<div>A groundwater chemistry, regolith chemistry and metadata record for legacy geochemical studies over the southern Curnamona Province done by GA and partners as part of CRC LEME from 1999 to 2005, that was never fully released. This includes comprehensive groundwater chemistry from more than 250 bores in the Broken Hill region, containing physicochemical parameters, major and trace elements, and a suite of isotopes (34S, Pb, Sr, 18O, D). Recent work on this dataset (in 2021) has added hydrostratigraphic information for these groundwater samples. Also included is a regolith geochemistry dataset collected adjacent to some of the groundwater bores which tests the geochemical response of a range of different size fractions, depths and digests.</div>

New provenance data from Palaeoproterozoic and possible Archaean sedimentary units in the central eastern Gawler Craton forms part of a growing dataset suggesting that the Gawler Craton shares important basin formation and tectonic time lines with the adjacent Curnamona Province and the Isan Inlier in northern Australia. U-Pb dating of detrital zircons from the Eba Formation (previously mapped as Tarcoola Formation), yield exclusively Archaean ages (~2530-3300 Ma). This is consistent with whole rock Nd and zircon Hf isotopic data for the Eba Formation which have evolved compositions. Elsewhere in the eastern Gawler Craton, cover sequences historically considered to be Palaeoproterozoic in age also contain exclusively Neo and Meso Archaean aged detrital zircons (Reid et al, 2009 Econ. Geol.; Szpunar et al, 2007, SGTSG). The absence of Palaeoproterozoic detrital grains in several differently mapped sequences (including the Eba Formation) despite the proximity of voluminous Palaeoproterozoic rock units, suggests that the Eba Formation may be part of a Neo-Archaean or early Palaeoproterozoic cover sequence derived from erosion of a complex Archaean aged source region. The Labyrinth Formation unconformably overlies the Eba Quartzite, and contains rhyolitic units that constrain deposition to 1715 ± 9 Ma (Fanning et al., 2007; PIRSA Bulletin 55). This age is identical to the timing of deposition of the lower Willyama Supergroup in the adjacent Curnamona Province. Detrital zircon ages in the Labyrinth Formation range from NeoArchaean to Palaeoproterozoic, and are consistent with derivation from > 1715 Ma components of the Gawler Craton. Isotopic zircon Hf data and whole rock Nd data also suggest a source region with a mixed crustal evolution (-Nd -4.5 to -6), consistent with what is known about the Gawler Craton. Compared to the Lower Willyama Supergroup, the Labyrinth Formation has a source more obviously reconcilable with the Gawler Craton.

Amino acid racemization (AAR) dating of the eolianite on Lord Howe Island is used to correlate several disparate successions and provides a geochronological framework that ranges from Holocene to Middle Pleistocene time. The reliability of the AAR data is assessed by analysing multiple samples from individual lithostratigraphic units, checking the stratigraphic order of the D/L ratios and the consistency of the relative extents of racemization for a suite of seven amino acids. Three aminozones are defined on the basis of the extent of racemization of amino acids in land snails (Placostylus bivaricosus) and 'whole-rock' eolianite samples. Aminozone A includes Placostylus from modern soil horizons (e.g. mean D/L-leucine ratio of 0.03±0.01) and whole-rock samples from unconsolidated lagoonal and beach deposits (0.10±0.01-0.07±0.03). Aminozone B includes Placostylus (0.45±0.03) and whole-rock samples from beach (0.48±0.01) and dune (0.45±0.02-0.30±0.02) units of the Neds Beach Formation, deposited during OIS 5. The oldest, Aminozone C, comprises Placostylus recovered from paleosols (0.76±0.02) and whole-rock eolianite samples (0.62±0.00) from the Searles Point Formation, which indicate the formation was likely deposited over several Oxygen Isotope Stages (OIS), during and prior to OIS 7. These data support independent lithostratigraphic interpretations and are in broad agreement with U/Th ages of speleothems from the Searles Point Formation and corals from the Neds Beach Formation, and with several TL ages of dune units in both formations. The AAR data reveal that eolianite deposition extends over a significantly longer time interval than previously appreciated and indicate that the deposition of the large dune units is linked to periods of relatively high sea level.

Australia as it exists today is a product of geological processes that have occurred over its 4.5 billion year history. Isotopic studies are one approach to understanding the history and evolution of the Australian continent. Isotope geochronology tells us about the timing of a wide range of geological processes like crystallisation, deformation and cooling of rocks. Isotope geochemistry informs on the precursor components from which the rocks formed, and can act as 'paleogeophysical' sensors to tell us more about the subsurface. The Isotopic Atlas of Australia brings together five of the most widely used isotopic systems in geology and delivers publicly available maps and datasets in a consistent format. This work is unlocking the collective value of decades of investment in data collection, and facilitating qualitative and quantitative comparison and integration with other datasets such as geophysical images. This talk will be an introduction to the world of isotopes as applied to understand geology, and an overview of the Isotopic Atlas recently produced as part of the Exploring for the Future Program.

This is a collection of conference program and abstracts presented at AOGC 2010, Canberra.

<div>The push of mineral exploration under cover requires developing new geochemical exploration approaches. Detailed hydrogeochemistry addresses these needs and is valuable as a non-invasive mineral exploration technique that can identify lithological changes and dispersion signatures associated with mineralisation. Here we integrate whole-rock geochemistry and hydrogeochemistry to evaluate suitable geochemical tracers in groundwater for detecting phosphate and/or Pb-Zn style mineralisation in the Georgina Basin. The known Georgina Basin’s phosphate deposits are within the basin’s aquifers, providing groundwater near deposits greater exposure and opportunity for water-rock interactions with mineralised geology, resulting in trace element and isotope signatures of mineralisation at detectable levels. These tracers can then be applied elsewhere in the basin as a screening tool for detecting mineralisation. To achieve this, we collected rock geochemistry from the MinEx CRC East Tennant National Drilling Initiative Campaign (ME-ET) drillcore, and integrated it with nearby hydrogeochemistry (from the Northern Australia Hydrogeochemical Survey (NAHS)). </div><div><br></div><div>The NAHS was collected by Geoscience Australia as part of EFTF, which included 170 samples from Georgina Basin aquifers. This hydrogeochemistry dataset is high quality, due to robust sampling, QA/QC procedures and a comprehensive analysis suite, making it a useful tool for mineral exploration in the Georgina Basin. The ME-ET drilled 10 stratigraphic holes east of Tennant Creek, Northern Territory, in support of Geoscience Australia’s Exploring for the Future program (EFTF). Seventy six Georgina Basin rock samples were collected for whole rock geochemistry and a subset for Pb and Sr isotopes. Samples were selected to target: 1) background unmineralised lithostratigraphy, 2) intervals with groundwater intersections, and 3) transects through zones with anomalous concentrations of P, Pb, Zn and Cu, as identified by portable XRF analysis. </div><div><br></div><div>Initial exploratory data analysis of the hydrogeochemistry is conducted at various scales using principle component analysis and clustering approaches to identify the key attributes (major and trace elements, isotopes, hydrogeology etc.) that are associated with higher P content in the groundwater. These relationships are tested by comparing groundwater samples proximal (in depth and spatially) to high P compositions in the host rock, providing insight into the water-rock interactions taking place. Additionally, vertical whole rock geochemistry transects within the drill-holes are investigated to evaluate the trace element and/or isotopic features that are diagnostic of the enriched phosphate zones. We take the robust geochemical relationships identified from both approaches and apply them as tracers across the NAHS to flag areas of potential undiscovered mineralisation. As we will demonstrate, the NAHS can detect subtle or diluted mineralisation signatures, and underpins a revised understanding of phosphate mineral prospectivity in the Georgina Basin.</div> Abstract submitted and presented at 2023 Australian Earth Science Convention (AESC), Perth WA (https://2023.aegc.com.au/)

This web service provides access to the Geoscience Australia (GA) ISOTOPE database containing compiled age and isotopic data from a range of published and unpublished (GA and non-GA) sources. The web service includes point layers (WFS, WMS, WMTS) with age and isotopic attribute information from the ISOTOPE database, and raster layers (WMS, WMTS, WCS) comprising the Isotopic Atlas grids which are interpolations of the point located age and isotope data in the ISOTOPE database.

<div>The bulk rock stable isotopes database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the stable isotopic composition of sedimentary rocks with an emphasis on calcareous rocks and minerals sampled from boreholes and field sites. The stable isotopes of carbon, oxygen, strontium, hydrogen, nitrogen, and sulfur are measured by various laboratories in service and exploration companies, Australian government institutions, and universities, using a range of instruments. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and the stable isotopes ratios. The carbon (¹³C/¹²C) and oxygen (¹⁸O/¹⁶O) isotope ratios of calcareous rocks are expressed in delta notation (i.e., &delta;¹³C and &delta;¹⁸O) in parts per mil (‰) relative to the Vienna Peedee Belemnite (VPDB) standard, with the &delta;¹⁸O values also reported relative to the Vienna Standard Mean Ocean Water (VSMOW) standard. Likewise, the stable isotope ratio of hydrogen (²H/¹H) is presented in delta notation (&delta;²H) in parts per mil (‰) relative to the VSMOW standard, the stable isotope ratio of nitrogen (¹⁵N/¹⁴N) is presented in delta notation (&delta;¹⁵N) in parts per mil (‰) relative to the atmospheric air (AIR) standard, and the stable isotope ratio of sulfur (³⁴S/³²S) is presented in delta notation (&delta;³⁴S) relative to the Vienna Canyon Diablo Troilite (VCDT) standard. For carbonates, the strontium (⁸⁷Sr/⁸⁶Sr) isotope ratios are also provided.</div><div><br></div><div>These data are used to determine the isotopic compositions of sedimentary rock with emphasis on the carbonate within rocks, either as minerals, the mineral matrix or cements. The results for the carbonate rocks are used to determine paleotemperature, paleoenvironment and paleoclimate, and establish regional- and global-scale stratigraphic correlations. These data are collated from Geoscience Australia records, destructive analysis reports (DARs), well completion reports (WCRs), and literature. The stable isotope data for sedimentary rocks are delivered in the Stable Isotopes of Carbonates web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

This web service provides access to the Geoscience Australia (GA) ISOTOPE database containing compiled age and isotopic data from a range of published and unpublished (GA and non-GA) sources. The web service includes point layers (WFS, WMS, WMTS) with age and isotopic attribute information from the ISOTOPE database, and raster layers (WMS, WMTS, WCS) comprising the Isotopic Atlas grids which are interpolations of the point located age and isotope data in the ISOTOPE database.

This service provides access to hydrochemistry data (groundwater and surface water analyses) obtained from water samples collected from Australian water bores or field sites.