Australia has been, and continues to be, a leader in isotope geochronology and geochemistry. While new isotopic data is being produced with ever increasing pace and diversity, there is also a rich legacy of existing high-quality age and isotopic data, most of which have been dispersed across a multitude of journal papers, reports and theses. Where compilations of isotopic data exist, they tend to have been undertaken at variable geographic scale, with variable purpose, format, styles, levels of detail and completeness. Consequently, it has been difficult to visualise or interrogate the collective value of age and isotopic data at continental-scale. Age and isotopic patterns at continental scale can provide intriguing insights into the temporal and chemical evolution of the continent (Fraser et al, 2020). As national custodian of geoscience data, Geoscience Australia has addressed this challenge by developing an Isotopic Atlas of Australia, which currently (as of November 2020) consists of national-scale coverages of four widely-used age and isotopic data-types: 4008 U-Pb mineral ages from magmatic, metamorphic and sedimentary rocks 2651 Sm-Nd whole-rock analyses, primarily of granites and felsic volcanics 5696 Lu-Hf (136 samples) and 553 O-isotope (24 samples) analyses of zircon 1522 Pb-Pb analyses of ores and ore-related minerals These isotopic coverages are now freely available as web-services for use and download from the GA Portal. While there is more legacy data to be added, and a never-ending stream of new data constantly emerging, the provision of these national coverages with consistent classification and attribution provides a range of benefits: vastly reduces duplication of effort in compiling bespoke datasets for specific regions or use-cases data density is sufficient to reveal meaningful temporal and spatial patterns a guide to the existence and source of data in areas of interest, and of major data gaps to be addressed in future work facilitates production of thematic maps from subsets of data. For example, a magmatic age map, or K-Ar mica cooling age map sample metadata such as lithology and stratigraphic unit is associated with each isotopic result, allowing for further filtering, subsetting and interpretation. The Isotopic Atlas of Australia will continue to develop via the addition of both new and legacy data to existing coverages, and by the addition of new data coverages from a wider range of isotopic systems and a wider range of geological sample media (e.g. soil, regolith and groundwater).

A major concern for regulators and the public with geological storage of CO2 is the potential for the migration of CO2 via a leaky fault or well into potable groundwater supplies. Given sufficient CO2, an immediate effect on groundwater would be a decrease in pH which could lead to accelerated weathering, an increase in alkalinity, release of major and minor ions and heavy metals (particularly Pd, Ni and Cr) as well as CO2 mobilisation of trace organic contaminants. These scenarios potentially occur in a high CO2 leakage event, therefore detection of a small leak, although barely perceptible, could provide an important early warning for a subsequent and more substantial impact. Different approaches are required for the detection and quantification of these low level leaks and are the subject of this paper. A 3 year groundwater survey was recently completed in the Surat Basin, which provided comprehensive water and isotopic analysis of groundwaters together with their exsolved gases. The gases were analysed for composition, -13CCO2, -13CCH4 and -2HCH4. Methane is prevalent in the major Surat Basin aquifers (e.g. Mooga, Gubberamunda and Hutton sandstones) and is invariably associated with a bacterial (methanogenic) carbonate reduction source, evident from its isotopic signature ('13CCH4 ~ -70', '2HCH4 ~ -220'). In addition to methane and low levels of CO2, trace ethane is common. Two neighbouring wells, however, were quite different to the other 85 wells surveyed. Their exsolved gases contained comparatively high ethane, but also C1-C6 hydrocarbons in addition to methane. Methane isotope systematics were significantly different from other groundwater wells completed in the same formation. The -13C of the CO2 was similar to the surrounding groundwater wells, but the relative proportion of CO2 in the gas was significantly higher. Combined, these characteristics are consistent with hydrocarbon biodegradation. There was little difference in the groundwater chemistry for these wells compared to the regional baseline. The study provides a useful analogue study for detection, at various scales, of a leaky well associated with a geological storage site. Compositional and isotopic analysis of exsolved gases from groundwater samples could be used to demonstrate non-equilibrium conditions and intrusion of exogenic CO2. Abstract for the 2013 International Association of Hydrologist Congress, Perth

This Record presents 40Ar/39Ar chronologic results acquired in support of collaborative regional geoscientific investigations and mapping programs conducted by Geoscience Australia (GA) and the Northern Territory Geological Survey (NTGS). Argon isotopic data and interpretations from hornblende, muscovite, and biotite from seven samples collected from the Aileron Province in ALCOOTA , HUCKITTA, HALE RIVER, and ILLOGWA CREEK in the Northern Territory are presented herein. The results complement pre-existing geochronological constraints from U–Pb zircon and monazite analyses of the same or related samples, and provide new constraints on the thermal and deformation history of the Aileron Province. Three samples (2003082017, 2003082021, 2003083040) were taken from ALCOOTA in the northeastern portion of the Aileron Province. Biotite in sample 2003082017 from the ca 1.81 Ga Crooked Hole Granite records cooling below 320–280°C at 441 ± 5 Ma. Biotite in sample 2003082021 from the ca 1.73 Ga Jamaica Granite records cooling below 320–280°C at or after 414 ± 2 Ma. Muscovite in sample 2003083040 from the Delny Metamorphics, which were deposited after ca 1.82 Ga and preserve evidence for metamorphism at ca 1.72 Ga and 1.69 Ga, records cooling below 430–390°C at 399 ± 2 Ma. The fabrics preserved in the samples from the Crooked Hole Granite and Delny Metamorphics are interpreted to have formed due to dynamic metamorphism related to movement on the Waite River Shear Zone, an extension of the Delny Shear Zone, during the Palaeoproterozoic. Portions of the northeastern Aileron Province are unconformably overlain by the Neoproterozoic–Cambrian Georgina Basin, indicating these samples were likely at or near the surface by the Neoproterozoic. Together, these data indicate that rocks of the Aileron Province in ALCOOTA were subjected to heating above ~400°C during the Palaeozoic. Two samples (2003087859K, 2003087862F) of exoskarn from an indeterminate unit were taken from drillhole MDDH4 in the Molyhil tungsten–molybdenum deposit in central HUCKITTA. The rocks hosting the Molyhil tungsten–molybdenum deposit are interpreted as ca 1.79 Ga Deep Bore Metamorphics and ca 1.80 Ga Yam Gneiss. They experienced long-lived metamorphism during the Palaeoproterozoic, with supersolidus metamorphism observed until at least ca 1.72 Ga. Hornblende from sample 2003087859K indicates cooling below 520–480°C by 1702 ± 5 Ma and may closely approximate timing of skarn-related mineralisation at the Molyhil deposit; hornblende from sample 2003087862F records a phase of fluid flow at the Molyhil deposit at 1660 ± 4 Ma. The Salthole Gneiss has a granitic protolith that was emplaced at ca 1.79 Ga, and experienced alteration at ca 1.77 Ga. Muscovite from sample 2010080001 of Salthole Gneiss from the Illogwa Shear Zone in ILLOGWA CREEK records cooling of the sample below ~430–390°C at 327 ± 2 Ma. This may reflect the timing of movement of, or fluid flux along, the Illogwa Shear Zone. An unnamed quartzite in the Casey Inlier in HALE RIVER has a zircon U–Pb maximum depositional age of ca 1.24 Ga. Muscovite from sample HA05IRS071 of this unnamed quartzite yields an age of 1072 ± 8 Ma, which likely approximates, or closely post-dates, the timing of deformation in this sample; it provides the first direct evidence for a Mesoproterozoic episode of deformation in this part of the Aileron Province.

This Record contains new zircon and monazite U-Pb geochronological data obtained via Sensitive High-Resolution Ion Micro Probe (SHRIMP) from nine samples of volcanic, volcaniclastic and plutonic igneous rocks of the central Lachlan Orogen and the New England Orogen, New South Wales. These data were obtained during the reporting period July 2014-June 2015, under the auspices of the collaborative Geochronology Project between the Geological Survey of New South Wales (GSNSW) and Geoscience Australia (GA), which is part of the National Collaboration Framework (NCF).

The unexpected discovery of oil in Triassic sedimentary rocks of the Phoenix South 1 well on Australia’s North West Shelf (NWS) has catalysed exploration interest in pre-Jurassic plays in the region. Subsequent neighbouring wells Roc 1–2, Phoenix South 2–3 and Dorado 1–3 drilled between 2015 and 2019 penetrated gas and/or oil columns, with the Dorado field containing one of the largest oil resources found in Australia in three decades. This study aims to understand the source of the oils and gases of the greater Phoenix area, Bedout Sub-basin using a multiparameter geochemical approach. Isotopic analyses combined with biomarker data confirm that these fluids represent a new Triassic petroleum system on the NWS unrelated to the Lower Triassic Hovea Member petroleum system of the Perth Basin. The Bedout Sub-basin fluids were generated from source rocks deposited in paralic environments with mixed type II/III kerogen, with lagoonal organofacies exhibiting excellent liquids potential. The Roc 1–2 gases and the Phoenix South 1 oil are likely sourced proximally by Lower–Middle Triassic TR10–TR15 sequences. Loss of gas within the Phoenix South 1 fluid due to potential trap breach has resulted in the formation of in-place oil. These discoveries are testament to new hydrocarbon plays within the Lower–Middle Triassic succession on the NWS.

Newer version v1.1 available at eCat <a href="https://pid.geoscience.gov.au/dataset/ga/147720">147720</a> Isotopic data from rocks and minerals have the potential to yield unique insights into the composition and evolution of the Earth's crust and mantle. Time-integrated records of crust and mantle differentiation (as preserved by the U-Pb, Sm-Nd and Lu-Hf isotopic systems, for example) are important in a wide range of geological applications, especially when successfully integrated with other geological, geophysical, and geochemical datasets. However, such integration requires (i) compilation of comprehensive isotopic data coverages, (ii) unification of datasets in a consistent structure to facilitate inter-comparison, and (iii) easy public accessibility of the compiled and unified datasets in spatial and tabular formats useful and useable by a broad range of industry, government and academic users. This constitutes a considerable challenge, because although a wealth of isotopic information has been collected from the Australian continent over the last 40 years, the published record is fragmentary, and derived from numerous and disparate sources. Unlocking and harnessing the collective value of isotopic datasets will enable more comprehensive and powerful interpretations, and significantly broaden their applicability to Earth evolution studies and mineral exploration. As part of the Exploring for the Future (EFTF) program (https://www.ga.gov.au/eftf), we have designed a new database structure and web service system to store and deliver full Lu-Hf isotope and associated O-isotope datasets, spanning new data collected during research programs conducted by Geoscience Australia (GA), as well as compiled literature data. Our approach emphasises the links between isotopic measurements and their spatial, geological, and data provenance information in order to support the widest possible range of uses. In particular, we build and store comprehensive links to the original sources of isotopic data so that (i) users can easily track down additional context and interpretation of datasets, and (ii) generators of isotopic data are appropriately acknowledged for their contributions. This system delivers complete datasets including (i) full analytical and derived data as published by the original author, (ii) additional, normalised derived data recalculated specifically to maximise inter-comparability of data from disparate sources, (iii) metadata related to the analytical setup, (iv) a broad range of sample information including sampling location, rock type, geological province and stratigraphic unit information, and (v) descriptions of (and links to) source publications. The data is delivered through the Geoscience Australia web portal (www.portal.ga.gov.au), and can also be accessed through any web portal capable of consuming Open Geospatial Consortium (OGC)-compliant web services, or any GIS system capable of consuming Web Map Services (WMS) or Web Feature Services (WFS). This Record describes the database system and web service tables. It also contains full tabulated datasets for data compiled from the North Australian Craton as part of the EFTF program. These data are predominantly micro-analytical zircon analyses which are linked at the spot-level across Lu-Hf, O, and U-Pb measurements. This data release comprises 5974 individual analyses from 149 unique rock samples.

Geoscience Australia has compiled U-Pb datasets from disparate sources into a single, standardised and publicly-available U–Pb geochronology compilation for all Australia. The national maps presented in this poster expand upon the data coverage previously compiled by Anderson et al. (2017) and Jones et al. (2018), which covered northern and western Australia only. This extension of a national coverage has been achieved through the development of Geoscience Australia’s Interpreted Ages database. In this database, there are now >4000 U–Pb sample points compiled from across Australia, with significant datasets to come from the southern Australia regions. These will be available to the public in the coming months through the Exploring for the Future Data Discovery Portal (eftf.ga.gov.au).

<p>The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the North West Margin Energy Studies Section (NWMES). This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. <p>The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018) and Dorado 1 (2018) in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata. The current study aims to better understand this new petroleum system and establish its extent. <p>As part of this program, compositional and isotopic analyses were undertaken by Geoscience Australia on gas samples from the wells Roc 1 and Roc 2 and data from these analyses are released in this dataset.

Petroleum geochemical datasets and information are essential to government for evidence-based decision making on natural resources, and to the petroleum industry for de-risking exploration. Geoscience Australia’s newly built Data Discovery Portal (https://portal.ga.gov.au/) enables digital discoverability and accessibility to key petroleum geochemical datasets. The portal’s web map services and web feature services allow download and visualisation of geochemical data for source rocks and petroleum fluids, and deliver a petroleum systems framework for northern Australian basins. The Petroleum Source Rock Analytics Tool enables interrogation of source rock data within boreholes and field sites, and facilitates correlation of these elements of the petroleum system within and between basins. The Petroleum Systems Summary Assessment Tool assists the user to search and query components of the petroleum system(s) identified within a basin. The portal functionality includes customised data searches, and visualisation of data via interactive maps, graphs and geoscientific tools. Integration of the petroleum systems framework with the supporting geochemical data enables the Data Discovery Portal to unlock the value of these datasets by affording the user a one-stop access to interrogate the data. This allows greater efficiency and performance in evaluating the petroleum prospectivity of Australia’s sedimentary basins, facilitating and accelerating decision making around exploration investment to ensure Australia’s future resource wealth <b>Citation:</b> Edwards, D.S., MacFarlane, S.K., Grosjean, E., Buckler, T., Boreham, C.J., Henson, P., Cherukoori, R., Tracey-Patte, T., van der Wielen, S., Ray, J. and Raymond, O., 2020. Australian source rocks, fluids and petroleum systems – a new integrated geoscience data discovery portal for maximising data potential. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

Plutonium (Pu) interactions in the environment are highly complex. Site-specific variables play an integral role in determining the chemical and physical form of Pu, and its migration, bioavailability, and immobility. This paper aims to identify the key variables that can be used to highlight regions of radioecological sensitivity and guide remediation strategies in Australia. Plutonium is present in the Australian environment as a result of global fallout and the British nuclear testing program of 1952 – 1958 in central and west Australia (Maralinga and Monte Bello islands). We report the first systematic measurements of 239+240Pu and 238Pu activity concentrations in distal (≥1,000 km from test sites) catchment outlet sediments from Queensland, Australia. The average 239+240Pu activity concentration was 0.29 mBq.g -1 (n = 73 samples) with a maximum of 4.88 mBq.g -1. 238Pu/239+240Pu isotope ratios identified a large range (0.02 – 0.29 (RSD: 74%)) which is congruent with the heterogeneous nuclear material used for the British nuclear testing programme at Maralinga and Montebello Islands. The use of a modified PCA relying on non-linear distance correlation (dCorr) provided broader insight into the impact of environmental variables on the transport and migration of Pu in this soil system. Primary key environmental indicators of Pu presence were determined to be actinide/lanthanide/heavier transition metals, elevation, electrical conductivity (EC), CaO, SiO2, SO3, landform, geomorphology, land use, and climate explaining 81.7% of the variance of the system. Overall this highlighted that trace level Pu accumulations are associated with the coarse, refractive components of Australian soils, and are more likely regulated by the climate of the region and overall soil type. <b>Citation:</b> Megan Cook, Patrice de Caritat, Ross Kleinschmidt, Joёl Brugger, Vanessa NL. Wong, Future migration: Key environmental indicators of Pu accumulation in terrestrial sediments of Queensland, Australia,<i> Journal of Environmental Radioactivity</i>, Volumes 223–224, 2020, 106398,ISSN 0265-931X, https://doi.org/10.1016/j.jenvrad.2020.106398