Natural gas is Australia's third largest energy resource after coal and uranium but despite this economic importance, the gas origin is not always recognized. To address this, isotope and geochemistry data have been collated on 850 natural gases from all of Australia's major gas provinces with proposed source ages spanning the earliest Paleozoic to the Cenozoic. Unaltered natural gases have a thermogenic origin ('13C methane ranges between -49 and -27'; 'D methane ranges between -290 and -125'). Microbially altered natural gases were identified primarily on the basis of 13C and D enrichments in propane and/or 13C depletion in methane and/or 13C enrichment in CO2. The carbon isotopic composition of the gas source has been estimated using '13C iso-butane as a surrogate for '13C kerogen while for gases where biodegradation is moderate to severe, '13C neo-pentane provides an alternative measure. The '13C kerogen of gas source rocks range from -47 to -22' with the older Paleozoic sources and marine kerogen amongst the most depleted in 13C. The '13C CO2 also provides an insight into crustal- and mantle-derived components while '15N N2 (-6.0 to 2.3' for N2 up to 47 %) distinguish between organic and inorganic (groundwater) inputs. This dataset provides a better understanding on the source and preservation history of Australian gas accumulations with direct implications on improving exploration success.

The New England Orogen contains a geological record dominated by subduction-related rocks, indicating that the orogen has been part of, or adjacent to, convergent plate margins of eastern Gondwanaland from at least the Cambrian until the end of the Early Cretaceous (~95 Ma). In the late Devonian, the orogen records the change from an island arc setting to an Andean-style convergent continental plate margin (e.g., Flood & Aitchison 1992; Skilbeck and Cawood, 1994). The rock record prior to the Middle Devonian is fragmentary, but the Late Devonian to Carboniferous components of the continental margin magmatic arc, forearc basin and accretionary wedge system are well preserved in the New England Orogen, with the Lachlan Orogen, Thomson Orogen and Drummond Basin to the west being in a backarc setting at this time. This system ended in the Late Carboniferous, with the subduction zone stepping to the east (Cawood, 1984). Nevertheless, until at least the Early Cretaceous, the Australian component of the continental margin of East Gondwanaland faced the Proto-Pacific (Panthalassan) Ocean, and has been interpreted to form part of a subduction-related convergent plate margin (e.g. Powell 1984; Cawood 2005; Glen 2005). Here, we examine aspects of the southern New England Orogen from the Cambrian to the Early Permian to further document the nature of the convergent plate margin over this period of time. We are interested especially in the Tamworth Belt, where the changeover is recorded from the Cambrian-Late Devonian island arc setting, to the development of the Devonian-Carboniferous continental margin in a convergent plate setting, with its well developed forearc basin and accretionary wedge. The island arc component is referred to as the Gamilaroi Terrane by Aitchison and Flood (1995) and Offler and Gamble (2002).

The oxygen isotopic record obtained from Globigerina bulloides, Globorotalia inflata, and Neogloboquadrina pachyderma (s.) was analysed for 5 sediment traps moored in the Southern Ocean and Southwest Pacific. The traps extend from Subtropical to the Polar Frontal environments, providing the first analysis of seasonal foraminiferal d18O records from these latitudes. Comparison between the foraminiferal records and various equations for predicted d18O of calcite reveals that the predicted d18O is best captured by the equations of Epstein et al. (1953) [Epstein, S., Buchsbaum, R., Lowenstam, H.A., Urey, H.C., 1953. Revised carbonate-water isotopic temperature scale. Geological Society of America Bulletin 64, 1315-1326.] and Kim and O'Neil (1997) [Kim, S.-T., O'Neil, J.R., 1997. Equilibrium and non-equilibrium oxygen isotope effects in synthetic carbonates. Geochimica et Cosmochimica Acta 61, 3461-3475.]. The Epstein equation shows a constant offset from the -18O of G. bulloides and N. pachyderma (s.) across the full range of latitudes. The seasonal range in -18O values for these two species implies a near-surface habitat across all sites, while G. inflata most likely dwells at 50 m depth. A significant finding in this study was that offsets from predicted -18O for G. bulloides do not correlate to changes in the carbonate ion concentration. This suggests that [CO32-] in and of itself may not capture the full range of carbonate chemistry conditions in the marine system. This sediment trap deployment also reveals distinct seasonal flux patterns for each species. Comparison between flux-weighted isotopic values calculated from the sediment traps and the isotopic composition of nearby surface sediments indicates that the sedimentary records retain this seasonal imprint. At the 51°S site, G. bulloides has a spring flux peak while N. pachyderma (s.) is dominated by summer production.

Intrusive and extrusive, predominantly felsic, magmatism of Carboniferous to Permian age occurs throughout the north Queensland region (Figure kennedy), and comprises the most widespread and voluminous magmatic event in the region. The great bulk of the exposed KIA is concentrated in the Townsville-Cairns-Cooktown-Georgetown-Charters Towers-Burdekin Falls regions (Figure Kennedy)-within the early-mid-Palaeozoic Hodgkinson and Broken River Provinces, the Etheridge Province and associated Proterozoic provinces, and in the northern part of the Thomson Orogen including the Greenvale, Charters Towers, and Barnard Provinces, and the northern Drummond Basin. The boundary between the northern Drummond Basin and Connors (nNEO) Subprovince is taken to be the Millaroo Fault Zone (MFZ). Geophysical data (and limited geochronology) show that Carboniferous-Permian granites also form a westerly trending belt-the Townsville-Mornington Island Belt (TMIB; originally Townsville-Mornington Island Igneous Belt), which extends under cover from north of Mount Surprise, at least as far as Mornington Island in the Gulf of Carpentaria, transecting regional trends (Wellman, 1992, 1995; Wellman et al., 1994). There is also recent geochronological evidence for KIA magmatism in the environs of the Millungera Basin (Neumann & Kositcin, 2011). Outcrop is discontinuous in the belt extending northwards from Cairns up Cape York Peninsula, to the islands of Torres Strait (and beyond) but geophysical evidence implies there is more extensive magmatism under cover.

New provenance data from Palaeoproterozoic and possible Archaean sedimentary units in the central eastern Gawler Craton forms part of a growing dataset suggesting that the Gawler Craton shares important basin formation and tectonic time lines with the adjacent Curnamona Province and the Isan Inlier in northern Australia. U-Pb dating of detrital zircons from the Eba Formation (previously mapped as Tarcoola Formation), yield exclusively Archaean ages (~2530-3300 Ma). This is consistent with whole rock Nd and zircon Hf isotopic data for the Eba Formation which have evolved compositions. Elsewhere in the eastern Gawler Craton, cover sequences historically considered to be Palaeoproterozoic in age also contain exclusively Neo and Meso Archaean aged detrital zircons (Reid et al, 2009 Econ. Geol.; Szpunar et al, 2007, SGTSG). The absence of Palaeoproterozoic detrital grains in several differently mapped sequences (including the Eba Formation) despite the proximity of voluminous Palaeoproterozoic rock units, suggests that the Eba Formation may be part of a Neo-Archaean or early Palaeoproterozoic cover sequence derived from erosion of a complex Archaean aged source region. The Labyrinth Formation unconformably overlies the Eba Quartzite, and contains rhyolitic units that constrain deposition to 1715 ± 9 Ma (Fanning et al., 2007; PIRSA Bulletin 55). This age is identical to the timing of deposition of the lower Willyama Supergroup in the adjacent Curnamona Province. Detrital zircon ages in the Labyrinth Formation range from NeoArchaean to Palaeoproterozoic, and are consistent with derivation from > 1715 Ma components of the Gawler Craton. Isotopic zircon Hf data and whole rock Nd data also suggest a source region with a mixed crustal evolution (-Nd -4.5 to -6), consistent with what is known about the Gawler Craton. Compared to the Lower Willyama Supergroup, the Labyrinth Formation has a source more obviously reconcilable with the Gawler Craton.

The Nolans Bore deposit, located in the Aileron Province of south-central Northern Territory, is a developing Australian rare earth element (REE) deposit. The deposit currently has a defined global resource of 30.2 Mt grading 2.8% rare earth oxides, 12.9% P2O5 and 200 ppm U3O8 (ASX:ARU 11/11/08). It consists of massive and brecciated fluorapatite veins that are up to 75-m-thick and hosted by ~1806 Ma granitic and metasedimentry units. Although initial drilling indicated that these veins dipped steeply to the NNW, more recent drilling has indicated a more complex 3D-vein configuration across the deposit. Even though apatite is the dominant mineral in the veins, the paragenesis is complex, with a massive zone of apatite-allanite-amphibole breccia, and numerous cross-cutting veins. The apatite hosts REE but it also typically contains abundant inclusions of other REE-bearing minerals, such as monazite and allanite along with other REE 'bearing phosphates, silicates and carbonates. Localised zones of higher grade REE mineralisation occur as intensely kaolinitised and clay altered rocks dominated by fine grained monazite and crandallite group minerals. A preliminary ~1240 Ma U-Pb age for apatite, which is interpreted as a minimum age, corresponds to a major period of global alkalic magmatism between 1300 and 1130 Ma. Low ?Nd and 87Sr/86Sr in the mineralisation are suggestive of EM-1 sources. The deposit is interpreted to be a carbonatite-related hydrothermal deposit. Fertilisation of the mantle to produce the EM-1 source may relate to subduction associated with older convergence along the southern margin of the North Australian Craton.

Australia as it exists today is a product of geological processes that have occurred over its 4.5 billion year history. Isotopic studies are one approach to understanding the history and evolution of the Australian continent. Isotope geochronology tells us about the timing of a wide range of geological processes like crystallisation, deformation and cooling of rocks. Isotope geochemistry informs on the precursor components from which the rocks formed, and can act as 'paleogeophysical' sensors to tell us more about the subsurface. The Isotopic Atlas of Australia brings together five of the most widely used isotopic systems in geology and delivers publicly available maps and datasets in a consistent format. This work is unlocking the collective value of decades of investment in data collection, and facilitating qualitative and quantitative comparison and integration with other datasets such as geophysical images. This talk will be an introduction to the world of isotopes as applied to understand geology, and an overview of the Isotopic Atlas recently produced as part of the Exploring for the Future Program.

Amino acid racemization (AAR) dating of the eolianite on Lord Howe Island is used to correlate several disparate successions and provides a geochronological framework that ranges from Holocene to Middle Pleistocene time. The reliability of the AAR data is assessed by analysing multiple samples from individual lithostratigraphic units, checking the stratigraphic order of the D/L ratios and the consistency of the relative extents of racemization for a suite of seven amino acids. Three aminozones are defined on the basis of the extent of racemization of amino acids in land snails (Placostylus bivaricosus) and 'whole-rock' eolianite samples. Aminozone A includes Placostylus from modern soil horizons (e.g. mean D/L-leucine ratio of 0.03±0.01) and whole-rock samples from unconsolidated lagoonal and beach deposits (0.10±0.01-0.07±0.03). Aminozone B includes Placostylus (0.45±0.03) and whole-rock samples from beach (0.48±0.01) and dune (0.45±0.02-0.30±0.02) units of the Neds Beach Formation, deposited during OIS 5. The oldest, Aminozone C, comprises Placostylus recovered from paleosols (0.76±0.02) and whole-rock eolianite samples (0.62±0.00) from the Searles Point Formation, which indicate the formation was likely deposited over several Oxygen Isotope Stages (OIS), during and prior to OIS 7. These data support independent lithostratigraphic interpretations and are in broad agreement with U/Th ages of speleothems from the Searles Point Formation and corals from the Neds Beach Formation, and with several TL ages of dune units in both formations. The AAR data reveal that eolianite deposition extends over a significantly longer time interval than previously appreciated and indicate that the deposition of the large dune units is linked to periods of relatively high sea level.

The Brattstrand Paragneiss, a highly deformed Neoproterozoic granulite-facies metasedimentary sequence, is cut by three generations of ~500 Ma pegmatite. The earliest recognizable pegmatite generation, synchronous with D2-3, forms irregular pods and veins up to a meter thick, which are either roughly concordant or crosscut S2 and S3 fabrics and are locally folded. Pegmatites of the second generation, D4, form planar, discordant veins up to 20-30 cm thick, whereas the youngest generation, post-D4, form discordant veins and pods. The D2-3 and D4 pegmatites are abyssal class (BBe subclass) characterized by tourmaline + quartz intergrowths and boralsilite (Al16B6Si2O37); the borosilicates prismatine, grandidierite, werdingite and dumortierite are locally present. In contrast, post-D4 pegmatites host tourmaline (no symplectite), beryl and primary muscovite and are assigned to the beryl subclass of the rare-element class. Spatial correlations between B-bearing pegmatites and B-rich units in the host Brattstrand Paragneiss are strongest for the D2-3 pegmatites and weakest for the post-D4 pegmatites, suggesting that D2-3 pegmatites may be closer to their source. Initial 87Sr/86Sr (at 500 Ma) is high and variable (0.7479-0.7870), while -Nd500 tends to be least evolved in the D2-3 pegmatites (-8.1 to -10.7) and most evolved in the post-D4 pegmatites (-11.8 to -13.0). Initial 206Pb/204Pb and 207Pb/204Pb and 208Pb/204Pb ratios, measured in acid-leached alkali feldspar separates with low U/Pb and Th/Pb ratios, vary considerably (17.71-19.97, 15.67-15.91, 38.63-42.84), forming broadly linear arrays well above global Pb growth curves. The D2-3 pegmatites contain the most radiogenic Pb while the post-D4 pegmatites have the least radiogenic Pb; data for D4 pegmatites overlap with both groups. Broad positive correlations for Pb and Nd isotope ratios could reflect source rock compositions controlled two components. Component 1 (206Pb/204Pb-20, 208Pb/204-43, Nd -8) most likely represents old upper crust with high U/Pb and very high Th/Pb. Component 2 (206Pb/204Pb -18, 208Pb/204Pb~38.5, -Nd500 -12 to -14) has a distinctive high-207Pb/206Pb signature which evolved through dramatic lowering of U/Pb in crustal protoliths during the Neoproterozoic granulite-facies metamorphism. Component 1, represented in the locally-derived D2-3 pegmatites, could reside within the Brattstrand Paragneiss, which contains detrital zircons up to 2.1 Ga old and has a wide range of U/Pb and Th/Pb ratios. The Pb isotope signature of component 2, represented in the 'far-from-source' post-D4 pegmatites, resembles feldspar Pb isotope ratios in Cambrian granites intrusive into the Brattstrand Paragneiss. However, given their much higher 87Sr/86Sr, the post-D4 pegmatite melts are unlikely to be direct magmatic differentiates of the granites, although they may have broadly similar crustal sources. Correlation of structural timing with isotopic signatures, with a general sense of deeper sources in the younger pegmatite generations, may reflect cooling of the crust after Cambrian metamorphism.

Aspects of the tectonic history of Paleo- to Mesoproterozoic Australia are recorded by metasedimentary basins in the Mt Isa, Etheridge Provinces, and Coen Inlier in northern Australia and in the Curnamona Province of southern Australia. These deformed and metamorphosed basins are interpreted to have been deposited in a tectonically-linked system based on similarities in depositional ages and stratigraphy (Giles at al 2002). Neodymium isotope compositions of sediments and felsic volcanics, when combined with U-Pb geochronology, are independent data that are important tools for inferring tectonic setting, palaeogeography and sediment provenance in deformed and metamorphosed terrains.