Petroleum geochemical datasets and information are essential to government for evidence-based decision making on natural resources, and to the petroleum industry for de-risking exploration. Geoscience Australia’s newly built Data Discovery Portal (https://portal.ga.gov.au/) enables digital discoverability and accessibility to key petroleum geochemical datasets. The portal’s web map services and web feature services allow download and visualisation of geochemical data for source rocks and petroleum fluids, and deliver a petroleum systems framework for northern Australian basins. The Petroleum Source Rock Analytics Tool enables interrogation of source rock data within boreholes and field sites, and facilitates correlation of these elements of the petroleum system within and between basins. The Petroleum Systems Summary Assessment Tool assists the user to search and query components of the petroleum system(s) identified within a basin. The portal functionality includes customised data searches, and visualisation of data via interactive maps, graphs and geoscientific tools. Integration of the petroleum systems framework with the supporting geochemical data enables the Data Discovery Portal to unlock the value of these datasets by affording the user a one-stop access to interrogate the data. This allows greater efficiency and performance in evaluating the petroleum prospectivity of Australia’s sedimentary basins, facilitating and accelerating decision making around exploration investment to ensure Australia’s future resource wealth <b>Citation:</b> Edwards, D.S., MacFarlane, S.K., Grosjean, E., Buckler, T., Boreham, C.J., Henson, P., Cherukoori, R., Tracey-Patte, T., van der Wielen, S., Ray, J. and Raymond, O., 2020. Australian source rocks, fluids and petroleum systems – a new integrated geoscience data discovery portal for maximising data potential. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Systems Section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. As part of this program, molecular and isotopic analyses were undertaken by Geoscience Australia on gas samples from the well Dorado 1 and the raw data from these analyses are released in this report.

Although the Canning Basin has yielded minor gas and oil within conventional and unconventional reservoirs, the relatively limited geological data available in this under-explored basin hinder a thorough assessment of its hydrocarbon potential. Knowledge of the Paleozoic Larapintine Petroleum Supersystem is restricted by the scarcity of samples, especially recovered natural gases, which are limited to those collected from recent exploration successes in Ordovician and Permo-Carboniferous successions along the margins of the Fitzroy Trough and Broome Platform. To address this shortcoming, gases trapped within fluid inclusions were analysed from 121 Ordovician to Permian rock samples (encompassing cores, sidewall cores and cuttings) from 70 exploration wells with elevated mud gas readings. The molecular and carbon isotopic compositions of these gases have been integrated with gas compositions derived from open-file sources and recovered gases analysed by Geoscience Australia. Fluid inclusion C1–C5 hydrocarbon gases record a snapshot of the hydrocarbon generation history. Where fluid inclusion gases and recovered gases show similar carbon isotopes, a simple filling history is likely; where they differ, a multicharge history is evident. Since some fluid inclusion gases fall outside the carbon isotopic range of recovered gases, previously unidentified gas systems may have operated in the Canning Basin. Interestingly, the carbon isotopes of the fluid-inclusion heavy wet gases converge with the carbon isotopes of the light oil liquids, indicating potential for gas–oil correlation. A regional geochemical database incorporating these analyses underpins our re-evaluation of gas systems and gas–gas correlations across the basin. <b>Citation:</b> Boreham, C.J., Edwards, D.S., Sohn, J.H., Palatty, P., Chen, J.H. and Mory, A.J., 2020. Gas systems in the onshore Canning Basin as revealed by gas trapped in fluid inclusions. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

<b>Organic Geochemistry (ORGCHEM) Schema. Australian Source Rock and Fluid Atlas</b> The databases tables held within Geoscience Australia's Oracle Organic Geochemistry (ORGCHEM) Schema, together with other supporting Oracle databases (e.g., Borehole database (BOREHOLE), Australian Stratigraphic Units Database (ASUD), and the Reservoir, Facies and Shows (RESFACS) database), underpin the Australian Source Rock and Fluid Atlas web services and publications. These products provide information in an Australia-wide geological context on organic geochemistry, organic petrology and stable isotope data related primarily to sedimentary rocks and energy (petroleum and hydrogen) sample-based datasets used for the discovery and evaluation of sediment-hosted resources. The sample data provide the spatial distribution of source rocks and their derived petroleum fluids (natural gas and crude oil) taken from boreholes and field sites in onshore and offshore Australian provinces. Sample depth, stratigraphy, analytical methods, and other relevant metadata are also supplied with the analytical results. Sedimentary rocks that contain organic matter are referred to as source rocks (e.g., organic-rich shale, oil shale and coal) and the organic matter within the rock matrix that is insoluble in organic solvents is named kerogen. The data in the ORGCHEM schema are produced by a wide range of destructive analytical techniques conducted on samples submitted by industry under legislative requirements, as well as on samples collected by research projects undertaken by Geoscience Australia, state and territory geological organisations and scientific institutions including the Commonwealth Scientific and Industrial Research Organisation (CSIRO) and universities. Data entered into the database tables are commonly sourced from both the basic and interpretive volumes of well completion reports (WCR) provided by the petroleum well operator to either the state and territory governments or, for offshore wells, to the Commonwealth Government under the Offshore Petroleum and Greenhouse Gas Storage Act (OPGGSA) 2006 and previous Petroleum (submerged Lands) Act (PSLA) 1967. Data are also sourced from analyses conducted by Geoscience Australia’s laboratory and its predecessor organisations, the Australian Geological Survey Organisation (AGSO) and the Bureau of Mineral Resources (BMR). Other open file data from company announcements and reports, scientific publications and university theses are captured. The ORGCHEM database was created in 1990 by the BMR in response to industry requests for organic geochemistry data, featuring pyrolysis, vitrinite reflectance and carbon isotopic data (Boreham, 1990). Funding from the Australian Petroleum Cooperative Research Centre (1991–2003) enabled the organic geochemical data to be made publicly available at no cost via the petroleum wells web page from 2002 and included BOREHOLE, ORGCHEM and the Reservoir, Facies and Shows (RESFACS) databases. Investment by the Australian Government in Geoscience Australia’s Exploring for the Future (EFTF) program facilitated technological upgrades and established the current web services (Edwards et al., 2020). The extensive scope of the ORGCHEM schema has led to the development of numerous database tables and web services tailored to visualise the various datasets related to sedimentary rocks, in particular source rocks, crude oils and natural gases within the petroleum systems framework. These web services offer pathways to access the wealth of information contained within the ORGCHEM schema. Web services that facilitate the characterisation of source rocks (and kerogen) comprise data generated from programmed pyrolysis (e.g., Hawk, Rock-Eval, Source Rock Analyser), pyrolysis-gas chromatography (Py-GC) and kinetics analyses, and organic petrological studies (e.g., quantitation of maceral groups and organoclasts, vitrinite reflectance measurements) using reflected light microscopy. Collectively, these data are used to establish the occurrence of source rocks and the post-burial thermal history of sedimentary basins to evaluate the potential for hydrocarbon generation. Other web services provide data to characterise source rock extracts (i.e., solvent extracted organic matter), fluid inclusions and petroleum (e.g., natural gas, crude oil, bitumen) through the reporting of their bulk properties (e.g., API gravity, elemental composition) and molecular composition using gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). Also reported are the stable isotope ratios of carbon, hydrogen, nitrogen, oxygen and sulfur using gas chromatography-isotope ratio mass spectrometry (GC-IRMS) and noble gas isotope abundances using ultimate high-resolution variable multicollection mass spectrometry. The stable isotopes of carbon, oxygen and strontium are also reported for sedimentary rocks containing carbonate either within the mineral matrix or in cements. Interpretation of these data enables the characterisation of petroleum source rocks and identification of their derived petroleum fluids, which comprise two key elements of petroleum systems analysis. Understanding a fluid’s physical properties and molecular composition are prerequisites for field development. The composition of petroleum determines its economic value and hence why the concentration of hydrocarbons (methane, wet gases, light and heavy oil) and hydrogen, helium and argon are important relative to those of nitrogen, carbon dioxide and hydrogen sulfide for gases, and heterocyclic compounds (nitrogen, oxygen or sulfur) found in the asphaltene, resin and polar fractions of crude oils. The web services and tools in the Geoscience Australia Data Discovery Portal (https://portal.ga.gov.au/), and specifically in the Source Rock and Fluid Atlas Persona (https://portal.ga.gov.au/persona/sra), allow the users to search, filter and select data based on various criteria, such as basin, formation, sample type, analysis type, and specific geochemical parameters. The web map services (WMS) and web feature services (WFS) enable the user to download data in a variety of formats (csv, Json, kml and shape file). The Source Rock and Fluid Atlas supports national resource assessments. The focus of the atlas is on the exploration and development of energy resources (i.e., petroleum and hydrogen) and the evaluation of resource commodities (i.e., helium and graphite). Some data held in the ORGCHEM tables are used for enhanced oil recovery and carbon capture, storage and utilisation projects. The objective of the atlas is to empower people to deliver Earth science excellence through data and digital capability. It benefits users who are interested in the exploration and development of Australia's energy resources by: • Providing a comprehensive and reliable source of information on the organic geochemistry of Australian source rocks • Enhancing the understanding of the spatial distribution, quality, and maturity of petroleum source rocks. • Facilitating the mapping of total petroleum and hydrogen systems and the assessment of the petroleum and hydrogen resource potential and prospectivity of Australian basins. • Facilitating the mapping of gases (e.g., methane, helium, carbon dioxide) within the geosphere as part of the transition to clean energy. • Enabling the integration and comparison of data from diverse sources and various acquisition methods, such as geological, geochemical, geophysical and geospatial data. • Providing data for integration into enhanced oil recovery and carbon capture, storage and utilisation projects. • Improving the accessibility and usability of data through user-friendly and interactive web-based interfaces. • Promoting the dissemination and sharing of data among Government, industry and community stakeholders. <b>References</b> Australian Petroleum Cooperative Research Centre (APCRC) 1991-2003. Australian Petroleum CRC (1991 - 2003), viewed 6 May 2024, https://www.eoas.info/bib/ASBS00862.htm and https://www.eoas.info/biogs/A001918b.htm#pub-resources Boreham, C. 1990. ORGCHEM Organic geochemical database. BMR Research Newsletter 13. Record 13:10-10. Geoscience Australia, Canberra. https://pid.geoscience.gov.au/dataset/ga/90326 Edwards, D.S., MacFarlane, S., Grosjean, E., Buckler, T., Boreham, C.J., Henson, P., Cherukoori, R., Tracey-Patte, T., van der Wielen, S.E., Ray, J., Raymond, O. 2020. Australian source rocks, fluids and petroleum systems – a new integrated geoscience data discovery portal for maximising data potential. Geoscience Australia, Canberra. http://dx.doi.org/10.11636/133751. <b>Citation</b> Edwards, D., Buckler, T. 2024. Organic Geochemistry (ORGCHEM) Schema. Australian Source Rock and Fluid Atlas. Geoscience Australia, Canberra. https://pid.geoscience.gov.au/dataset/ga/149422

<p>The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the North West Margin Energy Studies Section (NWMES). This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. <p>The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018) and Dorado 1 (2018) in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata. The current study aims to better understand this new petroleum system and establish its extent. <p>As part of this program, TOC and Rock-Eval pyrolysis analyses were undertaken by Geoscience Australia on selected rock samples from the well Roc 2 to establish their hydrocarbon-generating potential and thermal maturity.

Geoscience Australia currently uses two commercial petroleum system modelling software packages, PetroMod https://www.software.slb.com/products/petromod and Zetaware http://www.zetaware.com, to undertake burial and thermal history modelling on wells in Australian sedimentary basins. From the integration of geological (age-based sedimentary packages, uplift and erosional events), petrophysical (porosity, permeability, and thermal conductivity) and thermal (downhole temperature, heat flow, vitrinite reflectance, and Tmax) input data, to name the most significant, a best-fit model of the time-temperature history is generated. Since the transformation of sedimentary organic matter (kerogen) into petroleum (oil and gas) is a chemical reaction, it is governed by chemical kinetics i.e. time and temperature (in the geological setting, pressure is of secondary importance). Thus, the use of chemical kinetics associated with a formation-specific, immature potential source rock (where available) from the basin of interest is considered a better practical approach rather than relying on software kinetic defaults, which are generally based on the chemical kinetics determined experimentally on Northern Hemisphere organic matter types. As part of the Offshore Energy Systems program hydrocarbons from the Lower Cretaceous Eumeralla Formation were selected where available from onshore wells; compositional kinetics (1-, 2-, 4- and 14-component (phase) kinetics) were undertaken by GeoS4, Germany. The phase kinetics approach is outlined in Appendix 1. This report provides the compositional kinetics for potential source rocks from the Lower Cretaceous Otway Group, Otway Basin, Australia. The kinetic data were used in the offshore petroleum system modelling reported in Schenk et al. (2021).

<div>NDI Carrara 1 is a deep stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1120 m of Proterozoic sedimentary rocks unconformably overlain by 630 m of Georgina Basin carbonates.&nbsp;</div><div>Geoscience Australia has undertaken a range of investigations on the lithology, stratigraphy and geotechnical properties of NDI Carrara 1 as well as undertaking a range of analyses of about 500 physical samples recovered through the entire core. Analyses included geochronology, isotope studies, mineralogy, inorganic and organic geochemistry, petrophysics, geomechanics, thermal maturity and petroleum systems investigations.</div><div>Rock-Eval pyrolysis raw data undertaken by Geoscience Australia were reported in Butcher et al. (2021) on selected rock samples to establish their total organic carbon content, hydrocarbon-generating potential and thermal maturity. Interpretation of the Rock-Eval pyrolysis data concluded that a large portion of rocks within the Proterozoic section displayed unreliable Tmax values due to poorly defined S2 peaks resulting from high thermal maturity and low hydrogen content. In order to obtain more reliable Tmax values, Rock-Eval pyrolysis of selected isolated kerogens, where organic matter is concentrated and mineral matrix effects are removed, were conducted and the resulting data are presented in this report.&nbsp;</div><div><br></div>

<b>IMPORTANT NOTICE:</b> This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to a subset of Australian geoscience samples data held by Geoscience Australia. The subset currently relates specifically to Australian Boreholes.

<div>The Paleo- to Mesoproterozoic Birrindudu Basin is an underexplored frontier basin straddling the Northern Territory and Western Australia and is a region of focus for the second phase of Geoscience Australia’s Exploring for the Future (EFTF) program (2020–2024). Hydrocarbon exploration in the Birrindudu Basin has been limited and a thorough assessment of the basin's petroleum potential is lacking due to the absence of data in the region. To fill this data gap, a comprehensive analytical program including organic petrology, programmed pyrolysis and oil fluid inclusion analysis was undertaken on cores from six drill holes to improve the understanding of the basin’s source rock potential and assess petroleum migration. Organic petrological analyses reveal that the primary maceral identified in the cores is alginite mainly originating from filamentous cyanobacteria, while bitumen is the most common unstructured secondary organic matter. New reflectance data based on alginite and bitumen reflectance indicate the sampled sections have reached a thermal maturity suitable for hydrocarbon generation. Oil inclusion analyses provide evidence for oil generation and migration, and hence elements of a petroleum system are present in the basin. Presented at the Australian Energy Producers (AEP) Conference & Exhibition (https://energyproducersconference.au/conference/)

<div>Throughout geological history, marine organic-rich shales show variable but appreciable enrichment in uranium (U), < 5 to > 500 ppm. Here we report the results of high-energy resolution fluorescence detection (HERFD) x-ray absorption spectroscopy at U L3 and M4 edges to characterize U speciation in marine sediments.</div><div><br></div><div>We characterised U oxidation state in samples from the Cretaceous Toolebuc Formation of the Eromanga Basin, Australia. Nine samples were carbonaceous shales with high total organic carbon (TOC) content of 5.9 to 13.4 wt&nbsp;% and with low maturity organic matter. Two samples of coquinite were selected for comparison (TOC 0.3 and 2.4 wt %).</div><div><br></div><div>Our results suggest that a significant proportion of U in marine black shales (~20 to 30%) exists as U(VI) (Figures 1-2), despite the extremely reducing (anoxic to euxinic) conditions during sediment precipitation and diagenesis. Within individual samples, spot analyses indicate variation in the estimated oxidation state within a range of ~20% of U(VI). Uranium is unevenly distributed at mm to nanoscale. Nanoscale secondary ion mass spectrometry (NanoSIMS) reveals different associations that often coexist in single samples; nano-particulate uranium is associated with organic matter matrix or sulphide minerals, whereas phosphate minerals display diffuse uranium enrichment. The coquinite has a higher proportion of U(VI), consistent with the dysoxic depositional environment (Boreham and Powell, 1987).</div><div><br></div><div>The unexpectedly enhanced proportion of U(VI) relative to U(IV) within marine organic-rich shales implies that U might not be immediately fixed by reduction processes during sedimentation, but adsorbed by accumulating organic matter, at least in part as U(VI). This is consistent with the behaviour of uranium reported within the water column of the anoxic Black Sea (Anderson, 1989), experiments on U(VI) sorption by organic matter (e.g., Bhat et al., 2008), and previously documented redox state of U from continental organic-rich Eocene (56-34 Ma) sediments of paleochannel and lacustrine origin (Cumberland et al., 2018).</div><div><br></div><div>The results are significant for improving hydrocarbon exploration in known fields (covering the gap to a carbon-free economy without development of new greenfield oil provinces); economic geology (uranium, base-metal, and critical-metal deposits); and environmental management (evaluating potential mobilization of U by groundwaters).</div><div><br></div>This Abstract was submitted and presented to the 2023 Goldschmidt Conference Lyon, France (https://conf.goldschmidt.info/goldschmidt/2023/meetingapp.cgi)