The unexpected discovery of oil in Triassic sedimentary rocks of the Phoenix South 1 well on Australia’s North West Shelf (NWS) has catalysed exploration interest in pre-Jurassic plays in the region. Subsequent neighbouring wells Roc 1–2, Phoenix South 2–3 and Dorado 1–3 drilled between 2015 and 2019 penetrated gas and/or oil columns, with the Dorado field containing one of the largest oil resources found in Australia in three decades. This study aims to understand the source of the oils and gases of the greater Phoenix area, Bedout Sub-basin using a multiparameter geochemical approach. Isotopic analyses combined with biomarker data confirm that these fluids represent a new Triassic petroleum system on the NWS unrelated to the Lower Triassic Hovea Member petroleum system of the Perth Basin. The Bedout Sub-basin fluids were generated from source rocks deposited in paralic environments with mixed type II/III kerogen, with lagoonal organofacies exhibiting excellent liquids potential. The Roc 1–2 gases and the Phoenix South 1 oil are likely sourced proximally by Lower–Middle Triassic TR10–TR15 sequences. Loss of gas within the Phoenix South 1 fluid due to potential trap breach has resulted in the formation of in-place oil. These discoveries are testament to new hydrocarbon plays within the Lower–Middle Triassic succession on the NWS.

The National Geochemical Survey of Australia (NGSA) is Australia’s first national-scale geochemical survey. It was delivered to the public on 30 June 2011, after almost five years of stakeholder engagement, strategic planning, sample collection, preparation and analysis, quality assurance/quality control, and preliminary data analytics. The project was comprehensively documented in seven initial open-file reports and six data and map sets, followed over the next decade by more than 70 well-cited scientific publications. This review compiles the body of work and knowledge that emanated from the project to-date as an indication of the impact the NGSA had over the decade 2011-2021. The geochemical fabric of Australia as never seen before has been revealed by the NGSA. This has spurred further research and stimulated the mineral exploration industry. This paper also critically looks at operational decisions taken at project time (2007-2011) that were good and perhaps – with the benefit of hindsight – not so good, with the intention of providing experiential advice for any future large-scale geochemical survey of Australia or elsewhere. Strengths of the NGSA included stakeholder engagement, holistic approach to a national survey, involvement of other geoscience agencies, collaboration on quality assurance with international partners, and targeted promotion of results. Weaknesses included gaining successful access to all parts of the nation, and management of sample processing in laboratories. <b>Citation:</b> Patrice de Caritat; The National Geochemical Survey of Australia: review and impact. <i>Geochemistry: Exploration, Environment, Analysis </i>2022;; 22 (4): geochem2022–032. doi: https://doi.org/10.1144/geochem2022-032 This article appears in multiple journals (Lyell Collection & GeoScienceWorld)

Understanding the character of Australia's extensive regolith cover is crucial to the continuing success of mineral exploration. We hypothesize that the regolith contains geochemical fingerprints of processes related to the development and preservation of mineral systems at a range of scales. We test this hypothesis by analysing the composition of surface sediments within greenfield regional (southern Thomson Orogen) and continental (Australia) study areas. In the southern Thomson Orogen area, the first principal component (PC1) derived in our study (Ca, Sr, Cu, Mg, Au, and Mo at one end; rare earth elements (REEs) and Th at the other) is very similar to the empirical vector successfully used by a local company exploring for Cu-Au mineralisation (enrichment in Sr, Ca and Au concomitant with depletion in REEs). Mapping the spatial distribution of PC1 in the region reveals several areas of elevated values and possible mineralisation potential. One of the strongest targets in the PC1 map is located between Brewarrina and Bourke in northern New South Wales. Here both historical and recent exploration drilling has intersected mineralisation with up to 1 % Cu, 0.1 g/t Au, and 717 ppm Zn, purportedly related to a volcanic arc setting. The analysis of a comparable geochemical dataset at the continental scale yields a similar PC1 (Ca, Sr, Mg, Cu, Au, and Mo at one end; REEs and Th at the other) to the regional study. Mapping PC1 at the continental scale shows patterns that (1) are compatible with the regional study, and (2) reveal several geological regions possibly with an enhanced potential for this style of Cu-Au mineralisation. These include well-endowed mineral provinces such as the Curnamona, southern Pilbara, and Capricorn regions, but also some greenfield regions such as the Albany-Fraser/western Eucla, western Murray, and Eromanga geological regions. We conclude that the geochemical composition of Australia's regolith may hold critical information pertaining to mineralisation within/beneath it.

We describe a vision for a national-scale heavy mineral (HM) map generated through automated mineralogical identification and quantification of HMs contained in floodplain sediments from large catchments covering most of Australia. The composition of the sediments reflects the dominant rock types in each catchment, with the generally resistant HMs largely preserving the mineralogical fingerprint of their host protoliths through the weathering-transport-deposition cycle. Heavy mineral presence/absence, absolute and relative abundance, and co-occurrence are metrics useful to map, discover and interpret catchment lithotype(s), geodynamic setting, magmatism, metamorphic grade, alteration and/or mineralization. Underpinning this vision is a pilot project, focusing on a subset from the national sediment sample archive, which is used to demonstrate the feasibility of the larger, national-scale project. We preview a bespoke, cloud-based mineral network analysis (MNA) tool to visualize, explore and discover relationships between HMs as well as between them and geological settings or mineral deposits. We envisage that the Heavy Mineral Map of Australia and MNA tool will contribute significantly to mineral prospectivity analysis and modeling, particularly for technology critical elements and their host minerals, which are central to the global economy transitioning to a more sustainable, lower carbon energy model. The full, peer-reviewed article can be found here: Caritat, P. de, McInnes, B.I.A., Walker, A.T., Bastrakov, E., Rowins, S.M., Prent, A.M. 2022. The Heavy Mineral Map of Australia: vision and pilot project. Minerals, 12(8), 961, https://doi.org/10.3390/min12080961

<div>NDI Carrara 1 is a deep stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1120 m of Proterozoic sedimentary rocks unconformably overlain by 630 m of Georgina Basin carbonates.&nbsp;</div><div>Geoscience Australia has undertaken a range of investigations on the lithology, stratigraphy and geotechnical properties of NDI Carrara 1 as well as undertaking a range of analyses of about 500 physical samples recovered through the entire core. Analyses included geochronology, isotope studies, mineralogy, inorganic and organic geochemistry, petrophysics, geomechanics, thermal maturity and petroleum systems investigations.</div><div>Rock-Eval pyrolysis raw data undertaken by Geoscience Australia were reported in Butcher et al. (2021) on selected rock samples to establish their total organic carbon content, hydrocarbon-generating potential and thermal maturity. Interpretation of the Rock-Eval pyrolysis data concluded that a large portion of rocks within the Proterozoic section displayed unreliable Tmax values due to poorly defined S2 peaks resulting from high thermal maturity and low hydrogen content. In order to obtain more reliable Tmax values, Rock-Eval pyrolysis of selected isolated kerogens, where organic matter is concentrated and mineral matrix effects are removed, were conducted and the resulting data are presented in this report.&nbsp;</div><div><br></div>

<div>Exploring for the Future (EFTF) is an Australian Government program led by Geoscience Australia, in partnership with state and Northern Territory governments, and aimed at stimulating exploration now to ensure a sustainable, long-term future for Australia through an improved understanding of the nation’s minerals, energy and groundwater resource potential. </div><div>The EFTF program is currently focused on eight interrelated projects, united in growing our understanding of subsurface geology. One of these projects, the Barkly–Isa–Georgetown project, will deliver new data and knowledge to assess the mineral and energy potential in undercover regions between Tennant Creek, Mount Isa and Georgetown. Building on the work completed in the first four years of the Exploring for the Future program (2016-2020), the project undertook stratigraphic drilling in the East Tennant and South Nicholson regions, in collaboration with MinEx CRC and the Northern Territory Geological Survey (NTGS). This work tests geological interpretations and the inferred mineral and energy potential of these covered regions. Geoscience Australia is undertaking a range of analyses on physical samples from these drill holes including geochemistry and geochronology. </div><div>The South Nicholson National Drilling Initiative (NDI) Carrara 1 drill hole is the first drillhole to intersect the Proterozoic rocks of the Carrara Sub-Basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys acquired as part of the EFTF. It is located on the western flanks of the Carrara Sub-basin on the South Nicholson Seismic line 17GA-SN1, reaching a total depth of 1751 m, intersecting ca. 630 m of Cambrian Georgina Basin overlying ca. 1100 m of Proterozoic carbonates, black shales and minor siliciclastics.</div><div>The NDI BK10 drill hole is the tenth drill hole drilled as part of the East Tennant project aimed to constrain the East Tennant basement geology and calibrate predictive mineral potential maps to further our understanding of the prospectivity of this region. NDI BK10 reached a depth of 766 m and intersected basement at 734 m. Overlying these basement metasediments of the Alroy Formation, the drillhole intersected about 440 m of Proterozoic rocks underlain by ca. 300 m rocks of Cambrian age from the Georgina Basin.</div><div>During coring of NDI Carrara 1 and NDI BK10, cores containing oil stains were identified and sent for geochemical analysis to Geoscience Australia. This report presents the geochemical data from these oil stains including biomarker and isotopic data.</div>

A comprehensive compilation of rock, regolith and groundwater geochemistry across the Curnamona Province and overlying basins. This product is part of the Curnamona Geochemistry module of GA's Exploring for the Future program, which is seeking to understand geochemical baselines within the Curnamona Province to support mineral exploration under cover. Data is sourced from GA, CSIRO and state databases, and run through a quality control process to address common database issues (such as unit errors). The data has been separated by sample type and migrated into a standard data structure to make the data internally consistent. A central source for cleaned geochemical data in the same data format is a valuable resource for further research and exploration in the region.

Geoscience Australia currently uses two commercial petroleum system modelling software packages, PetroMod https://www.software.slb.com/products/petromod and Zetaware http://www.zetaware.com, to undertake burial and thermal history modelling on wells in Australian sedimentary basins. From the integration of geological (age-based sedimentary packages, uplift and erosional events), petrophysical (porosity, permeability, and thermal conductivity) and thermal (downhole temperature, heat flow, vitrinite reflectance, and Tmax) input data, to name the most significant, a best-fit model of the time-temperature history is generated. Since the transformation of sedimentary organic matter (kerogen) into petroleum (oil and gas) is a chemical reaction, it is governed by chemical kinetics i.e. time and temperature (in the geological setting, pressure is of secondary importance). Thus, the use of chemical kinetics associated with a formation-specific, immature potential source rock (where available) from the basin of interest is considered a better practical approach rather than relying on software kinetic defaults, which are generally based on the chemical kinetics determined experimentally on Northern Hemisphere organic matter types. As part of the Offshore Energy Systems program hydrocarbons from the Lower Cretaceous Eumeralla Formation were selected where available from onshore wells; compositional kinetics (1-, 2-, 4- and 14-component (phase) kinetics) were undertaken by GeoS4, Germany. The phase kinetics approach is outlined in Appendix 1. This report provides the compositional kinetics for potential source rocks from the Lower Cretaceous Otway Group, Otway Basin, Australia. The kinetic data were used in the offshore petroleum system modelling reported in Schenk et al. (2021).

Preamble: The 'National Geochemical Survey of Australia: The Geochemical Atlas of Australia' was published in July 2011 along with a digital copy of the NGSA geochemical dataset (http://dx.doi.org/10.11636/Record.2011.020). The NGSA project is described here: www.ga.gov.au/ngsa. The present dataset contains additional geochemical data obtained on NGSA samples: the Lead Isotopes Dataset. Abstract: Over 1200 new lead (Pb) isotope analyses were obtained on catchment outlet sediment samples from the NGSA regolith archive to document the range and patterns of Pb isotope ratios in the surface regolith and their relationships to geology and anthropogenic activity. The selected samples included 1204 NGSA Top Outlet Sediment (TOS) samples taken from 0 to 10 cm depth and sieved to <2 mm (or ‘coarse’ fraction); three of these were analysed in duplicate for a total of 1207 Pb isotope analyses. Further, 12 Northern Australia Geochemical Survey (NAGS; http://dx.doi.org/10.11636/Record.2019.002) TOS samples from within a single NGSA catchment, also sieved to <2 mm, were analysed to provide an indication of smaller scale variability. Combined, we thus present 1219 new TOS coarse, internally comparable data points, which underpin new national regolith Pb isoscapes. Additionally, 16 NGSA Bottom Outlet Sediment (BOS; ~60 to 80 cm depth) samples, also sieved to <2 mm, and 16 NGSA TOS samples sieved to a finer grainsize (<75 um, or ‘fine’) fraction from selected NGSA catchments were also included to inform on Pb mobility and residence. Lead isotope analyses were performed by Candan Desem as part of her PhD research at the School of Geography, Earth and Atmospheric Sciences, University of Melbourne. After an initial ammonium acetate (AmAc) leach, the samples were digested in aqua regia (AR). Although a small number of samples were analysed after the AmAc leach, all samples were analysed after the second, AR digestion, preparation step. The analyses were performed without prior matrix removal using a Nu Instruments Attom single collector Sector Field-Inductively Coupled Plasma-Mass Spectrometer (SF-ICP-MS). The dried soil digests were redissolved in 2% HNO3 run solutions containing high-purity thallium (1 ppb Tl) and diluted to provide ~1 ppb Pb in solution. Admixture of natural, Pb-free Tl (with a nominal 205Tl/203Tl of 2.3871) allowed for correction of instrumental mass bias effects. Concentrations of matrix elements in the diluted AR digests are estimated to be in the range of 1–2 ppm. The SF-ICP-MS was operated in wet plasma mode using a Glass Expansion cyclonic spray chamber and glass nebuliser with an uptake rate of 0.33 mL/min. The instrument was tuned for maximum sensitivity and provided ~1 million counts per second/ppb Pb while maintaining flat-topped peaks. Each analysis, performed in the Attom’s ‘deflector peak jump’ mode, consists of 30 sets of 2000 sweeps of masses 202Hg, 203Tl, 204Pb, 205Tl, 206Pb, 207Pb and 208Pb, with dwell times of 500 μs and a total analysis time of 4.5 min. Each sample acquisition was preceded by a blank determination. All corrections for baseline, sample Hg interference (202Hg/204Pb ratios were always <0.043) and mass bias were performed online, producing typical in-run precisions (2 standard errors) of ±0.047 for 206Pb/204Pb, ±0.038 for 207Pb/204Pb, ±0.095 for 208Pb/204Pb, ±0.0012 for 207Pb/206Pb and ±0.0026 for 208Pb/206Pb. A small number of samples with low Pb concentrations exhibited very low signal sizes during analysis resulting in correspondingly high analytical uncertainties. Samples producing within-run uncertainties of >1% relative (measured on the 207Pb/204Pb ratio) were discarded as being insufficiently precise to contribute meaningfully to the dataset. Data quality was monitored using interspersed analyses of Tl-doped ~1 ppb solutions of the National Institute of Standards and Technology (NIST) SRM981 Pb standard, and several silicate reference materials: United States Geological Survey ‘BCR-2’ and ‘AGV-2’, Centre de Recherches Pétrographiques et Géochimiques ‘BR’ and Japan Geological Survey ‘JB-2’. In a typical session, up to 50 unknowns plus 15 standards were analysed using an ESI SC-2 DX autosampler. Although previous studies using the Attom SF-ICP-MS used sample-standard-bracketing techniques to correct for instrumental Pb mass bias, Tl doping was found to produce precise, accurate and reproducible results. Based upon the data for the BCR-2 and AGV-2 secondary reference materials, for which we have the most analyses, deviations from accepted values (accuracy) were typically <0.17%. Data for the remaining silicate standards appear slightly less accurate but these results may, to some extent, reflect uncertainty in the assigned literature values for these materials. Replicate runs of selected AR digests yielded similar reproducibility estimates. The results show a wide range of Pb isotope ratios in the NGSA (and NAGS) TOS <2 mm fraction samples across the continent (N = 1219): 206Pb/204Pb: Min = 15.558; Med ± Robust SD = 18.844 ± 0.454; Mean ± SD = 19.047 ± 1.073; Max = 30.635 207Pb/204Pb; Min = 14.358; Med ± Robust SD = 15.687 ± 0.091; Mean ± SD = 15.720 ± 0.221; Max = 18.012 208Pb/204Pb; Min = 33.558; Med ± Robust SD = 38.989 ± 0.586; Mean ± SD = 39.116 ± 1.094; Max = 48.873 207Pb/206Pb; Min = 0.5880; Med ± Robust SD = 0.8318 ± 0.0155; Mean ± SD = 0.8270 ± 0.0314; Max = 0.9847 208Pb/206Pb; Min = 1.4149; Med ± Robust SD = 2.0665 ± 0.0263; Mean ± SD = 2.0568 ± 0.0675; Max = 2.3002 These data allow the construction of the first continental-scale regolith Pb isotope maps (206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, 207Pb/206Pb, and 208Pb/206Pb isoscapes) of Australia and can be used to understand contributions of Pb from underlying bedrock (including Pb-rich mineralisation), wind-blown dust and possibly from anthropogenic sources (industrial, transport, agriculture, residential, waste handling). The complete dataset is available to download as a comma separated values (CSV) file from Geoscience Australia's website (http://dx.doi.org/10.26186/5ea8f6fd3de64). Isoscape grids (inverse distance weighting interpolated grids with a power coefficient of 2 prepared in QGis using GDAL gridding tool based on nearest neighbours) are also provided for the five Pb isotope ratios (IDW2NN.TIF files in zipped folder). Alternatively, the new Pb isotope data can be downloaded from and viewed on the GA Portal (https://portal.ga.gov.au/).

<div>A powerpoint presentation given by Ivan Schroder at Uncover Curnamona 2022. The presentation covers the activities and upcoming products of the Curnamona Geochemistry module (within the Darling Curnamona Delamerian Project of the Exploring for the Future Program)</div>