<div>Environmental DNA (eDNA), elemental and mineralogical analyses of soil have been shown to be specific to their source material, prompting consideration of the use of dust for forensic provenancing. Dust is ubiquitous in the environment and is easily transferred to items belonging to a person of interest, making dust analysis an ideal tool in forensic casework. The advent of Next Generation Sequencing technologies means that metabarcoding of eDNA can uncover microbial, fungal, and even plant genetic fingerprints in dust particles. Combining this with elemental and mineralogical compositions offers multiple, complementary lines of evidence for tracing the origin of an unknown dust sample. This is particularly pertinent when recovering dust from a person of interest to ascertain where they may have travelled. Prior to proposing dust as a forensic trace material, however, the optimum sampling protocols and detection limits need to be established to place parameters around its utility in this context. We tested several approaches to collecting dust from different materials and determined the lowest quantity of dust that could be analysed for eDNA, geochemistry and mineralogy, whilst still yielding results capable of distinguishing between sites. We found that fungal eDNA profiles could be obtained from multiple sample types and that tape lifts were the optimum collection method for discriminating between sites. We successfully recovered both fungal and bacterial eDNA profiles down to 3&nbsp;mg of dust (the lowest tested quantity) and recovered elemental and mineralogical compositions for all tested sample quantities. We show that dust can be reliably recovered from different sample types, using different sampling techniques, and that fungal, bacterial, and elemental and mineralogical profiles, can be generated from small sample quantities, highlighting the utility of dust as a forensic provenance material.</div> <b>Citation:</b> Nicole R. Foster, Belinda Martin, Jurian Hoogewerff, Michael G. Aberle, Patrice de Caritat, Paul Roffey, Robert Edwards, Arif Malik, Priscilla Thwaites, Michelle Waycott, Jennifer Young, The utility of dust for forensic intelligence: Exploring collection methods and detection limits for environmental DNA, elemental and mineralogical analyses of dust samples, <i>Forensic Science International </i>, Volume 344, 2023, 111599, ISSN 0379-0738, https://doi.org/10.1016/j.forsciint.2023.111599. ISSN 0379-0738,

<b>IMPORTANT NOTICE:</b> This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to a subset of Australian geoscience samples data held by Geoscience Australia. The subset currently relates specifically to Australian Boreholes.

This database contains geochemical data for samples analysed both for inorganic and organic geochemistry. Analytical data are sourced from Geoscience Australia's Inorganic Geochemistry Database (OZCHEM) and Organic Geochemistry Database (ORGCHEM), respectively. The data are joined on a unique sample number. Inorganic geochemical data cover the majority of the periodic table, with metadata on analytical methods and detection limits. Organic geochemical data include results of pyrolysis, derivative calculated values, and, where available, isotopic composition of carbonates (D13C) and isotopic composition of rock nitrogen (D15N). Further, there are provisions for delivery of isotopic data for kerogen (H, C, N) and oxygen (O) for carbonates. Where available, sample descriptions include stratigraphic unit names and ages, and lithology. Location information includes coordinates of the sampled feature (eg, borehole), coordinates of the sample and sample depth. Interpretation of the combined inorganic and organic geochemistry for organic-rich shales will facilitate comprehensive characterisation of hydrocarbons source rocks and mineral commodities source and trap environments. All are achieved within the frameworks of petroleum and mineral systems analysis. The initial data delivered by this service include 1785 samples from 35 boreholes from 14 geological provinces, including recently released data for 442 samples from the South Nicholson National Drilling Initiative Carrara 1 stratigraphic drill hole (Butcher et al., 2021; Carson et al., 2021). Many sampled boreholes are located within the polygon of the Exploring for the Future Barkly-Isa-Georgetown project. This dataset will be updated periodically as more data become available.

<b>Legacy service retired 29/11/2022</b> This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data conforming to the GeoSciML version 4.0 specification. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.

<b>IMPORTANT NOTICE:</b> This web service has been deprecated. The Hydrochemistry Service OGC service at https://services.ga.gov.au/gis/hydrogeochemistry/ows should now be used for accessing Geoscience Australia hydrochemistry analyses data. This is an Open Geospatial Consortium (OGC) web service providing access to hydrochemistry data (groundwater analyses) obtained from water samples collected from Australian water bores.

<div>This dataset comprises hydrochemistry results for groundwater, surface water, and rainwater samples collected as part of the Upper Darling Floodplain groundwater study. Associated methods, interpretation, and integration with other datasets are found in the Upper Darling Floodplain geological and hydrogeological assessment (Geoscience Australia Ecat ID:149689). This project is part of the Exploring for the Future (EFTF) program, an eight-year, $225 million Australian Government funded geoscience data and precompetitive information acquisition program. The dataset contains 68 groundwater samples, 17 surface water samples, and four rainwater samples. Groundwater samples are from the Cenozoic formations within the alluvium of the Darling River, the Great Artesian Basin, and the Murray geological basin. Surface water samples are from the Darling River, and rainwater samples were taken within the study area. Subsets of the samples were analysed for major ions and trace metals, stable isotopes of water (δ2H and δ18O), radiocarbon (14C), stable carbon isotopes (δ13C), strontium isotopes (87Sr/86Sr), sulfur hexafluoride (SF6), chlorofluorocarbon (CFC) isotopes, chlorine-36 (36Cl), noble gases, and Radon-222. The results were used to inform a range of hydrogeological questions including aquifer distribution and quality, inter-aquifer connectivity, and groundwater-surface water connectivity.&nbsp;</div><div><br></div>

<div>Geochemistry of soils, stream sediments, and overbank sediments, plays an important part in informing geochemical environmental baselines, mineral prospectivity, and environmental management practices. Australia has a large number of such surveys, but they are spatially isolated and often used in isolation. First released in 2020, the Levelled Geochemical Baseline of Australia focused on levelling such surveys across the North Australian Craton, so that they could be used as a seamless dataset. This data release acts as an update to the Levelled Geochemical Baseline of Australia by changing the focus to national scale and incorporating recently reanalysed legacy samples.</div><div><br></div><div>This work was undertaken as part of the Exploring for the Future program, an eight-year program by the Australian government. The Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to net zero emissions, strong, sustainable resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, was an eight year, $225m investment by the Australian Government.</div><div><br></div><div><br></div><div><br></div><div><br></div>

Manuscript detailing the results of chlorite dissolution experiments conducted at Geoscience Australia.

<div>Alluvial sediments have long been used in geochemical surveys as their compositions are assumed to be representative of areas upstream. Overbank and floodplain sediments, in particular, are increasingly used for regional to continental-scale geochemical mapping. However, during downstream transport, sediments from heterogeneous source regions are carried away from their source regions and mixed. Consequently, using alluvial sedimentary geochemical data to generate continuous geochemical maps remains challenging. In this study we demonstrate a technique that numerically unmixes alluvial sediments to make a geochemical map of their upstream catchments. The unmixing approach uses a model that predicts the concentration of elements in downstream sediments, given a map of the drainage network and element concentrations in the source region. To unmix sedimentary chemistry, we seek the upstream geochemical map that, when mixed downstream, best fits geochemical observations downstream. To prevent overfitting we penalise the roughness of the geochemical model. To demonstrate our approach we apply it to alluvial samples gathered as part of the Northern Australia Geochemical Survey. This survey gathered samples collected over a ∼ 500,000 km2 area in northern Australia. We first validate our approach for this sample distribution with synthetic tests, which indicate that we can resolve geochemical variability at scales greater than 0.5 – 1◦ in size. We proceed to invert real geochemical data from the total digestion of fine-grained fraction of alluvial sediments. The resulting geochemical maps for two elements of potential economic interest, Cu and Nd, are evaluated in detail. We find that in both cases, our predicted downstream concentrations match well against a held-out, unseen subset of the data, as well as against data from an independent geochemical survey. By performing principal component analysis on maps generated for all 46 available elements we produce a synthesis map showing the significant geochemical domains of this part of northern Australia. This map shows strong spatial similarities to the underlying lithological map of the area. Finally, we compare the results from our approach to a geochemical map produced by kriging. We find that, unlike the method presented here, kriging generates geochemical maps that are both dampened relative to expected magnitude, as well as being spatially distorted. We argue that the unmixing approach is the most appropriate method for generating geochemical maps from regional-scale alluvial surveys.&nbsp;</div> <b>Citation:</b> Alex G. Lipp, Patrice de Caritat, Gareth G. Roberts, Geochemical mapping by unmixing alluvial sediments: An example from northern Australia, <i>Journal of Geochemical Exploration,</i> Volume 248, <b>2023</b>, 107174, ISSN 0375-6742, https://doi.org/10.1016/j.gexplo.2023.107174. (https://www.sciencedirect.com/science/article/pii/S0375674223000213)

As part of Geoscience Australia's Exploring for the Future program, the East Tennant region, which is centred on the Barkly Roadhouse in the Northern Territory, was identified as having favourable geological and geophysical indicators of mineral systems potential. Potentially prospective stratigraphy in the East Tennant region is completely concealed beneath Mesoproterozoic to Quaternary cover sequences. Prior to 2020 basement rocks in the East Tennant region were only known from a handful of legacy boreholes, supported by geophysical interpretation. In order to test geophysical interpretations and obtain additional samples of basement rocks for detailed analysis, a stratigraphic drilling campaign was undertaken in the East Tennant region as part of the MinEx CRC’s National Drilling Initiative. Ten stratigraphic boreholes were drilled through the cover sequences and into basement for a total of nearly 4000 m, including over 1500 m of diamond cored basement rocks to be used for scientific purposes. Inorganic geochemical samples from East Tennant National Drilling Initiative boreholes were taken to characterise cover and basement rocks intersected during drilling. Two sampling approaches were implemented based on the rocks intersected: 1) Borehole NDIBK04 contained localised sulphide mineralisation and elevated concentrations of several economically-significant elements in portable X-ray fluorescence data. In order to understand the geochemical variability and distribution of elements important for mineral system characterisation, the entire basement interval was sampled at nominal one metre intervals. This spacing was reduced to between 0.5 and 0.25 m from 237 m to 263 m to better understand a more intense zone of mineralisation, and 2) Samples from boreholes NDIBK01, NDIBK02, NDIBK03, NDIBK05, NDIBK06, NDIBK07, NDIBK08, NDIBK09 and NDIBK10 were selected to capture lithological and geochemical variability to establish bulk rock geochemical compositions for further interpretation. Attempts were made to sample representative, lithologically consistent intervals. A total of 402 samples were selected for analysis. Sample preparation was completed at Geoscience Australia and Bureau Veritas, with all analyses performed by Bureau Veritas in Perth. All samples were submitted for X-ray fluorescence (XRF), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), FeO determination, and loss on ignition (LOI). Samples from borehole NDIBK04 also underwent total combustion C and S, and Pb collection fire assay by ICP-MS for determination of Au, Pt and Pd concentrations. This data release presents inorganic geochemistry data acquired on rock samples from the ten East Tennant National Drilling Initiative boreholes.