Assessment and Sensitivity Considerations of a Potential Storage Site for Carbon Dioxide A Queensland Case Study Sayers, J.1, Marsh, C.1, Scott, A.1, Cinar, Y.2, Bradshaw, J.1, Hennig, A.3, Barclay, S.4 and Daniel, R.5 Cooperative Research Centre for Greenhouse Gas Technologies 1 Geoscience Australia, GPO Box 378, Canberra ACT 2601, Australia 2 School of Petroleum Engineering, University of New South Wales, Sydney NSW 2052, Australia 3 Commonwealth Scientific and Industrial Research Organisation (CSIRO) Petroleum, PO Box 1130, Bentley, WA 6102, Australia 4 Commonwealth Scientific and Industrial Research Organisation (CSIRO) Petroleum, PO Box 136, North Ryde, NSW 1670, Australia 5 Australian School of Petroleum, Santos Petroleum Engineering Building, University of Adelaide, SA 5005, Australia ABSTRACT Australia's coal-fired power plants produce about 70% of the nation's total installed electricity generation capacity and emit about 190 million tonnes of CO2/year, of which about 44 million tonnes come from central and southeast Queensland. A multi-disciplinary study has identified the onshore Bowen Basin as having potential for geological storage of CO2. Storage potential has been documented within a 295 km2 area on the eastern flank of the Wunger Ridge using a simplified regional 3-D model, and is based on estimating injection rates of 1.2 million tonnes CO2/year for 25 years. Paleogeographic interpretations of the Showgrounds Sandstone reservoir in the targeted injection area indicate a dominantly meandering channel system that grades downdip into a deltaic system. Seismic interpretation indicates a relatively unfaulted seal and reservoir section. The depth to the reservoir extends to 2700 m. CO2 injection simulations indicate that at least one horizontal or two vertical wells would be required to inject at the proposed rate into homogeneous reservoirs with a thickness of approximately 5 m and permeability of 1 darcy. The existence of intra-reservoir shale baffles necessitates additional wells to maintain the necessary injection rate: this is also true for medium-permeability reservoirs. The long-term storage of the injected CO2 involves either stratigraphic and residual gas trapping along a 10 to 15 km migration path, and ultimately, potentially, within updip depleted hydrocarbon fields; or trapping in medium-permeability rocks. Trapping success will be a function of optimal reservoir characteristics including specific permeability ranges and the distribution of seals and baffles. Sensitivity analysis of CO2 injectivity indicates that dissolution effects may increase injection rates by up to 20 %.

Phase two of the China Australia Geological Storage of CO2 (CAGS2) project aimed to build on the success of the previous CAGS project and promote capacity building, training opportunities and share expertise on the geological storage of CO2. The project was led by Geoscience Australia (GA) and China's Ministry of Science and Technology (MOST) through the Administrative Centre for China's Agenda 21 (ACCA21). CAGS2 has successfully completed all planned activities including three workshops, two carbon capture and storage (CCS) training schools, five research projects focusing on different aspects of the geological storage of CO2, and ten researcher exchanges to China and Australia. The project received favourable feedback from project partners and participants in CAGS activities and there is a strong desire from the Chinese government and Chinese researchers to continue the collaboration. The project can be considered a highly successful demonstration of bi-lateral cooperation between the Australian and Chinese governments. Through the technical workshops, training schools, exchange programs, and research projects, CAGS2 has facilitated and supported on-going collaboration between many research institutions and industry in Australia and China. More than 150 experts, young researchers and college students, from over 30 organisations, participated in CAGS2. The opportunity to interact with Australian and international experts at CAGS hosted workshops and schools was appreciated by the participants, many of whom do not get the opportunity to attend international conferences. Feedback from a CAGS impact survey found that the workshops and schools inspired many researchers and students to pursue geological storage research. The scientific exchanges proved effective and often fostered further engagement between Chinese and Australian researchers and their host organisations. The research projects often acted as a catalyst for attracting additional CCS funding (at least A$700,000), including two projects funded under the China Clean Development Mechanism Fund. CAGS sponsored research led to reports, international conference presentations, and Chinese and international journal papers. CAGS has established a network of key CCS/CCUS (carbon capture, utilisation and storage) researchers in China and Australia. This is exemplified by the fact that 4 of the 6 experts that provided input on the 'storage section' of the 12th Five-Year plan for Scientific and Technological Development of Carbon Capture, Utilization and Storage, which laid out the technical policy priorities for R&D and demonstration of CCUS technology in China, were CAGS affiliated researchers. The contributions of CAGS to China's capacity building and policy CCUS has been acknowledged by the Chinese Government. CAGS support of young Chinese researchers is particularly noted and well regarded. Letters have been sent to the Secretary of the Department of Industry and Science and to the Deputy CEO of Geoscience Australia, expressing China's gratitude for the Australian Government's support and GA's cooperation in the CAGS project.

No abstract available

This GHGT-12 conference paper hightlights some results of GA's work on "Regional assessment of the CO2 storage potential of the Mesozoic sucession in the Petrel Sub-basin, Northern Territory, Australia. Record 2014/11".

Sampling, prior to CO2 injection at the CO2CRC Otway Project, southeastern Victoria at the end of 2007 early 2008, provided a stocktake of the molecular and isotopic (carbon and hydrogen) compositions of the subsurface hydrocarbon and non-hydrocarbon gases (and heavier hydrocarbons) at, and in close proximity to, the injection site. This baseline study is also fundamental to the assessment of present sub-surface petroleum components as natural tracers for injected gases arriving at the monitoring well. The CO2CRC Otway Project will use the CO2-rich natural gas (containing 79% CO2 and 20% methane) from the Buttress-1 well; totalling 100,000 tons of gas injected over 2 years. This gas mixture will be injected supercritically into sandstones of the CRC-1 well below the original gas-water contact at ~2000 m in the Waarre Formation. The depleted natural gas well at Naylor-1 is the monitoring well, situated 300 m updip of the injection well. Gas from the Waarre Formation in Naylor-1 observation well contains <1% CO2, which is isotopically depleted in 13C (13C -15.8) by 9 compared to CO2 (13C -6.8) in Buttress-1. Thus the carbon isotopes of CO2 can act as a primary natural tracer for monitoring purposes. Isotopically, the minimum detection limit would result from an increase of ~20 % in the CO2 concentration at Naylor-1 from the Buttress-derived CO2. On the other hand, the carbon and hydrogen isotopes of methane, wet gases and higher hydrocarbons are very similar between Buttress-1, CRC-1 and Naylor-1, requiring addition of external conservative tracers (Boreham et al., 2007) for the monitoring of hydrocarbon components. Although the content of liquid hydrocarbons in the gases is very low (<1%), there is the potential for supercritical CO2 extraction of these high molecular weight components (e.g. black oil in the Caroline-1 CO2 gas field and solid wax at the Boggy Creek CO2 production plant) that can be either advantageous (lubrication) or detrimental (clogging) to monitoring equipment at Naylor-1. The CRC-1 well provided an opportunity to collect downhole mud gases over many formations. Maximum total hydrocarbon concentration of 0.97 % occurred in the Waarre Formation Unit C. Surprisingly, a free gas zone in the overlying Flaxmans Formation had a lower maximum concentration (0.17 %). Carbon isotopes for the hydrocarbon gases from 1907 to 2249 mRT showed little downhole variation, while the 13C CO2 averaged -16, identical to CO2 at Naylor-1. Interestingly, the condensate recovered from a MDT in the Flaxmans Formation showed depletions in 13C for the C11 to C20 n-alkanes of up to 6 for n-C15 compared to n-alkanes of oils and condensates sourced from the Eumeralla Formation of the eastern Otway Basin (Boreham et al., 2004). Water washing is suspected at CRC-1 but is not expected to be a major factor affecting hydrocarbon compositions in the short term. The results of this subsurface petroleum audit have been pivotal in demonstrating the need for the addition of external tracers, especially for the hydrocarbon components, and provide an integral part of the near-surface, soil gas and atmospheric monitoring activities of the CO2CRC Otway Project. References Boreham, C.J., Hope, J.M., Jackson, P., Davenport, R., Earl, K.L., Edwards, D.S., Logan, G.A., Krassay, A.A., 2004. Gas-oil-source correlations in the Otway Basin, southern Australia. In: Boult, P.J., Johns, D.R., Lang, S.C. (Eds.), Eastern Australasian Basins Symposium II, Petroleum Exploration Society of Australia, Special Publication, pp. 603-627. Boreham, C.J., Underschultz, J., Stalker, L., Freifeld, B., Volk, H., Perkins, E., 2007. Perdeuterated methane as a novel tracer in CO2 geosequestration. In: Farrimond, P. et al. (Eds.), The 23rd International Meeting on Organic Geochemistry, Torquay, England 9th-14th September 2007, Book of Abstracts, 713-714.

Phase two of the China Australia Geological Storage of CO2 (CAGS2) project aimed to build on the success of the previous CAGS project and promote capacity building, training opportunities and share expertise on the geological storage of CO2. The project was led by Geoscience Australia (GA) and China's Ministry of Science and Technology (MOST) through the Administrative Centre for China's Agenda 21 (ACCA21). CAGS2 has successfully completed all planned activities including three workshops, two carbon capture and storage (CCS) training schools, five research projects focusing on different aspects of the geological storage of CO2, and ten researcher exchanges to China and Australia. The project received favourable feedback from project partners and participants in CAGS activities and there is a strong desire from the Chinese government and Chinese researchers to continue the collaboration. The project can be considered a highly successful demonstration of bi-lateral cooperation between the Australian and Chinese governments. Through the technical workshops, training schools, exchange programs, and research projects, CAGS2 has facilitated and supported on-going collaboration between many research institutions and industry in Australia and China. More than 150 experts, young researchers and college students, from over 30 organisations, participated in CAGS2. The opportunity to interact with Australian and international experts at CAGS hosted workshops and schools was appreciated by the participants, many of whom do not get the opportunity to attend international conferences. Feedback from a CAGS impact survey found that the workshops and schools inspired many researchers and students to pursue geological storage research. The scientific exchanges proved effective and often fostered further engagement between Chinese and Australian researchers and their host organisations. The research projects often acted as a catalyst for attracting additional CCS funding (at least A$700,000), including two projects funded under the China Clean Development Mechanism Fund. CAGS sponsored research led to reports, international conference presentations, and Chinese and international journal papers. CAGS has established a network of key CCS/CCUS (carbon capture, utilisation and storage) researchers in China and Australia. This is exemplified by the fact that 4 of the 6 experts that provided input on the 'storage section of the 12th Five-Year plan for Scientific and Technological Development of Carbon Capture, Utilization and Storage, which laid out the technical policy priorities for R&D and demonstration of CCUS technology in China, were CAGS affiliated researchers. The contributions of CAGS to China's capacity building and policy CCUS has been acknowledged by the Chinese Government. CAGS support of young Chinese researchers is particularly noted and well regarded. Letters have been sent to the Secretary of the Department of Industry and Science and to the Deputy CEO of Geoscience Australia, expressing China's gratitude for the Australian Government's support and GA's cooperation in the CAGS project.

No abstract available

An atmospheric greenhouse gas (GHG) monitoring station began operation in July 2010 near Emerald, Queensland. The station is part of a collaborative project between Geoscience Australia (GA) and CSIRO Marine and Atmospheric Research (CMAR) to establish and operate a high precision atmospheric monitoring facility for measurement of baseline greenhouse gases (GHG) in a high priority geological carbon dioxide storage region. The primary purpose of the station is to field test newly developed greenhouse gas monitoring technology and demonstrate best practice for regional baseline atmospheric monitoring appropriate for geological storage of carbon dioxide. The GHG records were to be used as a reference for monitoring of the atmosphere at a CO2 storage project, providing a baseline to quantify typical variations in the area and a background against which any anomalies in the immediate vicinity of the storage might be detected. The site chosen for the GHG atmospheric monitoring station is in the locality of Arcturus, 50 km southeast of Emerald in the Central Highlands, Queensland. Site selection was based on the recommendations of the Carbon Storage Taskforce's National Carbon Mapping and Infrastructure Plan, regional assessments of prospective basins, regional atmospheric modelling, and consultation with key stakeholders. The key driver for the stakeholder consultation group was to support early projects for large scale onshore geological storage. Both the Bowen and Surat basins were identified as potential early mover onshore storage regions by the group and suitable for a regional atmospheric monitoring station. During early 2010, ZeroGen had an active exploration program for geological storage and the site was eventually located approximately 8km upwind from the boundary of ZeroGen's most prospective storage area in the northern Denison Trough, part of the larger Bowen Basin. The Arcturus site and environs is representative of the activities and ecology of Queenslan's Central Highlands and the greenhouse gas signals are likely be influenced by cropping, pasture, cattle production, and gas and coal activities. These same activities are also likely to be dominant sources of greenhouse gases in the Surat Basin. Importantly, the site is secure, can be accessed via an existing road, is not subject to flooding, and has easy access to electrical lines that only required the installation of a transformer on an electric pole. A long lead time for new electricity connections at remote sites (potentially greater than 12 months) was identified as a key risk to the project. Negotiations with the electricity supplier resulted in connection in less than 4 months. An access agreement was negotiated with the landowner to enable the installation of the monitoring station and access to the site.

The CO2CRC Otway Project in southwestern Victoria, Australia has injected over 17 months 65 445 tonnes of a mixed carbon dioxide-methane fluid into the water leg of a depleted natural gas reservoir at a depth of approximately 2km. Pressurized sub-surface fluids were collected from the Naylor-1 observation well using a tri-level U-tube sampling system located near the crest of the fault-bounded anticline trap, 300 metres up-dip of the CRC-1 gas injection well. Relative to the pre-injection gas-water contact (GWC), only the shallowest U-tube initially accessed the residual methane gas cap. The pre-injection gas cap at Naylor-1 contains CO₂ at 1.5 mol% compared to 75.4 mol% for the injected gas from the Buttress-1 supply well and its CO₂ is depleted in ¹³C by 4.5%₀ VPDB compared to the injected supercritical CO<Sub>2</sub>. Additional assurance of the arrival of injected gas at the observation well is provided by the use of the added tracer compounds, CD₄, Kr and SF₆ in the injected gas stream. Lessons learnt from the CO2CRC Otway Project have enabled us to better anticipate the challenges for rapid deployment of carbon dioxide in a commercial environment at much larger scales.

This publication is the successor to Oil and Gas Resources of Australia 2004 and continues as the definitive reference on exploration, development and production of Australia's petroleum resources. OGRA 2005 provides the background for much of the advice on petroleum resources given to the Australian Government. The data are presented in categories that will allow the user to rapidly access specific data they are after. The categories are: - Well data - Seismic Data - Discoveries - Reserves - Production and Development - Expenditure - Titles - Coalbed Methane