Inland sulfidic soils have recently formed throughout wetlands of the Murray River floodplain associated with increased salinity and river regulation (Lamontagne et al., 2006). Sulfides have the potential to cause widespread environmental degradation both within sulfidic soils and down stream depending on the amount of carbonate available to neutralise acidity (Dent, 1986). Sulfate reduction is facilitated by organic carbon decomposition, however, little is known about the sources of sedimentary organic carbon and carbonate or the process of sulfide accumulation within inland sulfidic wetlands. This investigation uses stable isotopes from organic carbon (13C and 15N), inorganic sulfur (34S) and carbonate (13C and 18O) to elucidate the sources and cycling of sulfur and carbon within sulfidic soils of the Loveday Disposal Basin.

Initial lead isotope ratios from Archean volcanic-hosted massive sulfide (VHMS) and lode gold deposits and neodymium isotope model ages from igneous rocks from the geological provinces that host these deposits identify systematic spatial and temporal patterns, both within and between the provinces. The Abitibi-Wawa Subprovince of the Superior Province is characterized by highly juvenile lead and neodymium. Most other Archean provinces, however, are characterized by more evolved isotopes, although domains within them can be characterized by juvenile isotope ratios. Metal endowment (measured as the quantity of metal contained in geological resources per unit surface area) of VHMS and komatiite-associated nickel sulfide (KANS) deposits is related to the isotopic character, and therefore the tectonic history, of provinces that host these deposits. Provinces with extensive juvenile crust have significantly higher endowment of VHMS deposits, possibly as a consequence of higher heat flow and extension-related faults. Provinces with evolved crust have higher endowment of KANS deposits, possibly because such crust provided either a source of sulfur or a stable substrate for komatiite emplacement. In any case, initial radiogenic isotope ratios can be useful in predicting the endowment of Archean terranes for VHMS and KANS deposits. Limited data suggest similar relationships may hold in younger terranes.

Recent national and state assessments have concluded that sedimentary formations that underlie or are within the Great Artesian Basin (GAB) may be suitable for the storage of greenhouse gases. These same formations contain methane and naturally generated carbon dioxide that has been trapped for millions of years. The Queensland government has released exploration permits for Greenhouse Gas Storage in the Bowen and Surat basins. An important consideration in assessing the potential economic, environmental, health and safety risks of such projects is the potential impact CO2 migrating out of storage reservoirs could have on overlying groundwater resources. The risk and impact of CO2 migrating from a greenhouse gas storage reservoir into groundwater cannot be objectively assessed without knowledge of the natural baseline characteristics of the groundwater within these systems. Due to the phase behaviour of CO2, geological storage of carbon dioxide in the supercritical state requires depths greater than 800m, but there are no hydrochemical studies of such deeper aquifers in the prospective storage areas. Geoscience Australia (GA) and the Geological Survey of Queensland (GSQ), Queensland Department of Mines and Energy, worked collaboratively under the National Geoscience Agreement (NGA) to characterise the regional hydrochemistry of the Denison Trough and Surat Basin and trialled different groundwater monitoring strategies. The output from this Project constitutes part of a regional baseline reference set for future site-specific and semi-regional monitoring and verification programmes conducted by geological storage proponents. The dataset provides a reference of hydrochemistry for future competing resource users.

The Brattstrand Paragneiss, a highly deformed Neoproterozoic granulite-facies metasedimentary sequence, is cut by three generations of ~500 Ma pegmatite. The earliest recognizable pegmatite generation, synchronous with D2-3, forms irregular pods and veins up to a meter thick, which are either roughly concordant or crosscut S2 and S3 fabrics and are locally folded. Pegmatites of the second generation, D4, form planar, discordant veins up to 20-30 cm thick, whereas the youngest generation, post-D4, form discordant veins and pods. The D2-3 and D4 pegmatites are abyssal class (BBe subclass) characterized by tourmaline + quartz intergrowths and boralsilite (Al16B6Si2O37); the borosilicates prismatine, grandidierite, werdingite and dumortierite are locally present. In contrast, post-D4 pegmatites host tourmaline (no symplectite), beryl and primary muscovite and are assigned to the beryl subclass of the rare-element class. Spatial correlations between B-bearing pegmatites and B-rich units in the host Brattstrand Paragneiss are strongest for the D2-3 pegmatites and weakest for the post-D4 pegmatites, suggesting that D2-3 pegmatites may be closer to their source. Initial 87Sr/86Sr (at 500 Ma) is high and variable (0.7479-0.7870), while -Nd500 tends to be least evolved in the D2-3 pegmatites (-8.1 to -10.7) and most evolved in the post-D4 pegmatites (-11.8 to -13.0). Initial 206Pb/204Pb and 207Pb/204Pb and 208Pb/204Pb ratios, measured in acid-leached alkali feldspar separates with low U/Pb and Th/Pb ratios, vary considerably (17.71-19.97, 15.67-15.91, 38.63-42.84), forming broadly linear arrays well above global Pb growth curves. The D2-3 pegmatites contain the most radiogenic Pb while the post-D4 pegmatites have the least radiogenic Pb; data for D4 pegmatites overlap with both groups. Broad positive correlations for Pb and Nd isotope ratios could reflect source rock compositions controlled two components. Component 1 (206Pb/204Pb-20, 208Pb/204-43, Nd -8) most likely represents old upper crust with high U/Pb and very high Th/Pb. Component 2 (206Pb/204Pb -18, 208Pb/204Pb~38.5, -Nd500 -12 to -14) has a distinctive high-207Pb/206Pb signature which evolved through dramatic lowering of U/Pb in crustal protoliths during the Neoproterozoic granulite-facies metamorphism. Component 1, represented in the locally-derived D2-3 pegmatites, could reside within the Brattstrand Paragneiss, which contains detrital zircons up to 2.1 Ga old and has a wide range of U/Pb and Th/Pb ratios. The Pb isotope signature of component 2, represented in the 'far-from-source' post-D4 pegmatites, resembles feldspar Pb isotope ratios in Cambrian granites intrusive into the Brattstrand Paragneiss. However, given their much higher 87Sr/86Sr, the post-D4 pegmatite melts are unlikely to be direct magmatic differentiates of the granites, although they may have broadly similar crustal sources. Correlation of structural timing with isotopic signatures, with a general sense of deeper sources in the younger pegmatite generations, may reflect cooling of the crust after Cambrian metamorphism.

Metallogenic, geologic and isotopic data indicate secular changes in the character of VHMS deposits relate to changes in tectonic processes, tectonic cycles, and changes in the hydrosphere and atmosphere. The distribution of these deposits is episodic, with peaks at 2740-2680 Ma, 1910-1840 Ma, 510-460 Ma and 370-355 Ma that correspond to the assembly of Kenorland, Nuna, Gondwana and Pangea. Quiescent periods of VHMS formation correspond to periods of supercontinent stability. Large ranges in source 238U/204Pb that characterize VHMS deposits in the Archean and Proterozoic indicate early (Hadean to Paleoarchean) differentiation. A progressive decrease in - variability suggests homogenisation with time of these differentiated sources. Secular increases in the amount of lead and decreases in 100Zn/(Zn+Pb) relate to an increase in felsic-dominated sequences as hosts to deposits and an absolute increase in the abundance of lead in the crust with time. The increase in sulfate minerals in VHMS deposits from virtually absent in the Meso- to Neoarchean to relatively common in the Phanerozoic relates to oxidation of the hydrosphere. Total sulfur in the oceans increased, resulting in an increasingly important contribution of seawater sulfur to VHMS ore fluids with time. Most sulfur in Archean to Paleoproterozoic deposits was derived by leaching rocks below deposits, with little contribution from seawater, resulting in uniform, near-zero-permil values of 34Ssulfide. In contrast the more variable values of younger deposits reflect the increasing importance of seawater sulfur. Unlike Meso- to Neoarchean deposits, Paleoarchean deposits contain abundant barite, which is inferred to have been derived from photolytic decomposition of atmospheric SO2 and does not reflect overall oxidised oceans. Archean and Proterozoic seawater was more salty than Phanerozoic, particularly upper Phanerozoic, seawater. VHMS fluids ore fluids reflect this, also being saltier in Precambrian deposits.

This service provides access to hydrochemistry data (groundwater and surface water analyses) obtained from water samples collected from Australian water bores or field sites.

The Kingoonya Palaeovalley is one of the largest arid zone palaeovalley systems in South Australia. Situated in the remote central-western Gawler Craton this relict drainage network, now buried and obscured by surficial Quaternary sediments, is characterised by multiple headwater tributaries which flowed predominantly westwards towards the Eucla Basin. Fluvial and lacustrine sediments infilling the incised palaeovalley, in places forming stacked sequences >100 metres thick, were sporadically deposited from the Mid Eocene to the Early Pliocene. Previous drilling transects indicated a variety of channel shapes and heterogeneous sediment packages, with favourable aquifer sequences (sand-rich) common in deeper parts. In 2010 detailed groundwater sampling from existing bores was conducted in the Kingoonya Palaeovalley for the National Water Commission-funded Palaeovalley Groundwater Project. Analysis of these samples indicates that most Kingoonya groundwaters are moderately to highly saline and dominated by Na and Cl ions. Trace element enrichments are uncommon, although locally elevated levels of some metals (e.g., Fe and Mn) likely reflect groundwater interactions with the heterogenous sediments. The Kingoonya groundwaters also have near-neutral to slightly acidic pH, low alkalinity and are mostly oxidising. Stable water isotopes define a distinct trend away from the LMWL, interpreted as multiple stages of evaporative recycling and relative enrichment from the original isotopic signatures (precipitation derived from nearby Southern Ocean). Radiocarbon ages indicate a spectrum of groundwater residence times, ranging from modern recharge to groundwater signatures >20,000 years in deeper parts of the basal palaeovalley aquifer.

The ca. 1000 Ma Brattstrand Paragneiss in the Larsemann Hills contains a unique assemblage of borosilicate-rich rocks: tourmaline (Tur) quartzite, prismatine (Prs) leucogneiss and grandidierite (Gdd) borosilicate gneiss. In situ analyses with a Cameca ims 4f ion microprobe gave '11B (= {[sample11B/10B / SRM 95111B/10B] - 1} × 1000) to be '3.0 to '14.3? in Tur, '9.6 to '18.1' in Prs and '1.9 to '8.7' in Gdd (1s mostly 1-2' per sample). In anatectic pegmatites, Tur '11B = 4.8 to '12.1'; comparison with host rock Tur implies melting and crystallization from melt together did not fractionate B isotopes. With two exceptions, average '11B increases in a given sample Prs < Tur < Gdd with Prs B 4.8±1.6' lighter and Gdd B 2.8±1.9' heavier than Tur B. This regularity is consistent with the preference of 10B for tetrahedral sites (Prs) and 11B for trigonal sites (Tur, Gdd) and crystallization in near isotopic equilibrium. The precursor of the B-rich rock least changed by metamorphism, Tur quartzite, is interpreted to be a product of pre-metamorphic, hydrothermal B-metasomatism. If there had been no '11B decrease from devolatization during metamorphism, quartzite Tur '11B ('8.7 to '5.7') constrains '11B of premetamorphic fluid to be '3 to 0' (2008 Tur-fluid '11B for 200 C), consistent with a continental source. However, more likely devolatization decreased Tur '11B, and '11B > 0' in the premetamorphic fluid, so an alternative precursor, such as mud volcanoes, should be considered.

This report is published in two volumes; Volume I: Bowen-Surat and Cooper-Eromanga Basins, Volume II: Gippsland, Bass, Otway, Stansbury, McArthur, Amadeus, Adavale, Galilee and Drummond Basins. Following the basin-by-basin analysis of geochemical characteristics of eastern Australia's oils, a selection of oils that best represented the major families of each region were selected. These oils were statistically analysed using a subset of geochemical (OilMod) parameters derived from GC, GC-MS and carbon isotopic analyses. This exercise was intended to display the variability in oil compositions across the whole of the eastern part of the continent. The chemical classification of oils follows closely upon, and verifies the analysis based on, palaeogeography and the supersystem concepts.

Amino acid racemization (AAR) dating of the eolianite on Lord Howe Island is used to correlate several disparate successions and provides a geochronological framework that ranges from Holocene to Middle Pleistocene time. The reliability of the AAR data is assessed by analysing multiple samples from individual lithostratigraphic units, checking the stratigraphic order of the D/L ratios and the consistency of the relative extents of racemization for a suite of seven amino acids. Three aminozones are defined on the basis of the extent of racemization of amino acids in land snails (Placostylus bivaricosus) and 'whole-rock' eolianite samples. Aminozone A includes Placostylus from modern soil horizons (e.g. mean D/L-leucine ratio of 0.03±0.01) and whole-rock samples from unconsolidated lagoonal and beach deposits (0.10±0.01-0.07±0.03). Aminozone B includes Placostylus (0.45±0.03) and whole-rock samples from beach (0.48±0.01) and dune (0.45±0.02-0.30±0.02) units of the Neds Beach Formation, deposited during OIS 5. The oldest, Aminozone C, comprises Placostylus recovered from paleosols (0.76±0.02) and whole-rock eolianite samples (0.62±0.00) from the Searles Point Formation, which indicate the formation was likely deposited over several Oxygen Isotope Stages (OIS), during and prior to OIS 7. These data support independent lithostratigraphic interpretations and are in broad agreement with U/Th ages of speleothems from the Searles Point Formation and corals from the Neds Beach Formation, and with several TL ages of dune units in both formations. The AAR data reveal that eolianite deposition extends over a significantly longer time interval than previously appreciated and indicate that the deposition of the large dune units is linked to periods of relatively high sea level.