hydrocarbons
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The extreme variation in the natural endowment of petroleum resources between regions has been a key geo-political driver in the last century and may well remain so in the decades ahead. Most of the world?s oil is located in a latitudinal belt lying predominantly north of the equator, running from the Gulf of Mexico and Venezuela, to North Africa, through the Middle East, the Caspian and Central Asia and down to Indonesia. Klemme and Ulmishek (1991) calculated that this Tethyan Petroleum Province contained 68% of global original petroleum reserves. Its vast petroleum resources were derived largely from the organic rich marine rocks deposited in low latitude in restricted basins and on shallow carbonate shelves flanking the various Palaeozoic, Mesozoic and Cainozoic incarnations of the east-west orientated Tethys Ocean.
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Conference volume and CD are available through the Petroleum Exploration Society of Australia
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Few published studies have demonstrated that coals have sourced significant volumes of oil, while none have clearly implicated coals in the Australian context. This paper presents strong geochemical evidence for coals being the source for the sub-economic oil accumulations in the Bass Basin. Oils in the Bass Basin form a single oil population. Biodegradation of Cormorant oil results in a separate oil family compared to Pelican and Yolla crudes. Oil-to-source correlation based on biomarkers and carbon isotopes shows that the Early Eocene to Palaeocene coals are effective source rocks in the Bass Basin. This is in contrast to previous work which favoured disseminated organic matter in claystone as the sole source (Miyazaki, 1995). Potential oil-prone source rocks in the Bass Basin are the early Tertiary coals, mainly concentrated in the Middle to Early Eocene succession. These coals have hydrogen indices (HI) up to 500 mg HC/gTOC) and are associated with disseminated organic matter in claystones that are mainly gas prone. Maturity is sufficient for oil and gas generation with vitrinite reflectance (VR) up to 1.8 % at base of Pelican-5. Igneous intrusions, mainly within Palaeocene, Oligocene and Miocene sediments, produce localised elevated maturity to 5 % VR. The key events in the process of petroleum generation and migration from the effective coaly source rocks in the Bass Basin are: (i) the onset of oil generation at a VR of 0.65 % (2450m in Pelican-5); (ii) the onset of expulsion (primary migration) at a VR of 0.75 % (2700 to 3200m in Bass Basin; 2850m in Pelican-5); (iii) the main oil window between VR of 0.75 % and 0.95 % (2850-3300m in Pelican-5); and, (iv) the main gas window at VR >1.2 % (>3650m in Pelican-5).
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D/H ratios of terrestrially-sourced whole oils and their respective saturated, aromatic, and polar fractions, individual n-alkanes, formation waters and non-exchangeable hydrogen in kerogen were measured from source rocks from seven Australian petroleum basins. Data for 75 oils and condensates, their sub-fractions, and 52 kerogens indicate that oil sub-fractions have deltaD values comparable to deltaDoil, with a deltadeltaD offset (deltaDkerogen - deltaDoil) averaging ca. 23?. The weighted-average deltaD of individual n-alkanes is usually identical to deltaDoil and deltaDsaturate. A trend of increasing deltaD with n-alkane chain length in most oils causes individual n-alkanes from an oil to vary in deltaD by 30? or more. A modest correlation between deltaD for aromatic sub-fractions and formation waters indicates that about 50% of aromatic C-bound H has exchanged with water. In contrast, deltaDoil and deltaDsaturated show no evidence for H-exchange with formation water under reservoir conditions at temperatures up to 150 oC. Acyclic isoprenoids and n-alkanes show essentially indistinguishable deltaD, indicating that primary isotopic differences from biosynthesis have been erased. Overall, extensive exchange of C-bound H in petroleum with other hydrogen is apparent, but seems to have affected most hydrocarbons only during their chemical genesis from precursor molecules. Our isotopic findings from terrestrial-sourced oils should be qualitatively relevant for marine oils as well.
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Genetic relationships, identified using a combination of molecular and isotopic (carbon and hydrogen) compositions, have been found between natural gases, oils, oil stains, bitumens and potential source rocks in the onshore and offshore Otway Basin. The gas-gas, gas-oil and oil-source correlations herein challenge the validity of some previously accepted oil families and re-enforces the strong compartmentalisation of petroleum systems in the Otway Basin. Previous geochemical studies in the Otway Basin, mainly focussed on the oils and oil stains, have established that the Otway Basin hosts the most diverse array of petroleum systems within Australia. Up to five different oil families have previously been identified. These oils are sourced from a wide range of depositional environments from fresh to saline lacustrine, fluvio-lacustrine to peat swamp and marine, with suspected effective source rock ages from Late Jurassic to Late Cretaceous. Such depositional settings are consistent with the progressive development of source rocks facies intimately linked to basin development from initial rifting to thermal sag. It is now concluded that there is no indigenous representation of the saline lacustrine oil population in the Otway Basin. The geochemical signal is attributed to downhole contamination from gilsonite; a solid bitumen from the Eocene Green River Formation, USA. Oils stains are thought to be a result of primary migration from mature source rocks into juxtaposed sands and are not a strong advocate for secondary oil migration fairways. The natural gases show a strong geochemical association with their respective oils, suggesting that both are generated together from the same source. Also the gases and oils and their effective source rocks have a strong stratigraphic and geographic relationship, indicating mainly short- to medium-range migration distances from source to trap. Gas and oil in the western Otway Basin are sourced from the fluvio-lacustrine Casterton Formation?Crayfish Group sediments while in the eastern Otway Basin the gas and oil from the Shipwreck Trough and its onshore extension are from the coaly Eumeralla Formation sediments. Gas and oil in the central Otway Basin have a mixed source but predominantly are of Eumeralla Formation source Multiple charge histories are also evident with the widespread influx of overmature, dry gas focused in the western Otway Basin and more recently magmatic CO2 influx. Successive natural gas charges have the potential to displace and/or alter the composition of the pre-existing reservoired gas and oil. In-reservoir biodegradation of oil is seen in the shallower reservoirs but this is not a significant risk in the Otway Basin since nearly all reservoired petroleum is below the temperature/depth limits for biologically sustainable life.
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No product available. Removed from website 25/01/2019
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The molecular composition of fluid inclusion (FI) oils from Leander Reef-1, Houtman 1 and Gage Roads-2 provide evidence of the origin of palaeo-oil accumulations in the offshore Perth Basin. These data are complemented by compound specific isotope (CSI) profiles of n-alkanes for the Leander Reef-1 and Houtman-1 samples, which were acquired on purified n-alkane fractions gained by micro-fractionation of lean FI oil samples, showing the technical feasibility of this technique. The Leander Reef-1 FI oil from the top Carynginia Formation shares many biomarker similarities with oils from the Dongara and Yardarino oilfields, which have been correlated with the Early Triassic Kockatea Shale. However, the heavier isotopic values for the C15-C25 n-alkanes in the Leander Reef-1 FI oil indicate that it is a mixture, and suggest that the main part of this oil (~90%) was sourced from the more terrestrial and isotopically heavier Early Permian Carynginia Formation or Irwin River Coal Measures. This insight would have been precluded when looking at molecular evidence alone. The Houtman-1 FI oil from the top Cattamarra Coal Measures (Middle Jurassic) was sourced from a clay-rich, low sulphur source rock with a significant input of terrestrial organic matter, deposited under oxic to suboxic conditions. Biomarkers suggest sourcing from a more prokaryotic-dominated facies than for the other FI oils, possibly a saline lagoon. The Houtman-1 FI oil ?13C CSI data are similar to data acquired on the Walyering-2 oil. Possible lacustrine sources include the Early Jurassic Eneabba Formation or the Late Jurassic Yarragadee Formation. The low maturity Gage Roads-2 FI oil from the Carnac Formation (Early Cretaceous) was derived from a strongly terrestrial, non-marine source rock containing a high proportion of Araucariacean-type conifer organic matter. It has some geochemical differences to the presently reservoired oil in Gage Roads-1, and was probably sourced from the Early Cretaceous Parmelia Formation.
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Petroleum accumulations have been discovered in the Bonaparte, Browse and Carnarvon basins over the last fifty years. However, a regional synthesis of the geochemistry of these North West Shelf hydrocarbons has not been published. To address this, this study documents the biomarker and isotopic analyses of ~300 North West Shelf oils/condensate samples that have been statistically characterised into genetically related families. Carbon and hydrogen isotopic signatures of ~50 gas samples, together with existing molecular data for ~1000 gas samples, show regional trends in wetness and abundance of non-combustible gases. These petroleum accumulations can be attributed to source rocks of Early Carboniferous, Permian, Triassic, Jurassic and Early Cretaceous age; however, most economic oil and gas accumulations are sourced from Mesozoic (Triassic Jurassic) sediments. The oils produced from the Bonaparte (Vulcan Sub-basin, northern Bonaparte) and Carnarvon (Dampier, Barrow and Exmouth sub-basins) basins are geochemically similar, being sourced from Late Jurassic marine rift-fill sediments (lower Vulcan Formation/Dingo Claystone) that contain variable amounts of terrigenous (particularly gymnosperm-derived) organic matter. Variations in their biomarker signatures can be explained by maturity differences, multiple charging and secondary alteration processes. Gas produced from the northern Rankin Platform is predominantly sourced from Triassic Jurassic fluvio-deltaic sediments. Proven and potential supergiant and giant gas accumulations occur in the deepwater areas of the North West Shelf. Case studies focussing on the geochemistry of the outer Browse (Scott Reef trend) and Carnarvon (deepwater Exmouth Plateau and Rankin Platform) gas accumulations will be presented with emphasis on d13C and d2H isotopic data.
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An inverted phase (polar to non-polar) column set has been compared with a non-polar to polar column set for the GC-GC separation of petroleum hydrocarbons crude oil. This is shown to provide greatly enhanced resolution for less polar compounds and makes greater use of the two-dimensional separation space. This column configuration improves resolution of a greater number of components within one analysis and offers new possibilities for crude oil fingerprinting.
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Exploration for Unconventional Hydrocarbons in Australia reached a new milestone when Beach Energy announced the first successful flow test of a shale gas target in the Cooper Basin. The ever expanding coal seam gas industry on Australia's east coast in addition to the large resource potential of shale and tight gas in Australia's eastern basins has put Australia firmly on the radar of many local and international exploration companies. Over the next 12 months Geoscience Australia in collaboration with its counterparts in the State and Territory resource and energy departments will begin an assessment of Australia's coal seam gas, shale gas and oil and tight gas resource potential. Capitalising on decades of high quality geological data held by the Commonwealth and the States and Territories, the aim of this collaboration is to develop nationally consistent assessment methodologies and provide robust national resource estimates in an internationally accepted standard. Overall, the programme aims to answer the 'where' and 'how much' questions for government, as well as provide this new industry with pre-competitive data and tools for comparing exploration opportunities. The immediate goal is to provide a first-pass, high level estimate of the likely resource volumes, which will be reported in the second edition of the Australian Energy Resource Assessment (published by RET). The longer term work program aims to assess Australia's onshore basins in terms of their resource potential and provide pre-competitive data to industry. To achieve this, several geological techniques will be applied including, but not limited to, geochemical screening, mapping of source rock occurrences and their distributions as well as physical rock property studies.