Australia's CO2CRC Otway Site hosts a carbon capture and storage (CCS) demonstration facility that has, to date, injected over 80,000 tonnes of CO2 into two separate geological reservoirs. The reservoir geology is well understood and the site has been the subject of several seismic investigations, though relatively little is known about the near-surface geology and how potential leaks from the injection wells would migrate, particularly within the Port Campbell Limestone. No shallow core has been taken from relevant petroleum wells or water bores, and although there is extensive exposure in the prominent sea cliffs, these are mostly inaccessible. In order to further define the structure and geology of the Port Campbell Limestone at the Otway site, a high-resolution, shallow focused, 3D seismic survey has recently been conducted. The assessment of the near-surface geology described in this paper was used to assist with planning the survey. Using available data, the Port Campbell Limestone is assessed as a series of laterally continuous intercalated limestone, marl, and marly limestones. Interpretation of three previously acquired 3D seismic surveys using a minimum similarity attribute demonstrates evidence for a shallow, steeply east-dipping fault striking approximately NNW-SSE directly below the Otway site. This is observed from approximately 100 m to 380 m depth below surface, where it appears to die out. In the shallow section, the fault is undetectable primarily due to low seismic resolution, and so it is unknown how shallow it propagates. Extrapolation of the fault to the surface projects to between the wells Naylor-1 and CRC-1. A recently acquired high-resolution 3D seismic survey over the study area will allow for this fault to be further delineated. Appeared in the Energy Procedia Journal, Volume 114, Pages 4424-4435, July 2017

Recent national and state assessments have concluded that sedimentary formations that underlie or are within the Great Artesian Basin (GAB) may be suitable for the storage of greenhouse gases. These same formations contain methane and naturally generated carbon dioxide that has been trapped for millions of years. The Queensland government has released exploration permits for Greenhouse Gas Storage in the Bowen and Surat basins. An important consideration in assessing the potential economic, environmental, health and safety risks of such projects is the potential impact CO2 migrating out of storage reservoirs could have on overlying groundwater resources. The risk and impact of CO2 migrating from a greenhouse gas storage reservoir into groundwater cannot be objectively assessed without knowledge of the natural baseline characteristics of the groundwater within these systems. Due to the phase behaviour of CO2, geological storage of carbon dioxide in the supercritical state requires depths greater than 800m, but there are no hydrochemical studies of such deeper aquifers in the prospective storage areas. Geoscience Australia (GA) and the Geological Survey of Queensland (GSQ), Queensland Department of Mines and Energy, worked collaboratively under the National Geoscience Agreement (NGA) to characterise the regional hydrochemistry of the Denison Trough and Surat Basin and trialled different groundwater monitoring strategies. The output from this Project constitutes part of a regional baseline reference set for future site-specific and semi-regional monitoring and verification programmes conducted by geological storage proponents. The dataset provides a reference of hydrochemistry for future competing resource users.

This study looks at the question of whether time-lapse gravity measurements could be used to monitor the density and geometry carbon dioxide plume in the ground for a typical Gippsland Basin reservoir. The considerations made indicate that gravity measurements would not be suitable as a means to detect carbon dioxide density, distribution and movement in a reservoir the size of the West Seahorse field. The maximum gravity anomaly that would be expected is calculated to be 1.4 -Gal, while the experience in other parts of the world, using sensitive sea floor gravity metres, indicate that at present this technology can resolve about 5 -Gal. Furthermore, the horizontal and vertical gradients of the maximum anomaly are of the order of 0.007 E ( 0.007 ?m/s2/km), while the most sensitive reported airship measurements of gravity gradient are reported to be resolving of the order of 1.7 E.

Australia has become the first country to offer commercial offshore acreage for the purpose of storing greenhouse gases in geological formations. Ten offshore areas in five basins/sub-basins are open for applications for Assessment Permits, which will allow exploration in those areas for suitable geological formations and conditions for storage of greenhouse gases (predominantly CO2). The acreage was released on the 27th March 2009 under the Offshore Petroleum and Greenhouse Gas Storage Act 2006. The acreage release is modelled on Australia's annual Offshore Petroleum Acreage Release; applicants can apply for an Assessment Permit for any of the ten areas, which is approximately equivalent to an exploration permit in petroleum terms. Applications will be assessed on a work-bid basis and other selection criteria outlined in the Regulations and Guidance Notes for Applicants. Following the assessment period, project proponents may apply for an injection license (equivalent to a production license in the petroleum industry) to inject and store greenhouse gas substances in the permit area. The areas offered in this first round of Acreage Release include five areas located within the Gippsland and Otway basins, offshore Victoria and South Australia, and the other five areas are located in the Vlaming and Petrel sub-basins, offshore Western Australia and the Northern Territory. The offshore areas offered for GHG geological storage assessment are significantly larger than their offshore petroleum counterparts to account for, and fully contain, the expected migration pathways of the injected GHG substances.

In mid 2011, the Australian Government announced funding of a new four year National CO2 Infrastructure Plan (NCIP) to accelerate the identification and development of sites suitable for the long term storage of CO2 in Australia that are within reasonable distances of major energy and industrial CO2 emission sources. The NCIP program promotes pre-competitive storage exploration and provides a basis for the development of transport and storage infrastructure. The Plan follows on from recommendations of the Carbon Storage Taskforce and the National CCS Council (formerly, the National Low Emissions Coal Council). It builds on the work funded under the National Low Emissions Coal Initiative and the need for adequate storage to be identified as a national priority. Geoscience Australia is providing strategic advice in delivering the plan and will lead in the acquisition of pre-competitive data and geological studies to assess storage potential. Four offshore sedimentary basins (Bonaparte, Browse, Perth and Gippsland basins) and several onshore basins have been identified for pre-competitive data acquisition and study.

Geoscience Australia and CO2CRC have constructed a greenhouse gas controlled release facility to simulate surface emissions of CO2 (and other greenhouse gases) from the soil into the atmosphere under controlled conditions. The facility is located at an experimental agricultural station maintained by CSIRO Plant Industry at Ginninderra, Canberra. The design of the facility is modelled on the ZERT controlled release facility in Montana. The facility is equipped with a 2.5 tonne liquid CO2 storage vessel, vaporiser and mass flow controller unit with a capacity for 6 individual metered CO2 gas streams (up to 600 kg/d capacity in total). Injection of CO2 into the soil is via a 120m long slotted HDPE pipe installed horizontally 2m underground. This is equipped with a packer system to partition the well into six CO2 injection chambers. The site is characterised by the presence of deep red and yellow podsolic soils with the subsoil containing mainly kaolinite and subdominant illite. Injection is above the water table. The choice of well orientation based upon the effects of various factors such as topography, wind direction, soil properties and ground water depth will be discussed. An above ground release experiment was conducted from July - October 2010 leading to the development of an atmospheric tomography technique for quantifying and locating CO2 emissions1. An overview of monitoring experiments conducted during the first subsurface release (January-March 2012), including application of the atmospheric tomography technique, soil flux surveys, microbiological surveys, and tracer studies, will be presented. Additional CO2 release experiments are planned for late 2012 and 2013. Poster presented at 11th Annual Conference on Carbon Capture Utilization & Sequestration, April 30 - May 3, 2012, Pittsburgh, Pennsylvania

The middle to lower Jurassic sequence in Australia's Surat Basin has been identified as a potential reservoir system for geological CO2 storage. The sequence comprises three major formations with distinctly different mineral compositions, and generally low salinity formation water (TDS<3000 mg/L). Differing geochemical responses between the formations are expected during geological CO2 storage. However, given the prevailing use of saline reservoirs in CCS projects elsewhere, limited data are available on CO2-water-rock dynamics during CO2 storage in such low-salinity formations. Here, a combined batch experiment and numerical modelling approach is used to characterise reaction pathways and to identify geochemical tracers of CO2 migration in the low-salinity Jurassic sandstone units. Reservoir system mineralogy was characterized for 66 core samples from stratigraphic well GSQ Chinchilla 4, and six representative samples were reacted with synthetic formation water and high-purity CO2 for up to 27 days at a range of pressures. Low formation water salinity, temperature, and mineralization yield high solubility trapping capacity (1.18 mol/L at 45°C, 100 bar), while the paucity of divalent cations in groundwater and the silicate reservoir matrix results in very low mineral trapping capacity under storage conditions. Formation water alkalinity buffers pH at elevated CO2 pressures and exerts control on mineral dissolution rates. Non-radiogenic, regional groundwater-like 87Sr/86Sr values (0.7048-0.7066) indicate carbonate and authigenic clay dissolution as the primary reaction pathways regulating solution composition, with limited dissolution of the clastic matrix during the incubations. Several geochemical tracers are mobilised in concentrations greater than found in regional groundwater, most notably cobalt, concentrations of which are significantly elevated regardless of CO2 pressure or sample mineralogy.

The CO2CRC Otway Project is Australia's first demonstration of geological storage of CO2 within deep underground reservoirs. The project has undergone many phases of implementation and the latest work program, Phase 2C, is aimed at injecting between 10,000 and 30,000 tonnes of CO2 into the saline Paraatte Formation located around 1,400m below surface. One of the key measures of success for Phase 2C is successful seismic detection of the injected gas stream. The geophysics team from Curtin University of Technology have previously conducted three 3D surface seismic surveys, and numerous smaller experiments, at the Otway CO2 re-injection site. These tests were completed during Phase 1 of the Otway Project whereby an (80-20%) CO2-CH4 gas mixture was re-injected into the depleted Warre-C gas reservoir. The feasibility of seismic monitoring of the CO2-CH4 gas mixture injected into the Paraatte Formation is expected to be improved over the Warre-C reservoir due to the increased fluid property contrast between brine and the CO2-CH4 mixture and the shallower depth of the reservoir. A comprehensive desktop feasibility study has been completed by the Curtin/CSIRO geophysics team to assess the probability of successful seismic detection and the preliminary results are encouraging. A Seismic Assurance Review workshop was completed incorporating seismic expertise from both academia and industry to assess the risk of unsuccessful seismic detection. The workshop was held on the 3rd and 4th of November, 2011, at Curtin University of Technology.

A study conducted under the Storage Programme of the Cooperative Research Centre for Greenhouse Gas Technologies (CO2CRC), investigating the potential for CO2 storage in the southern portion of the Perth Basin. The aim was to identify the sites most suitable for future carbon capture and storage projects (CCS) surrounding the emission centres of the Perth region. The study employed the methods developed under the GEODISC program: Project 2- Site Specific Studies, wherein a site is assessed for its CO2 emissions and site details; geology and stratigraphy; reservoir capacity; containment potential; and impacts on natural resources.

Phase two of the China Australia Geological Storage of CO2 (CAGS2) project aimed to build on the success of the previous CAGS project and promote capacity building, training opportunities and share expertise on the geological storage of CO2. The project was led by Geoscience Australia (GA) and China's Ministry of Science and Technology (MOST) through the Administrative Centre for China's Agenda 21 (ACCA21). CAGS2 has successfully completed all planned activities including three workshops, two carbon capture and storage (CCS) training schools, five research projects focusing on different aspects of the geological storage of CO2, and ten researcher exchanges to China and Australia. The project received favourable feedback from project partners and participants in CAGS activities and there is a strong desire from the Chinese government and Chinese researchers to continue the collaboration. The project can be considered a highly successful demonstration of bi-lateral cooperation between the Australian and Chinese governments. Through the technical workshops, training schools, exchange programs, and research projects, CAGS2 has facilitated and supported on-going collaboration between many research institutions and industry in Australia and China. More than 150 experts, young researchers and college students, from over 30 organisations, participated in CAGS2. The opportunity to interact with Australian and international experts at CAGS hosted workshops and schools was appreciated by the participants, many of whom do not get the opportunity to attend international conferences. Feedback from a CAGS impact survey found that the workshops and schools inspired many researchers and students to pursue geological storage research. The scientific exchanges proved effective and often fostered further engagement between Chinese and Australian researchers and their host organisations. The research projects often acted as a catalyst for attracting additional CCS funding (at least A$700,000), including two projects funded under the China Clean Development Mechanism Fund. CAGS sponsored research led to reports, international conference presentations, and Chinese and international journal papers. CAGS has established a network of key CCS/CCUS (carbon capture, utilisation and storage) researchers in China and Australia. This is exemplified by the fact that 4 of the 6 experts that provided input on the 'storage section of the 12th Five-Year plan for Scientific and Technological Development of Carbon Capture, Utilization and Storage, which laid out the technical policy priorities for R&D and demonstration of CCUS technology in China, were CAGS affiliated researchers. The contributions of CAGS to China's capacity building and policy CCUS has been acknowledged by the Chinese Government. CAGS support of young Chinese researchers is particularly noted and well regarded. Letters have been sent to the Secretary of the Department of Industry and Science and to the Deputy CEO of Geoscience Australia, expressing China's gratitude for the Australian Government's support and GA's cooperation in the CAGS project.