<div>An Isotopic Atlas of Australia provides a convenient visual overview of age and isotopic patterns reflecting geological processes that have led to the current configuration of the Australian continent, including progressive development of continental crust from the mantle. This poster provides example maps produced from compiled data of multiple geochronology and isotopic tracer datasets from this Isotopic Atlas.&nbsp;It is also a promotion for the release of the Victorian and Tasmanian age compilation datasets (Waltenbeg et al., 2021; Jones et al., 2022).</div>

<div>Magmatic arcs represent a critical source of modern civilisation’s mineral wealth, with their importance only enhanced by the ongoing global transition to a low-carbon society. The ~830-495 Ma Delamerian Orogen, formed at Australia’s eastern cratonic margin, represents rocks ascribed to rift/passive-margin, convergent margin arc, orogenic, and post-orogenic settings. However, poor exposure has limited exploration activity across much of the orogen, despite demonstrated potential for numerous mineral systems. To address this issue, an orogen-wide zircon Hf-O isotope and trace element survey was performed on 55 magmatic samples to constrain the crustal architecture, evolution, and fertility of the Delamerian Orogen, and in turn map parameters that can be used as a guide to mineral potential. These new data define two broad magmatic episodes at: (1) ~585-480 Ma, related to rift/passive margin, convergent arc, orogenic, and post-orogenic activity (Delamerian Cycle); and (2) magmatism associated with the ~490-320 Ma Lachlan Orogen, with peaks at ~420 Ma (onshore, Tabberabberan Cycle) and ~370 Ma (western Tasmania). Isotopic and geochemical mapping of these events show that the ~585-480 Ma Delamerian Cycle has significant orogen-wide variation in magmatic Hf-O isotopes and oxidation-state, suggesting a spatial variation in the occurrence and type of potential mineral systems. The ~420 Ma magmatic event involved predominantly mantle-like Hf-O and oxidised magmatism, whilst the ~370 Ma magmatism shows opposing features. In general, The potential to host Cu-Au porphyry and VMS mineralisation (e.g., Stavely, Koonenberry) is present, but restricted, whereas signatures favourable for Sn-W granite-hosted systems (e.g., Tasmania), are more common. These new data constrain time-space variations in magma composition that provide a valuable geological framework for mineral system fertility assessments across the Delamerian Orogen. Furthermore, these data and associated maps can used to assess time-space mineral potential and facilitate more effective exploration targeting in this covered region.</div> <b>Citation:</b> Mole, D., Bodorkos, S., Gilmore, P.J., Fraser, G., Jagodzinski, E.A., Cheng, Y., Clark, A.D., Doublier, M., Waltenberg, K., Stern, R.A., Evans, N.J., 2023. Architecture, evolution and fertility of the Delamerian Orogen: Insights from zircon. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, <a href+"https://dx.doi.org/10.26186/148981">https://dx.doi.org/10.26186/148981</a>

<div>A regional hydrocarbon prospectivity assessment has been undertaken of the offshore Otway Basin by the Offshore Energy Systems Section. This program was designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the offshore Otway Basin and attract exploration investment to Australia. The inboard part of the basin is an established hydrocarbon province with onshore and shallow-water offshore discoveries, whereas the outboard deep-water region, where water depths range from 500 to 6300&nbsp;m, is comparatively underexplored and considered a frontier area.</div><div><br></div><div>As part of this program, molecular and noble gas isotopic analyses were undertaken by Smart Gas Sciences, under contract to Geoscience Australia on available gas samples from the Waarre Formation in the Shipwreck Trough in the offshore eastern Otway Basin, with data from these analyses being released in this report. This report provides additional compositional information for gases in the Waarre Formation reservoirs and builds on previously established gas-gas correlations and gas-oil correlations. Noble gas isotopic data can be used in conjunction with carbon and hydrogen isotopic data to determine the origin of both inorganic and organic (hydrocarbon) gases. This information can be used in future geological programs to determine the source and distribution of hydrogen and helium in natural gases and support acreage releases by the Australian Government.</div><div><br></div><div><br></div>

<div>The noble gas database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for molecular and noble gas isotopic analyses on natural gases sampled from boreholes and fluid inclusion gases from rocks sampled in boreholes and field sites. Data includes the borehole or field site location, sample depths, shows and tests, stratigraphy, analytical methods, other relevant metadata, and the molecular and noble gas isotopic compositions for the natural gas samples. The molecular data are presented in mole percent (mol%) and cubic centimetres (at Standard Pressure and Temperature) per cubic centimetre (ccSTP/cc). The noble gas isotopic values that can be measured are; Helium (He, ³He, ⁴He), Neon (Ne, ²⁰Ne, ²¹Ne, ²²Ne), Argon (Ar, ³⁶Ar, ³⁸Ar, ⁴⁰Ar), Krypton (Kr, ⁷⁸Kr, ⁸⁰Kr, ^82<Kr, ⁸³Kr, ⁸⁴Kr, ⁸⁶Kr) and Xenon (Xe, ¹²⁴Xe, ¹²⁶Xe, ¹²⁸Xe, ¹²⁹Xe, ¹³⁰Xe, ¹³¹Xe, ¹³²Xe, ¹³⁴Xe, ¹³⁶Xe) which are presented in cubic micrometres per cubic centimetre (mcc/cc), cubic nanometres per cubic centimetre (ncc/cc) and cubic picometres per cubic centimetre (pcc/cc). Acquisition of the molecular compounds are by gas chromatography (GC) and the isotopic ratios by mass spectrometry (MS). Compound concentrations that are below the detection limit (BDL) are reported as the value -99999.</div><div><br></div><div>These data provide source information about individual compounds in natural gases and can elucidate fluid migration pathways, irrespective of microbial activity, chemical reactions and changes in oxygen fugacity, which are useful in basin analysis with derived information being used to support Australian exploration for energy resources and helium. These data are collated from Geoscience Australia records and well completion reports. The noble gas data for natural gases and fluid inclusion gases are delivered in the Noble Gas Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div><div><br></div><div><br></div>

<div>Historically, isotopic data are collected at the individual sample level on local- to regional-scale features and are dispersed among decades of both published and unpublished individual academic literature, university theses and geological survey reports, in disparate formats and with widely varying levels of detail. Consequently, it has been difficult to visualise or interrogate the collective value of age and isotopic data at continental-scale. Geoscience Australia’s (GA) continental-scale Isotopic Atlas of Australia (Fraser et al., 2020), breaks this cycle of single-use science by compiling and integrating <strong>multiple radiometric age and isotopic tracer datasets</strong> and making them publicly accessible and useable through GA’s Exploring for the Future (EFTF) Portal.</div><div><br></div><div>The first iteration of a continental-scale Isotopic Atlas of Australia was introduced by Geoscience Australia at the 2019 SGGMP conference in Devonport, Tasmania, through a talk and poster display. In the three years since, progress on this Isotopic Atlas has continued and expanded datasets are now publicly available and downloadable via Geoscience Australia’s Exploring for the Future (EFTF) Geochronology and Isotopes Data Portal.&nbsp;</div>

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa), with a few additional Northern Australia Geochemical Survey infill samples. The present study targeted the northern parts of Western Australia, the Northern Territory and Queensland in Australia, north of 21.5 °S. The samples were taken mostly from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (&lt;2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 &lt; 87Sr/86Sr &lt; 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (&gt;100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a &gt;500 km-long northwest-southeast-trending low anomaly (87Sr/86Sr &lt; 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, conversely, high 87Sr/86Sr values (&gt; 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape and model derived therefrom can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations. &nbsp;The new spatial dataset is publicly available through the Geoscience Australia portal https://portal.ga.gov.au/.</div>

<div>Lithospheric and crustal architecture — the framework of major tectonic blocks, terranes and their boundaries — represents a fundamental first-order control on major geological systems, including the location of world-class mineral camps. Traditionally, lithospheric and crustal architecture are constrained using predominantly geophysical methods. However, Champion and Cassidy (2007) pioneered the use of regional Sm–Nd isotopic data from felsic igneous rocks to produce isotopic contour maps of the Yilgarn Craton, demonstrating the effectiveness of ‘isotopic mapping’, and the potential to map ‘time-constrained’ crustal architecture. Mole et al. (2013) demonstrated the association between lithospheric architecture and mineral systems, highlighting the potential of isotopic mapping as a greenfield area selection tool. Additional work, using Lu-Hf isotopes (Mole et al., 2014), demonstrated that the technique could constrain a range of temporal events via ‘time-slice mapping’, explaining how Ni-Cu-PGE mineralized komatiite systems migrated with the evolving lithospheric boundary of the Yilgarn Craton from 2.9 to 2.7 Ga. Similar studies have since been conducted in West Africa (Parra-Avila et al., 2018), Tibet (Hou et al., 2015), and Canada (Bjorkman, 2017; Mole et al., 2021; 2022). This work continues in Geoscience Australia’s $225 million Exploring for the Future program (2016-present). Isotopic mapping, which forms an integral part of a combined geology-geophysics-geochemistry approach, is currently being applied across southeast Australia, covering the eastern Gawler Craton, Delamerian Orogen, and western Lachlan Orogen, encompassing more than 3 Gyrs of Earth history with demonstrable potential for large mineral systems.</div><div> <b>Reference(s):</b></div><div> Bjorkman, K.E., 2017. 4D crust-mantle evolution of the Western Superior Craton: Implications for Archean granite-greenstone petrogenesis and geodynamics. University of Western Australia, PhD Thesis, 134 pp.</div><div> Champion, D.C. and Cassidy, K.F., 2007. An overview of the Yilgarn Craton and its crustal evolution. In: F.P. Bierlein and C.M. Knox-Robinson (Editors), Proceedings of Geoconferences (WA) Inc. Kalgoorlie '07 Conference. Geoscience Australia Record 2007/14, Kalgoorlie, Western Australia, pp. 8-13.</div><div> Hou, Z., Duan, L., Lu, Y., Zheng, Y., Zhu, D., Yang, Z., Yang, Z., Wang, B., Pei, Y., Zhao, Z. and McCuaig, T.C., 2015. Lithospheric architecture of the Lhasa terrane and its control on ore deposits in the Himalayan-Tibetan orogen. Economic Geology, 110(6): 1541-1575.</div><div> Mole, D.R., Fiorentini, M.L., Cassidy, K.F., Kirkland, C.L., Thebaud, N., McCuaig, T.C., Doublier, M.P., Duuring, P., Romano, S.S., Maas, R., Belousova, E.A., Barnes, S.J. and Miller, J., 2013. Crustal evolution, intra-cratonic architecture and the metallogeny of an Archaean craton. Geological Society, London, Special Publications, 393: pp. 23-80.</div><div> Mole, D.R., Fiorentini, M.L., Thebaud, N., Cassidy, K.F., McCuaig, T.C., Kirkland, C.L., Romano, S.S., Doublier, M.P., Belousova, E.A., Barnes, S.J. and Miller, J., 2014. Archean komatiite volcanism controlled by the evolution of early continents. Proceedings of the National Academy of Sciences, 111(28): 10083-10088.</div><div> Mole, D.R., Thurston, P.C., Marsh, J.H., Stern, R.A., Ayer, J.A., Martin, L.A.J. and Lu, Y., 2021. The formation of Neoarchean continental crust in the south-east Superior Craton by two distinct geodynamic processes. Precambrian Research, 356: 106104.</div><div> Mole, D.R., Frieman, B.M., Thurston, P.C., Marsh, J.H., Jørgensen, T.R.C., Stern, R.A., Martin, L.A.J., Lu, Y.J. and Gibson, H.L., 2022. Crustal architecture of the south-east Superior Craton and controls on mineral systems. Ore Geology Reviews, 148: 105017.</div><div> Parra-Avila, L.A., Belousova, E., Fiorentini, M.L., Eglinger, A., Block, S. and Miller, J., 2018. Zircon Hf and O-isotope constraints on the evolution of the Paleoproterozoic Baoulé-Mossi domain of the southern West African Craton. Precambrian Research, 306: 174-188.</div><div> This Abstract was submitted/presented to the Target 2023 Conference 28 July (https://6ias.org/target2023/)

<div>The Yilgarn Craton of Western Australia represents one of the largest pieces of Precambrian crust on Earth, and a key repository of information on the Meso-Neoarchean period. Understanding the crustal, tectonic, thermal, and chemical evolution of the craton is critical in placing these events into an accurate geological context, as well as developing holistic tectonic models for the Archean Earth. In this study, we collected a large U-Pb (420 collated samples) and Hf isotopic (2163 analyses) dataset on zircon to investigate the evolution of the craton. These data provide strong evidence for a Hadean-Eoarchean origin for the Yilgarn Craton from mafic crust at ca. 4000 Ma. This ancient cratonic nucleus was subsequently rifted, expanded and reworked by successive crustal growth events at ca. 3700 Ma, ca. 3300 Ma, 3000-2900 Ma, 2825-2800 Ma, and ca. 2730-2620 Ma. The <3050 Ma crustal growth events correlate broadly with known komatiite events, and patterns of craton evolution, revealed by Hf isotope time-slice mapping, image the periodic break-up of the Yilgarn proto-continent and the formation of rift-zones between the older crustal blocks. Crustal growth and new magmatic pulses were focused into these zones and at craton margins, resulting in continent growth via internal (rift-enabled) expansion, and peripheral (crustal extraction at craton margins) magmatism. Consequently, we interpret these major geodynamic processes to be analogous to plume-lid tectonics, where the majority of tonalite-trondhjemite-granodiorite (TTG) felsic crust, and later granitic crust, was formed by reworking of hydrated mafic rocks and TTGs, respectively, via a combination of infracrustal and/or drip-tectonic settings. While this process of crust formation and evolution is not necessarily restricted to a specific geodynamic system, we find limited direct evidence that subduction-like processes formed a major tectonic component, aside from re-docking the Narryer Terrane to the craton at ca. 2740 Ma. Overall, these 'rift-expansion' and 'craton margin' crustal growth process led to an intra-cratonic architecture of younger, juvenile terranes located internal and external to older, long-lived, reworked crustal blocks. This framework provided pathways that localized later magmas and fluids, driving the exceptional mineral endowment of the Yilgarn Craton.</div> This Abstract/Poster was submitted to & presented at the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)

<div>Archean greenstone belts are a vital window into the tectonostratigraphic processes that operated in the early Earth and the geodynamics that drove them. However, the majority of greenstone belts worldwide are highly-deformed, complicating geodynamic interpretations. The volcano-sedimentary sequence of the 2775-2690 Ma Fortescue Group is different in that it is largely undeformed, offering a unique insight into the architecture of greenstone sequences. In the Fortescue magmatic rocks, geochemical signatures that in deformed belts in the Superior or Yilgarn Cratons might have been interpreted as arc-like, are explained by contamination of rift-related mantle and plume-derived magmas with Pilbara basement crust; understanding the wider geological and structural setting allows a more complete interpretation.</div><div> However, contamination of Fortescue magmas by an enriched sub-continental mantle lithosphere (SCLM) is an alternative hypothesis to the crustal contamination model. If demonstrated, the addition of sediments and fluids to the SCLM, required to form enriched/metasomaytised SCLM, would suggest active subduction prior to the Neoarchean. To test this hypothesis, we collected Hf-O isotopic data on zircons from felsic volcanic rocks throughout the Fortescue Group; if the contamination had a subducted sedimentary component (δ18O>20‰), then the O-isotopes should record a heavy signature.</div><div> The results show that the ca. 2775 Ma Mt Roe Formation has εHfi from 0 to -5.6, and δ18OVSMOW of +4.8- +0.3‰, with the majority of values <+3‰. The ca. 2765 Ma Hardey Formation (mostly sediments) has highly unradiogenic εHfi of -5 to -9.4, and δ18O of +7.8- +6.6‰. The ca. 2730 Ma Boongal Formation displays similar values as for Mt Roe, with εHfi +1.9 to -5.5 and δ18O +3.0 to -0.6‰. The ca. 2720 Ma Tumbiana Formation shows the greatest range in εHfi from +4.9 to -4.6, with δ18O +7.1- +0.7‰, with the majority between +4.5 and +2.5‰. Data from the 2715 Ma Maddina Formation are more restricted, with εHfi between +4.0 and -0.1, and δ18O +5.0- +3.8‰. The youngest formation, the 2680 Ma Jeerinah Formation, has εHfi +2.3 to -6.2, and δ18O +5.1 to -2.1‰.</div><div> Importantly, these data provide little evidence of a cryptic enriched SCLM source in the Fortescue magmas. Furthermore, the dataset contains some of the lightest δ18O data known for Archean zircon, highlighting a ca. 100 Myr period of high-temperature magma-water interaction, with long-term continental emergence implied by the trend to meteoric δ18O compositions. The exception to this is the Hardey Formation, which may have formed via crustal anatexis in a period of reduced heat-flow between the 2775-2665 and 2730-2680 Ma events. Data from the other formations show a broad trend of increasing δ18O and εHf from 2775 to 2680 Ma. We suggest this represents the effects of progressive cratonic rifting, allowing mantle-derived magmas to reach the surface less impeded, and also a decreasing role of meteoric water in the rift zone as the sea invades. As a result, the εHf and δ18O data from the Fortescue Group represent the evolving nature of an Archean rift zone, from an emergent volcanic centre, to a submarine environment.</div><div><br></div>This Abstract was submitted/presented to the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)

<div>Archean crustal evolution, and its tectonic paradigm, can be directly linked to the evolution of the mantle, the hydrosphere-atmosphere, oxygenation of the Earth, and the formation and storage of ore deposits. Hence, it is vital to understand the evolution of the early crust if we are to understand our planet’s evolution as well as transformational events in its history.</div><div> The collection of vast amounts of isotopic data, especially U-Pb, Sm-Nd, Lu-Hf, and δ18O, over the last 30 years, has significantly advanced our understanding of crustal processes and their timing. However, we rarely look at these data in a spatial context. This study aims to constrain the time-space evolution of the south-east Superior Craton, Canada, by mapping the zircon Hf-O isotopes and trace element data from 148 Archean magmatic rocks (6340 total analyses).</div><div> In Lu-Hf space, the dataset demonstrates the highly juvenile nature of this region, with the majority of values between εHfi +6 and +2. When plotted spatially, the most juvenile data (+4 to +6 εHfi) delineate an E-W oriented zone, broadly in-line and sub-parallel to the Cadillac-Larder Lake and Porcupine-Destor structures. Surrounding this juvenile region is less juvenile crust (0 to +3 εHf). Corresponding δ18O values show that light to mantle-like data (3.0-5.6‰) correlate with the most juvenile crust imaged by the εHf, with heavier δ18O (5.8-7.5‰) plotting to the south, east and west of this zone. Zircon trace element proxies for hydration (Eu/Eu*), oxidation (ΔFMQ using Ti, Ce, U), and continental vs. oceanic origin (Ui/Yb) replicate the pattern observed in the Lu-Hf and δ18O. This suggests that, broadly, the SE Superior consists of a central E-W orientated juvenile zone consisting of the most reduced, least hydrated, least continental, and most high-temperature hydrothermally-altered crust. This zone is surrounded by crust which is more hydrated, oxidised, has a greater supracrustal δ18O component, and is slightly less juvenile. The major ore systems of the Abitibi subprovince, including VMS, gold and komatiite-hosted Ni-Cu-PGE systems, fall within the E-W highly-juvenile zone.</div><div> Current tectonic models for this region of the Superior Craton range from (1) long-lived Neoarchean subduction across the whole Abitibi tectono-thermal ‘event’ (2750-<2695 Ma) – ‘horizontal’ tectonics; and (2) a variety of non-arc processes such as plume-related crustal overthickening (i.e., oceanic plateau), sagduction/drip tectonics, and subcretion, amongst others – ‘vertical’ tectonics. Models combining arc and non-arc processes have also been suggested (i.e., plume-arc interaction), and our data broadly support a combined model. We propose the E-W zone delineated by the various geochemical data represents a paleo-rift zone, driven by ambient mantle or mantle plume processes. The dry, reduced, oceanic character of the zone appears to preclude an arc or back-arc setting prior to ca. 2.7 Ga. However, temporal changes in hydration, oxidation, and the increased heavy δ18O component at ca. 2.7 Ga suggest a major geodynamic shift, potentially marking the onset of subduction and associated compression. This is contribution 2020-050 of the Mineral Exploration Research Centre (MERC) Metal Earth project.</div><div> This Abstract was submitted/presented to the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)