In July 2010 Geoscience Australia and CSIRO Marine & Atmospheric Research jointly commissioned a new atmospheric composition monitoring station (' Arcturus') in central Queensland. The facility is designed as a proto-type remotely operated `baseline monitoring station' such as could be deployed in areas that are likely targets for commercial scale carbon capture and geological storage (CCS). It is envisaged that such a station could act as a high quality reference point for later in-fill, site based, atmospheric monitoring associated with geological storage of CO2. The station uses two wavelength scanned cavity ringdown instruments to measure concentrations of carbon dioxide (CO2), methane (CH4), water vapour and the isotopic signature (?13C) of CO2. Meteorological parameters such as wind speed and wind direction are also measured. In combination with CSIRO's TAPM (The Air Pollution Model), data will be used to understand the local variations in CO2 and CH4 and the contributions of natural and anthropogenic sources in the area to this variability. The site is located in a region that supports cropping, grazing, cattle feedlotting, coal mining and gas production activities, which may be associated with fluxes of CO2 and CH4. We present in this paper some of the challenges found during the installation and operation of the station in a remote, sub-tropical environment and how these were resolved. We will also present the first results from the site coupled with preliminary modelling of the relative contribution of large point source anthropogenic emissions and their contribution to the background.

CO2CRC Project 1 - Site Specific Studies for Geological Storage of carbon Dioxide Part 1: Southeast Queensland CO2 Storage Sites - Basin Desk-top, Geological Interpretation and Reservoir Simulation of Regional Model

Abstract for submission to 11th IEA GHG International Conference on Greenhouse Gas Control Technologies. Conference paper to follow pending selection for oral or poster presentation. Abstract covers the GA-ACCA21 China Australia Geological Storage of CO2 (CAGS) Project run through PMD/ED 2009-2012.

Geological storage of CO₂ requires fundamental knowledge and predictive capabilities on the transport and reactions of injected CO₂ and associated gases to assess the short and long term consequences. CO₂ can be stored in the subsurface through various mechanisms including structural trapping, solubility trapping and by precipitation of carbonate minerals. While mineral strapping is considered to be the safest storage mechanism as it permanently immobilizes the CO₂, the reaction rates and the likely importance for geosequestration is poorly understood. This project has five objectives, which aim to make CO₂ storage more predictable and safer. A range of approaches will be used including desk top studies, laboratory and field experiments and geochemical modelling.

A geomechanical assessment of the Naylor Field, Otway Basin, Australia has been undertaken to investigate the possible geomechanical effects of CO2 injection and storage. The study aims to evaluate the geomechanical behaviour of the caprock/reservoir system and to estimate the risk of fault reactivation. The stress regime in the onshore Victorian Otway Basin is inferred to be strike-slip if the maximum horizontal stress is calculated using frictional limits and DITF (drilling induced tensile fracture) occurrence, or normal if maximum horizontal stress is based on analysis of dipole sonic log data. The NW-SE maximum horizontal stress orientation (142 degrees N) determined from a resistivity image log is broadly consistent with previous estimates and confirms a NW-SE maximum horizontal stress orientation for the Otway Basin. An analytical geomechanical solution is used to describe stress changes in the subsurface of the Naylor Field. The computed reservoir stress path for the Naylor Field is then incorporated into fault reactivation analysis to estimate the minimum pore pressure increase required to cause fault reactivation (Pp) The highest reactivation propensity (for critically-oriented faults) ranges from an estimated pore pressure increase (Pp) of 1MPa to 15.7MPa (estimated pore pressure of 18.5-233. MPa) depending on assumptions made about maximum horizontal stress magnitude, fault strength,reservoir stress path and Biot's coefficient. The critical pore pressure changes for known faults at Naylor Field range from an estimated pore pressure increase (Pp) of 2MPa to 17MPa (estimated pore pressure of 19.5-34.5 MPa).

This study looks at the question of whether time-lapse gravity measurements could be used to monitor the density and geometry carbon dioxide plume in the ground for a typical Gippsland Basin reservoir. The considerations made indicate that gravity measurements would not be suitable as a means to detect carbon dioxide density, distribution and movement in a reservoir the size of the West Seahorse field. The maximum gravity anomaly that would be expected is calculated to be 1.4 -Gal, while the experience in other parts of the world, using sensitive sea floor gravity metres, indicate that at present this technology can resolve about 5 -Gal. Furthermore, the horizontal and vertical gradients of the maximum anomaly are of the order of 0.007 E ( 0.007 ?m/s2/km), while the most sensitive reported airship measurements of gravity gradient are reported to be resolving of the order of 1.7 E.

In mid 2011, the Australian Government announced funding of a new four year National CO2 Infrastructure Plan (NCIP) to accelerate the identification and development of sites suitable for the long term storage of CO2 in Australia that are within reasonable distances of major energy and industrial CO2 emission sources. The NCIP program promotes pre-competitive storage exploration and provides a basis for the development of transport and storage infrastructure. The Plan follows on from recommendations of the Carbon Storage Taskforce and the National CCS Council (formerly, the National Low Emissions Coal Council). It builds on the work funded under the National Low Emissions Coal Initiative and the need for adequate storage to be identified as a national priority. Geoscience Australia is providing strategic advice in delivering the plan and will lead in the acquisition of pre-competitive data and geological studies to assess storage potential. Four offshore sedimentary basins (Bonaparte, Browse, Perth and Gippsland basins) and several onshore basins have been identified for pre-competitive data acquisition and study.

Two shallow sub-surface CO2 controlled release experiments were conducted at the Ginninderra test site during 2012. The theme of the first experiment was CO2 detection in the soil and surface emissions quantification. The theme for the second experiment was investigating sub-surface migration and broad scale detection technologies. Our objective overall is to design cheaper monitoring technologies to evaluate leakage and environmental impact in the shallow sub-surface. Over 10 different monitoring techniques were evaluated at the site against a known CO2 release. These included soil gas, soil CO2 flux, soil analysis, eddy covariance, atmospheric tomography, noble gas tracers, ground penetrating radar, electromagnetic surveys, airborne hyperspectral, in-field phenotyping (thermal, hyperspectral and 3D imaging), and microbial soil genomics. Technique highlights and an assessment of the implications for large scale storage are presented in the following corresponding talks. Presented at the 2013 CO2CRC Research Symposium

Regional geological properties of sedimentary basins play a significant role in determining the safety of CO2 storage. Four major trapping mechanism have been identified: Structural and stratigraphic trapping is the containment of supercritical CO2 by low permeability / low porosity rocks and is the dominant mechanism during injection and initial storage phase. Residual or capillary trapping is the retention of supercritical CO2 in the pore space between grains and tends to be most relevant on a scale of tens to thousands of years. Solubility trapping is the uptake of CO2 into the formation water, which is considered to be the most important trapping mechanism over hundreds to millions of years (1). Mineral trapping leads to the permanent immobilization of carbon through the precipitation of carbonate minerals. This study assesses the conditions for solubility trapping in major Australian sedimentary basins. The total dissolved solid (TDS) concentration of the formation water has been compiled from over 900 wells as it, along with pressure and temperature, is a key variable controlling CO2 solubility and the associated change in fluid density. Fluid density is a critical factor in driving fluid advection which determines the rate of solubility trapping and downward migration in the formation. This process is vital in reducing the amount of highly mobile supercritical CO2 at the top of the formation and storing it as dissolved CO2 in deeper parts of the formation.

Covering an area of approximately 247 000km2, the Galilee Basin is a significant feature of central Queensland. Three main depocentres contain several hundred metres of Late Carboniferous to Middle Triassic sediments. Sedimentation in the Galilee Basin was dominated by fluvial to lacustrine depositional systems. This resulted in a sequence of sandstones, mudstones, siltstones, coals and minor tuff in what was a relatively shallow intracratonic basin with little topographic relief. Forty years or more of exploration in the Galilee Basin has failed to discover any economic accumulations of hydrocarbons, despite the presence of apparently fair to very good reservoirs and seals in both the Permian and Triassic sequence. Despite some relatively large distances (upwards of 500km) between sources and sinks, previous and ongoing work on the Galilee Basin suggests that it has potential to sequester a significant amount of Queensland's carbon dioxide emissions. Potential reservoirs include the Early Permian Aramac Coal Measures, the Late Permian Colinlea Sandstone and the Middle Triassic Clematis Sandstone. These are sealed by several intraformational and local seals as well as the regional Triassic Moolayember Formation. With few suitable structural traps and little faulting throughout the Galilee sequence, residual trapping within saline reservoir is the most likely mechanism for storing CO2. The current study is aimed at building a sound geological model of the basin through activities such as detailed mapping, well correlation, and reservoir and seal analysis leading to reservoir simulations to gain a better understanding of the basin.