Organic Geochemistry
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<div>Exploring for the Future (EFTF) is a program dedicated to exploring Australia’s resource potential and boosting investment. This program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of onshore basins and attract exploration investment to Australia. This record presents geochemical analyses of natural gases sampled from Nangwarry 1, located in the onshore Otway Basin, undertaken in partnership with the Department for Energy and Mining – Energy Resources, Government of South Australia, as part of the EFTF program Natural Hydrogen module. The Nangwarry Joint Venture drilled Nangwarry 1 to investigate the potential for the development of food grade, carbon dioxide production from this well. The results of the molecular and stable carbon and hydrogen isotopic analyses undertaken by Geoscience Australia are released in this report. The molecular data show that the gas composition in this well has an average of 96 mol% CO2 with an isotopic signature indicative of a magmatic origin, being comparable with previously produced gases from onshore Otway Basin wells (e.g. Boggy Creek 1, Caroline 1) for use by the food industry. The carbon and hydrogen isotopic composition of the C1–C5 hydrocarbon gases from Nangwarry 1 are suggestive of a source from within the Crayfish Supersequence.</div>
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Geoscience Australia's Australian National Hydrocarbon Geochemistry Data Collection comprises Oracle database tables from the Organic Geochemistry (ORGCHEM) schema and derivative information in the Petroleum Systems Summary database (Edwards et al., 2020, 2023; Edwards and Buckler, 2024). The ORGCHEM schema includes organic geochemistry, organic petrology and stable isotope database tables that capture the analytical results from sample-based datasets used for the discovery and evaluation of sediment-hosted resources. A focus is to capture open file data relevant to energy (i.e., petroleum and hydrogen) exploration, including source rocks, crude oils and natural gases from both onshore and offshore Australian sedimentary basins. The database tables also include complementary physical properties and complementary inorganic analyses on sedimentary rocks and hydrocarbon-based earth materials. The data are produced by a wide range of destructive analytical techniques conducted on samples submitted by industry under legislative requirements, as well as on samples collected by research projects undertaken by Geoscience Australia, other government agencies and scientific institutions. Some of these results have been generated by Geoscience Australia, whereas other data are compiled from service company reports, well completions reports, government reports, published papers and theses. The data is non-confidential and available for use by Government, the energy exploration industry, research organisations and the community. The Petroleum Systems Summary database stores the compilation of the current understanding of petroleum systems information, including the statistical evaluation of the analytical data by basin across the Australian continent. <b>Value: </b>These data in the ORGCHEM database tables comprise the raw organic geochemistry, organic petrological and stable isotopic values generated for Australian source rocks, crude oils and natural gases and is the only public comprehensive database at the national scale. The raw data are used as input values to other studies, such as basin analysis, petroleum systems evaluation and modelling, resource assessments, enhanced oil recovery projects, and national mapping projects. Derived datasets and value-add products are created based on calculated values and interpretations to provide information on the subsurface petroleum prospectivity of the Australian continent, as summarised in the Petroleum Systems Summary database. The data collection aspires to build a national scale understanding of Australia's petroleum and hydrogen resources. This data collection is useful to government for evidence-based decision making on sediment-hosted energy resources and the energy industry for de-risking both conventional and unconventional hydrocarbon exploration programs, hydrogen exploration programs, and carbon capture, utilisation and storage programs. <b>Scope: </b>The database initially comprised organic geochemical and organic petrological data on organic-rich sedimentary rocks, crude oils and natural gas samples sourced from petroleum wells drilled in the onshore and offshore Australian continent, including those held in the Australian National Offshore Wells Data Collection. Over time, other sample types (e.g., fluid inclusions, mineral veins, bitumen) from other borehole types (e.g., minerals, stratigraphic including the Integrated Ocean Drilling Program, and coal seam gas), marine dredge samples and field sites (outcrop, mines, surface seepage samples, coastal bitumen strandings) have been analysed for their molecular and stable isotopic chemical compositions and are captured in the databases. The organic geochemical database tables and derivative data compiled in the Petroleum Systems Summary database are delivered by web services and analytical tools in the <a href="https://portal.ga.gov.au/">Geoscience Australia Data Discovery Portal </a> and specifically in the <a href="https://portal.ga.gov.au/persona/sra">Source Rock and Fluid Atlas Persona</a>. These web services enable interrogation of source rock and petroleum fluids data within boreholes and from field sites and facilitate correlation of these elements of the petroleum system within and between basins. <b>Reference</b> Edwards, D.S., Buckler, T., Grosjean, E. & Boreham, C.J. 2024. Organic Geochemistry (ORGCHEM) Database. Australian Source Rock and Fluid Atlas. Geoscience Australia, Canberra. https://pid.geoscience.gov.au/dataset/ga/149422 Edwards, D., Hawkins, S., Buckler, T., Cherukoori, R., MacFarlane, S., Grosjean, E., Sedgmen, A., Turk, R. 2023. Petroleum Systems Summary database. Geoscience Australia, Canberra. https://dx.doi.org/10.26186/148979 Edwards, D.S., MacFarlane, S., Grosjean, E., Buckler, T., Boreham, C.J., Henson, P., Cherukoori, R., Tracey-Patte, T., van der Wielen, S.E., Ray, J., Raymond, O. 2020. Australian source rocks, fluids and petroleum systems – a new integrated geoscience data discovery portal for maximising data potential. Geoscience Australia, Canberra. http://dx.doi.org/10.11636/133751.
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NDI Carrara 1 is a deep stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-Basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) recently acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1120 m of Proterozoic sedimentary rocks unconformably overlain by 630 m of Cambrian Georgina Basin carbonates. Continuous cores recovered from 283 m to a total depth of 1750 m provide samples of the highest quality for a comprehensive geochemical program designed to inform on the energy and mineral prospectivity of the Carrara Sub-basin. Total Organic Carbon (TOC) contents from Rock-Eval pyrolysis of the Cambrian and Proterozoic sections demonstrate the potential for several thick black shales as source rocks and unconventional plays. Evidence for retained hydrocarbons included bituminous oil stains in centimetre-scale vugs within the Cambrian Georgina Basin and several oil bleeds within the Proterozoic section. The latter also contains surface gas with up to 2% methane concentrations measured within carbonaceous mudstones. Geochemical analyses of hydrocarbon shows highlight the occurrence of several petroleum systems operating in this frontier region. The results at NDI Carrara 1 offer the promise of a new exciting resource province in northern Australia.
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This presentation describes source rock data in addition to new compositional and stable isotopic data for 17 oils and six gases from the Amadeus Basin, central Australia. All data was analysed and interpreted by Geoscience Australia. The results of this study provide new insights into the origin and preservational history of hydrocarbons in the basin and provide a platform for future research directions.
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The hydrocarbon generative potential and the thermal maturity of source rocks in the offshore northern Perth Basin was reassessed based on existing and new geochemical data to get a better understanding of the basin's prospectivity. The study establishes for the first time that the main source of onshore accumulations, the Late Permian-Early Triassic Hovea Member, is well developed offshore and contains organic-rich sediments of oil-prone character. This finding shatters the long-held view that the Hovea Member was either absent or of poor quality offshore and provides a new perspective on the basin's prospectivity. The source potential of the Hovea Member varies spatially with best source rocks observed in the Beagle Ridge and Central Abrolhos Sub-basin. The Late Permian Irwin River Sequence and several Jurassic Sequences are also identified as prime potential source rocks offshore, mostly for their gas-generative potential. Oil-generative potential was identified in the Middle to Late Jurassic Yarragadee Sequence and possibly in the Middle Jurassic Cadda Sequence.
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<div>The Birrindudu Basin is a region of focus for the second phase of the Geoscience Australia’s Exploring for the Future (EFTF) program (2020–2024). The Paleo to Mesoproterozoic Birrindudu Basin is an underexplored frontier basin located in northwestern Northern Territory and northeastern Western Australia. Interpretation of industry seismic data indicates it contains strata of similar age to the prospective McArthur Basin, South Nicholson region and Mount Isa Province, but remains comparatively poorly understood. Furthermore, much of the age of the stratigraphy of the Birrindudu Basin, particularly the younger stratigraphic units, and regional correlations to the greater McArthur Basin remains provisional and speculative. </div><div><br></div><div>This report presents data from Rock-Eval pyrolysis analyses undertaken by Geoscience Australia on selected rock samples to establish their total organic carbon content, hydrocarbon-generating potential and thermal maturity from 178 drill core samples from six drill holes intersecting units of the Birrindudu Basin including: 99VRNTGSDD1, 99VRNTGSDD2, WLMB001B, LBD2, LMDH4, and ANT003. </div><div><br></div>
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This database contains geochemical data for samples analysed both for inorganic and organic geochemistry. Analytical data are sourced from Geoscience Australia's Inorganic Geochemistry Database (OZCHEM) and Organic Geochemistry Database (ORGCHEM), respectively. The data are joined on a unique sample number. Inorganic geochemical data cover the majority of the periodic table, with metadata on analytical methods and detection limits. Organic geochemical data include results of pyrolysis, derivative calculated values, and, where available, isotopic composition of carbonates (D13C) and isotopic composition of rock nitrogen (D15N). Further, there are provisions for delivery of isotopic data for kerogen (H, C, N) and oxygen (O) for carbonates. Where available, sample descriptions include stratigraphic unit names and ages, and lithology. Location information includes coordinates of the sampled feature (eg, borehole), coordinates of the sample and sample depth. Interpretation of the combined inorganic and organic geochemistry for organic-rich shales will facilitate comprehensive characterisation of hydrocarbons source rocks and mineral commodities source and trap environments. All are achieved within the frameworks of petroleum and mineral systems analysis. The initial data delivered by this service include 1785 samples from 35 boreholes from 14 geological provinces, including recently released data for 442 samples from the South Nicholson National Drilling Initiative Carrara 1 stratigraphic drill hole (Butcher et al., 2021; Carson et al., 2021). Many sampled boreholes are located within the polygon of the Exploring for the Future Barkly-Isa-Georgetown project. This dataset will be updated periodically as more data become available.
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The Browse Basin, located offshore on Australia's North West Shelf, contains major natural gas accumulations, some of which present high abundances of helium. The basin also contains large quantities of CO2 with some wells containing up to ~18 mol% CO2. Currently there is no information as to the origins of He and CO2 within the Browse Basin, despite this providing important information to the evolution of the natural gas. By understanding where components of the gas originate, it is possible to make predictions about areas that may be high in CO2, which would be problematic for production; conversely areas rich in He could present a second revenue stream from the same well.
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In 2014, the surprise discovery of oil in the well Phoenix South 1 on Australia’s North West Shelf (NWS) heralded the Bedout Sub-basin as Australia’s new petroleum province. The well had initially targeted gas in Triassic reservoirs of the Keraudren Formation and Locker Shale but unexpectedly encountered oil instead. This has fuelled a revival of exploration in the area with subsequent wells Roc 1, Roc 2, Phoenix South 2 and Dorado 1 all successful in penetrating hydrocarbon columns. The Phoenix South 1 accumulation is significant as it demonstrates the occurrence of an effective oil-prone source rock within the Lower–Middle Triassic for the first time on the NWS. It also raised the possibility that a source rock analogue to the Hovea Member of the Lopingian–Lower Triassic Kockatea Shale, a well-established source of oil and gas in the northern Perth Basin, may also be effective on the NWS. In order to understand the origin of the Phoenix South 1 accumulation, its geochemical composition was compared to those of Triassic-sourced oils from the Perth Basin and petroleum fluids from the neighbouring Browse Basin, and Beagle and Dampier sub-basins.
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<p>The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the North West Margin Energy Studies Section (NWMES). This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. <p>The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018) and Dorado 1 (2018) in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata. The current study aims to better understand this new petroleum system and establish its extent. <p>As part of this program, compositional and isotopic analyses were undertaken by Geoscience Australia on gas samples from the wells Roc 1 and Roc 2 and data from these analyses are released in this dataset.