Organic Geochemistry
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Geoscience Australia and its predecessors have analysed the hydrochemistry of water sampled from bores, surface features, rainwater and core samples (pore water). Samples have been collected during drilling or monitoring projects, including Exploring for the Future (EFTF). The hydrochemistry database includes physical-chemical parameters (EC, pH, redox potential, dissolved oxygen), major and minor ions, trace elements, isotopes and nutrients. The resource is accessible via the Geoscience Australia Portal <a href="https://portal.ga.gov.au/">(https://portal.ga.gov.au/)</a>
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This database contains geochemical data for samples analysed both for inorganic and organic geochemistry. Analytical data are sourced from Geoscience Australia's Inorganic Geochemistry Database (OZCHEM) and Organic Geochemistry Database (ORGCHEM), respectively. The data are joined on a unique sample number. Inorganic geochemical data cover the majority of the periodic table, with metadata on analytical methods and detection limits. Organic geochemical data include results of pyrolysis, derivative calculated values, and, where available, isotopic composition of carbonates (D13C) and isotopic composition of rock nitrogen (D15N). Further, there are provisions for delivery of isotopic data for kerogen (H, C, N) and oxygen (O) for carbonates. Where available, sample descriptions include stratigraphic unit names and ages, and lithology. Location information includes coordinates of the sampled feature (eg, borehole), coordinates of the sample and sample depth. Interpretation of the combined inorganic and organic geochemistry for organic-rich shales will facilitate comprehensive characterisation of hydrocarbons source rocks and mineral commodities source and trap environments. All are achieved within the frameworks of petroleum and mineral systems analysis. The initial data delivered by this service include 1785 samples from 35 boreholes from 14 geological provinces, including recently released data for 442 samples from the South Nicholson National Drilling Initiative Carrara 1 stratigraphic drill hole (Butcher et al., 2021; Carson et al., 2021). Many sampled boreholes are located within the polygon of the Exploring for the Future Barkly-Isa-Georgetown project. This dataset will be updated periodically as more data become available.
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<b> Legacy service retired 29/11/2022</b> This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data conforming to the GeoSciML version 4.0 specification. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.
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The hydrocarbon generative potential and the thermal maturity of source rocks in the offshore northern Perth Basin was reassessed based on existing and new geochemical data to get a better understanding of the basin's prospectivity. The study establishes for the first time that the main source of onshore accumulations, the Late Permian-Early Triassic Hovea Member, is well developed offshore and contains organic-rich sediments of oil-prone character. This finding shatters the long-held view that the Hovea Member was either absent or of poor quality offshore and provides a new perspective on the basin's prospectivity. The source potential of the Hovea Member varies spatially with best source rocks observed in the Beagle Ridge and Central Abrolhos Sub-basin. The Late Permian Irwin River Sequence and several Jurassic Sequences are also identified as prime potential source rocks offshore, mostly for their gas-generative potential. Oil-generative potential was identified in the Middle to Late Jurassic Yarragadee Sequence and possibly in the Middle Jurassic Cadda Sequence.
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This presentation describes source rock data in addition to new compositional and stable isotopic data for 17 oils and six gases from the Amadeus Basin, central Australia. All data was analysed and interpreted by Geoscience Australia. The results of this study provide new insights into the origin and preservational history of hydrocarbons in the basin and provide a platform for future research directions.
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Hydrochemistry data for Australian groundwater, including field and laboratory measurements of chemical parameters (electrical conductivity (EC), potential of hydrogen (pH), redox potential, and dissolved oxygen), major and minor ions, trace elements, nutrients, pesticides, isotopes and organic chemicals. < <b>Value: </b>The chemical properties of groundwater are key parameters to understand groundwater systems and their functions. Groundwater chemistry information includes the ionic and isotopic composition of the water, representing the gases and solids that are dissolved in it. Hydrochemistry data is used to understand the source, flow, and interactions of groundwater samples with surface water and geological units, providing insight into aquifer characteristics. Hydrochemistry information is key to determining the quality of groundwater resources for societal, agricultural, industrial and environmental applications. Insights from hydrochemical analyses can be used to assess a groundwater resource, the impact of land use changes, irrigation and groundwater extraction on regional groundwater quality and quantity, assess prospective mineral exploration targets, and determine how groundwater interacts with surface water in streams and lakes. <b>Scope: </b>The database was inaugurated in 2016 with hydrochemical data collected over the Australian landmass by Geoscience Australia and its predecessors, and has expanded with regional and national data. It has been in the custodianship of the hydrochemists in Geoscience Australia's Minerals, Energy and Groundwater Division and its predecessors. Explore the <b>Geoscience Australia portal - https://portal.ga.gov.au/</b>
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<b>Legacy service Retired 29/11/2022 IMPORTANT NOTICE: </b>This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data. This web service is intended to complement the borehole GeoSciML-Portrayal v4.0 web service, providing access to the data in a simple, non-standardised structure. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.
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<div>Exploring for the Future (EFTF) is a program dedicated to exploring Australia’s resource potential and boosting investment. This program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of onshore basins and attract exploration investment to Australia. This record presents geochemical analyses of natural gases sampled from Nangwarry 1, located in the onshore Otway Basin, undertaken in partnership with the Department for Energy and Mining – Energy Resources, Government of South Australia, as part of the EFTF program Natural Hydrogen module. The Nangwarry Joint Venture drilled Nangwarry 1 to investigate the potential for the development of food grade, carbon dioxide production from this well. The results of the molecular and stable carbon and hydrogen isotopic analyses undertaken by Geoscience Australia are released in this report. The molecular data show that the gas composition in this well has an average of 96 mol% CO2 with an isotopic signature indicative of a magmatic origin, being comparable with previously produced gases from onshore Otway Basin wells (e.g. Boggy Creek 1, Caroline 1) for use by the food industry. The carbon and hydrogen isotopic composition of the C1–C5 hydrocarbon gases from Nangwarry 1 are suggestive of a source from within the Crayfish Supersequence.</div>
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Geoscience Australia currently uses two commercial petroleum system modelling software packages, PetroMod https://www.software.slb.com/products/petromod and Zetaware http://www.zetaware.com, to undertake burial and thermal history modelling on wells in Australian sedimentary basins. From the integration of geological (age-based sedimentary packages, uplift and erosional events), petrophysical (porosity, permeability, and thermal conductivity) and thermal (downhole temperature, heat flow, vitrinite reflectance, and Tmax) input data, to name the most significant, a best-fit model of the time-temperature history is generated. Since the transformation of sedimentary organic matter (kerogen) into petroleum (oil and gas) is a chemical reaction, it is governed by chemical kinetics i.e. time and temperature (in the geological setting, pressure is of secondary importance). Thus, the use of chemical kinetics associated with a formation-specific, immature potential source rock (where available) from the basin of interest is considered a better practical approach rather than relying on software kinetic defaults, which are generally based on the chemical kinetics determined experimentally on Northern Hemisphere organic matter types. As part of the Offshore Energy Systems program hydrocarbons from the Lower Cretaceous Eumeralla Formation were selected where available from onshore wells; compositional kinetics (1-, 2-, 4- and 14-component (phase) kinetics) were undertaken by GeoS4, Germany. The phase kinetics approach is outlined in Appendix 1. This report provides the compositional kinetics for potential source rocks from the Lower Cretaceous Otway Group, Otway Basin, Australia. The kinetic data were used in the offshore petroleum system modelling reported in Schenk et al. (2021).
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<div>NDI Carrara 1 is a deep stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1120 m of Proterozoic sedimentary rocks unconformably overlain by 630 m of Georgina Basin carbonates. </div><div>Geoscience Australia has undertaken a range of investigations on the lithology, stratigraphy and geotechnical properties of NDI Carrara 1 as well as undertaking a range of analyses of about 500 physical samples recovered through the entire core. Analyses included geochronology, isotope studies, mineralogy, inorganic and organic geochemistry, petrophysics, geomechanics, thermal maturity and petroleum systems investigations.</div><div>Rock-Eval pyrolysis raw data undertaken by Geoscience Australia were reported in Butcher et al. (2021) on selected rock samples to establish their total organic carbon content, hydrocarbon-generating potential and thermal maturity. Interpretation of the Rock-Eval pyrolysis data concluded that a large portion of rocks within the Proterozoic section displayed unreliable Tmax values due to poorly defined S2 peaks resulting from high thermal maturity and low hydrogen content. In order to obtain more reliable Tmax values, Rock-Eval pyrolysis of selected isolated kerogens, where organic matter is concentrated and mineral matrix effects are removed, were conducted and the resulting data are presented in this report. </div><div><br></div>