carbon dioxide
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This publication is the successor to Oil and Gas Resources of Australia 2001 and continues as the definitive reference on exploration, development and production of Australia's petroleum resources. OGRA 2002 provides the background for much of the advice on petroleum resources given to the Australian Government.
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Accurate seismic velocity model is essential for depth conversion and rock property determination in the context of fluid flow modelling to support site selection for secure storage of carbon dioxide. The Bonaparte CO2 Storage project funded by the Australian Government will assess the carbon dioxide geological storage potential of two blocks in the Petrel Sub-basin on the Australian NW Margin. These blocks were offered as part of the 2009 release of offshore areas for greenhouse gas (GHG) storage assessment. The Petrel Sub-basin is a northwest-trending Paleozoic rift within the southern Bonaparte Basin. The geological reservoirs of interest include the Jurassic Plover Formation and the Early Cretaceous Sandpiper Sandstone. Primary and secondary seals of interest include the Late Jurassic Frigate Formation and the Cretaceous Bathurst Island Group (regional seal). Trapping mechanisms for injected CO2 may include faulted anticlines, stratigraphic traps, salt diapirs and/or migration dissolution and residual trapping. Water depths are generally less than 100m and depths to reservoir/seal pairs range between 800-2500m below the sea surface. All three main types of seismic velocity measurements are available within the area of our study: velocities derived from stacking of multi-channel reflection seismic data; velocities determined in the process of ray tracing modelling of large offset refraction data acquired by the ocean bottom seismographs (OBS) along the coincident reflection/refraction transect, and velocities from well log (sonic, vertical seismic profiling and check shot) measurements.
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In this paper, we present a high resolution study focussed mainly on the Gorgon field and associated Rankin Trend gas fields, Carnarvon Basin, Australia (Figure 1). These gas fields are characterized by numerous stacked reservoirs with varying CO2 contents and provide a relevant natural laboratory for characterizing CO2 migration, dissolution and reaction by looking at chemical characteristics of the different reservoirs (Figure 2). The data we present reveal interesting trends for CO2 mol% and -13C both spatially and with each other as observed by Edwards et al. (2007). Our interpretation of the data suggests that mineral carbonation in certain fields can be significant and relatively rapid. The Gorgon and Rankin Trend fields natural gases may therefore be a unique natural laboratory, which give further insights into the rates and extent of carbonate mineral sequestration as applied to carbon storage operations.
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Groundwater has been sampled from 21 shallow (Port Campbell Limestone) and 3 deep (Dilwyn Formation) groundwater bores within a radius of 10 km around well CRC-1 between June 2006 and March 2008. The objectives of the study are (1) to establish baseline aquifer conditions prior to CO2 injection at CRC-1, which started in April 2008, and (2) to enable detection monitoring for CO2 leakage, should any occur in the future. In addition to sampling, standing water levels have been monitored continuously in 6 of the bores using barometric loggers. The water samples were analysed for pH, electrical conductivity (EC), temperature (T), dissolved oxygen (DO), redox potential (Eh), reduced iron (Fe2+) and alkalinity (dissolved inorganic carbon, DIC, as HCO3-) in the field, and for a suite of major, minor and trace inorganic species in the laboratory. Stable isotopes of O and H in water, of S in sulfate and of C and O in DIC were also determined. The shallow groundwaters have compositions typical of carbonate aquifer hosted waters, being fresh (EC 800-4000 uS/cm), dominated by Ca, Na, HCO3- and Cl-, cool (T 12-23°C), and near-neutral (pH 6.6-7.5). Most deep groundwater samples are similarly fresh or fresher (EC 400-1600 uS/cm), also dominated by Ca, Na, HCO3- and Cl-, cool (T 15-21°C), but are more alkaline (pH 7.5-9.5). Time-series reveal that parameters measured have been relatively stable over the sampling period, although some shallow bores display increasing EC and T, some show decreasing then increasing alkalinity while others show steadily increasing alkalinity (with or without increasing Cl- and Na, and decreasing Ca). Alkalinity of the deep groundwater tends to decrease slightly over the period. Groundwater levels in some of the shallow bores show a seasonal variation with longer term trends evident in both aquifers.
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Atmospheric tomography is a monitoring technique that uses an array of sampling sites and a Bayesian inversion technique to simultaneously solve for the location and magnitude of a gaseous emission. Application of the technique to date has relied on air samples being pumped over short distances to a high precision FTIR Spectrometer, which is impractical at larger scales. We have deployed a network of cheaper, less precise sensors during three recent large scale controlled CO2 release experiments; one at the CO2CRC Ginninderra site, one at the CO2CRC Otway Site and another at the Australian Grains Free Air CO2 Enrichment (AGFACE) facility in Horsham, Victoria. The purpose of these deployments was to assess whether an array of independently powered, less precise, less accurate sensors could collect data of sufficient quality to enable application of the atmospheric tomography technique. With careful data manipulation a signal suitable for an inversion study can be seen. A signal processing workflow based on results obtained from the atmospheric array deployed at the CO2CRC Otway experiment is presented.
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Abstract for submission to 11th IEA GHG International Conference on Greenhouse Gas Control Technologies. Conference paper to follow pending selection for oral or poster presentation. Abstract covers the GA-ACCA21 China Australia Geological Storage of CO2 (CAGS) Project run through PMD/ED 2009-2012.
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No abstract available
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Between March 2008 and August 2009, 65,445 tonnes of ~75 mol% CO2 gas were injected in a depleted natural gas reservoir approximately 2000 m below surface at the Otway project site in Victoria, Australia. Groundwater flow and composition were monitored biannually in 2 near-surface aquifers between June 2006 and March 2011, spanning the pre-, syn- and post-injection periods. The shallow (~0-100 m), unconfined, porous and karstic aquifer of the Port Campbell Limestone and the deeper (~600-900 m), confined and porous aquifer of the Dilwyn Formation contain valuable fresh water resources. Groundwater levels in either aquifer have not been affected by the drilling, pumping and injection activities that were taking place, or by the rainfall increase observed during the project. In terms of groundwater composition, the Port Campbell Limestone groundwater is fresh (electrical conductivity = 801-3900 ?S/cm), cool (temperature = 12.9-22.5 C), and near-neutral (pH 6.62-7.45), whilst the Dilwyn Formation groundwater is fresher (electrical conductivity 505-1473 ?S/cm), warmer (temperature = 42.5-48.5 C), and more alkaline (pH 7.43-9.35). Evapotranspiration and carbonate dissolution control the composition of the groundwaters. Comparing the chemical and isotopic composition of the groundwaters collected before, during and after injection shows either no sign of statistically significant changes or, where they are statistically significant, changes that are generally opposite those expected if CO2 addition had taken place. The monitoring program demonstrates that the physical and chemical properties of the groundwaters at the sampled bores have not been affected by CO2 sequestration.
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No abstract available
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Phase two of the China Australia Geological Storage of CO2 (CAGS2) project aimed to build on the success of the previous CAGS project and promote capacity building, training opportunities and share expertise on the geological storage of CO2. The project was led by Geoscience Australia (GA) and China's Ministry of Science and Technology (MOST) through the Administrative Centre for China's Agenda 21 (ACCA21). CAGS2 has successfully completed all planned activities including three workshops, two carbon capture and storage (CCS) training schools, five research projects focusing on different aspects of the geological storage of CO2, and ten researcher exchanges to China and Australia. The project received favourable feedback from project partners and participants in CAGS activities and there is a strong desire from the Chinese government and Chinese researchers to continue the collaboration. The project can be considered a highly successful demonstration of bi-lateral cooperation between the Australian and Chinese governments. Through the technical workshops, training schools, exchange programs, and research projects, CAGS2 has facilitated and supported on-going collaboration between many research institutions and industry in Australia and China. More than 150 experts, young researchers and college students, from over 30 organisations, participated in CAGS2. The opportunity to interact with Australian and international experts at CAGS hosted workshops and schools was appreciated by the participants, many of whom do not get the opportunity to attend international conferences. Feedback from a CAGS impact survey found that the workshops and schools inspired many researchers and students to pursue geological storage research. The scientific exchanges proved effective and often fostered further engagement between Chinese and Australian researchers and their host organisations. The research projects often acted as a catalyst for attracting additional CCS funding (at least A$700,000), including two projects funded under the China Clean Development Mechanism Fund. CAGS sponsored research led to reports, international conference presentations, and Chinese and international journal papers. CAGS has established a network of key CCS/CCUS (carbon capture, utilisation and storage) researchers in China and Australia. This is exemplified by the fact that 4 of the 6 experts that provided input on the 'storage section of the 12th Five-Year plan for Scientific and Technological Development of Carbon Capture, Utilization and Storage, which laid out the technical policy priorities for R&D and demonstration of CCUS technology in China, were CAGS affiliated researchers. The contributions of CAGS to China's capacity building and policy CCUS has been acknowledged by the Chinese Government. CAGS support of young Chinese researchers is particularly noted and well regarded. Letters have been sent to the Secretary of the Department of Industry and Science and to the Deputy CEO of Geoscience Australia, expressing China's gratitude for the Australian Government's support and GA's cooperation in the CAGS project.