Geological storage of CO2 is a leading strategy for large-scale greenhouse gas emission mitigation. Monitoring and verification is important for assuring that CO2 storage poses minimal risk to people's health and the environment, and that it is effective at reducing anthropogenic CO2 emissions. Eddy Covariance (EC) has been proposed as a long-term monitoring solution for geological storage projects and is considered suitable for monitoring areas 1000 - 100,000 m2 in size. Eddy Covariance is a key micrometeorological technique which has traditionally been used for assessing ecosystem exchange of CO2 in a variety of natural and agricultural settings. It measures the vertical transfer of scalar variables such as CO2 via eddies from upwind of the instrumentation, and correlates the measured CO2 flux to the upwind source area based on several key assumptions. These assumptions include that the upwind source area is homogeneous, flat and uniform, which in turn requires that horizontal gradients in CO2 concentration are zero and that horizontal and vertical gradients in the covariance of CO2 concentration and orthogonal wind directions are zero. Work undertaken at the GA-CO2CRC Gininnderra controlled release facility, where CO2 is released from the shallow subsurface (at 2 m depth), suggests that CO2 leakage in the near subsurface will follow paths of least resistance up to the surface. Similar observations have been observed at the ZERT facility in Montana and CO2 Field Lab in Norway. This leads to CO2 leaks having localised, patchy surface expression, rather than a diffuse wide-scale leak which one typically expects (Lewicki et al. 2010). The implication of this is that the source area for a leak is highly inhomogeneous, meaning the magnitudes of CO2 flux values measured using EC are grossly unreliable. These limitations were discussed in Leuning et al.'s (2008) review on CCS atmospheric monitoring technologies yet are not addressed in much of the recent EC leak quantification literature. This presentation will present findings from the first subsurface release at the CO2CRC facility in Canberra (March - May 2012), where EC data was analysed for application in leak detection and quantification. The CO2 release rate was 144 kg/d. Eddy Covariance was successfully used to detect the leak by comparing CO2 fluxes in the direction of the leak to baseline wind sectors. Median CO2 fluxes in the leak direction were 9.1 µmol/m2/s, while the median background flux was 1.0 µmol/m2/s. Separate measurements taken using a soil flux meter found that the daytime background soil flux had a median flux of 1.8 µmol/m2/s but the peak soil flux over a leak was 1100 µmol/m2/s. Quantification and spatially locating the leak were attempted, but due to the problem of source area inhomogeneity, no substantive progress could be made. How an inhomogeneous source area contributes to 'lost' CO2 from the system, through advection and diffusion, will be discussed, coupled with suggestions for how these parameters can be evaluated in future experimental design. Leuning R., Etheridge D., Luhar A., and Dunse B., 2008. Atmospheric monitoring and verification technologies for CO2 sequestration. International Journal of Greenhouse Gas Control, 2(3), 401-414. Lewicki J. L., Hilley G. E., Dobeck L., and Spangler L., 2010. Dynamics of CO2 fluxes and concentrations during a shallow subsurface CO2 release. Environmental Earth Sciences, 60(2), 285-297. Presented at the 2014 Australian Earth Sciences Convention (AESC)

Eddy Covariance (EC) has been proposed as a surface monitoring solution for long-term deployment at CCS sites. However, its suitability when applied to a highly inhomogeneous source area- as would be the case for a small-scale CO2 surface leak- has been poorly established. For this reason, EC has been implemented for two controlled CO2 releases conducted at the Ginninderra controlled release facility, with the aim of determining the technique's suitability for the location, detection and quantification of a small magnitude CO2 leak (144 kg/d). By comparing results from the two release experiments, this poster highlights the variable success of using EC for detection, and how this may depend on changing experimental and climatic variables such as leak location, tower height and depth to groundwater. The detection significance of grouped EC measurements will be established through statistical analysis using Cramer-Von Mises tests. In addition, the application of two EC towers concurrently for leak detection and location will be explored, with a second tower deployed for the latter portion of the 2013 release experiment. Quantification of the leak using EC was attempted, but due to the problems in the fundamental assumptions of the technique, no substantive progress could be made. This will be explained with respect to the 'lost' CO2 from the system in part due to advection and diffusion. Presented at the 2014 CO2CRC Research Symposium