Regolith
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The regolith landform maps are drawn at various scales and illustrate the distribution of regolith materials and the landforms on which they occur. Regolith landforms are described using the regolith terrain mapping (RTMAP) scheme developed at Geoscience Australia or the Residual-Erosional-Depositional (RED) mapping scheme developed by the CSIRO Division of Exploration and Mining.
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Bulk quantitative mineralogy of regolith is a useful indicator of lithological precursor (protolith), degree of weathering, and soil properties affecting various potential landuse decisions. To date, no national-scale maps of regolith mineralogy are available in Australia. Catchment outlet sediments collected over 80% of the continent as part of the National Geochemical Survey of Australia (NGSA) afford a unique opportunity to rapidly and cost-effectively determine regolith mineralogy using the archived sample material. This report releases mineralogical data and metadata obtained as part of a feasibility study in a selected pilot area for such a national regolith mineralogy database and atlas. The area chosen for this study is within the Darling-Curnamona-Delamerian (DCD) region of southeastern Australia. The DCD region was selected as a ‘deep-dive’ data acquisition and analysis by the Exploration for the Future (2020-2024) federal government initiative managed at Geoscience Australia. One hundred NGSA sites from the DCD region were prepared for X-Ray Diffraction (XRD) analysis, which consisted of qualitative mineral identification of the bulk samples (i.e., ‘major’ minerals), qualitative clay mineral identification of the <2 µm grain-size fraction, and quantitative analysis of both ‘major’ and clay minerals of the bulk sample. The identified mineral phases were quartz, plagioclase, K-feldspar, calcite, dolomite, gypsum, halite, hematite, goethite, rutile, zeolite, amphibole, talc, kaolinite, illite (including muscovite and biotite), palygorskite (including interstratified illite-smectite and vermiculite), smectite (including interstratified illite-smectite), vermiculite, and chlorite. Poorly diffracting material (PDM) was also quantified and reported as ‘amorphous’. Mineral identification relied on the EVA® software, whilst quantification was performed using Siroquant®. Resulting mineral abundances are reported with a Chi-squared goodness-of-fit between the actual diffractogram and a modelled diffractogram for each sample, as well as an estimated standard error (esd) measurement of uncertainty for each mineral phase quantified. Sensitivity down to 0.1 wt% (weight percent) was achieved, with any mineral detection below that threshold reported as ‘trace’. Although detailed interpretation of the mineralogical data is outside the remit of the present data release, preliminary observations of mineral abundance patterns suggest a strong link to geology, including proximity to fresh bedrock, weathering during sediment transport, and robust relationships between mineralogy and geochemistry. The mineralogical data generated by this study are presented in Appendix A of this report and are downloadable as a .csv file. Mineral abundance or presence/absence maps are shown in Appendices B and C to document regional mineralogical patterns.
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<div>Geochemistry of soils, stream sediments, and overbank sediments, plays an important part in informing geochemical environmental baselines, mineral prospectivity, and environmental management practices. Australia has a large number of such surveys, but they are spatially isolated and often used in isolation. First released in 2020, the Levelled Geochemical Baseline of Australia focused on levelling such surveys across the North Australian Craton, so that they could be used as a seamless dataset. This data release acts as an update to the Levelled Geochemical Baseline of Australia by changing the focus to national scale and incorporating recently reanalysed legacy samples.</div><div><br></div><div>This work was undertaken as part of the Exploring for the Future program, an eight-year program by the Australian government. The Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to net zero emissions, strong, sustainable resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, was an eight year, $225m investment by the Australian Government.</div><div><br></div><div><br></div><div><br></div><div><br></div>
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Remotely sensed data and updated DEM and radiometric datasets, combined with existing surface material and landform mapping were used to map regolith landform units for the Ti Tree, Western Davenport and Tennant Creek regions of the SSC project. This report describes the methods used and outlines the new mapping.
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Estimating the relative contributions of bedrock geology, mineralisation and anthropogenic contamination to the chemistry of samples collected at the Earth’s surface is critical in research and application fields as diverse as environmental impact studies and regional mineral exploration programs. The element lead (Pb) is a particularly useful tracer in this context, representing a toxin of environmental concern and associated with many other anthropogenic contaminants (e.g. mine wastes, waters, paints, aerosols), as well as with mineralisation. Although Pb concentration data are frequently collected in geochemical studies, isotopic analysis offers an important advantage, allowing discrimination between different sources of Pb. The Pb isotopic composition of regolith is likely to reflect contributions from underlying rock (including Pb-rich mineralisation), wind-blown dust and possibly anthropogenic sources (industry, transport, agriculture, residential, waste handling). Regolith samples collected at different depths may show distinct compositions; bedrock isotopic signatures are expected to dominate in deeper soils, whilst airborne dust and anthropogenic signatures are more important at the surface. Pb isotope ratios in the continental crust show large variations, which will be transferred to the regolith, providing a potentially unique bedrock signal that is easily measured. This research program examines if soil Pb isotope mapping can identify the underlying geology and metallogenic provinces, if different sampling and analytical approaches produce very different results, and how anthropogenic signals vary across the continent. Here, we present our results for the Northern Territory, where single regolith samples from many (not all) catchments define apparently consistent isotopic domains that can be interpreted in relation to the underlying geology (crystalline basement, basins) and mineral deposits. <b>Citation:</b> Desem, C.U., Maas, R., Woodhead, J., Carr, G. and de Caritat P., 2020. Towards a Pb isotope regolith map of the Australian continent: a Northern Territory perspective. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.
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Preamble: The 'National Geochemical Survey of Australia: The Geochemical Atlas of Australia' was published in July 2011 along with a digital copy of the NGSA geochemical dataset (http://dx.doi.org/10.11636/Record.2011.020). The NGSA project is described here: www.ga.gov.au/ngsa. The present dataset contains additional geochemical data obtained on NGSA samples: the Lead Isotopes Dataset. Abstract: Over 1200 new lead (Pb) isotope analyses were obtained on catchment outlet sediment samples from the NGSA regolith archive to document the range and patterns of Pb isotope ratios in the surface regolith and their relationships to geology and anthropogenic activity. The selected samples included 1204 NGSA Top Outlet Sediment (TOS) samples taken from 0 to 10 cm depth and sieved to <2 mm (or ‘coarse’ fraction); three of these were analysed in duplicate for a total of 1207 Pb isotope analyses. Further, 12 Northern Australia Geochemical Survey (NAGS; http://dx.doi.org/10.11636/Record.2019.002) TOS samples from within a single NGSA catchment, also sieved to <2 mm, were analysed to provide an indication of smaller scale variability. Combined, we thus present 1219 new TOS coarse, internally comparable data points, which underpin new national regolith Pb isoscapes. Additionally, 16 NGSA Bottom Outlet Sediment (BOS; ~60 to 80 cm depth) samples, also sieved to <2 mm, and 16 NGSA TOS samples sieved to a finer grainsize (<75 um, or ‘fine’) fraction from selected NGSA catchments were also included to inform on Pb mobility and residence. Lead isotope analyses were performed by Candan Desem as part of her PhD research at the School of Geography, Earth and Atmospheric Sciences, University of Melbourne. After an initial ammonium acetate (AmAc) leach, the samples were digested in aqua regia (AR). Although a small number of samples were analysed after the AmAc leach, all samples were analysed after the second, AR digestion, preparation step. The analyses were performed without prior matrix removal using a Nu Instruments Attom single collector Sector Field-Inductively Coupled Plasma-Mass Spectrometer (SF-ICP-MS). The dried soil digests were redissolved in 2% HNO3 run solutions containing high-purity thallium (1 ppb Tl) and diluted to provide ~1 ppb Pb in solution. Admixture of natural, Pb-free Tl (with a nominal 205Tl/203Tl of 2.3871) allowed for correction of instrumental mass bias effects. Concentrations of matrix elements in the diluted AR digests are estimated to be in the range of 1–2 ppm. The SF-ICP-MS was operated in wet plasma mode using a Glass Expansion cyclonic spray chamber and glass nebuliser with an uptake rate of 0.33 mL/min. The instrument was tuned for maximum sensitivity and provided ~1 million counts per second/ppb Pb while maintaining flat-topped peaks. Each analysis, performed in the Attom’s ‘deflector peak jump’ mode, consists of 30 sets of 2000 sweeps of masses 202Hg, 203Tl, 204Pb, 205Tl, 206Pb, 207Pb and 208Pb, with dwell times of 500 μs and a total analysis time of 4.5 min. Each sample acquisition was preceded by a blank determination. All corrections for baseline, sample Hg interference (202Hg/204Pb ratios were always <0.043) and mass bias were performed online, producing typical in-run precisions (2 standard errors) of ±0.047 for 206Pb/204Pb, ±0.038 for 207Pb/204Pb, ±0.095 for 208Pb/204Pb, ±0.0012 for 207Pb/206Pb and ±0.0026 for 208Pb/206Pb. A small number of samples with low Pb concentrations exhibited very low signal sizes during analysis resulting in correspondingly high analytical uncertainties. Samples producing within-run uncertainties of >1% relative (measured on the 207Pb/204Pb ratio) were discarded as being insufficiently precise to contribute meaningfully to the dataset. Data quality was monitored using interspersed analyses of Tl-doped ~1 ppb solutions of the National Institute of Standards and Technology (NIST) SRM981 Pb standard, and several silicate reference materials: United States Geological Survey ‘BCR-2’ and ‘AGV-2’, Centre de Recherches Pétrographiques et Géochimiques ‘BR’ and Japan Geological Survey ‘JB-2’. In a typical session, up to 50 unknowns plus 15 standards were analysed using an ESI SC-2 DX autosampler. Although previous studies using the Attom SF-ICP-MS used sample-standard-bracketing techniques to correct for instrumental Pb mass bias, Tl doping was found to produce precise, accurate and reproducible results. Based upon the data for the BCR-2 and AGV-2 secondary reference materials, for which we have the most analyses, deviations from accepted values (accuracy) were typically <0.17%. Data for the remaining silicate standards appear slightly less accurate but these results may, to some extent, reflect uncertainty in the assigned literature values for these materials. Replicate runs of selected AR digests yielded similar reproducibility estimates. The results show a wide range of Pb isotope ratios in the NGSA (and NAGS) TOS <2 mm fraction samples across the continent (N = 1219): 206Pb/204Pb: Min = 15.558; Med ± Robust SD = 18.844 ± 0.454; Mean ± SD = 19.047 ± 1.073; Max = 30.635 207Pb/204Pb; Min = 14.358; Med ± Robust SD = 15.687 ± 0.091; Mean ± SD = 15.720 ± 0.221; Max = 18.012 208Pb/204Pb; Min = 33.558; Med ± Robust SD = 38.989 ± 0.586; Mean ± SD = 39.116 ± 1.094; Max = 48.873 207Pb/206Pb; Min = 0.5880; Med ± Robust SD = 0.8318 ± 0.0155; Mean ± SD = 0.8270 ± 0.0314; Max = 0.9847 208Pb/206Pb; Min = 1.4149; Med ± Robust SD = 2.0665 ± 0.0263; Mean ± SD = 2.0568 ± 0.0675; Max = 2.3002 These data allow the construction of the first continental-scale regolith Pb isotope maps (206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, 207Pb/206Pb, and 208Pb/206Pb isoscapes) of Australia and can be used to understand contributions of Pb from underlying bedrock (including Pb-rich mineralisation), wind-blown dust and possibly from anthropogenic sources (industrial, transport, agriculture, residential, waste handling). The complete dataset is available to download as a comma separated values (CSV) file from Geoscience Australia's website (http://dx.doi.org/10.26186/5ea8f6fd3de64). Isoscape grids (inverse distance weighting interpolated grids with a power coefficient of 2 prepared in QGis using GDAL gridding tool based on nearest neighbours) are also provided for the five Pb isotope ratios (IDW2NN.TIF files in zipped folder). Alternatively, the new Pb isotope data can be downloaded from and viewed on the GA Portal (https://portal.ga.gov.au/).
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<div>Bulk quantitative mineralogy of regolith is a useful indicator of lithological precursor (protolith), degree of weathering, and soil properties affecting various potential landuse decisions. To date, no empirical national-scale maps of regolith mineralogy are available in Australia. Satellite-derived mineralogical proxy products exist, however, they require on-the-ground validation. Catchment outlet sediments collected over 80% of the continent as part of the National Geochemical Survey of Australia (NGSA) afford a unique opportunity to rapidly and cost-effectively determine regolith mineralogy using the archived sample material. This report releases mineralogical data and metadata obtained as part of a study extending a previous pilot project for such a national regolith mineralogy database and atlas.</div><div>The area chosen for this study includes the part of South Australia not inside the pilot project, which focussed on the 2020-2024 Exploring for the Future (EFTF) Darling-Curnamona-Delamerian (DCD) region of southeastern Australia, as well as the EFTF Barkly-Isa-Georgetown (BIG) region of northern Australia. The South Australian part of the study was selected because the Geological Survey of South Australia indicated interest in expanding the pilot (DCD) project to the rest of the State. The BIG region was selected because it is a ‘deep-dive’ data acquisition and analysis area within the EFTF Australian Government initiative managed at Geoscience Australia. The whole study area essentially describes a continuous north-south trans-continental transect spanning South Australia (SA), Queensland (Qld) and the Northern Territory (NT), and is herein abbreviated as SA-Qld-NT.</div><div>Two hundred and sixty four NGSA sites from the SA-Qld-NT region were prepared for X-Ray Diffraction (XRD) analysis, which consisted of qualitative mineral identification of the bulk samples (i.e., ‘major’ minerals), qualitative clay mineral identification of the <2 µm grain-size fraction, and quantitative analysis of both major and clay minerals of the bulk sample. The identified mineral phases were quartz, kaolinite, plagioclase, K-feldspar, nosean (a sulfate bearing feldspathoid), calcite, dolomite, aragonite, ankerite, hornblende, gypsum, bassanite (a partially hydrated calcium sulfate), halite, hematite, goethite, magnetite, rutile, anatase, pyrite, interstratified or mixed-layer illite-smectite, smectite, muscovite, chlorite (group), talc, palygorskite, jarosite, alunite, and zeolite (group). Poorly diffracting material was also quantified and reported as ‘amorphous.’ Mineral identification relied on the EVA® software, whilst quantification was performed using Siroquant®. Resulting mineral abundances are reported with a Chi-squared goodness-of-fit between the actual diffractogram and a modelled diffractogram for each sample, as well as an estimated standard error (esd) measurement of uncertainty for each mineral phase quantified. Sensitivity down to 0.1 weight percent (wt%) was achieved, with any mineral detection below that threshold reported as ‘trace.’ </div><div>Although detailed interpretation of the mineralogical data is outside the remit of the present data release, preliminary observations of mineral abundance patterns suggest a strong link to geology, including proximity to fresh bedrock, weathering during sediment transport, and robust relationships between mineralogy and geochemistry. The mineralogical data generated by this study are downloadable as a .csv file from the Geoscience Australia website (https://dx.doi.org/10.26186/147990). </div>
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<div>This data package contains interpretations of airborne electromagnetic (AEM) conductivity sections in the Exploring for the Future (EFTF) program’s Eastern Resources Corridor (ERC) study area, in south eastern Australia. Conductivity sections from 3 AEM surveys were interpreted to provide a continuous interpretation across the study area – the EFTF AusAEM ERC (Ley-Cooper, 2021), the Frome Embayment TEMPEST (Costelloe et al., 2012) and the MinEx CRC Mundi (Brodie, 2021) AEM surveys. Selected lines from the Frome Embayment TEMPEST and MinEx CRC Mundi surveys were chosen for interpretation to align with the 20 km line-spaced EFTF AusAEM ERC survey (Figure 1).</div><div>The aim of this study was to interpret the AEM conductivity sections to develop a regional understanding of the near-surface stratigraphy and structural architecture. To ensure that the interpretations took into account the local geological features, the AEM conductivity sections were integrated and interpreted with other geological and geophysical datasets, such as boreholes, potential fields, surface and basement geology maps, and seismic interpretations. This approach provides a near-surface fundamental regional geological framework to support more detailed investigations. </div><div>This study interpreted between the ground surface and 500 m depth along almost 30,000 line kilometres of nominally 20 km line-spaced AEM conductivity sections, across an area of approximately 550,000 km2. These interpretations delineate the geo-electrical features that correspond to major chronostratigraphic boundaries, and capture detailed stratigraphic information associated with these boundaries. These interpretations produced approximately 170,000 depth estimate points or approximately 9,100 3D line segments, each attributed with high-quality geometric, stratigraphic, and ancillary data. The depth estimate points are formatted for compliance with Geoscience Australia’s (GA) Estimates of Geological and Geophysical Surfaces (EGGS) database, the national repository for standardised depth estimate points. </div><div>Results from these interpretations provided support to stratigraphic drillhole targeting, as part of the Delamerian Margins NSW National Drilling Initiative campaign, a collaboration between GA’s EFTF program, the MinEx CRC National Drilling Initiative and the Geological Survey of New South Wales. The interpretations have applications in a wide range of disciplines, such as mineral, energy and groundwater resource exploration, environmental management, subsurface mapping, tectonic evolution studies, and cover thickness, prospectivity, and economic modelling. It is anticipated that these interpretations will benefit government, industry and academia with interest in the geology of the ERC region.</div>
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Managed aquifer recharge (MAR) enhances recharge to aquifers. As part of the Exploring for the Future Southern Stuart Corridor project, remotely sensed data were used to map regolith materials and landforms, and to identify areas that represent potential MAR target areas for future investigation. Nine areas were identified, predominantly associated with alluvial landforms in low-gradient landscape settings. The surface materials are typically sandy, or sandy and silty, with the prospective areas overlying newly identified groundwater resources associated with Paleozoic sedimentary rocks of the Wiso and Georgina basins. The workflow used here can be rapidly rolled out across broader areas, and can be supplemented by higher-resolution, longer time-series remote-sensing data, coupled with data analytics, modelling and expert knowledge. Such an approach will help to identify areas of the arid interior that may be suitable for MAR schemes that could supplement water for remote communities, and agricultural and other natural resource developments. <b>Citation:</b> Smith, M.L., Hostetler, S. and Northey, J., 2020. Managed aquifer recharge prospectivity mapping in the Northern Territory arid zone using remotely sensed data. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.
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The National Geochemical Survey of Australia (NGSA) provides an internally consistent, state-of-the-art, continental-scale geochemical dataset that can be used to assess areas of Australia more elevated in commodity metals and/or pathfinder elements than others. But do regions elevated in such elements correspond to known mineralized provinces, and what is the best method for detecting and thus potentially predicting those? Here, using base metal associations as an example, I compare a trivariate rank-based index and a multivariate-based Principal Component Analysis method. The analysis suggests that the simpler rank-based index better discriminates catchments endowed with known base metal mineralization from barren ones and could be used as a first-pass prospectivity tool. <b>Citation:</b> Patrice de Caritat, Continental-scale geochemical surveys and mineral prospectivity: Comparison of a trivariate and a multivariate approach, <i>Journal of Geochemical Exploration</i>, Volume 188, 2018, Pages 87-94, ISSN 0375-6742, https://doi.org/10.1016/j.gexplo.2018.01.014