We collected 38 groundwater and two surface water samples in the semi-arid Lake Woods region of the Northern Territory to better understand the hydrogeochemistry of this system, which straddles the Wiso, Tennant Creek and Georgina geological regions. Lake Woods is presently a losing waterbody feeding the underlying groundwater system. The main aquifers comprise mainly carbonate (limestone and dolostone), siliciclastic (sandstone and siltstone) and evaporitic units. The water composition was determined in terms of bulk properties (pH, electrical conductivity, temperature, dissolved oxygen, redox potential), 40 major, minor and trace elements as well as six isotopes (δ18Owater, δ2Hwater, δ13CDIC, δ34SSO4=, δ18OSO4=, 87Sr/86Sr). The groundwater is recharged through infiltration in the catchment from monsoonal rainfall (annual average rainfall ~600 mm) and runoff. It evolves geochemically mainly through evapotranspiration and water–mineral interaction (dissolution of carbonates, silicates, and to a lesser extent sulfates). The two surface waters (one from the main creek feeding the lake, the other from the lake itself) are extraordinarily enriched in 18O and 2H isotopes (δ18O of +10.9 and +16.4 ‰ VSMOW, and δ2H of +41 and +93 ‰ VSMOW, respectively), which is interpreted to reflect evaporation during the dry season (annual average evaporation ~3000 mm) under low humidity conditions (annual average relative humidity ~40 %). This interpretation is supported by modelling results. The potassium (K) relative enrichment (K/Cl mass ratio over 50 times that of sea water) is similar to that observed in salt-lake systems worldwide that are prospective for potash resources. Potassium enrichment is believed to derive partly from dust during atmospheric transport/deposition, but mostly from weathering of K-silicates in the aquifer materials (and possibly underlying formations). Further studies of Australian salt-lake systems are required to reach evidence-based conclusions on their mineral potential for potash, lithium, boron and other low-temperature mineral system commodities such as uranium. <b>Citation:</b> P. de Caritat, E. N. Bastrakov, S. Jaireth, P. M. English, J. D. A. Clarke, T. P. Mernagh, A. S. Wygralak, H. E. Dulfer & J. Trafford (2019) Groundwater geochemistry, hydrogeology and potash mineral potential of the Lake Woods region, Northern Territory, Australia, <i>Australian Journal of Earth Sciences</i>, 66:3, 411-430, DOI: 10.1080/08120099.2018.1543208

The Walloway Artesian Basin is approximately 160 miles north of Adelaide and is traversed by the main road from Adelaide to Maree via Orroroo and Hawker. The town of Orroroo lies on its western margin in the south-western corner of the Hundred of Walloway and the village of Johnburgh is situated in its northern part. The geophysical survey was carried out at the request of the Director of Mines for South Australia to assist his Department in the selection of sites for boring for artesian water and to delineate more precisely the limitations of the basin with regard to artesian flows. The gravity method was used as this method has proved successful elsewhere in determining the dimensions and form of sedimentary basins. This report gives an account of the survey and its results.

The Great Artesian Basin Research Priorities Workshop, organised by Geoscience Australia (GA), was held in Canberra on 27 and 28 April 2016. Workshop attendees represented a spectrum of stakeholders including government, policy, management, scientific and technical representatives interested in GAB-related water management. This workshop was aimed at identifying and documenting key science issues and strategies to fill hydrogeological knowledge gaps that will assist federal and state/territory governments in addressing groundwater management issues within the GAB, such as influencing the development of the next Strategic Management Plan for the GAB. This report summarises the findings out of the workshop.

Abundant, micron-scale, spherical aggregates of 2?5 nm diameter sphalerite (ZnS) particles formed within natural biofilms dominated by relatively aerotolerant sulfate-reducing bacteria of the family Desulfobacteriaceae. The biofilm zinc concentration is about 106 times that of associated groundwater (0.09 ? 1.1 ppm Zn). Sphalerite also concentrates arsenic (0.01 wt %) and selenium (0.004 wt %). The almost monomineralic product results from buffering of sulfide concentrations at low values by sphalerite precipitation. These results show how microbes control metal concentrations in groundwater and wetland-based remediation systems and suggest biological routes for formation of some low temperature ZnS deposits.

Freshwater coastal aquifers provide an important resource for irrigated agriculture, human consumption and the natural environment. Approximately 18 million people live within 50 km of the coast in Australia, and many coastal communities are reliant on groundwater. These coastal aquifers are vulnerable to seawater intrusion (SWI) - the landward encroachment of seawater - due to their close proximity to the ocean. To assess the threat of SWI in Australia, a comprehensive literature review was undertaken with input from state/territory agencies. The literature review, in combination with contributions from stakeholders, identified sites within each of the states and the Northern Territory where SWI had been reported or where it was considered to be a serious threat. International Association of Hydrogeologists 2013 Congress poster

The Clarence-Moreton and the Surat basins in Queensland and northern New South Wales contain the coal-bearing sedimentary sequences of the Jurassic Walloon Coal Measures, composed of up to approximately 600 m of mudstone, siltstone, sandstone and coal. In recent years, the intensification of exploration for coal seam gas (CSG) resources within both basins has led to concerns that the depressurisation associated with future resource development may cause adverse impacts on water resources in adjacent aquifers. In order to identify the most suitable tracers to study groundwater recharge and flow patterns within the Walloon Coal Measures and their degree of connectivity with over- or underlying formations, samples were collected from the Walloon Coal Measures and adjacent aquifers in the northern Clarence-Moreton Basin and eastern Surat Basin, and analysed for a wide range of hydrochemical and isotopic parameters. Parameters that were analysed include major ion chemistry, -13C-DIC, -18O, 87Sr/86Sr, Rare Earth Elements (REE), 14C, -2H and -13C of CH4 as well as concentrations of dissolved gases (including methane). Dissolved methane concentrations range from below the reporting limit (10 µg/L) to approximately 50 mg/L in groundwaters of the Walloon Coal Measures. However, the high degree of spatial variability of methane concentrations highlights the general complexity of recharge and groundwater flow processes, especially in the Laidley Sub-Basin of the Clarence-Moreton Basin, where numerous volcanic cones penetrate the Walloon Coal Measures and may form pathways for preferential recharge to the Walloon Coal Measures. Interestingly, dissolved methane was also measured in other sedimentary bedrock units and in alluvial aquifers in areas where no previous CSG exploration or development has occurred, highlighting the natural presence of methane in different aquifers. Radiocarbon ages of Walloon Coal Measure groundwaters are also highly variable, ranging from approximately 2000 yrs BP to >40000 yrs BP. While groundwaters sampled in close proximity to the east and west of the Great Dividing Range are mostly young, suggesting that recharge to the Walloon Coal Measures through the basalts of the Great Dividing Range occurs here, there are otherwise no clearly discernable spatial patterns and no strong correlations with depth or distance along inferred flow paths in the Clarence-Moreton Basin. In contrast to this strong spatial variability of methane concentrations and groundwater ages, REE and 87Sr/86Sr isotope ratios of Walloon Coal Measures groundwaters appear to be very uniform and clearly distinct from groundwaters contained in other bedrock units. This difference is attributed to the different source material of the Walloon Coal Measures (mostly basalts in comparison to other bedrock units which are mostly composed of mineralogical more variable Paleozoic basement rocks of the New England Orogen). This study suggests that REE and 87Sr/86Sr ratios may be a suitable tracer to study hydraulic connectivity of the Walloon Coal Measures with over- or underlying aquifers. In addition, this study also highlights the need to conduct detailed water chemistry and isotope baseline studies prior to the development of coal seam gas resources in order to differentiate between natural background values of methane and potential impacts of coal seam gas development.

Geoscience Australia was recently involved in the reconceptualisation of the hydrogeology of the Great Artesian Basin (GAB), as part of the Great Artesian Basin Water Resource Assessment. The project refined the understanding of key hydrostratigraphic units within the GAB. This brochure describes key aquifers in the GAB and is designed to be distributed with samples from the aquifers. Aquifers covered are the Winton-Mackunda, Cadna-owie-Hooray, Adori Sandstone/Springbok Sandstone, Hutton Sandstone and Precipice Sandstone. Brochure prepared for the International Association of Hydrogeologists Congress 2013, Perth, Australia

Poster prepared for International Association of Hydrogeologists Congress 2013 Surface-groundwater interactions are often poorly understood. This is particularly true of many floodplain landscapes in Australia, where there is limited mapping of recharge and discharge zones along the major river systems, and only generalised quantification of hydrological fluxes based on widely spaced surface gauging stations. This is compounded by a lack of temporal data, with poor understanding of how surface-groundwater interactions change under different rainfall, river flow and flood regimes. In this study, high resolution LiDAR, in-river sonar, and airborne electromagnetic (AEM) datasets (validated by drilling) have been integrated to produce detailed 3-dimensional mapping that combines surface geomorphology and hydrogeology. This mapping enables potential recharge zones in the river and adjacent landscape to be identified and assessed under different flow regimes. These potential recharge zones and groundwater flow pathways were then compared against the spatial distribution of discontinuities in near-surface and deeper aquitard layers derived from the AEM interpretation. These 3D mapping constructs provide a framework for considering groundwater processes. Hydrochemistry data, allied with hydraulic data from a bore monitoring network, demonstrate the importance of recharge during significant flood events. In many places, the AEM data also affirm the spatial association between fresher groundwater resources and sites of river and floodplain leakage. At a more localised scale, hydrogeochemical data allows discrimination of lateral and vertical fluxes. Overall, this integrated approach provides an important conceptual framework to constrain hydrogeological modelling, and assessments of sustainable yield. The constructs are also invaluable in targeting and assessing managed aquifer recharge (MAR) options.

Poster prepared for International Association of Hydrogeologists Congress 2013 In this study, AEM mapping validated by drilling has enabled the lateral extents and thickness of the Pliocene aquifers to be identified. The Pliocene in this area dominantly comprises the fluvial Calivil Formation, with the shallow marine Loxton-Parilla Sands restricted to the southernmost part of the area. Post-depositional warping, tilting and discrete offsets associated with neotoectonics are also recognised. Facies analysis indicates the Calivil was deposited in deep braided streams across a dissected sedimentary landscape. Overall, the sequence is fining-upwards, with evidence for progradation over the Loxton-Parilla. Channel fill materials comprise gravels and sands, and local fine-grained units represent abandoned channels and local floodplain sediments. Integration of textural and hydraulic testing data has revealed there are five hydraulic classes within the Calivil,. At a local scale (10s to 100s of metres), there is considerable lithological heterogeneity, however at a regional scale (kms), sands and gravels are widely distributed with particularly good aquifers developed in palaeochannels and at the confluence of palaeo-river systems. Aquifer testing has revealed Calivil to be an excellent aquifer, with high storage capacity, and locally very high transmissivities (up to 50 l/s). Integration of the AEM data with borehole geophysical data (gamma, induction and NMR) and textural and pore fluid data has enabled maps of aquifer properties including groundwater salinity, porosity, storage and hydraulic conductivity to be derived. Overall, the multi-disciplinary approach adopted has enabled rapid delineation of new groundwater resources, and facilitated assessment of the Pliocene aquifers for managed aquifer recharge.

This technical report details the results of groundwater hydrochemical characterisation in coal seams and adjacent aquifers in Queensland's Surat Region and Laura Basin. The report also provides information on environmental values of groundwater in relation to ecological and human use in the study areas and also offers general guidance on groundwater quality monitoring strategies.