Devonian-Carboniferous granites are widespread in Tasmania. In the east they intrude the Ordovician-Early Devonian quartzwacke turbidites of the Mathinna Supergroup, whereas the western Tasmanian granites intrude a more diverse terrane of predominantly shelf sequences, with depositional ages extending probably back to the Late Mesoproterozoic. The earliest (~400 Ma) I-type granodiorites in the east may be arc-related and pre-date the Tabberabberan Orogeny (~388 Ma), which appears to represent the juxtaposition of the two terranes. Subsequently more felsic and finally strongly fractionated I- and S-type granites were emplaced until ~373 Ma. In western Tasmania, mostly felsic and fractionated I- and S-types granites were emplaced from ~374-351 Ma, possibly in response to back-arc or post-collisional crustal extension

Aspects of the tectonic history of Paleo- to Mesoproterozoic Australia are recorded by metasedimentary basins in the Mt Isa, Etheridge Provinces, and Coen Inlier in northern Australia and in the Curnamona Province of southern Australia. These deformed and metamorphosed basins are interpreted to have been deposited in a tectonically-linked system based on similarities in depositional ages and stratigraphy (Giles at al 2002). Neodymium isotope compositions of sediments and felsic volcanics, when combined with U-Pb geochronology, are independent data that are important tools for inferring tectonic setting, palaeogeography and sediment provenance in deformed and metamorphosed terrains.

In this paper, we present a high resolution study focussed mainly on the Gorgon field and associated Rankin Trend gas fields, Carnarvon Basin, Australia (Figure 1). These gas fields are characterized by numerous stacked reservoirs with varying CO2 contents and provide a relevant natural laboratory for characterizing CO2 migration, dissolution and reaction by looking at chemical characteristics of the different reservoirs (Figure 2). The data we present reveal interesting trends for CO2 mol% and -13C both spatially and with each other as observed by Edwards et al. (2007). Our interpretation of the data suggests that mineral carbonation in certain fields can be significant and relatively rapid. The Gorgon and Rankin Trend fields natural gases may therefore be a unique natural laboratory, which give further insights into the rates and extent of carbonate mineral sequestration as applied to carbon storage operations.

The New England Orogen (NEO) forms the easternmost part of continental Australia, being one of a number of identified orogenic belts within the Tasman Orogenic Zone of eastern Australia. The NEO borders parts of the Lachlan, Thomson and North Queensland Orogens (see Fig. 1), though actual contacts are largely obscured by the Sydney-Gunnedah-Bowen basin system and other cover rocks. The NEO consists of a collage of terranes and has a complex history that stretches from the Neoproterozoic to the Late Mesozoic, although most of the exposed geology is Devonian and younger. A major characteristic of the NEO in this convergent margin setting is the voluminous Carboniferous to Triassic magmatism, which forms a major component of the orogen. Importantly, this magmatism is not confined to the NEO. Carboniferous to mid Triassic felsic magmatism (ca. 350-220 Ma) (Post-Kanimblan Orogeny to Hunter-Bowen Orogeny) forms a major part of the Tasman Orogenic Zone, extending in a wide belt from central New South Wales (the Bathurst region) to islands within the Torres Straits, straddling the Lachlan, Thomson, New England and North Queensland Orogens (Fig. 1), as well as extending into the Proterozoic basement west of the Tasman Orogenic Zone in northern Queensland (Fig. 1). As such, the geochemical and isotopic characteristics of these magmatic rocks, and their regional variations, have the potential to provide significant information regarding the nature and age of the crust in these orogens, as well as to provide constraints on the relationship of the development of the NEO to the neighbouring orogens.

The Brattstrand Paragneiss, a highly deformed Neoproterozoic granulite-facies metasedimentary sequence, is cut by three generations of ~500 Ma pegmatite. The earliest recognizable pegmatite generation, synchronous with D2-3, forms irregular pods and veins up to a meter thick, which are either roughly concordant or crosscut S2 and S3 fabrics and are locally folded. Pegmatites of the second generation, D4, form planar, discordant veins up to 20-30 cm thick, whereas the youngest generation, post-D4, form discordant veins and pods. The D2-3 and D4 pegmatites are abyssal class (BBe subclass) characterized by tourmaline + quartz intergrowths and boralsilite (Al16B6Si2O37); the borosilicates prismatine, grandidierite, werdingite and dumortierite are locally present. In contrast, post-D4 pegmatites host tourmaline (no symplectite), beryl and primary muscovite and are assigned to the beryl subclass of the rare-element class. Spatial correlations between B-bearing pegmatites and B-rich units in the host Brattstrand Paragneiss are strongest for the D2-3 pegmatites and weakest for the post-D4 pegmatites, suggesting that D2-3 pegmatites may be closer to their source. Initial 87Sr/86Sr (at 500 Ma) is high and variable (0.7479-0.7870), while -Nd500 tends to be least evolved in the D2-3 pegmatites (-8.1 to -10.7) and most evolved in the post-D4 pegmatites (-11.8 to -13.0). Initial 206Pb/204Pb and 207Pb/204Pb and 208Pb/204Pb ratios, measured in acid-leached alkali feldspar separates with low U/Pb and Th/Pb ratios, vary considerably (17.71-19.97, 15.67-15.91, 38.63-42.84), forming broadly linear arrays well above global Pb growth curves. The D2-3 pegmatites contain the most radiogenic Pb while the post-D4 pegmatites have the least radiogenic Pb; data for D4 pegmatites overlap with both groups. Broad positive correlations for Pb and Nd isotope ratios could reflect source rock compositions controlled two components. Component 1 (206Pb/204Pb-20, 208Pb/204-43, Nd -8) most likely represents old upper crust with high U/Pb and very high Th/Pb. Component 2 (206Pb/204Pb -18, 208Pb/204Pb~38.5, -Nd500 -12 to -14) has a distinctive high-207Pb/206Pb signature which evolved through dramatic lowering of U/Pb in crustal protoliths during the Neoproterozoic granulite-facies metamorphism. Component 1, represented in the locally-derived D2-3 pegmatites, could reside within the Brattstrand Paragneiss, which contains detrital zircons up to 2.1 Ga old and has a wide range of U/Pb and Th/Pb ratios. The Pb isotope signature of component 2, represented in the 'far-from-source' post-D4 pegmatites, resembles feldspar Pb isotope ratios in Cambrian granites intrusive into the Brattstrand Paragneiss. However, given their much higher 87Sr/86Sr, the post-D4 pegmatite melts are unlikely to be direct magmatic differentiates of the granites, although they may have broadly similar crustal sources. Correlation of structural timing with isotopic signatures, with a general sense of deeper sources in the younger pegmatite generations, may reflect cooling of the crust after Cambrian metamorphism.

The oxygen isotopic record obtained from Globigerina bulloides, Globorotalia inflata, and Neogloboquadrina pachyderma (s.) was analysed for 5 sediment traps moored in the Southern Ocean and Southwest Pacific. The traps extend from Subtropical to the Polar Frontal environments, providing the first analysis of seasonal foraminiferal d18O records from these latitudes. Comparison between the foraminiferal records and various equations for predicted d18O of calcite reveals that the predicted d18O is best captured by the equations of Epstein et al. (1953) [Epstein, S., Buchsbaum, R., Lowenstam, H.A., Urey, H.C., 1953. Revised carbonate-water isotopic temperature scale. Geological Society of America Bulletin 64, 1315-1326.] and Kim and O'Neil (1997) [Kim, S.-T., O'Neil, J.R., 1997. Equilibrium and non-equilibrium oxygen isotope effects in synthetic carbonates. Geochimica et Cosmochimica Acta 61, 3461-3475.]. The Epstein equation shows a constant offset from the -18O of G. bulloides and N. pachyderma (s.) across the full range of latitudes. The seasonal range in -18O values for these two species implies a near-surface habitat across all sites, while G. inflata most likely dwells at 50 m depth. A significant finding in this study was that offsets from predicted -18O for G. bulloides do not correlate to changes in the carbonate ion concentration. This suggests that [CO32-] in and of itself may not capture the full range of carbonate chemistry conditions in the marine system. This sediment trap deployment also reveals distinct seasonal flux patterns for each species. Comparison between flux-weighted isotopic values calculated from the sediment traps and the isotopic composition of nearby surface sediments indicates that the sedimentary records retain this seasonal imprint. At the 51°S site, G. bulloides has a spring flux peak while N. pachyderma (s.) is dominated by summer production.

Paleoarchean rocks of the tonalite-trondhjemite-granodiorite (TTG) series require a basaltic source region more enriched in K, LILE, Th and LREE than the low-K tholeiites typical of Archean supracrustal sequences. Most TTG of the Pilbara Craton, in northwestern Australia, formed between 3.5 and 3.42 Ga through infracrustal melting of a source older than 3.5 Ga. Basaltic to andesitic rocks of the 3.51 Ga Coucal Formation, at the base of the Pilbara Supergroup, are amongst the only well-preserved remnants of pre-3.5 Ga supracrustal material on Earth, and may have formed a large proportion of pre-3.5 Ga Pilbara crust. These rocks are significantly enriched in K, LILE, Th and LREE compared to post-3.5 Ga Paleoarchean basalts and andesites, and form a compositionally suitable source for TTG. Enrichment in these basalts was not the result of crustal assimilation but was inherited from a mantle source that was less depleted than modern MORBsource and was enriched in recycled crustal components.We suggest that the formation of Paleoarchean TTG and of their voluminous mafic source regions reflects both a primitive stage in the thermal and compositional evolution of the mantle and a significant prehistory of crustal recycling.

The carbon and hydrogen isotopic data of natural gases provide a crucial tool to interpret the origin, occurrence and inter-relationships of natural gases. The CF-GC-IRMS is a convenient system to separate gas mixture and obtain continuous, on-line isotopic data of individual compounds. With CF-GC-IRMS system, the abundance of target components is crucial. For an accurate result, there should be enough target compound going through the furnace to be measured as CO2 using isotopic ratio mass spectrometry. For carbon isotopes, a m/z 44 response below 0.3 V (or over 7V) is regarded as unreliable. For high abundant compounds, there is no difficulty in attaining a voltage over 0.3V with a normal injection of under 100ul with adjusted split flow. However, the acquisition for the low concentration component is problematic since "normal" injection would not produce a strong enough signal. In this presentation, we demonstrated the techniques used to obtain low concentration components occurring in the Australian natural gases and how we apply the results in gas comparison studies. Cryogenics (liquid nitrogen trap) is applied to trap and concentrate low amount of compounds other than methane (C1), including CO2, C2 and above. With this method, extreme low concentration of C2 from very dry gases was obtained with large volume injection of 10ml. Back-flash is used together with cryogenics. For analyses for only C4 and C5 compounds, cryogenics was not needed, since they focus at the front of the column at 40oC and elute from the column under oven temperature programming as single peaks. Neo-pentane (neo-C5) is generally the least abundant wet gas component. Its concentration is enhanced in the gases which are biodegraded, wherein the other gas components have been selectively removed by microbial activity. Neo-pentane is extremely resistant to biodegradation and shows no isotopic alteration even in severely biodegraded gas. In such cases, neo-C5 is the only gas component that can be confidently used in gas-gas correlation. Neo-pentane is an example where we employ injection of a large volume (e.g. to 40ml for hydrogen isotopes), combining a back-flashing technique for compounds eluting before C4 (inclusive) and C5 compounds. The neo-C5 elutes between nC4 and i-C5. Under the current GC conditions, there is a time "window" of less than 40 seconds to capture neo-C5. A manual operation to set back-flash to straight flow to allow capture neo-C5 just after n-C4 elutes and then back to back-flush to eliminate interference of C5's compounds. Mass balance estimation indicates that there is no loss of neo-C5 during the large volume injection and repeatability is excellent.

Inland sulfidic soils have recently formed throughout wetlands of the Murray River floodplain associated with increased salinity and river regulation (Lamontagne et al., 2006). Sulfides have the potential to cause widespread environmental degradation both within sulfidic soils and down stream depending on the amount of carbonate available to neutralise acidity (Dent, 1986). Sulfate reduction is facilitated by organic carbon decomposition, however, little is known about the sources of sedimentary organic carbon and carbonate or the process of sulfide accumulation within inland sulfidic wetlands. This investigation uses stable isotopes from organic carbon (13C and 15N), inorganic sulfur (34S) and carbonate (13C and 18O) to elucidate the sources and cycling of sulfur and carbon within sulfidic soils of the Loveday Disposal Basin.

Initial lead isotope ratios from Archean volcanic-hosted massive sulfide (VHMS) and lode gold deposits and neodymium isotope model ages from igneous rocks from the geological provinces that host these deposits identify systematic spatial and temporal patterns, both within and between the provinces. The Abitibi-Wawa Subprovince of the Superior Province is characterized by highly juvenile lead and neodymium. Most other Archean provinces, however, are characterized by more evolved isotopes, although domains within them can be characterized by juvenile isotope ratios. Metal endowment (measured as the quantity of metal contained in geological resources per unit surface area) of VHMS and komatiite-associated nickel sulfide (KANS) deposits is related to the isotopic character, and therefore the tectonic history, of provinces that host these deposits. Provinces with extensive juvenile crust have significantly higher endowment of VHMS deposits, possibly as a consequence of higher heat flow and extension-related faults. Provinces with evolved crust have higher endowment of KANS deposits, possibly because such crust provided either a source of sulfur or a stable substrate for komatiite emplacement. In any case, initial radiogenic isotope ratios can be useful in predicting the endowment of Archean terranes for VHMS and KANS deposits. Limited data suggest similar relationships may hold in younger terranes.