The stabilities of uranyl-carbonate and uranyl-hydroxide aqueous complexes were experimentally determined at temperatures ranging from 25 to 125 °C using in situ UV–vis and Raman spectroscopic techniques. Combined with earlier determinations of the stability of chloride, sulfate, and hydroxide complexes at temperatures up to 250 °C, these data permit to create a consolidated dataset suitable for modeling of U(VI) mobilization in natural systems. The parameters of the Modified Ryzhenko-Bryzgalin and the Helgeson-Kirkham-Flowers (HKF) Equations of State (EoS) were derived based on this dataset and used for thermodynamic modeling different scenarios of U(VI) mobilization. These models suggest that at conditions relevant to natural systems, carbonate-mediated transport of U(VI) is likely suppressed by the high stability of solid UO2(OH)2 and Na2U2O7. In contrast, sulfate-mediated mobilization mechanisms are highly efficient at acidic and near-neutral pH conditions and can lead to effective hydrothermal mobilization of U(VI). <b>Citation:</b> A. Migdisov, E. Bastrakov, C. Alcorn, M. Reece, H. Boukhalfa, F.A. Capporuscio, C. Jove-Colon, A spectroscopic study of the stability of uranyl-carbonate complexes at 25–150 °C and re-visiting the data available for uranyl-chloride, uranyl-sulfate, and uranyl-hydroxide species, <i>Geochimica et Cosmochimica Acta</i>, 2024, ISSN 0016-7037, https://doi.org/10.1016/j.gca.2024.04.023.

<b>Legacy service Retired 29/11/2022 IMPORTANT NOTICE: </b>This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data. This web service is intended to complement the borehole GeoSciML-Portrayal v4.0 web service, providing access to the data in a simple, non-standardised structure. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.

This report presents the results of an elemental and carbon and oxygen isotope chemostratigraphy study on three historic wells; Kidson-1, Willara-1 and Samphire Marsh-1, from the southern Canning Basin, Western Australia. The objective of this study was to correlate the Early to Middle Ordovician sections of the three wells to each other and to wells with existing elemental and carbonate carbon isotope chemostratigraphy data from the Broome Platform, Kidson and Willara sub-basins, and the recently drilled and fully cored stratigraphic Waukarlycarly 1 well from the Waukarlycarly Embayment.

<div>A groundwater chemistry, regolith chemistry and metadata record for legacy geochemical studies over the southern Curnamona Province done by GA and partners as part of CRC LEME from 1999 to 2005, that was never fully released. This includes comprehensive groundwater chemistry from more than 250 bores in the Broken Hill region, containing physicochemical parameters, major and trace elements, and a suite of isotopes (34S, Pb, Sr, 18O, D). Recent work on this dataset (in 2021) has added hydrostratigraphic information for these groundwater samples. Also included is a regolith geochemistry dataset collected adjacent to some of the groundwater bores which tests the geochemical response of a range of different size fractions, depths and digests.</div>

As part of the Exploring for the Future (EFTF) program, a chemostratigraphic framework for the Officer Basin was developed that correlates inorganic geochemical sequences between exploration wells. The Officer Basin spans 525,000 km² across Western Australia and South Australia, where it remains an unproven frontier basin which has seen little exploration. The objective of this study was to undertake a bulk rock elemental chemostratigraphy study on ten historic wells in order to better correlate the Neoproterozoic and Cambrian sections. Ten study wells, five from Western Australia and five from South Australia, were selected, and core (241) and cuttings (1,245) samples were acquired from their respective state core libraries. All samples were analysed using Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS), resulting in quantitative data for 50 elements. The approximate proportions of dolomite, clastics, halite and anhydrite for the samples were derived using stoichiometric geochemical calculations. Halite was identified in some formations based on mud log and wireline data, but was not always preserved in the cuttings samples. This non-detection of halite resulted in poor matches between the wireline gamma ray (GR) and ChemGR profiles for halite-bearing units in some wells (e.g. Dragoon-1, Mulyawara-1, and Yowalga-3). Key element and ratios utilised to subdivide the strata were principally chosen to highlight changes in sediment provenance, climatic, and organic matter changes, as they typically have the best correlation potential over a greater distance. The stratigraphy within the study wells has been subdivided into eight chemostratigraphic mega-sequences referred to as MS1 to MS8, which are further subdivided into a total of twenty-four sequences. Mega-Sequences MS1 to MS4 broadly correspond to the published Neoproterozoic–Cambrian Centralian Supersequences (CS1 to CS4). While overall there is broad agreement between these two schemes, there are also sections where the stratigraphy has been reassigned. For example, within Kutjara-1, the section previously assigned to Centralian Supersequence CS2, and equivalent to the Cryogenian Tapley Hill Formation, is assigned to Mega-Sequence MS3 (not MS2). Within MS4, the lithostratigraphically defined members of the Observatory Hill Formation show some significant variation to the chemostratigraphy, with differences occurring within sequences MS4-S3, MS4-S4 and MS4-S5 (e.g. Birksgate-1; Trainor Echo-1). Mega-Sequence MS6 encompasses the Mount Chandler Sandstone in Trainor Echo-1 in the east and the lithological lateral equivalent Lennis Sandstone in Lungkarta-1/ST1 and Yowalga-1 in the west; however, these two argillaceous sandstones are chemically distinct. Carbonate-containing samples from three wells (Birksgate-1, Yowalga-3, and Giles-1) were analysed for their δ13Ccarb and δ18Ocarb isotope signature using Isotope-Ratio Mass Spectrometry (IRMS), with results from the least altered carbonates being of sufficient quality to attempt preliminary age dating. Comparison of the Officer Basin isotope data to global type sections enabled tentative correlation of the Yowalga-3 carbonates to the Tonian and late Ediacaran, and the Birksgate-1 carbonates to the early Cambrian. The geochemistry analyses from 10 basin-wide wells provide a robust dataset that has been used to confirm which sections correlate within the existing lithostratigraphic and sequence stratigraphic framework. This study also highlights where further work needs to be undertaken to elucidate the spatial and temporal relationships of some Cryogenian and early Cambrian sections across the entire basin, given that rocks of these ages contain both potential source and reservoir rocks for petroleum generation and accumulation.

Hydrothermal magnetite from the Starra iron oxide‑copper gold (IOCG) deposit in northwest Queensland, Australia, records a gradual decrease in V, Ni, Cr, and Mn that correlates with the transition from early, amphibole-biotite-magnetite dominant alteration to late, chlorite-quartz-hematite-dominated alteration assemblages. The observed systematic change in multivariate elements in magnetite is interpreted to indicate an increase in fO2 during the main Cu(Au) mineralization. We suggest that variations in the V, Ni, and Cr contents of magnetite at Starra indicate either a primary magmatic fluid source or the leaching of mafic rocks by fluids during early albitization. Late silician magnetite contained in ankerite veins that crosscut the pre-existing alteration assemblages in the hanging wall to the Starra 222 ore body is likely the result of a second mineralization phase, which contributed additional metals to the Starra ore bodies. Existing data on magnetite chemistry from several IOA, IOCG, Fe, and Fe-W skarn deposits show that the ratio of V to Ga discriminates the various ore types effectively. Skarn deposits are separated from IOA and IOCG by lower concentrations of V, Ni, and Cr, suggesting a more primitive fluid source or the precipitation of magnetite at distinct physicochemical conditions than IOA and IOCG deposits. Magnetite from IOA deposits exhibits a consistently elevated V concentration whereas magnetite from Fe(–– W) skarn records an increase in V concentration with the evolution of the system. A pronounced decrease in the V contents of magnetite associated with Cu Au mineralization at Starra is interpreted as a change in redox conditions from reduced to oxidized at the time of mineralization. Such variations are also observed in other IOCG deposits. We propose that systematic decreases in V concentration in magnetite during the paragenetic evolution of the host mineral system is a diagnostic indicator for Cu(Au) mineralization in IOCG deposits, and as such, it may be used as a proxy for Cu-Au exploration, if the paragenetic context of magnetite is well constrained. <b>Citation:</b> Max Hohl, Jeffrey A. Steadman, Jonathan Cloutier, Shaun L.L. Barker, Ivan Belousov, Karsten Goemann, David R. Cooke, Trace element systematics of magnetite from the Starra iron oxide‑copper gold deposits reveals early fluid conditions characteristic for Cu mineralization, <i>Chemical Geology</i>, Volume 648, 2024, 121960, ISSN 0009-2541, https://doi.org/10.1016/j.chemgeo.2024.121960

Geoscience Australia and its predecessors have analysed the hydrochemistry of water sampled from bores, surface features, rainwater and core samples (pore water). Samples have been collected during drilling or monitoring projects, including Exploring for the Future (EFTF). The hydrochemistry database includes physical-chemical parameters (EC, pH, redox potential, dissolved oxygen), major and minor ions, trace elements, isotopes and nutrients. The resource is accessible via the Geoscience Australia Portal <a href="https://portal.ga.gov.au/">(https://portal.ga.gov.au/)</a>

As part of Geoscience Australia's Exploring for the Future program, the East Tennant region, which is centred on the Barkly Roadhouse in the Northern Territory, was identified as having favourable geological and geophysical indicators of mineral systems potential. Potentially prospective stratigraphy in the East Tennant region is completely concealed beneath Mesoproterozoic to Quaternary cover sequences. Prior to 2020 basement rocks in the East Tennant region were only known from a handful of legacy boreholes, supported by geophysical interpretation. In order to test geophysical interpretations and obtain additional samples of basement rocks for detailed analysis, a stratigraphic drilling campaign was undertaken in the East Tennant region as part of the MinEx CRC’s National Drilling Initiative. Ten stratigraphic boreholes were drilled through the cover sequences and into basement for a total of nearly 4000 m, including over 1500 m of diamond cored basement rocks to be used for scientific purposes. Inorganic geochemical samples from East Tennant National Drilling Initiative boreholes were taken to characterise cover and basement rocks intersected during drilling. Two sampling approaches were implemented based on the rocks intersected: 1) Borehole NDIBK04 contained localised sulphide mineralisation and elevated concentrations of several economically-significant elements in portable X-ray fluorescence data. In order to understand the geochemical variability and distribution of elements important for mineral system characterisation, the entire basement interval was sampled at nominal one metre intervals. This spacing was reduced to between 0.5 and 0.25 m from 237 m to 263 m to better understand a more intense zone of mineralisation, and 2) Samples from boreholes NDIBK01, NDIBK02, NDIBK03, NDIBK05, NDIBK06, NDIBK07, NDIBK08, NDIBK09 and NDIBK10 were selected to capture lithological and geochemical variability to establish bulk rock geochemical compositions for further interpretation. Attempts were made to sample representative, lithologically consistent intervals. A total of 402 samples were selected for analysis. Sample preparation was completed at Geoscience Australia and Bureau Veritas, with all analyses performed by Bureau Veritas in Perth. All samples were submitted for X-ray fluorescence (XRF), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), FeO determination, and loss on ignition (LOI). Samples from borehole NDIBK04 also underwent total combustion C and S, and Pb collection fire assay by ICP-MS for determination of Au, Pt and Pd concentrations. This data release presents inorganic geochemistry data acquired on rock samples from the ten East Tennant National Drilling Initiative boreholes.

<div>Geoscience Australia has a large holding of surface sediment samples, such as stream and overbank sediments, from geochemical surveys conducted over more than 50 years across the Australian continent. Geochemical data from these surface materials are of national importance as they can contribute significantly to establishing geochemical environmental baselines and their use in land management, as well as aiding in the discovery of new mineral deposits. Samples from these legacy surveys provide valuable insights into areas of Australia that are remote, difficult to access, or have since been developed. The age of a large number of these surveys, however, means that the original results included data for a&nbsp;smaller range of chemical elements, typically with poorer analytical precision and accuracy than those of modern surveys. This small range of chemical elements also typically doesn’t include important elements for modern use, such as critical minerals (i.e. Co, Bi, REEs), which are increasing in their importance. As part of Geoscience Australia’s Exploring for the Future program, a collection of over 9000 samples from these surveys was reanalysed using modern analytical techniques for a&nbsp;suite of 60 chemical elements. These samples cover several regions within Australia, including Kakadu, Cape York, the Mount Isa region, and near the Canberra region. The new analytical data maximise the value of the historical geochemical surveys and will provide new insights into the mineral potential of these regions and improve the quality of geochemical environmental baselines.&nbsp;</div><div><br></div><div>This data release includes: 1) information on the surveys and their samples; 2) quality assurance results; 3) a discussion of sample preparation and analytical methods used; 4) results for total content geochemistry (XRF and LA-ICP-MS); and 5) individual element maps for each of the regions for preliminary interpretation of the data.</div><div><br></div><div>Acquisition and release of this dataset forms part of a larger program aimed at creating a levelled geochemical baseline for the whole Australia (Main and Champion, 2020).</div>

<div>Quality assurance and quality control (QAQC) of geochemical data is an important first step before any interpretation of the data is undertaken. Due to the increasing number of elements that are being reported by laboratories undertaking multi-element analysis, the time to undertake QAQC of the data has increased. In order to alleviate the increasing time constraints of undertaking QAQC this python script was developed. This script provides a quick first pass of the data automatically to produce summary statistics and plots of the included standards laboratory duplicates and analytical duplicates. The statistics and plots allow for rapid assessment of geochemical data to discover potential issues with the data and trends though time, whilst also providing a consistent approach. It should be noted that no general quality cut-offs have been included within the script as it does not replace the need for an expert examining the data to identify potential issues.</div>