The ca. 1.4 Ga Roper Group of the greater McArthur Basin in northern Australia comprises the sedimentary fill of one of the most extensive Precambrian hydrocarbon-bearing basins preserved in the geological record. It is interpreted to have been deposited in a large epeiric sea known as the Roper Seaway. Trace element data suggest that the redox structure of the basin was a shallow oxic layer overlying deeper suboxic to anoxic waters along with a prominent episode of euxinia. These anoxic and sulfidic conditions, as inferred by redox sensitive trace element (TE) abundances, (molybdenum, vanadium and uranium), developed due to high organic carbon loading consistent with models that suggest that euxinic conditions cannot develop until the flux of organic matter is significantly greater than the flux of bioavailable iron (Fe³⁺), which permits sulphate reduction to proceed. Considering the high reactive iron and molybdenum contents of these shales and the requirement for S/Fe ratios >2 for euxinia to develop, suggest sufficient atmospheric O₂ was available for oxidative scavenging of S and Mo from the continents. This is further supported by prominent negative cerium anomalies within these shales, indicative of active oxidative redox cycling of cerium. We propose that the high organic matter flux was the result of increased nutrient loading to the Roper Seaway from weathering of the continental hinterland. Data from both major and high-field strength elements (niobium, tantalum, zirconium and, hafnium) together with neodymium isotopes (¹⁴³Nd/¹⁴⁴Nd) indicate that a likely mechanism for this enhanced nutrient delivery was a shift in sedimentary provenance to a more primitive (i.e. mafic) precursor lithology. This switch in provenance would have increased phosphorus delivery to the Roper Seaway, contributing to high primary productivity and the onset of euxinia. This dataset and model serve as a basis for understanding the temporal evolution of the deepest sections of the Roper Seaway and finer scale changes in the environment at this time. <b>Citation:</b> Grant M. Cox, Amber Jarrett, Dianne Edwards, Peter W. Crockford, Galen P. Halverson, Alan S. Collins, André Poirier, Zheng-Xiang Li, Basin redox and primary productivity within the Mesoproterozoic Roper Seaway, <i>Chemical Geology</i>, Volume 440, 2016, Pages 101-114, ISSN 0009-2541, https://doi.org/10.1016/j.chemgeo.2016.06.025.

The Geological and Bioregional Assessments (GBA) Program is a series of independent scientific studies undertaken by Geoscience Australia and the CSIRO, supported by the Bureau of Meteorology, and managed by the Department of Agriculture, Water and the Environment. The Program consists of three stages across three regions with potential to deliver gas to the East Coast Gas Market. Stage 1 was a rapid regional prioritisation conducted by Geoscience Australia, to identify those sedimentary basins with the greatest potential to deliver shale and/or tight gas to the East Coast Gas Market within the next five to ten years. This prioritisation process assessed 27 onshore eastern and northern Australian basins with shale and/or tight gas potential. Further screening reduced this to a shortlist of nine basins where exploration was underway. The shortlisted basins were ranked on a number of criteria. The Cooper Basin, the Beetaloo Sub-basin and the Isa Superbasin were selected for more detailed assessment. Stage 2 of the program involved establishing a baseline understanding of the identified regions. Geoscience Australia produced regional geological evaluations and conceptualisations that inform the assessment of shale and/or tight gas prospectivity, ground- and surface-water impacts, and hydraulic fracturing models. Geoscience Australia’s relative prospectivity assessments provide an indication of where viable petroleum plays are most likely to be present. These data indicate areal and stratigraphic constraints that support the program’s further work in Stage 3, on understanding likely development scenarios, impact assessments, and causal pathways. <b>Citation:</b> Hall Lisa S., Orr Meredith L., Lech Megan E., Lewis Steven, Bailey Adam H. E., Owens Ryan, Bradshaw Barry E., Bernardel George (2021) Geological and Bioregional Assessments: assessing the prospectivity for tight, shale and deep-coal resources in the Cooper Basin, Beetaloo Subbasin and Isa Superbasin. <i>The APPEA Journal</i><b> 61</b>, 477-484. https://doi.org/10.1071/AJ20035

<p>The Isa Superbasin is a Paleoproterozoic to Mesoproterozoic succession (approximately 1670-1575 Ma), primarily described in north-west Queensland. Despite the basin’s frontier status, recent exploration in the northern Lawn Hill Platform has demonstrated shale gas potential in the Lawn and River supersequences. Here, we characterise the unconventional reservoir properties of these supersequences, providing new insights into regional shale gas prospectivity. <p>The depths, thicknesses and mappable extents of the Lawn and River supersequences are based on the 3D geological model of Bradshaw et al. (2018). Source rock net thickness, total organic carbon (TOC), kerogen type and maturity are characterised based on new and existing Rock-Eval and organic petrology data, integrated with petroleum systems modelling. Petrophysical properties, including porosity, permeability and gas saturation, are evaluated based on well logs. Mineralogy is used to calculate brittleness (see also Jarrett et al., 2019, this volume). Regional stress and pressure regimes are also reviewed. <p>Abundant source rocks are present in the Isa Superbasin succession. Overall, shale rock characteristics were found to be favourable for both sequences assessed; both the Lawn and River supersequences host thick, extensive, and organically rich source rocks with up to 7.1 wt% total organic carbon (TOC) in the Lawn Supersequence and up to 11.3 wt% TOC in the River Supersequence. Net shale thicknesses demonstrate an abundance of potential shale gas reservoir units across the Lawn Hill Platform. <p>With average brittleness indices of greater than 0.5, both the Lawn and River supersequences are interpreted as likely to be favourable for fracture stimulation. As-received total gas content from air-dried samples is favourable, with average values of 0.909 scc/g for the Lawn Supersequence and 1.143 scc/g for the River Supersequence <p>The stress regime in the Isa Superbasin and the surrounding region is poorly defined; however, it is likely dominated by strike-slip faulting. Modelling demonstrates limited stress variations based on both lithology and the thickness of the overlying Phanerozoic basins, resulting in likely inter- and intra-formational controls over fracture propagation. No evidence of overpressure has been observed to date, however, it is possible that overpressures may exist deeper in the basin where less permeable sediments exist. <p>This review of the shale reservoir properties of the Lawn and River supersequences of the Isa Superbasin significantly improves our understanding of the distribution of potentially prospective shale gas plays across the Lawn Hill Platform and more broadly across this region of northern Australia.

Shale gas plays require technology such as fracture stimulation to increase rock permeability and achieve commercial rates of flow. The brittleness of shales are a major control on the ease of fracture stimulation. The Brittleness Index (BI) is a proxy for rock strength, based on geomechanical parameters, and/or rock mineralogy, and provides an indication of hydraulic stimulation effectiveness. Legacy drill core does not always have the geophysical logs needed for assessment of shale brittleness, therefore mineralogical and geochemical derived proxies for shale brittlenesss are often used with varying success. Shales from the Paleoproterozoic Lawn Hill Platform of north-west Queensland and the Northern Territory are known to contain organic-rich sedimentary units with the potential to host shale-gas plays. The Egilabria 2 DW1 well demonstrated a technical success in flowing gas from the Lawn Supersequence and recent geomechanical logging in the Egilabria prospect have demonstrated the presence of brittle rocks favourable for fracture stimulation with similarities between logged geophysics and X-Ray Diffraction (XRD) derived brittleness (Bailey et al., 2019). In this study we assess the brittleness of shales from twelve wells across the Isa Superbasin that do not have geophysical log data using XRD, major elemental analyses from X-Ray Fluorescence (XRF) and mineral carbon (MinC) techniques. The results of this study demonstrate highly variable mineral components between all analysed supersequences. The brittleness index (BI) of the shales derived from XRD ranges from ductile to brittle with zones of brittle shales present in all supersequences. Shale brittleness is controlled by increasing quartz and decreasing clay content with little influence from carbonates. Major elements based on XRF showed moderate to poor correlations to mineral type and the brittleness index was significantly higher than the results calculated by XRD. XRF analyses are not recommended as a proxy for shale brittleness in the Isa Superbasin region. The MinC parameter was highly effective as a proxy for carbonate based on comparisons with XRD derived carbonate concentrations. An important finding in this study is the variations in BI and TOC between supersequences, and within supersequences. This is evident down-hole and spatially across the area sampled. Future work is needed to investigate sweet spots for shale gas production.

Assessing the regional prospectivity of tight, shale and deep coal gas resources in the Cooper Basin is an integral component of the Australian Government’s Geological and Bioregional Assessment Program, which aims to encourage exploration and understand the potential impacts of resource development on water and the environment. The Permo-Triassic Cooper Basin is Australia’s premier onshore conventional hydrocarbon-producing province, yet is relatively underexplored for unconventional gas resources. A chance of success mapping workflow, using rapid integration of new and existing data, was developed to evaluate the regional distribution of key gas plays within the Gidgealpa Group. For each play type, key physical properties (e.g. lithology, formation depths and extents, source rock and reservoir characteristics, and rock mechanics) were identified and criteria were used to assign prospectivity rankings. Parameter maps for individual physical properties were classified, weighted and then combined into prospectivity confidence maps that represent each play’s relative chance of success. These combined maps show a high chance of success for tight, shale and deep coal gas plays in the Nappamerri, Patchawarra and Windorah troughs, largely consistent with exploration results to-date. The outputs of this regional screening process help identify additional areas warranting investigation, and may encourage further exploration investment in the basin. This methodology can be applied to other unconventional hydrocarbon plays in frontier and proven basins.

Small-angle neutron scattering (SANS) measurements were performed on 32 rock samples from the southern Georgina Basin, central Australia to assess nanopore anisotropy. Anisotropy can only be determined from oriented core material, hence the samples were cut perpendicular to bedding in cores selected from three wells that intersect the base of the hydrocarbon-bearing, organic-rich middle Cambrian Arthur Creek Formation; the latter is the source rock for both unconventional and conventional plays in the basin. The evolution of anisotropy of two-dimensional SANS intensity profiles with depth (for pore diameters ranging from 10 nm to 100 nm) was quantified and correlated with SANS intensity and total organic carbon (TOC) content. Our results confirm hydrocarbon generation at the base of the Arthur Creek Formation. The nanopore anisotropy in the basal Arthur Creek Formation at the well locations CKAD0001 (oil generation window) and MacIntyre 1 (late oil generation window) varies roughly according to normal compaction. When the Arthur Creek Formation is in the gas window, as sampled at Baldwin 1, there is a strong (negative) correlation between the average vertical-to-horizontal pore shape anisotropy and SANS intensity. The results indicate that unconventional gas production from organic-rich regions of over mature shale may be adversely affected by abnormal pore compaction.

The Officer Basin spanning South Australia and Western Australia is the focus of a regional stratigraphic study being undertaken as part of the Exploring for the Future (EFTF) program, an Australian Government initiative dedicated to increasing investment in resource exploration in Australia. Despite numerous demonstrated oil and gas shows, the Officer Basin remains a frontier basin for energy exploration with significant uncertainties due to data availability. Under the EFTF Officer-Musgrave Project, Geoscience Australia acquired new geomechanical rock property data from forty core samples in five legacy stratigraphic and petroleum exploration wells that intersected Paleozoic and Neoproterozoic aged intervals. These samples were subjected to unconfined compressive rock strength tests, Brazilian tensile strength tests and laboratory ultrasonic measurements. Petrophysical properties were also characterised via X-ray computerised tomography scanning, grain density and porosity-permeability analysis. Accurate characterisation of static geomechanical rock properties through laboratory testing is essential. In the modern exploration environment, these datasets are a precompetitive resource that can simplify investment decisions in prospective frontier regions such as the Officer Basin. Appeared in The APPEA Journal 62 S385-S391, 13 May 2022

The Palaeoproterozoic Fraynes Formation in the Birrindudu Basin is a chronostratigraphic counterpart to the highly prospective Barney Creek Formation in the McArthur Basin. However, there is limited understanding of its source potential in comparison. As part of Geoscience Australia’s Exploring for the Future program, this study aims to assess the hydrocarbon generating potential and shale gas prospectivity of the Fraynes Formation in the exploration drillhole Manbulloo S1 through the reconstruction of original source-rock generating potential and well log interpretation. Internal units inside the Fraynes Formation were defined according to sedimentary facies. The hydrocarbon generation potential was estimated using the original TOC content, hydrogen index and thermal maturity data. The shale total porosity was re-interpreted from bulk density logs by removing the organic matter effect and adding organic porosity for the organic-rich shales. The water saturation was then updated accordingly. The maximum amount of generated gas of the organic-rich source rocks are 3969 Mcf/a-ft, 2769 Mcf/a-ft and 1912 Mcf/a-ft when assuming the kerogen compositions of 100 Type I, mix of 50-50% Type I and II, and 100% Type II, respectively. The richness of organic matter and interpreted water saturation (<100%) imply favourable shale gas prospectivity in the Fraynes Formation. This work expands our knowledge on the unconventional energy resources in the west of the greater McArthur Basin. Paper presented at the 2024 Australian Energy Producers (AEP) Conference &amp; Exhibition (https://pesa.com.au/events/2024-aep-conference-exhibition/)