<div>The Petroleum Systems Summary database stores the compilation of the current understanding of petroleum systems information by basin across Australia. The Petroleum Systems Summary database and delivery tool provide high-level information of the current understanding of key petroleum systems for areas of interest. For example, geological studies in the Exploring for the Future (EFTF) program have included the Canning, McArthur and South Nicholson basins (Carr et al., 2016; Hashimoto et al., 2018). The database and tool aim to assist geological studies by summarising and interpreting key datasets related to conventional and unconventional hydrocarbon exploration. Each petroleum systems summary includes a synopsis of the basin and key figures detailing the basin outline, major structural components, data availability, petroleum systems events chart and stratigraphy, and a précis of the key elements of source, reservoir and seal. Standardisation of petroleum systems nomenclature establishes a framework for each basin after Bradshaw (1993) and Bradshaw et al. (1994), with the source-reservoir naming conventions adopted from Magoon and Dow (1994).&nbsp;</div><div><br></div><div>The resource is accessible via the Geoscience Australia Portal&nbsp;(https://portal.ga.gov.au/) via the Petroleum Systems Summary Tool (Edwards et al., 2020).</div>

<div><strong>Output type: </strong>Exploring for the Future Extended Abstract</div><div><br></div><div><strong>Short abstract: </strong>Australian sediment-hosted mineral systems play a crucial role in providing base metals and critical minerals essential for the global low-carbon economy. The Georgina Basin has the key components for forming and preserving a sediment-hosted Zn-Pb mineral system, but historically has been considered ‘cover’ to deeper, more prospective Proterozoic basement rocks. Thus, the basin has remained relatively under-explored, with many questions yet to be resolved on its sediment-hosted Zn-Pb mineral system and prospectivity for Zn-Pb. Utilising new whole-rock and isotope geochemistry of the Georgina Basin from recently drilled holes in the Northern Territory, we demonstrate the sensitivity of local redox boundaries to detect regional mineralisation. Two geochemically enriched zones have been identified and interpreted as redox interfaces which have trapped and concentrated metals from the surrounding basin, a ‘supergene zone’ and a ‘water intercept zone’. The ‘supergene zone’ is a paleo water table horizon, while the ‘water intercept zone’ is an active redox front at the uppermost part of the Cambrian Limestone Aquifer. The enrichment of these redox zones is consistent across multiple drill holes, reaching up to 395 ppm Pb and 1550 ppm Zn. Additionally, the Pb isotopes of high-Pb and sulfidic intervals have a highly radiogenic character (206Pb/204Pb ~22.0–23.0) that is diagnostic of Georgina Basin’s Mississippi Valley-type Zn-Pb mineralisation. Taken together, these results suggest there may be buried mineralisation in this part of the Georgina Basin, as well as highlight the potential of these redox interfaces as a regional reconnaissance target for exploration.</div><div><br></div><div><strong>Citation: </strong>Schroder I.F., Huston D. & de Caritat P., 2024. The geochemistry of redox interfaces for insights into Zn-Pb prospectivity in the Georgina Basin. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, https://doi.org/10.26186/149116 </div>

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa), with a few additional Northern Australia Geochemical Survey infill samples. The present study targeted the northern parts of Western Australia, the Northern Territory and Queensland in Australia, north of 21.5 °S. The samples were taken mostly from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (&lt;2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 &lt; 87Sr/86Sr &lt; 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (&gt;100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a &gt;500 km-long northwest-southeast-trending low anomaly (87Sr/86Sr &lt; 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, conversely, high 87Sr/86Sr values (&gt; 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape and model derived therefrom can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations. &nbsp;The new spatial dataset is publicly available through the Geoscience Australia portal https://portal.ga.gov.au/.</div>

<div>This study was commissioned by Geoscience Australia (GA) as part of the Exploring for the Future program to produce a report on the organic petrology for rock samples from drill holes of the Birrindudu Basin, Northern Territory, Australia. A suite of 130 drill core samples from 6 drill holes was analysed using standard organic petrological methods to identify the types of organic matter present, assess their relative abundances and determine the levels of thermal maturity attained by the sedimentary organic matter using the reflectance of organoclasts present. </div>

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (NGSA; www.ga.gov.au/ngsa). The present study targeted the Yilgarn geological region in southwestern Australia. The samples were mostly taken from a depth of ~60-80 cm (Bottom Outlet Sediments, BOS) in floodplain deposits at or near the outlet of large catchments (drainage basins). A small number of surface (0-10 cm) samples (Top Outlet Sediments, TOS) were also included in the study. For all, a coarse grain-size fraction (<2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Overall, 107 NGSA BOS < 2 mm and 13 NGSA TOS < 2 mm were analysed for Sr isotopes. Given that there are ~10 % field duplicates in the NGSA, all those samples originate from within 97 NGSA catchments, which together cover 533 000 km2 of southwestern Australia. Preliminary results for the BOS samples demonstrate a wide range of strontium isotopic values (0.7152 < 87Sr/86Sr < 1.0909) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (>100 km) patterns that appear to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, catchments in the western and central Yilgarn dominated by felsic intrusive basement geology have radiogenic 87Sr/86Sr signatures in the floodplain sediments consistent with published whole-rock data. Similarly, unradiogenic signatures in sediments in the eastern Yilgarn are in agreement with published whole-rock data. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape and model derived therefrom can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations.&nbsp; The new spatial dataset is publicly available through the Geoscience Australia portal https://portal.ga.gov.au/.</div>

<div>The bulk oils database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the bulk properties of petroleum liquids (e.g., condensate, crude oil, bitumen) sampled from boreholes and field sites. The analyses are performed by various laboratories in service and exploration companies, Australian government institutions, and universities using a range of instruments. Petroleum is composed primarily of hydrocarbons (carbon and hydrogen) with minor quantities of heterocyclic compounds containing either nitrogen, oxygen or sulfur. Data includes the borehole or field site location, sample depth, shows and tests, stratigraphy, analytical methods, other relevant metadata, and various data types including; API gravity, elemental composition and photographs of the samples. The stable carbon (¹³C/¹²C) and hydrogen (²H/¹H) isotopic ratios of crude oil and derivative saturated and aromatic hydrocarbon fractions are presented in parts per mil (‰) and in delta notation as &delta;¹³C and &delta;²H, respectively. Results are also included from methods that separate crude oils into bulk components, such as the quantification of saturated hydrocarbon, aromatic hydrocarbon, resin, and asphaltene (SARA) fractions according to their polarity.</div><div><br></div><div>These data provide information about the petroleum fluid’s composition, source, thermal maturity, secondary alteration, and fluid migration pathways. They are also useful for enhanced oil recovery assessments, petroleum systems mapping and basin modelling. Hence, these sample-based datasets are used for the discovery and evaluation of sediment-hosted resources. Some data are generated in Geoscience Australia’s laboratory and released in Geoscience Australia records. Data are also collated from destructive analysis reports (DARs), well completion reports (WCRs), and literature. The bulk oils data are delivered in the Petroleum Bulk Properties and Stable Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div>The pyrolysis-reflectance tie database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases, which combine key properties related to thermal maturity. These data are typically used as input parameters in basin analysis and petroleum systems modelling to assist with the discovery and evaluation of sediment-hosted energy resources. The programmed pyrolysis analyses and the maceral reflectance analyses undertaken using reflected light microscopy are conducted on rock samples, either as cores, cuttings or rock chips, taken from boreholes and field sites in Australian sedimentary basins. The full datasets are available in the pyrolysis, vitrinite reflectance, maceral reflectance and organoclast maturity web services. These analyses are performed by various laboratories in service and exploration companies, Australian government institutions and universities using a range of instruments.</div><div><br></div><div>These data are collated from destructive analysis reports (DARs), well completion reports (WCRs), and literature. The data are delivered in the Combined Pyrolysis and Vitrinite Reflectance web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div><strong>Output Type: </strong>Exploring for the Future Extended Abstract</div><div><br></div><div><strong>Short Abstract: </strong>Groundwater geochemistry is an important and often under-appreciated medium to understand geology below surface and is a valuable tool as part of a regional mineral exploration program. This study presents an assessment of hydrogeochemical results from the Curnamona and Mundi region with respect to their insights into mineral prospectivity and characterisation of groundwater baselines. The work is a collaboration with the Mineral Exploration Cooperative Research Centre (MinEx CRC), the Geological Survey of New South Wales and the Geological Survey of South Australia as part of Geoscience Australia’s Exploring for the Future program. It combines new and legacy groundwater chemistry from 297 samples to identify multiple elevated multi-element anomalies (Ag, Pb, Cd) and signatures of sulfide mineralisation (d34S and sulfur excess), which are interpreted as potential features from subsurface Broken Hill Type mineralisation (Pb-Zn-Ag). Additional multi-element anomalies (Cu, Mo, Co, Au) may be attributable to Cu-Au, Cu-Mo and Au mineralisation. We then apply hierarchical cluster analysis to understand sample hydrostratigraphy and characterise robust hydrogeochemical baselines for the major aquifer systems in the region. This reveals that the majority of anomalies are restricted to groundwaters derived from basement fractured rock aquifer systems, with a couple anomalies observed in the Lake Eyre Basin cover, which helps narrow the search-space for future groundwater-based mineral exploration in this region (to prioritise these aquifers and anomalies). In addition, we demonstrate the capability of these local hydrogeochemical baselines to support more sensitive resolution of hydrogeochemical anomalies relating to mineralisation, as well as reveal hydrogeological processes such as mixing.</div><div><br></div><div><strong>Citation: </strong>Reid, N., Schroder, I., Thorne, R., Folkes, C., Hore, S., Eastlake, M., Petts, A., Evans, T., Fabris, A., Pinchand, T., Henne A., & Palombi, B.R., 2024. Hydrogeochemistry of the Curnamona and Mundi region. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts. Geoscience Australia, Canberra. https://doi.org/10.26186/149509</div>

<div>The fluid inclusion stratigraphy database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for Fluid Inclusion Stratigraphy (FIS) analyses performed by FIT, a Schlumberger Company (and predecessors), on fluid inclusions in rock samples taken from boreholes. Data includes the borehole location, sample depth, stratigraphy, analytical methods and other relevant metadata, as well as the mass spectrometry results presented as atomic mass units (amu) from 2 to 180 in parts per million (ppm) electron volts.</div><div> Fluid inclusions (FI) are microscopic samples of fluids trapped within minerals in the rock matrix and cementation phases. Hence, these FIS data record the bulk volatile chemistry of the fluid inclusions (i.e., water, gas, and/or oil) present in the rock sample and determine the relative abundance of the trapped compounds (e.g., in amu order, hydrogen, helium, methane, ethane, carbon dioxide, higher molecular weight aliphatic and aromatic hydrocarbons, and heterocyclic compounds containing nitrogen, oxygen or sulfur). The FI composition can be used to identify the presence of organic- (i.e., biogenic or thermogenic) and inorganic-sourced gases. These data provide information about fluid preservation, migration pathways and are used to evaluate the potential for hydrocarbon (i.e. dry gas, wet gas, oil) and non-hydrocarbon (e.g., hydrogen, helium) resources in a basin. These data are collated from Geoscience Australia records, destructive analysis reports (DARs) and well completion reports (WCRs), with the results being delivered in the Fluid Inclusion Stratigraphy (FIS) web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div>We present the first national-scale lead (Pb) isotope maps of Australia based on surface regolith for five isotope ratios, ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, ²⁰⁸Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁶Pb, and ²⁰⁸Pb/²⁰⁶Pb, determined by single collector Sector Field-Inductively Coupled Plasma-Mass Spectrometry after an Ammonium Acetate leach followed by Aqua Regia digestion. The dataset is underpinned principally by the National Geochemical Survey of Australia (NGSA) archived floodplain sediment samples. We analysed 1219 ‘top coarse’ (0-10 cm depth, &lt;2 mm grain size) samples, collected near the outlet of 1098 large catchments covering 5.647 million km2 (~75% of Australia). This paper focusses on the Aqua Regia dataset. The samples consist of mixtures of the dominant soils and rocks weathering in their respective catchments (and possibly those upstream) and are therefore assumed to form a reasonable representation of the average isotopic signature of those catchments. This assumption was tested in one of the NGSA catchments, within which 12 similar ‘top coarse’ samples were also taken; results show that the Pb isotope ratios of the NGSA catchment outlet sediment sample are close to the average of the 12 sub-catchment, upstream samples. National minimum, median and maximum values reported for ²⁰⁶Pb/²⁰⁴Pb were 15.558, 18.844, 30.635; for ²⁰⁷Pb/²⁰⁴Pb 14.358, 15.687, 18.012; for ²⁰⁸Pb/²⁰⁴Pb 33.558, 38.989, 48.873; for ²⁰⁷Pb/²⁰⁶Pb 0.5880, 0.8318, 0.9847; and for ²⁰⁸Pb/²⁰⁶Pb 1.4149, 2.0665, 2.3002, respectively. The new dataset was compared with published bedrock and ore Pb isotope data, and was found to dependably represent crustal elements of various ages from Archean to Phanerozoic. This suggests that floodplain sediment samples are a suitable proxy for basement and basin geology at this scale, despite various degrees of transport, mixing, and weathering experienced in the regolith environment, locally over protracted periods of time. An example of atmospheric Pb contamination around Port Pirie, South Australia, where a Pb smelter has operated since the 1890s, is shown to illustrate potential environmental applications of this new dataset. Other applications may include elucidating detail of Australian crustal evolution and mineralisation-related investigations.&nbsp;</div> <b>Citation:</b> Desem, C. U., de Caritat, P., Woodhead, J., Maas, R., and Carr, G.: A regolith lead isoscape of Australia, <o>Earth Syst. Sci. Data</i>, 16, 1383–1393, https://doi.org/10.5194/essd-16-1383-2024, 2024.