This report describes the results of an extended national field spectroscopy campaign designed to validate the Landsat 8 and Sentinel 2 Analysis Ready Data (ARD) surface reflectance (SR) products generated by Digital Earth Australia. Field spectral data from 55 overpass coincident field campaigns have been processed to match the ARD surface reflectances. The results suggest the Landsat 8 SR is validated to within 10%, the Sentinel 2A SR is validated to within 6.5% and Sentinel 2B is validated to within 6.8% . Overall combined Sentinel 2A and 2B are validated within 6.6% and the SR for all three ARD products are validated to within 7.7%.

1. Band ratio: B7/B8 Blue-cyan is magnesite-dolomite, amphibole, chlorite Red is calcite, epidote, amphibole useful for mapping: (1) exposed parent material persisting through "cover"; (2) "dolomitization" alteration in carbonates - combine with Ferrous iron in MgOH product to help separate dolomite versus ankerite; (3) lithology-cutting hydrothermal (e.g. propyllitic) alteration - combine with FeOH content product and ferrous iron in Mg-OH to isolate chlorite from actinolite versus talc versus epidote; and (4) layering within mafic/ultramafic intrusives. useful for mapping: (1) exposed parent material persisting through "cover"; (2) "dolomitization" alteration in carbonates - combine with Ferrous iron in MgOH product to help separate dolomite versus ankerite; (3) lithology-cutting hydrothermal (e.g. propyllitic) alteration - combine with FeOH content product and ferrous iron in Mg-OH to isolate chlorite from actinolite versus talc versus epidote; and (4) layering within mafic/ultramafic intrusives. useful for mapping: (1) exposed parent material persisting through "cover"; (2) "dolomitization" alteration in carbonates - combine with Ferrous iron in MgOH product to help separate dolomite versus ankerite; (3) lithology-cutting hydrothermal (e.g. propyllitic) alteration - combine with FeOH content product and ferrous iron in Mg-OH to isolate chlorite from actinolite versus talc versus epidote; and (4) layering within mafic/ultramafic intrusives.

1. 3 band RGB composite Red: B3/B2 Green: B3/B7 Blue: B4/B7 (white = green vegetation) Use this image to help interpret (1) the amount of green vegetation cover (appears as white); (2) basic spectral separation (colour) between different regolith and geological units and regions/provinces; and (3) evidence for unmasked cloud (appears as green).

B6/B5 (potential includes: pyrophyllite, alunite, well-ordered kaolinite) Blue is low content, Red is high content Useful for mapping: (1) different clay-type stratigraphic horizons; (2) lithology-overprinting hydrothermal alteration, e.g. high sulphidation, "advanced argillic" alteration comprising pyrophyllite, alunite, kaolinite/dickite; and (3) well-ordered kaolinite (warmer colours) versus poorly-ordered kaolinite (cooler colours) which can be used for mapping in situ versus transported materials, respectively.

1. Band ratio: B5/B4 Blue is low ferrous iron content in carbonate and MgOH minerals like talc and tremolite. Red is high ferrous iron content in carbonate and MgOH minerals like chlorite and actinolite. Useful for mapping: (1) un-oxidised "parent rocks" - i.e. mapping exposed parent rock materials (warm colours) in transported cover; (2) talc/tremolite (Mg-rich - cool colours) versus actinolite (Fe-rich - warm colours); (3) ferrous-bearing carbonates (warm colours) potentially associated with metasomatic "alteration"; (4) calcite/dolomite which are ferrous iron-poor (cool colours); and (5) epidote, which is ferrous iron poor (cool colours) - in combination with FeOH content product (high).

1. Band ratio: (B6+B8)/B7 Blue is low content, Red is high content (potentially includes: chlorite, epidote, jarosite, nontronite, gibbsite, gypsum, opal-chalcedony) Useful for mapping: (1) jarosite (acid conditions) - in combination with ferric oxide content (high); (2) gypsum/gibbsite - in combination with ferric oxide content (low); (3) magnesite - in combination with ferric oxide content (low) and MgOH content (moderate-high) (4) chlorite (e.g. propyllitic alteration) - in combination with Ferrous in MgOH (high); and (5) epidote (calc-silicate alteration) - in combination with Ferrous in MgOH (low).

1. Band ratio: B13/B10 Blue is low silica content Red is high silica content (potentially includes Si-rich minerals, such as quartz, feldspars, Al-clays) Geoscience Applications: Broadly equates to the silica content though the intensity (depth) of this reststrahlen feature is also affected by particle size <250 micron. Useful product for mapping: (1) colluvial/alluvial materials; (2) silica-rich (quartz) sediments (e.g. quartzites); (3) silification and silcretes; and (4) quartz veins. Use in combination with quartz index, which is often correlated with the Silica index.

1. Band ratio: B2/B1 Blue-cyan is goethite rich, Green is hematite-goethite, Red-yellow is hematite-rich (1) Mapping transported materials (including palaeochannels) characterised by hematite (relative to geothite). Combine with AlOH composition to find co-located areas of hematite and poorly ordered kaolin to map transported materials; and (2) hematite-rish areas in drier conditions (eg above the water table) whereas goethite-rich in wetter conditions (eg at/below the water or areas recently exposed). May also be climate driven.

1. Band ratio: B1/B4 Blue is low abundance, Red is high abundance (potentially includes carbon black (e.g. ash), magnetite, Mn oxides, and sulphides in unoxidised envornments Useful for mapping: (1) magnetite-bearing rocks (e.g. BIF); (2) maghemite gravels; (3) manganese oxides; (4) graphitic shales. Note 1: (1) and (4) above can be evidence for "reduced" rocks when interpreting REDOX gradients. Combine with AlOH group Content (high values) and Composition (high values) products, to find evidence for any invading "oxidised" hydrothermal fluids which may have interacted with reduced rocks evident in the Opaques index product.

1. Band ratio: B4/B3 Blue is low abundance, Red is high abundance (1) Exposed iron ore (hematite-goethite). Use in combination with the "Opaques index" to help separate/map dark (a) surface lags (e.g. maghemite gravels) which can be misidentified in visible and false colour imagery; and (b) magnetite in BIF and/or bedded iron ore; and (3) Acid conditions: combine with FeOH Group content to help map jarosite which will have high values in both products. Mapping hematite versus goethite mapping is NOT easily achieved as ASTER's spectral bands were not designed to capture diagnostic iron oxide spectral behaviour. However, some information on visible colour relating in part to differences in hematite and/or goethite content can be obtained using a ratio of B2/B1 especially when this is masked using a B4/B3 to locate those pixels with sufficient iro oxide content.