, paleoenvironment and paleoclimate, and establish regional- and global-scale stratigraphic correlations. These data are collated from Geoscience Australia records, destructive analysis reports (DARs), well completion reports (WCRs), and literature. The stable isotope data for sedimentary rocks are delivered in the Stable Isotopes of Carbonates web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

The mapping of seabed environments is fundamental to successful fisheries management and environmental monitoring, however, there is an emerging need to better characterise habitats based upon appropriate physical parameters. In this study, relationships between seabed geomorphology and the distribution of benthic habitats were examined using multibeam sonar, underwater video, predicted wave energy, and sediment data for Esperance Bay, part of the Recherche Archipelago. This shallow (<50 m), high energy, biogenic sediment dominated environment is located in temperate southwestern Australia. Exposure to wave energy appears to determine the distribution of unconsolidated substrate, and is the most useful regional scale predictor of rhodolith and seagrass habitats. Although they are intermittently smothered by mobile sediments, limestone reefs provide habitat for a wide range of sessile organisms, even in very high wave exposure environments. The distribution of rhodolith beds is related to poorly sorted sediments that contain high gravel, mud, and CaCO3 percentages. Our results reveal that in the Recherche Archipelago, wave abrasion coupled with localised sediment transport and accumulation play a major role in increasing the diversity of inner shelf benthic habitats. This highlights the value of assessing geomorphic processes in order to better understand the distribution and structure of benthic habitats.

We combine two- and three-dimensional seismic stratigraphic interpretation with paleobathymetric analysis from benthic foraminifera to understand the genetic significance of prominent seismic discontinuity surfaces typically mapped as "sequence boundaries" and "flooding surfaces" in the late Paleogene-early Neogene Northern Carnarvon Basin. The progradational succession, dominated by heterozoan carbonate sediments, is divided into five northwest-prograding clinoformal sequences and 19 sub-sequences. Clinoform fronts progress from smooth to highly dissected, with intense gullying apparent only after the mid Miocene optimum. Once initiated, gullies become the focus for sediment distribution across the front. Bottomsets remain relatively sediment-starved without the development of aprons on the lower slope and basin. Small-scale variability suggests heterogeneous sediment dispersal through the slope conduits. Along-strike sediment transport superimposed on progradation changes from south-directed in the late Oligocene to north-directed in the late mid-Miocene suggesting a major reorganization of circulation in the southeastern Indian Ocean. Prominent seismic discontinuity surfaces represent both intervals of shallow paleo-water depth and flooding of the shelf. Partial exposure of the shelf indicated by karst morphology is coeval with middle to outer neritic paleo-water depths on the outer shelf. Rather than build to sea-level, progradation occurs with shelf paleo-water depths at the clinoform rollover >100 m. Therefore, in the Northern Carnarvon Basin onlap onto the clinoform front is not coastal and the sensitivity of the clinoforms to sea-level changes is muted.

Concern about the impact of ocean acidification on organisms secreting high magnesium calcite skeletons has led to renewed interest in the mineralogy of these organisms. The identification of minerals making up the skeletons of tropical coralline algae, and in particular the determination of the Mg-content of calcite, is most commonly performed with X-ray diffraction. This method, based on XRD peak position, attracted criticism in the past because it produced Mg-contents that were in some cases lower compared to those based on chemical analyses of the bulk sample (in solution). The recent discovery of dolomite and magnesite in living coralline algae skeletons in addition to Mg-calcite explained this issue, and it is our goal in the present study to reinstate XRD as a reliable, quick and affordable method for the study of the mineral make-up of coralline algae species. In this paper we review the history of mineralogical analyses on tropical coralline algae and identify physical preparation methods that can affect results. We build on existing XRD methods to develop simple sampling and analytical methods to identify the presence of dolomite and magnesite, and numerically assess peak asymmetry that is caused by the overlapping reflections of calcite, dolomite and magnesite. These methods do not require specialist crystallographic knowledge or expensive or time consuming processes. The additional information our methods produce can be used to study intra-cellular calcification, and helps to rapidly assess and compare the mineral make-up of large numbers of samples. We conclude that XRD should be an integral part of any mineralogical analysis of coralline algae skeletons, which may be composed of not only Mg-calcite (Ca1.0-0.6Mg0-0.4CO3), but also dolomite (Ca0.5Mg0.5CO3), magnesite (MgCO3) and aragonite (CaCO3).

With the increasing need to extend mineral exploration undercover, new approaches are required to better constrain concealed geology, thereby reducing exploration risk and search space. Hydrogeochemistry is an under-utilised tool that can identify subsurface geology and buried mineral system components, while also providing valuable insights into environmental baselines, energy systems and groundwater resources. With this aim, 238 water bores spanning seven geological provinces in the Northern Territory and Queensland were sampled and analysed for major cations and anions, trace elements, stable and radiogenic isotopes, organic species, and dissolved gases. Here, we demonstrate the utility of this dataset for identifying carbonate-rich aquifers and mineral system components therein. First, we use trends in major element ratios (Ca+Mg)/Cl– and SiO2/HCO–3, then strontium isotope ratios (87Sr/86Sr), to define subpopulations that reflect both spatial and compositional differences. We then apply mafic-to-felsic trace element ratios (V/Cs and Cu/Rb) to reveal elevated base metal concentrations near Lake Woods caused by water–rock interaction with dolerite intrusions. Correlated Sr concentrations between groundwater and surface sediments suggest that the geochemical evolution of these mediums in carbonate-dominated terrains is coupled. Our work develops an approach to guide mineral exploration undercover via the characterisation and differentiation of groundwaters from different aquifers, resulting in improved identification of geochemical anomalies. <b>Citation:</b> Schroder, I., de Caritat, P. and Wallace, L., 2020. The Northern Australia Hydrogeochemical Survey: aquifer lithologies, local backgrounds and undercover processes. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

The Recherche Archipelago lies within the westernmost reaches of the Great Australian Bight, a large cool-water carbonate depositional province on the southern Australian margin. The inner shelf of the archipelago comprises numerous islands, typically comprising Proterozoic granites, which protrude from the shelf of mainly recent carbonate sediments. The area is influenced by extreme Southern Ocean swell energy, which results in a typically wave-abraded inner shelf, and sediment deposition mainly on the mid- to outer shelf. For Esperance Bay, a large shallow-water embayment within the archipelago, we examined the relationships between bottom sediments, geomorphology and the distribution of biotic habitats by integrating multibeam sonar, underwater video and sediment grab sample information. Major benthic habitats, such as seagrass beds, rhodolith beds, rocky reefs and mobile sand sheets are characterised in terms of their sea bed morphology, sedimentology and bioclastic composition. The littoral zone comprises mature quartz sand dominated by seagrasses, whereas the mainly carbonate-dominated shelf sediments are typically coarse gravely sands, and contain significant quantities of granitic material that is accumulating in areas of low wave exposure, typically behind the rocky islands. Bioclasts are dominated by red algal, bryozoan and foraminiferal components, as well as relict material. Sediment lags and calcarenite reefs occur in areas of high wave exposure, often with significant covers of macro-algae and sponges. The abundance of sediment producing organisms such as shallow-water rhodoliths and the presence of large-scale mobile sediment bedforms suggests that due to the influence of the rocky islands, the localised production and accumulation of carbonate sediments in the Recherche Archipelago is significantly greater than that observed in other parts of the Great Australian Bight inner shelf.

The submarine Kenn Plateau has an area of about 140,000 km² and lies 500 km east of central Queensland beyond the Marion Plateau. It is one of several thinned continental fragments lying east of Australia that were once part of Australia, and it originally fitted south of the Marion Plateau as far south as Brisbane. It is cut into smaller blocks by east and northeast trending faults, with thinly sedimented basement highs separated by basins containing several kilometres of sediment. In the Cretaceous, it was probably underlain by rocks of the New England Fold Belt on which were stacked Late Triassic to Late Cretaceous basins. Late Cretaceous stretching and breakup was followed by Paleocene drifting, and the Kenn Plateau moved away to the northeast, rotating 45 degrees clockwise and leaving the Tasman Basin oceanic basalts behind. During these processes, siliciclastic sediments poured into the basins from the mainland and from locally eroding highs, but this sequence was terminated by a regional Late Paleocene to Early Eocene unconformity. Rift volcanics are common on the northern plateau. Radiolarian chalks were widely deposited until biosiliceous sedimentation ended with the regional Late Eocene to Early Oligocene unconformity, and warming surface waters led to younger chalk deposition. Some seismic profiles show the Middle to Late Eocene compression so well exemplified in the New Caledonian obduction to the east. Hotspots formed two volcanic chains as the plateau moved northward: the Oligocene Tasmantid chain in the west, and the Neogene Lord Howe chain in the east. As the volcanoes subsided they were fringed by reefs, some of which have persisted until the present day, whereas other reefs have not kept up with subsidence so guyots formed. The plateau has subsided 2000 m or more since breakup and is now subject solely to pelagic carbonate sedimentation.

This movie describes the main findings of two Geoscience Australia surveys to the Gulf of Carpentaria in 2003 (survey 238) and 2005 (survey 276). The story relates to the discovery of submerged coral reefs across the southern Gulf and how they were identified using new multibeam sonar technology. The age of the reefs was determined using drill-core samples collected from the reefs, and measured by the Uranium/Thorium method at the Australian National University. The submerged reefs in the Gulf were not known to exist prior to this study and their discovery adds a new coral reef province to be managed and protected as part of Australia's marine zone.