We measured the light absorption properties of two naturally occurring Australian hydrocarbon oils, a Gippsland light crude oil and a North West Shelf light condensate. Using these results in conjunction with estimated sensor environmental noise thresholds, the theoretical minimum limit of detectability of each oil type (as a function of oil thickness) was calculated for both the hyperspectral HYMAP and multispectral Quickbird sensors. The Gippsland crude oil is discernable at layer thickness of 20 micro metres or more in the Quickbird green channel. The HYMAP sensor was found to be theoretically capable of detecting a layer of Gippsland crude oil with a thickness of 10 micro metres in approximately six sensor channels. By contrast, the North West Shelf light condensate was not able to be detected by either sensor for any thickness up to 200 icro metres. Optical remote sensing is therefore not applicable for detecting diagnostic absorption features associated with this light condensate oil type, which is considered representative for the prospective Australian Northwest Shelf area. We conclude that oil type is critical to the applicability of optical remote sensing for natural oil slick detection and identification. We recommend that a sensor- and oil-specific sensitivity study should be conducted prior to applying optical remote sensors for oil exploration. The oil optical properties were obtained using two different laboratory methods, a reflectance-based approach and transmittance-based approach. The reflectance-based approach was relatively complex to implement, but was chosen in order to replicate as closely as possible real world remote sensing measurement conditions of an oil film on water. The transmittance-based approach, based upon standard laboratory spectrophotometric measurements was found to generate results in good agreement with the reflectance-based approach. Therefore, for future oil- and sensor-specific sensitivity studies, we recommend the relatively accessible transmittance-based approach, which is detailed in this paper.

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Geoscience Australia has recently completed a survey searching for evidence of natural hydrocarbon seepage in the offshore northern Perth Basin, off Western Australia. The survey formed part of a regional assessment of the basin's petroleum prospectivity in support of ~17,000 sq km of frontier exploration acreage release in the region in 2011. Multibeam bathymetry, sub-bottom profiler, sidescan sonar and echosounder data were acquired to map seafloor and water column features and characterise the shallow sub-surface sediments. A remotely operated vehicle (ROV) was used to observe and record evidence of seepage on the seafloor. 71 sediment grabs and 28 gravity cores were collected and are currently being analysed for headspace gas, high molecular weight biomarkers and infaunal content. Survey data identified an area of high 'seepage' potential in the northernmost part of the study area. Recent fault reactivation and amplitude anomalies in the shallow strata correlate with raised, high-backscatter regions and pockmarks on the seafloor. A series of hydroacoustic flares identified with the sidescan sonar may represent gas bubbles rising through the water column. The ROV underwater video footage identified a dark-coloured fluid in 500 metres water depth proximal to the sidescan flares which may be oil that naturally seeped from the seafloor. The integration of the datasets acquired during the marine survey is indicative of natural oil seepage and provides additional support for the presence of an active petroleum system on this part of the continental margin.

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1. Blevin et al.:Hydrocarbon prospectivity of the Bight Basin - petroleum systems analysis in a frontier basin 2. Boreham et al : Geochemical Comparisons Between Asphaltites on the Southern Australian Margin and Cretaceous Source Rock Analogues 3. Brown et al: Anomalous Tectonic Subsidence of the Southern Australian Passive Margin: Response to Cretaceous Dynamic Topography or Differential Lithospheric Stretching? 4. Krassay and Totterdell : Seismic stratigraphy of a large, Cretaceous shelf-margin delta complex, offshore southern Australia 5. Ruble et al : Geochemistry and Charge History of a Palaeo-Oil Column: Jerboa-1, Eyre Sub-Basin, Great Australian Bight 6. Struckmeyer et al : Character, Maturity and Distribution of Potential Cretaceous Oil Source Rocks in the Ceduna Sub-Basin, Bight Basin, Great Australian Bight 7. Struckmeyer et al: The role of shale deformation and growth faulting in the Late Cretaceous evolution of the Bight Basin, offshore southern Australia 8. Totterdell et al : A new sequence framework for the Great Australian Bight: starting with a clean slate 9. Totterdell and Bradshaw : The structural framework and tectonic evolution of the Bight Basin 10. Totterdell and Krassay : The role of shale deformation and growth faulting in the Late Cretaceous evolution of the Bight Basin, offshore southern Australia

Many of the onshore sedimentary basins in Australia are underexplored with respect to hydrocarbons. With domestic oil production in steady decline, and increasing offshore exploration costs, the Onshore Energy Security Program was funded by the Australian Government over five years (2006-2011), for Geoscience Australia to provide precompetitive geoscience data and assessments of the potential for onshore energy resources. As part of the Onshore Energy Security Program, deep seismic reflection data have been acquired across several frontier sedimentary basins to stimulate petroleum exploration in onshore Australia. The basins studied in this project include the Arrowie Basin (South Australia) and the Burke River Structural Zone of the Georgina Basin (northwest Queensland). The interpretation of deep seismic reflection profiles from these onshore sedimentary basins focussed on the overall stratigraphic and structural architecture of the basins. Petroleum systems maturation modelling was also undertaken to increase the understanding of the petroleum potential of these basins.

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A recent Geoscience Australia sampling survey in the Bight Basin recovered hundreds of dredge samples of Early Cenomanian to Late Maastrichtian age. Given the location of these samples near the updip northern edge of the Ceduna Sub-basin, they are all immature for hydrocarbon generation with vitrinite reflectance - 0.5% RVmax, Tmax < 440oC and PI < 0.1. Excellent hydrocarbon generative potential is seen for marine, outer shelf, black shales and mudstones with TOC to 6.9% and HI up to 479 mg hydrocarbons/g TOC. These sediments are exclusively of Late Cenomanian-Early Turonian (C/T) in age. The high hydrocarbon potential of the C/T dredge samples is further supported by a dominance of the hydrogen-rich exinite maceral group (liptinite, lamalginite and telalginite macerals), where samples with the highest HI (> 200 mg hydrocarbons/g TOC) contain > 70% of the exinite maceral group. Pyrolysis-gas chromatography and pyrolysis-gas chromatography mass spectrometry of the C/T kerogens reveal moderate levels of sulphur compounds and the relative abundances of aliphatic and aromatic hydrocarbons predict the generation of a paraffinic-naphthenic-aromatic low wax oil in nature. Not enough oom for rest of Abstract

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