Here we report on the application of a new CO2 quantification and localization technique, called atmospheric tomography. The results of the study indicate that, through careful data processing, measurements from the comparatively inexpensive but lower accuracy and lower precision CO2 sensor array can provide useful data. Results from the application of the tomography technique will be presented and limitations of the technique discussed. From the 9th International Carbon Dioxide Conference, Beijing, China

Geoscience Australia and the CO2CRC have constructed a greenhouse gas controlled release facility at an experimental agricultural station maintained by CSIRO Plant Industry at Ginninderra, Canberra. The facility is designed to simulate surface emissions of CO2 from the soil into the atmosphere and is modelled on the ZERT controlled release facility in Montana. Injection of CO2 into the soil is via a 120 m long slotted HDPE pipe installed horizontally 2 m underground. An eddy covariance (EC) system was installed at Ginninderra during the first sub-surface release (March - June 2012). The EC system, which generated 15 minute averages using a 10 Hz sampling frequency, measured net radiation (as a function of upwelling and downwelling, solar and longwave radiation); wind speed and direction in 3 dimensions; CO2 and H2O concentration; and temperature and pressure. The EC system was installed to provide baseline atmospheric measurements and assess methods for quantifying CO2 leakages. The daily CO2 release rate was 100 kg/d. Here we report on the application of the CO2 emissions quantification method developed by Pan et al. (2010) for detecting and quantifying CO2 leakages using EC techniques. The approach seeks to isolate the CO2 leakage signal from the natural variation inherent in flux data, using a time-window splitting scheme, median filtering and scaling techniques. Results from application of the EC method at the Ginninderra site will be presented and modifications to the method and its limitations discussed. Pan, L.; Lewicki, J.L.; Oldenburg C.M.; and Fischer M.L., (2010). Time-window based filtering method for near-surface detection of leakage from geological carbon sequestration sites, Environmental Earth Sciences, 60, pp 359-369. Proceedings of the 2013 International Carbon Dioxide Conference - Beijing China

Abstract for a Poster for the CO2CRC Symposium 2013: Atmospheric tomography is a CO2 quantification and localisation technique that uses an array of sampling points and a Bayesian inversion method to solve for the location and magnitude of a CO2 leak. Knowledge of a normalized three-dimensional dispersion plume is required in order to accurately model a leak using many meteorological parameters. A previous small scale (~20 m) study using a high precision Fourier Transform Infrared found that the emission rate was determined to within 3% of the actual release rate and the localisation within 1 m of the correct position. The technique was applied during the CO2CRC Otway Stage 2B residual saturation and dissolution test in August-October 2011. A network of eight independent CO2 sensors (Vaisala GMP343 CO2 probes) were positioned at distances ranging from 154 to 473 m from the well. A 3D sonic anemometer within the measurement area collected wind turbulence data. The results of the study indicate that, through careful data processing, measurements from the reasonably inexpensive (but lower accuracy and lower precision) CO2 sensor array can provide useful data for the application of atmospheric tomography. Results have found that the low precision of the sensors over time becomes a problem due to sensor drift. A reference measurement of CO2 helps to resolve this problem and improves the perturbation signal during data processing. Preliminary inversion modeling results will be shown to show the best estimation of locating a CO2 leakage source for the Otway Stage 2B residual saturation and dissolution test. CO2CRC Symposium 2013, Hobart

The ultimate purpose of carbon capture and storage is to keep CO2 out of the atmosphere. However there are some scenarios in which leakage to atmosphere may occur. Because of the large and variable level of naturallyoccurring CO2 , and rapid dispersion in the atmosphere, leakage to atmosphere can be difficult to detect from concentration measurements. By using prior information from risk assessments about plausible location of leaks, it is possible to design simple yet effective systems for identifying the location of a leak within a pre-defined area of surveillance. We have designed an inexpensive system of autonomous sensors that can locate leaks of CO2 , and have tested it during a controlled release at the CO2CRC Otway site. The system proved effective and it, and its associated workflow, could be adapted and implemented in a variety of storage settings.

There is increasing recognition that minimising methane emissions from the oil and gas sector is a key step in reducing global greenhouse gas emissions in the near term. Atmospheric monitoring techniques are likely to play an important future role in measuring the extent of existing emissions and verifying emission reductions. They can be very suitable for monitoring gas fields as they are continuous and integrate emissions from a number of potential point and diffuse sources that may vary in time. Geoscience Australia and CSIRO Marine & Atmospheric Research have collected three years of continuous methane and carbon dioxide measurements at their atmospheric composition monitoring station ('Arcturus') in the Bowen Basin, Australia. Methane signals in the Bowen Basin are likely to be influenced by cattle production, landfill, coal production, and conventional and coal seam gas (CSG) production. Australian CSG is typically 'dry' and is characterised by a mixed thermogenic-biogenic methane source with an absence of C3-C6+ alkanes. The range of '13C isotopic signatures of the CSG is similar to methane from landfill gas and cattle emissions. The absence of standard in-situ tracers for CSG fugitive emissions suggests that having a comprehensive baseline will be critical for successful measurement of fugitive emissions using atmospheric techniques. In this paper we report on the sensitivity of atmospheric techniques for the detection of fugitive emissions from a simulated new CSG field against a three year baseline signal. Simulation of emissions was performed for a 1-year period using the coupled prognostic meteorological and air pollution model TAPM at different fugitive emission rates (i.e. estimates of <1% to up to 10% of production lost) and distances (i.e. 10 - 50 km) from the station. Emissions from the simulated CSG field are based on well density, production volumes, and field size typical of CSG fields in Australia. The distributions of the perturbed and baseline signals were evaluated and statistically compared to test for the presence of fugitive methane emissions. In addition, a time series model of the methane baseline was developed in order to generate alternative realizations of the baseline signal. These were used to provide measures of both the likelihood of detecting fugitive emissions at various emission levels and of the false alarm rate. Results of the statistical analysis and an indicative minimum fugitive methane emission rate that can be detected using a single monitoring station are presented. Poster presented at the American Geophysical Union meeting, December 2013, San Francisco

Source The data was sourced from CSIRO (Victoria) in 2012 by Bob Cechet. It is not known specifically which division of CSIRO, although it is likely to have been the Marine and Atmospheric Research Division (Aspendale), nor the contact details of the person who provided the data to Bob. The data was originally produced by CSIRO for their input into the South-East Queensland Climate Adaptation Research Initiative (SEQCARI). Reference, from an email of 16 March 2012 sent from Bob Cechet to Chris Thomas (Appendix 1 of the README doc stored at the parent folder level with the data), is made to 'download NCEP AVN/GFS files' or to source them from the CSIRO archive. Content The data is compressed into 'tar' files. The name content is separated by a dot where the first section is the climatic variable as outlined in the table format below: Name Translation rain 24 hr accumulated precipitation rh1_3PM Relative humidity at 3pm local time tmax Maximum temperature tmin Minimum temperature tscr_3PM Screen temperature (2 m above ground) at 3pm local time u10_3PM 10-metre above ground eastward wind speed at 3pm local time v10_3PM 10-metre above ground northward wind speed at 3pm local time The second part of the name is the General Circulation Model (GCM) applied: Name Translation gfdlcm21 GFDL CM2.1 miroc3_2_medres MIROC 3.2 (medres) mpi_echam5 MPI ECHAM5 ncep NCEP The third, and final, part of the tarball name is the year range that the results relate to: 1961-2000, 1971-2000, 2001-2040 and 2041-2099 Data format and extent Inside each of the tarball files is a collection of NetCDF files covering each simulation that constitutes the year range (12 simulations for each year). A similar naming protocol is used for the NetCDF files with a two digit extension added to the year for each of the simulations for that year (e.g 01-12). The spatial coverage of the NetCDF files is shown in the bounding box extents as shown below. Max X: -9.92459297180176 Min X: -50.0749073028564 Max Y: 155.149784088135 Min Y: 134.924812316895 The cell size is 0.15 degrees by 0.15 degrees (approximately 17 km square at the equator) The data is stored relative to the WGS 1984 Geographic Coordinate System. The GCMs were forced with the Intergovernmental Panel on Climate Change (IPCC) A2 emission scenario as described in the IPCC Special Report on Emissions Scenarios (SRES) inputs for the future climate. The GCM results were then downscaled from a 2 degree cell resolution by CSIRO using their Cubic Conformal Atmospheric Model (CCAM) to the 0.15 degree cell resolution. Use This data was used within the Rockhampton Project to identify the future climate changes based on the IPCC A2 SRES emissions scenario. The relative difference of the current climate GCM results to the future climate results was applied to the results of higher resolution current climate natural hazard modelling. Refer to GeoCat # 75085 for the details relating to the report and the 59 attached ANZLIC metadata entries for data outputs.

The CO2CRC has been leading the international development and application of atmospheric techniques for CO2 leak detection and quantification for CCS. CSIRO's atmospheric monitoring program at the CO2CRC Otway Project demonstrated world's leading practice for atmospheric monitoring at geological storage sites. The GA-CO2CRC Ginninderra controlled release facility has enabled development and testing of a new atmospheric tomography approach for accurately quantifying CO2 emissions using atmospheric techniques. A scaled-up version of the technique using an array of more cost effective (but less accurate) sensors was applied at a larger scale at the Otway Stage 2B controlled release. Additional techniques have been developed including data filtering to optimize the detection of emitted gases against the ecosystem background and Bayesian inverse modeling to locate and quantify a source. GA and CSIRO operate a joint baseline atmospheric station in the Bowen Basin and have been independently investigating the sensitivity of CO2 leak detection through coupling of measurements taken in a sub-tropical environment with simulated leakage events. An outcome from this body of work is the importance of good quality, calibrated measurements, a long baseline record and the development and application of techniques using atmospheric models for quantifying gaseous emissions from the ground to the atmosphere. These same measurement requirements and quantification techniques have direct application to fugitive methane emissions from open cut coal mines, coal seam gas, tight gas, and conventional gas emissions. Application is easier for methane: the background signal is lower, sensors are available at affordable cost, and the emissions are measureable now. The Bowen Basin site, for example, is detecting fugitive methane emitted from open cut coal mining activities tens of kilometres away. An example of the sensitivity of atmospheric techniques for the detection of fugitive emissions from a simulated methane source will be presented.

In July 2010, Geoscience Australia and CSIRO Marine & Atmospheric Research jointly commissioned a new atmospheric composition monitoring station, named Arcturus, in sub-tropical Queensland, Australia. The facility is designed as a proto-type remotely operated `baseline monitoring station' that could be deployed in areas that are likely targets for commercial scale geological storage of carbon dioxide. A key question, given the ecosystem and anthropogenic sources of CO2 in the region, and the absence of a 'clean-wind' sector baseline, is how large would a CO2 leak have to be from a geological storage site before it can be detected above the background CO2 signal? To address this, CO2 leak simulation modelling was performed for 1-year period using the coupled prognostic meteorological and air pollution model TAPM at various locations, emission rates and distances (1-10 km) from the station.

Lagrangian stochastic (LS) forward modelling of CO2 plumes from above-surface release experiments conducted at the GA-CO2CRC Ginninderra GHG controlled release facility demonstrated that small surface leaks are likely to disperse rapidly and unlikely to be detected at heights greater 4 m; this was verified using a rotorcraft to map out the plume. The CO2 sensing rotorcraft unmanned aerial vehicle (RUAV) developed at the Australian National University, Canberra, is equipped with a CO2 sensor (3 ppm accuracy and 2 s response time), a GPS, lidar and a communication module. It was developed to detect, locate and quantify CO2 gas leaks. The choice of a rotorcraft UAV allows slower flight speeds compared to speeds of a fixed-wing UAV; and the electric powered motor enables flight times of 12 min. During the experiments, gaseous CO2 (100 kg per day) was released from a small diffuse source located in the middle of the paddock of the controlled release facility, and the RUAV, flying repeatedly over the CO2 source at a few metres height, recorded CO2 concentrations up to 85 ppm above background. Meteorological parameters measured continuously at the site were input in the LS model. Mapped out horizontal and vertical CO2 concentrations established the need to be close to the ground in order to detect CO2 leakage using aerial techniques. Using the rotorcraft as a mobile sensor could be an expedient mechanism to detect plumes over large areas, and would be important for early detection of CO2 leaks arising from CO2 geological storage activities.

Results from the first pass application of the tomography technique using low accuracy sensors is presented and limitations of the sensors and technique discussed. BUll. Seismol. Soc. AM.