<div>Poster for the Specialist Group in Geochemistry, Mineralogy & Petrology (SGGMP) conference in Yallingup WA in November 2022.</div><div><br></div>This Poster was presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)

This report presents the results of chemostratigraphic analyses for samples of the Waukarlycarly 1 deep stratigraphic well drilled in in the Waukarlycarly Embayment of the Canning Basin. The drilling of the well was funded by Geoscience Australia’s Exploring for the Future initiative to improve the understanding of the sub-surface geology of this underexplored region of the southern Canning Basin. The well was drilled in partnership with Geological Survey of Western Australia (GSWA) as project operator. Waukarlycarly 1 reached a total depth (TD) of 2680.53 m at the end of November 2019 and was continuously cored from 580 mRT to TD. The work presented in this report constitutes part of the post-well data acquisition. An elemental and isotope chemostratigraphic study was carried out on 100 samples of the well to enable stratigraphic correlations to be made across the Canning Basin within the Ordovician section known to host source rocks. Nine chemostratigraphically distinct sedimentary packages are identified in the Waukarlycarly 1 well and five major chemical boundaries that may relate to unconformities, hiatal surfaces or sediment provenance changes are identified. The Ordovician sections in Waukarlycarly 1 have different chemical signals in comparison to those in other regional wells, suggestive of a different provenance for the origin of the sediments in the Waukarlycarly Embayment compared to the Kidson Sub-basin (Nicolay 1) and Broome Platform (Olympic 1).

The ISOTOPE database stores compiled age and isotopic data from a range of published and unpublished (GA and non-GA) sources. This internal database is only publicly accessible through the webservices given as links on this page. This data compilation includes sample and bibliographic links. The data structure currently supports summary ages (e.g., U-Pb and Ar/Ar) through the INTERPRETED_AGES tables, as well as extended system-specific tables for Sm-Nd, Pb-Pb, Lu-Hf and O- isotopes. The data structure is designed to be extensible to adapt to evolving requirements for the storage of isotopic data. ISOTOPE and the data holdings were initially developed as part of the Exploring for the Future (EFTF) program. During development of ISOTOPE, some key considerations in compiling and storing diverse, multi-purpose isotopic datasets were developed: 1) Improved sample characterisation and bibliographic links. Often, the usefulness of an isotopic dataset is limited by the metadata available for the parent sample. Better harvesting of fundamental sample data (and better integration with related national datasets such as Australian Geological Provinces and the Australian Stratigraphic Units Database) simplifies the process of filtering an isotopic data compilation using spatial, geological and bibliographic criteria, as well as facilitating ‘audits’ targeting missing isotopic data. 2) Generalised, extensible structures for isotopic data. The need for system-specific tables for isotopic analyses does not preclude the development of generalised data-structures that reflect universal relationships. GA has modelled relational tables linking system-specific Sessions, Analyses, and interpreted data-Groups, which has proven adequate for all of the Isotopic Atlas layers developed thus far. 3) Dual delivery of ‘derived’ isotopic data. In some systems, it is critical to capture the published data (i.e. isotopic measurements and derived values, as presented by the original author) and generate an additional set of derived values from the same measurements, calculated using a single set of reference parameters (e.g. decay constant, depleted-mantle values, etc.) that permit ‘normalised’ portrayal of the data compilation-wide. 4) Flexibility in data delivery mode. In radiogenic isotope geochronology (e.g. U-Pb, Ar-Ar), careful compilation and attribution of ‘interpreted ages’ can meet the needs of much of the user-base, even without an explicit link to the constituent analyses. In contrast, isotope geochemistry (especially microbeam-based methods such as Lu-Hf via laser ablation) is usually focused on the individual measurements, without which interpreted ‘sample-averages’ have limited value. Data delivery should reflect key differences of this kind.

The purpose of this study was to constrain the processes of Paleoproterozoic crustmantle evolution by investigating the Lu-Hf, Sm-Nd and oxygen isotope systematics of igneous rocks of the Lamboo Province of the Halls Creek and King Leopold Orogens, in the Kimberley region of Western Australia. The specific objectives were to: 1. Ascertain the nature of the source rocks of the granites, and to test whether granite formation involved the reworking of ancient meta-igneous protoliths in an intra-plate environment or complex crust-mantle interaction processes typical of modern plate tectonic settings; 2. Use data from granite-hosted zircons to quantify the proportion of new crust formed during discrete magmatic events, and to link this with the longer-term record of crustal evolution preserved by detrital zircons, and 3. Constrain the tectonic setting of the Lamboo Province, and thus the geodynamic controls on global crustal growth in this key time period.

Geoscience Australia has compiled U-Pb datasets from disparate sources into a single, standardised and publicly-available U–Pb geochronology compilation for all Australia. The national maps presented in this poster expand upon the data coverage previously compiled by Anderson et al. (2017) and Jones et al. (2018), which covered northern and western Australia only. This extension of a national coverage has been achieved through the development of Geoscience Australia’s Interpreted Ages database. In this database, there are now >4000 U–Pb sample points compiled from across Australia, with significant datasets to come from the southern Australia regions. These will be available to the public in the coming months through the Exploring for the Future Data Discovery Portal (eftf.ga.gov.au).

<div>At the 2021 AESC (Australian Earth Sciences Convention), Geoscience Australia (GA) introduced a continental-scale Isotopic Atlas of Australia (Fraser et al., 2020) through an interactive poster display (Fraser et al., 2021). In the two years since, progress on this Isotopic Atlas has continued and expanded datasets are now publicly available and downloadable via Geoscience Australia’s Exploring for the Future (EFTF) Geochronology and Isotopes Data Portal.</div><div><br></div><div>This poster provides example maps produced from the compiled data of multiple geochronology and isotopic tracer datasets, now available in the Geochronology and Isotopes Data Portal. Available data include Sm–Nd model ages of magmatic rocks (Champion et al., 2013); Lu–Hf isotopes from zircon and associated O-isotope data (Waltenberg et al., 2023); Pb–Pb isotopes from ore-related minerals such as galena and pyrite (Huston et al., 2019); Rb–Sr stable isotopes from surface regolith (de Caritat et al., 2022, 2023); U–Pb interpreted ages of magmatic, metamorphic and sedimentary rocks (Jones et al., 2018); and K–Ar, Ar–Ar, Re–Os, Rb–Sr and fission-track interpreted ages from minerals and whole rocks.</div><div><br></div><div>Significant recent additions to the datasets include geochronology compilations for Victoria (Waltenberg et al., 2021) and Tasmania (Jones et al., 2022) and full geochronology analytical data tables for GA’s SHRIMP (Sensitive High Resolution Ion Micro Probe) U–Pb results. The online data portal provides tools for visualizing data in commonly-used diagrammatic formats (e.g. Time-Space style plots for geochronology, isotope evolution diagrams for Nd and Hf data). Data are also available for download in a range of formats (CSV, JSON, KML, Shapefile) to allow manipulation and visualization offline for specific purposes.</div><div><br></div><div>Work is ongoing to improve the coverage of legacy interpreted ages geochronology data, to include geochronology analytical data tables for both ID-TIMS and LA-ICP-MS data, and to update the Sm-Nd and Pb-Pb in ores coverages with new data. New work is in progress to develop a Pb-Pb isotopic coverage from representative ‘basement’ rocks (Liebmann et al., 2022) and to expand the coverage of oxygen and Lu-Hf isotopes from zircon, with a current focus in south-eastern Australia (Mole et al., 2022).</div><div><br></div><div>This Isotopic Atlas of Australia provides a convenient visual overview of age and isotopic patterns reflecting geological processes that have led to the current configuration of the Australian continent, including progressive development of continental crust from the mantle. These datasets and maps unlock the collective value of several decades of geochronological and isotopic studies conducted across Australia, and provide an important complement to other geological maps and geophysical images—in particular, by adding a time dimension to 2D and 3D maps and models.</div> Abstract/Poster submitted and presented at 2023 Australian Earth Science Convention (AESC), Perth WA (https://2023.aegc.com.au/)

<div>Scientific studies undertaken on core from the Barnicarndy 1 well drilled in 2019 in the onshore Canning Basin in Western Australia as part of the Exploring for the Future program have shown that the well penetrated a thick section of the early Ordovician Nambeet Formation which contains abundant fossils reflective of deposition in an open marine environment. Although the calcareous shales are organically poor (average total organic carbon content 0.17 wt%) processing of 42 drill core samples recovered a plethora of acid-resistant, organic-walled microfossils. Seven core samples with the highest organic content were analysed for their molecular (biomarker) fossils and stable isotopic composition to provide insights into the type of organic matter preserved, and the redox conditions of the sediments during deposition.</div><div><br></div>This Abstract was submitted/presented to the 2022 Australian Organic Geochemistry Conference 27-29 November (https://events.csiro.au/Events/2022/October/5/Australian-Organic-Geochemistry-Conference)

<div>A minor update to Version 1.0: Lu Hf and O isotope data structure and delivery.</div><div><br></div><div>Isotopic data from rocks and minerals have the potential to yield unique insights into the composition and evolution of the Earth's crust and mantle. Time-integrated records of crust and mantle differentiation (as preserved by the U-Pb, Sm-Nd and Lu-Hf isotopic systems, for example) are important in a wide range of geological applications, especially when successfully integrated with other geological, geophysical, and geochemical datasets. However, such integration requires (i) compilation of comprehensive isotopic data coverages, (ii) unification of datasets in a consistent structure to facilitate inter-comparison, and (iii) easy public accessibility of the compiled and unified datasets in spatial and tabular formats useful and useable by a broad range of industry, government and academic users. This constitutes a considerable challenge, because although a wealth of isotopic information has been collected from the Australian continent over the last 40 years, the published record is fragmentary, and derived from numerous and disparate sources. Unlocking and harnessing the collective value of isotopic datasets will enable more comprehensive and powerful interpretations, and significantly broaden their applicability to Earth evolution studies and mineral exploration.</div><div><br></div><div>As part of the Exploring for the Future (EFTF) program (https://www.ga.gov.au/eftf), we have designed a new database structure and web service system to store and deliver full Lu-Hf isotope and associated O-isotope datasets, spanning new data collected during research programs conducted by Geoscience Australia (GA), as well as compiled literature data. Our approach emphasises the links between isotopic measurements and their spatial, geological, and data provenance information in order to support the widest possible range of uses. In particular, we build and store comprehensive links to the original sources of isotopic data so that (i) users can easily track down additional context and interpretation of datasets, and (ii) generators of isotopic data are appropriately acknowledged for their contributions.</div><div><br></div><div>This system delivers complete datasets including (i) full analytical and derived data as published by the original author, (ii) additional, normalised derived data recalculated specifically to maximise inter-comparability of data from disparate sources, (iii) metadata related to the analytical setup, (iv) a broad range of sample information including sampling location, rock type, geological province and stratigraphic unit information, and (v) descriptions of (and links to) source publications. The data is delivered through the Geoscience Australia web portal (www.portal.ga.gov.au), and can also be accessed through any web portal capable of consuming Open Geospatial Consortium (OGC)-compliant web services, or any GIS system capable of consuming Web Map Services (WMS) or Web Feature Services (WFS).</div><div><br></div><div>Version 1.0 of this Record (Waltenberg et al., 2021) described the database system and web service tables, and featured normalised Lu-Hf data that utilised CHondritic Uniform Reservoir (CHUR) parameters from Blichert-Toft and Albarède (1997). It also presented full tabulated datasets compiled from the North Australian Craton as part of the initial EFTF (2016–2020) program, comprising 5974 individual analyses from 149 unique rock samples. This update (version 1.1) enacts minor changes to some field names within the web services tables to ensure consistency with other web services offered by GA, and for normalised Lu-Hf data, it applies the CHUR parameters of Bouvier et al. (2008) to the entire dataset. The digital datasets presented by Waltenberg et al. (2021) have also been supplemented by more recent analyses collected as part of GA projects in Queensland and New South Wales, in collaboration with the relevant State geological surveys. Version 1.1 does not include an updated tabular data release; the digital dataset available via the web portal now comprises 7630 individual analyses from 180 unique rock samples.</div>

This study assesses the effect of chemical abrasion on in-situ mass spectrometric isotopic and elemental analyses in zircon. Chemical abrasion improves the U-Pb systematics of SIMS (Secondary Ion Mass Spectrometry) analyses of reference zircons, while leaving other isotopic systems largely unchanged. SIMS ²⁰⁶Pb/²³⁸U ages of chemically abraded reference materials TEMORA-2, 91500, QGNG, and OG1 are precise to within 0.25 to 0.4%, and are within uncertainty of chemically abraded TIMS reference ages, while SIMS ²⁰⁶Pb/²³⁸U ages of untreated zircons are within uncertainty of TIMS reference ages where chemical abrasion was not used. Chemically abraded and untreated zircons appear to cross-calibrate within uncertainty using all but one possible permutations of reference materials, provided that the corresponding chemically abraded or untreated reference age is used for the appropriate material. In the case of reference zircons QGNG and OG1, which are slightly discordant, the SIMS U-Pb ages of chemically abraded and untreated material differ beyond their respective 95% confidence intervals. SIMS U-Pb analysis of chemically abraded zircon with multiple growth stages are more difficult to interpret. Treated igneous rims on zircon crystals from the S-type Mount Painter Volcanics are much lower in common Pb than the rims on untreated zircon grains. However, the analyses of chemically abraded material show excess scatter. Chemical abrasion also changes the relative abundance of the ages of zircon cores inherited from the sedimentary protolith, presumably due to some populations being more likely to survive the chemical abrasion process than others. We consider these results from inherited S-type zircon cores to be indicative of results for detrital zircon grains from unmelted sediments. Trace element, &delta;¹⁸O, and εHf analyses were also performed on these zircons. None of these systems showed substantial changes as a result of chemical abrasion. The most discordant reference material, OG1, showed a loss of OH as a result of chemical abrasion, presumably due to dissolution of hydrous metamict domains, or thermal dehydration during the annealing step of chemical abrasion. In no case did zircon gain fluorine due to exchange of lattice-bound substituted OH or other anions with fluorine during the HF partial dissolution phase of the chemical abrasion process. As the OG1, QGNG, and TEMORA-2 zircon samples are known to be compositionally inhomogenous in trace element composition, spot-to-spot differences dominated the trace element results. Even the 91500 megacrystic zircon pieces exhibited substantial chip-to-chip variation. The LREE in chemically abraded OG1 and TEMORA-2 were lower than in the untreated samples. Ti concentration and phosphorus saturation ((Y+REE)/P) were generally unchanged in all samples. <b>Citation:</b> Kooymans, C., Magee Jr., C. W., Waltenberg, K., Evans, N. J., Bodorkos, S., Amelin, Y., Kamo, S. L., and Ireland, T.: Effect of chemical abrasion of zircon on SIMS U–Pb, &delta;¹⁸O, trace element, and LA-ICPMS trace element and Lu–Hf isotopic analyses, Geochronology, 6, 337–363, https://doi.org/10.5194/gchron-6-337-2024, 2024.

<div>We present the first national-scale lead (Pb) isotope maps of Australia based on surface regolith for five isotope ratios, ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, ²⁰⁸Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁶Pb, and ²⁰⁸Pb/²⁰⁶Pb, determined by single collector Sector Field-Inductively Coupled Plasma-Mass Spectrometry after an Ammonium Acetate leach followed by Aqua Regia digestion. The dataset is underpinned principally by the National Geochemical Survey of Australia (NGSA) archived floodplain sediment samples. We analysed 1219 ‘top coarse’ (0-10 cm depth, &lt;2 mm grain size) samples, collected near the outlet of 1098 large catchments covering 5.647 million km2 (~75% of Australia). This paper focusses on the Aqua Regia dataset. The samples consist of mixtures of the dominant soils and rocks weathering in their respective catchments (and possibly those upstream) and are therefore assumed to form a reasonable representation of the average isotopic signature of those catchments. This assumption was tested in one of the NGSA catchments, within which 12 similar ‘top coarse’ samples were also taken; results show that the Pb isotope ratios of the NGSA catchment outlet sediment sample are close to the average of the 12 sub-catchment, upstream samples. National minimum, median and maximum values reported for ²⁰⁶Pb/²⁰⁴Pb were 15.558, 18.844, 30.635; for ²⁰⁷Pb/²⁰⁴Pb 14.358, 15.687, 18.012; for ²⁰⁸Pb/²⁰⁴Pb 33.558, 38.989, 48.873; for ²⁰⁷Pb/²⁰⁶Pb 0.5880, 0.8318, 0.9847; and for ²⁰⁸Pb/²⁰⁶Pb 1.4149, 2.0665, 2.3002, respectively. The new dataset was compared with published bedrock and ore Pb isotope data, and was found to dependably represent crustal elements of various ages from Archean to Phanerozoic. This suggests that floodplain sediment samples are a suitable proxy for basement and basin geology at this scale, despite various degrees of transport, mixing, and weathering experienced in the regolith environment, locally over protracted periods of time. An example of atmospheric Pb contamination around Port Pirie, South Australia, where a Pb smelter has operated since the 1890s, is shown to illustrate potential environmental applications of this new dataset. Other applications may include elucidating detail of Australian crustal evolution and mineralisation-related investigations.&nbsp;</div> <b>Citation:</b> Desem, C. U., de Caritat, P., Woodhead, J., Maas, R., and Carr, G.: A regolith lead isoscape of Australia, <o>Earth Syst. Sci. Data</i>, 16, 1383–1393, https://doi.org/10.5194/essd-16-1383-2024, 2024.