Preamble -- The 'National Geochemical Survey of Australia: The Geochemical Atlas of Australia' was published in July 2011 along with a digital copy of the NGSA geochemical dataset (doi: 10.11636/Record.2011.020). The NGSA project is described here: www.ga.gov.au/ngsa. The present dataset contains additional geochemical data obtained on NGSA samples: the Plutonium Isotopes Dataset. Abstract -- Seventy three fine-fraction (<75 um) Top Outlet Sediment (TOS, 0 – 10 cm depth) NGSA samples from Queensland were analysed for the plutonium (Pu) isotopes 238Pu and 239+240Pu (unresolved 239Pu and 240Pu) to determine: (1) if Pu is detectable in the Australian environment; and (2) what the levels and ranges of Pu retention in selected Queensland catchment soils are. Radiochemical analyses were performed by alpha spectrometry at the radioanalytical laboratories of Radiation and Nuclear Sciences, Department of Health, Queensland, and at the Australian Radiation Protection and Nuclear Safety Agency (ARPANSA), Victoria. The method yielded a 239+240Pu trace-level detection limit of 0.04 mBq/g (equivalent to 10.4 fg/kg or 0.0056 net counts per minute) with a relative standard deviation (RSD) of 15.1%. The average tracer recovery was 69% (RSD 25%) over a 3-day count. Total analytical uncertainty ranged from 19% to 90% at close to detection limits. Field duplicate repeatability for 239+240Pu activity concentration ranged from 18% to 45%, which in part at least reflects the inherent heterogeneity of soil/sediments containing refractory particles exhibiting variation in Pu activity concentrations. Analytical duplicate repeatability for 239+240Pu activity concentration ranged from 10% to 23%, with the mean activity concentration and error of the replicates reported with propagation of errors. The results show a wide range of 239+240Pu activity concentration in the fine TOS NGSA samples across Queensland (N = 73): 239+240Pu: Min = <0.04 mBq/g; Med ± MAD (median absolute deviation) = 0.09 ± 0.07 mBq/g; Mean ± SD = 0.29 ± 0.72 mBq/g; 95th percentile = 1.53 mBq/g; Max = 4.88 mBq/g. In comparison the world average background is estimated at 0.2 mBq/g. Analytical results for 39% of samples were below detection. Six samples with 239+240Pu > 0.18 mBq/g (70th percentile) were also analysed for 238Pu by the same alpha spectrometry method. Results ranged from 0.04 to 0.1 mBq/g (N = 6). The complete dataset is available to download as a comma separated values (CSV) file from Geoscience Australia's website (https://pid.geoscience.gov.au/dataset/ga/144101).

<p>Australia has a significant number of surface sediment geochemical surveys that have been undertaken by industry and government during the past 50 years. These surveys represent a vast investment, but up to now have been used in isolation from one another. The key to maximising the full potential of these data and the information they provide for mineral exploration, environmental management and agricultural purposes is using all surveys together, seamlessly. These geochemical surveys have not only sampled various landscape elements but have used multiple analytical techniques, instrumentation and laboratories. The geochemical data from these surveys need to be levelled to eliminate, as much as possible, non-geological variation. Using a variety of methodologies, including reanalysis of both international standards and small subsets of samples from previous surveys, we have created a seamless surface geochemical map for northern Australia, from nine surveys with 15605 samples. We tested our approach using two surveys from the southern Thomson Orogen, which removed interlaboratory and other analytical variation. Creation of the new combined and levelled northern Australian dataset paves the way for the application of statistical techniques, such as principal component analysis and machine learning, which maximise the value of these legacy data holdings. The methodology documented here can be applied to additional geochemical datasets that become available. <p><b>Citation:</b> Main, P. T. and Champion, D. C., 2020. Geochemistry of the North Australian Craton: piecing it together. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

This data package, completed as part of Geoscience Australia’s National Groundwater Systems (NGS) Project, presents results of the second iteration of the 3D Great Artesian Basin (GAB) and Lake Eyre Basin (LEB) (Figure 1) geological and hydrogeological models (Vizy & Rollet, 2023) populated with volume of shale (Vshale) values calculated on 2,310 wells in the Surat, Eromanga, Carpentaria and Lake Eyre basins (Norton & Rollet, 2023). This provides a refined architecture of aquifer and aquitard geometry that can be used as a proxy for internal, lateral, and vertical, variability of rock properties within each of the 18 GAB-LEB hydrogeological units (Figure 2). These data compilations and information are brought to a common national standard to help improve hydrogeological conceptualisation of groundwater systems across multiple jurisdictions. This information will assist water managers to support responsible groundwater management and secure groundwater into the future. This 3D Vshale model of the GAB provides a common framework for further data integration with other disciplines, industry, academics and the public and helps assess the impact of water use and climate change. It aids in mapping current groundwater knowledge at a GAB-wide scale and identifying critical groundwater areas for long-term monitoring. The NGS project is part of the Exploring for the Future (EFTF) program—an eight-year, $225 million Australian Government funded geoscience data and precompetitive information acquisition program. The program seeks to inform decision-making by government, community, and industry on the sustainable development of Australia's mineral, energy, and groundwater resources, including those to support the effective long-term management of GAB water resources. This work builds on the first iteration completed as part of the Great Artesian Basin Groundwater project (Vizy & Rollet, 2022; Rollet et al., 2022), and infills previous data and knowledge gaps in the GAB and LEB with additional borehole, airborne electromagnetic and seismic interpretation. The Vshale values calculated on additional wells in the southern Surat and southern Eromanga basins and in the whole of Carpentaria and Lake Eyre basins provide higher resolution facies variability estimates from the distribution of generalised sand-shale ratio across the 18 GAB-LEB hydrogeological units. The data reveals a complex mixture of sedimentary environments in the GAB, and highlights sand body development and hydraulic characteristics within aquifers and aquitards. Understanding the regional extents of these sand-rich areas provides insights into potential preferential flow paths, within and between the GAB and LEB, and aquifer compartmentalisation. However, there are limitations that require further study, including data gaps and the need to integrate petrophysics and hydrogeological data. Incorporating major faults and other structures would also enhance our understanding of fluid flow pathways. The revised Vshale model, incorporating additional boreholes to a total of 2,310 boreholes, contributes to our understanding of groundwater flow and connectivity in the region, from the recharge beds to discharge at springs, and Groundwater Dependant Ecosystems (GDEs). It also facilitates interbasinal connectivity analysis. This 3D Vshale model offers a consistent framework for integrating data from various sources, allowing for the assessment of water use impacts and climate change at different scales. It can be used to map groundwater knowledge across the GAB and identify areas that require long-term monitoring. Additionally, the distribution of boreholes with gamma ray logs used for the Vshale work in each GAB and LEB units (Norton & Rollet, 2022; 2023) is used to highlight areas where additional data acquisition or interpretation is needed in data-poor areas within the GAB and LEB units. The second iteration of surfaces with additional Vshale calculation data points provides more confidence in the distribution of sand bodies at the whole GAB scale. The current model highlights that the main Precipice, Hutton, Adori-Springbok and Cadna-owie‒Hooray aquifers are relatively well connected within their respective extents, particularly the Precipice and Hutton Sandstone aquifers and equivalents. The Bungil Formation, the Mooga Sandstone and the Gubberamunda Sandstone are partial and regional aquifers, which are restricted to the Surat Basin. These are time equivalents to the Cadna-owie–Hooray major aquifer system that extends across the Eromanga Basin, as well as the Gilbert River Formation and Eulo Queen Group which are important aquifers onshore in the Carpentaria Basin. The current iteration of the Vshale model confirms that the Cadna-owie–Hooray and time equivalent units form a major aquifer system that spreads across the whole GAB. It consists of sand bodies within multiple channel belts that have varying degrees of connectivity' i.e. being a channelised system some of the sands will be encased within overbank deposits and isolated, while others will be stacked, cross-cutting systems that provide vertical connectivity. The channelised systemtransitions vertically and laterally into a shallow marine environment (Rollet et al., 2022). Sand-rich areas are also mapped within the main Poolowanna, Brikhead-Walloon and Westbourne interbasinal aquitards, as well as the regional Rolling Downs aquitard that may provide some potential pathways for upward leakage of groundwater to the shallow Winton-Mackunda aquifer and overlying Lake Eyre Basin. Further integration with hydrochemical data may help groundtruth some of these observations. This metadata document is associated with a data package including: • Seventeen surfaces with Vshale property (Table 1), • Seventeen surfaces with less than 40% Vshale property (Table 2), • Twenty isochore with average Vshale property (Table 3), • Twenty isochore with less than 40% Vshale property (Table 4), • Sixteen Average Vshale intersections of less than 40% Vshale property delineating potential connectivity between isochore (Table 5), • Sixteen Average Vshale intersections of less than 40% Vshale property delineating potential connectivity with isochore above and below (Table 6), • Seventeen upscaled Vshale log intersection locations (Table 7), • Six regional sections showing geology and Vshale property (Table 8), • Three datasets with location of boreholes, sections, and area of interest (Table 9).

This report, completed as part of Geoscience Australia’s Exploring for the Future Program National Groundwater Systems (NGS) Project, presents results of the second iteration of 3D geological and hydrogeological surfaces across eastern Australian basins. The NGS project is part of the Exploring for the Future (EFTF) program—an eight-year, $225 million Australian Government funded geoscience data and precompetitive information acquisition program. The program seeks to inform decision-making by government, community, and industry on the sustainable development of Australia's mineral, energy, and groundwater resources, including those to support the effective long-term management of GAB water resources. This work builds on the first iteration completed as part of the Great Artesian Basin Groundwater project. The datasets incorporate infills of data and knowledge gaps in the Great Artesian Basin (GAB), Lake Eyre Basin (LEB), Upper Darling Floodplain (UDF) and existing data in additional basins in eastern Australia. The study area extends from the offshore Gulf of Carpentaria in the north to the offshore Bight, Otway, and Gippsland basins in the South and from the western edge of the GAB in the west to the eastern Australian coastline to the east. The revisions are an update to the surface extents and thicknesses for 18 region-wide hydrogeological units produced by Vizy & Rollet, 2022. The second iteration of the 3D model surfaces further unifies geology across borders and provides the basis for a consistent hydrogeological framework at a basin-wide, and towards a national-wide, scale. The stratigraphic nomenclature used follows geological unit subdivisions applied: (1) in the Surat Cumulative Management Area (OGIA - Office of Groundwater Impact Assessment, 2019) to correlate time equivalent regional hydrogeological units in the GAB and other Jurassic and Cretaceous time equivalent basins in the study area and (2) in the LEB to correlate Cenozoic time equivalents in the study area. Triassic to Permian and older basins distribution and thicknesses are provided without any geological and hydrogeological unit sub-division. Such work helps to (1) reconcile legacy and contemporary regional studies under a common stratigraphic framework, (2) support the effective management of groundwater resources, and (3) provide a regional geological context for integrated resource assessments. The 18 hydrogeological units were constructed using legacy borehole data, 2D seismic and airborne electromagnetic (AEM) data that were compiled for the first iteration of the geological and hydrogeological surfaces under the GAB groundwater project (Vizy & Rollet, 2022a) with the addition of: • New data collected and QC’d from boreholes (including petroleum, CSG [Coal Seam Gas], stratigraphic, mineral and water boreholes) across Australia (Vizy & Rollet, 2023a) since the first iteration, including revised stratigraphic correlations filling data and knowledge gaps in the GAB, LEB, UDF region (Norton & Rollet, 2023) with revised palynological constraints (Hannaford & Rollet 2023), • Additional AEM interpretation since the first iteration in the GAB, particularly in the northern Surat (McPherson et al., 2022b), as well as in the LEB (Evans et al., in prep), in the southern Eromanga Basin (Wong et al., 2023) and in the UDF region (McPherson et al., 2022c), and • Additional 2D seismic interpretation in the Gulf of Carpentaria (Vizy & Rollet, 2023b) and in the western and central Eromanga Basin (Szczepaniak et al., 2023). These datasets were then analysed and interpreted in a common 3D domain using a consistent chronostratigraphic framework tied to the geological timescale of 2020, as defined by Hannaford et al. (2022). Confidence maps were also produced to highlight areas that need further investigation due to data gaps, in areas where better seismic depth conversion or improved well formation picks are required. New interpretations from the second iteration of the 18 surfaces include (1) new consistent and regionally continuous surfaces of Cenozoic down to Permian and older sediments beyond the extent of the GAB across eastern Australia, (2) revised extents and thicknesses of Jurassic and Cretaceous units in the GAB, including those based on distributed thickness, (3) revised extents and thicknesses of Cenozoic LEB units constrained by the underlying GAB 3D model surfaces geometry. These data constraints were not used in the model surfaces generated for the LEB detailed inventory (Evans et al., 2023), and (4) refinements of surfaces due to additional seismic and AEM interpretation used to infill data and knowledge gaps. Significant revisions include: • The use of additional seismic data to better constrain the base of the Poolowanna-Evergreen formations and equivalents and the top of Cadna-owie Formation and equivalents in the western and central Eromanga Basin, and the extent and thicknesses of the GAB units and Cenozoic Karumba Basin in the Gulf of Carpentaria, • The use of AEM interpretations to refine the geometry of outcropping units in the northern Surat Basin and the basement surface underneath the UDF region, and • A continuous 3D geological surface of base Cenozoic sediments across eastern Australia including additional constraints for the Lake Eyre Basin (borehole stratigraphy review), Murray Basin (AEM interpretation) and Karumba Basin (seismic interpretation). These revisions to the 18 geological and hydrogeological surfaces will help improve our understanding on the 3D spatial distribution of aquifers and aquitards across eastern Australia, from the groundwater recharge areas to the deep confined aquifers. These data compilations and information brought to a common national standard help improve hydrogeological conceptualisation of groundwater systems across multiple jurisdictions to assist water managers to support responsible groundwater management and secure groundwater into the future. These 3D geological and hydrogeological modelled surfaces also provide a tool for consistent data integration from multiple datasets. These modelled surfaces bring together variable data quality and coverage from different databases across state and territory jurisdictions. Data integration at various scale is important to assess potential impact of different water users and climate change. The 3D modelled surfaces can be used as a consistent framework to map current groundwater knowledge at a national scale and help highlight critical groundwater areas for long-term monitoring of potential impacts on local communities and Groundwater Dependant Ecosystems. The distribution and confidence on data points used in the current iteration of the modelled surfaces highlight where data poor areas may need further data acquisition or additional interpretation to increase confidence in the aquifers and aquitards geometry. The second iteration of surfaces highlights where further improvements can be made, notably for areas in the offshore Gulf of Carpentaria with further seismic interpretation to better constrain the base of the Aptian marine incursion (to better constrain the shape and offshore extent of the main aquifers). Inclusion of more recent studies in the offshore southern and eastern margins of Australia will improve the resolution and confidence of the surfaces, up to the edge of the Australian continental shelf. Revision of the borehole stratigraphy will need to continue where more recent data and understanding exist to improve confidence in the aquifer and aquitard geometry and provide better constraints for AEM and seismic interpretation, such as in the onshore Carpentaria, Clarence-Moreton, Sydney, Murray-Darling basins. Similarly adding new seismic and AEM interpretation recently acquired and reprocessed, such as in the eastern Eromanga Basin over the Galilee Basin, would improve confidence in the surfaces in this area. Also, additional age constraints in formations that span large periods of time would help provide greater confidence to formation sub-divisions that are time equivalent to known geological units that correlate to major aquifers and aquitards in adjacent basins, such as within the Late Jurassic‒Early Cretaceous in the Eromanga and Carpentaria basins. Finally, incorporating major faults and structures would provide greater definition of the geological and hydrogeological surfaces to inform with greater confidence fluid flow pathways in the study area. This report is associated with a data package including (Appendix A – Supplementary material): • Nineteen geological and hydrogeological surfaces from the Base Permo-Carboniferous, Top Permian, Base Jurassic, Base Cenozoic to the surface (Table 1.1), • Twenty-one geological and hydrogeological unit thickness maps from the top crystalline basement to the surface (Figure 3.1 to Figure 3.21), • The formation picks and constraining data points (i.e., from boreholes, seismic, AEM and outcrops) compiled and used for gridding each surface (Table 2.7). Detailed explanation of methodology and processing is described in the associated report (Vizy & Rollet, 2023).

The document summarises new seismic interpretation metadata for two key horizons from Base Jurassic to mid-Cretaceous strata across the western and central Eromanga Basin, and the underlying Top pre-Permian unconformity. New seismic interpretations were completed during a collaborative study between the National Groundwater Systems (NGS) and Australian Future Energy Resources (AFER) projects. The NGS and AFER projects are part of Exploring for the Future (EFTF)—an eight year, $225 million Australian Government funded geoscience data and precompetitive information acquisition program to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This will help support a strong economy, resilient society and sustainable environment for the benefit of all Australians. The EFTF program is supporting Australia’s transition to a low emissions economy, industry and agriculture sectors, as well as economic opportunities and social benefits for Australia’s regional and remote communities. Further details are available at http://www.ga.gov.au/eftf. The seismic interpretations build on previous work undertaken as part of the ‘Assessing the Status of Groundwater in the Great Artesian Basin’ (GAB) Project, commissioned by the Australian Government through the National Water Infrastructure Fund – Expansion (Norton & Rollet, 2022; Vizy & Rollet, 2022; Rollet et al., 2022; Rollet et al., in press.), the NGS Project (Norton & Rollet, 2023; Rollet et al., 2023; Vizy & Rollet, 2023) and the AFER Project (Bradshaw et al., 2022 and in press, Bernecker et al., 2022, Iwanec et al., 2023; Iwanec et al., in press). The recent iteration of revisions to the GAB geological and hydrogeological surfaces (Vizy & Rollet, 2022) provides a framework to interpret various data sets consistently (e.g., boreholes, airborne electromagnetic, seismic data) and in a 3D domain, to improve our understanding of the aquifer geometry, and the lateral variation and connectivity in hydrostratigraphic units across the GAB (Rollet et al., 2022). Vizy and Rollet (2022) highlighted some areas with low confidence in the interpretation of the GAB where further data acquisition or interpretation may reduce uncertainty in the mapping. One of these areas was in the western and central Eromanga Basin. New seismic interpretations are being used in the western Eromanga, Pedirka and Simpson basins to produce time structure and isochore maps in support of play-based energy resource assessment under the AFER Project, as well as to update the geometry of key aquifers and aquitards and the GAB 3D model for future groundwater management under the NGS Project. These new seismic interpretations fill in some data and knowledge gaps necessary to update the geometry and depth of key geological and hydrogeological surfaces defined in a chronostratigraphic framework (Hannaford et al., 2022; Bradshaw et al., 2022 and in press; Hannaford & Rollet, 2023). The seismic interpretations are based on a compilation of newly reprocessed seismic data (Geoscience Australia, 2022), as part of the EFTF program, and legacy seismic surveys from various vintages brought together in a common project with matching parameters (tying, balancing, datum correcting, etc.). This dataset has contributed to a consolidated national data coverage to further delineate groundwater and energy systems, in common data standards and to be used further in integrated workflows of mineral, energy and groundwater assessment. The datasets associated with the product provides value added seismic interpretation in the form of seismic horizon point data for two horizons that will be used to improve correlation to existing studies in the region. The product also provides users with an efficient means to rapidly access a list of core data used from numerous sources in a consistent and cleaned format, all in a single package. The following datasets are provided with this product: 1) Seismic interpretation in a digital format (Appendix A), in two-way-time, on key horizons with publically accessible information, including seismic interpretation on newly reprocessed data: Top Cadna-owie; Base Jurassic; Top pre-Permian; 2) List of surveys compiled and standardised for a consistent interpretation across the study area (Appendix B). 3) Isochore points between Top Cadna-owie and Base Jurassic (CC10-LU00) surfaces (Appendix C). 4) Geographical layer for the seismic lines compiled across Queensland, South Australia and the Northern Territory (Appendix D). These new interpretations will be used to refine the GAB geological and hydrogeological surfaces in this region and to support play-based energy resource assessments in the western Eromanga, Pedirka and Simpson basins.

The National Geochemical Survey of Australia (<a href="http://www.ga.gov.au/ngsa" title="NGSA website" target="_blank">NGSA</a>) is Australia’s only internally consistent, continental-scale <a href="http://dx.doi.org/10.11636/Record.2011.020" title="NGSA geochemical atlas and dataset" target="_blank">geochemical atlas and dataset</a>. The present dataset contains additional mineralogical data obtained on NGSA samples selected from the Darling-Curnamona-Delamerian (<a href="https://www.ga.gov.au/eftf/projects/darling-curnamona-delamerian" title="DCD website" target="_blank">DCD</a>) region of southeastern Australia for the first partial data release of the Heavy Mineral Map of Australia (HMMA) project. The HMMA, a collaborative project between Geoscience Australia and Curtin University underpinned by a pilot project establishing its feasibility, is part of the Australian Government-funded Exploring for the Future (<a href="https://www.ga.gov.au/eftf" title="EFTF website" target="_blank">EFTF</a>) program. The selected 223 NGSA sediment samples fall within the DCD polygon plus an approximately one-degree buffer. The samples were taken on average from 60 to 80 cm depth in floodplain landforms, dried and sieved to a 75-430 µm grainsize fraction, and the contained heavy minerals (HMs; i.e., those with a specific gravity >2.9 g/cm³) were separated by dense fluids and mounted on cylindrical epoxy mounts. After polishing and carbon-coating, the mounts were subjected to automated mineralogical analysis on a TESCAN® Integrated Mineral Analyzer (TIMA). Using scanning electron microscopy and backscatter electron imaging integrated with energy dispersive X-ray analysis, the TIMA identified over 140 different HMs in the DCD area. The dataset, consisting of over 29 million individual mineral grains identified, was quality controlled and validated by an expert team. The data released here can be visualised, explored and downloaded using an online, bespoke mineral network analysis tool (<a href="https://geoscienceaustralia.shinyapps.io/mna4hm/" title="MNA website" target="_blank">MNA</a>) built on a cloud-based platform. Accompanying this report are a data file of TIMA results and a mineralogy vocabulary file. When completed in 2023, it is hoped the HMMA project will positively impact mineral exploration and prospectivity modelling around Australia, as well as have other applications in earth and environmental sciences.