The Browse Basin is located in the southern Timor Sea region of Australia's North West Shelf and covers an area of ~140,000 km2. It was identified as containing potential Environmentally Suitable Sites for carbon dioxide (CO2) Injection (ESSCI) by the Australian Petroleum CRC's GEODISC program (1999-2003). A regional geological reconnaissance of Cenozoic sandstone and carbonate sequences in the Browse Basin was undertaken in 2007 to determine the potential storage and sealing capacity for geological storage of CO2, the results of which are presented in this report. Methods included the review of available literature and well-completion reports, lithological and mineral analysis of selected well cuttings and interpretation of the wire-line and seismic response of the Cenozoic section.

<div>The bulk rock stable isotopes database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the stable isotopic composition of sedimentary rocks with an emphasis on calcareous rocks and minerals sampled from boreholes and field sites. The stable isotopes of carbon, oxygen, strontium, hydrogen, nitrogen, and sulfur are measured by various laboratories in service and exploration companies, Australian government institutions, and universities, using a range of instruments. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and the stable isotopes ratios. The carbon (¹³C/¹²C) and oxygen (¹⁸O/¹⁶O) isotope ratios of calcareous rocks are expressed in delta notation (i.e., &delta;¹³C and &delta;¹⁸O) in parts per mil (‰) relative to the Vienna Peedee Belemnite (VPDB) standard, with the &delta;¹⁸O values also reported relative to the Vienna Standard Mean Ocean Water (VSMOW) standard. Likewise, the stable isotope ratio of hydrogen (²H/¹H) is presented in delta notation (&delta;²H) in parts per mil (‰) relative to the VSMOW standard, the stable isotope ratio of nitrogen (¹⁵N/¹⁴N) is presented in delta notation (&delta;¹⁵N) in parts per mil (‰) relative to the atmospheric air (AIR) standard, and the stable isotope ratio of sulfur (³⁴S/³²S) is presented in delta notation (&delta;³⁴S) relative to the Vienna Canyon Diablo Troilite (VCDT) standard. For carbonates, the strontium (⁸⁷Sr/⁸⁶Sr) isotope ratios are also provided.</div><div><br></div><div>These data are used to determine the isotopic compositions of sedimentary rock with emphasis on the carbonate within rocks, either as minerals, the mineral matrix or cements. The results for the carbonate rocks are used to determine paleotemperature, paleoenvironment and paleoclimate, and establish regional- and global-scale stratigraphic correlations. These data are collated from Geoscience Australia records, destructive analysis reports (DARs), well completion reports (WCRs), and literature. The stable isotope data for sedimentary rocks are delivered in the Stable Isotopes of Carbonates web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

High-CO2 gas fields serve as important analogues for understanding various processes related to CO2 injection and storage. The chemical signatures, both within the fluids and the solid phases, are especially useful for elucidating preferred gas migration pathways and also for assessing the relative importance of mineral dissolution and/or solution trapping efficiency. In this paper, we present a high resolution study focussed on the Gorgon gas field and associated Rankin trend gases on Australia's Northwest Shelf of Australia. The Gorgon field is characterized by a series of stacked reservoirs (Figure 1), and is therefore well placed to characterize CO2 migration, dissolution and reaction by looking at geochemical signatures in the different reservoirs. Hydrological data at the Gorgon field also suggests that many of the major faults possess very low transmissivities, which should prevent or limit mixing of reservoir fluids with different chemical imprints. The gas data we present here reveal correlatable trends for mole %-CO2 and --C CO2 both areally and vertically as observed by Edwards et al. (2007). We suggest that the observed relationships are imparted due to mineral carbonation reactions that occurred along the CO2 migration pathway. These results have important implications for carbon storage operations and suggest that under certain conditions mineral sequestration might occur over longer migration distances and on shorter timescales than previously thought.

The Recherche Archipelago lies within the westernmost reaches of the Great Australian Bight, a large cool-water carbonate depositional province on the southern Australian margin. The inner shelf of the archipelago comprises numerous islands, typically comprising Proterozoic granites, which protrude from the shelf of mainly recent carbonate sediments. The area is influenced by extreme Southern Ocean swell energy, which results in a typically wave-abraded inner shelf, and sediment deposition mainly on the mid- to outer shelf. For Esperance Bay, a large shallow-water embayment within the archipelago, we examined the relationships between bottom sediments, geomorphology and the distribution of biotic habitats by integrating multibeam sonar, underwater video and sediment grab sample information. Major benthic habitats, such as seagrass beds, rhodolith beds, rocky reefs and mobile sand sheets are characterised in terms of their sea bed morphology, sedimentology and bioclastic composition. The littoral zone comprises mature quartz sand dominated by seagrasses, whereas the mainly carbonate-dominated shelf sediments are typically coarse gravely sands, and contain significant quantities of granitic material that is accumulating in areas of low wave exposure, typically behind the rocky islands. Bioclasts are dominated by red algal, bryozoan and foraminiferal components, as well as relict material. Sediment lags and calcarenite reefs occur in areas of high wave exposure, often with significant covers of macro-algae and sponges. The abundance of sediment producing organisms such as shallow-water rhodoliths and the presence of large-scale mobile sediment bedforms suggests that due to the influence of the rocky islands, the localised production and accumulation of carbonate sediments in the Recherche Archipelago is significantly greater than that observed in other parts of the Great Australian Bight inner shelf.

New 2D seismic data acquired in the Mentelle Basin by Geoscience Australia in 2008-09 has been used for a seismic facies study of the post-rift succession. The Mentelle Basin is a large deep to ultra deep-water, frontier basin located on Australia's southwestern margin about 200 km southwest of Perth. The study focused on the post-rift sequences deposited following the breakup between Australia and Greater India. Stratigraphic wells DSDP 258 and DSDP 264 provide age and lithological constraints on the upper portion of the post-rift succession down to mid-Albian strata. The depositional environment and lithology of the older sequences are based on analysis of the seismic facies, stratal geometries and comparisons to the age equivalent units in the south Perth Basin. Fourteen seismic facies were identified based on reflection continuity, amplitude and frequency, internal reflection configuration and external geometries. They range from high continuity, high amplitude, parallel sheet facies to low continuity, low amplitude, parallel, subparallel and chaotic sheet, wedge and basin fill facies. Channel and channel fill features are common in several facies along with a mounded facies (probably contourite) and its associated ponded turbidite fill. A progradational sigmoidal to oblique wedge facies occurs at several stratigraphic levels in the section. A chaotic mound facies, probably comprising debrite deposits, has a localised distribution.

Dense hydrocoral-sponge communities have been identified on the upper continental slope of George V Land, East Antarctica and declared Vulnerable Marine Ecosystems. Analysis of physical and biological datasets collected during the 2007/08 CEAMARC survey identified that the richest communities are found in the heads of canyons which receive Antarctic Bottom Water formed on the George V shelf, and the canyons harbouring rich benthos are also those that cut the shelf break. This led to several hypotheses regarding their distribution and three main factors were identified. These hypotheses were tested during a recent marine science voyage in January 2011 to the same region. Initial analysis of the new data supports the hypotheses regarding the physical controls on hydrocoral-sponge community distribution.

This study was undertaken as part of a program to collect baseline data from the seabed environments over the Van Diemen Rise, which comprises a series of carbonate platforms and banks in the eastern Joseph Bonaparte Gulf, northwest of Darwin. Samples were collected during a survey on board the RV Solander in August and September 2009. The state of saturation for the different carbonate minerals (aragonite, calcite, high-magnesium calcite) was calculated for each sampling site from the ratio of the ion activity product and the solubility product. The carbonate ion concentration used for the ion activity product was calculated from total alkalinity and pH. The solubility products of the carbonate minerals were derived from literature data, e.g. the solubility for high-magnesium calcite as a function of the mol% MgCO3 was based on experimental results by Plummer and Mackenzie (1974, American Journal of Science vol. 274, p. 61-83). The calculated average state of saturation was 1.4 (range: 0.8-1.9) for high-magnesium calcite, 4.2 (range: 3.4-4.6) for aragonite, and 6.4 (range: 5.1-6.8) for calcite. Values close to 1 suggest the mineral is in thermodynamic equilibrium with ambient water, which is the case for high-magnesium calcite. In contrast, aragonite and calcite are distinctively supersaturated. Given the near-equilibrium state of high-magnesium calcite, this mineral phase will likely be lost over a time scale of decades as ocean acidification progresses. This ongoing process will alter the sediment composition significantly given the high abundance of high-magnesium calcite. This study supports the concept of using high-magnesium calcite as an indicator for the progression of ocean acidification where surface sediments have been sampled and preserved over time.

Concern about the impact of ocean acidification on organisms secreting high magnesium calcite skeletons has led to renewed interest in the mineralogy of these organisms. The identification of minerals making up the skeletons of tropical coralline algae, and in particular the determination of the Mg-content of calcite, is most commonly performed with X-ray diffraction. This method, based on XRD peak position, attracted criticism in the past because it produced Mg-contents that were in some cases lower compared to those based on chemical analyses of the bulk sample (in solution). The recent discovery of dolomite and magnesite in living coralline algae skeletons in addition to Mg-calcite explained this issue, and it is our goal in the present study to reinstate XRD as a reliable, quick and affordable method for the study of the mineral make-up of coralline algae species. In this paper we review the history of mineralogical analyses on tropical coralline algae and identify physical preparation methods that can affect results. We build on existing XRD methods to develop simple sampling and analytical methods to identify the presence of dolomite and magnesite, and numerically assess peak asymmetry that is caused by the overlapping reflections of calcite, dolomite and magnesite. These methods do not require specialist crystallographic knowledge or expensive or time consuming processes. The additional information our methods produce can be used to study intra-cellular calcification, and helps to rapidly assess and compare the mineral make-up of large numbers of samples. We conclude that XRD should be an integral part of any mineralogical analysis of coralline algae skeletons, which may be composed of not only Mg-calcite (Ca1.0-0.6Mg0-0.4CO3), but also dolomite (Ca0.5Mg0.5CO3), magnesite (MgCO3) and aragonite (CaCO3).

This record contains the preliminary results of Geoscience Australia marine survey 238 (SS04/2003) to southeast Gulf of Carpentaria. The survey was completed between 9 May and 10 June 2003 using Australia's national facility research vessel Southern Surveyor. The survey included Geoscience Australia and CSIRO and Marine and Atmospheric Research scientists.

We combine two- and three-dimensional seismic stratigraphic interpretation with paleobathymetric analysis from benthic foraminifera to understand the genetic significance of prominent seismic discontinuity surfaces typically mapped as "sequence boundaries" and "flooding surfaces" in the late Paleogene-early Neogene Northern Carnarvon Basin. The progradational succession, dominated by heterozoan carbonate sediments, is divided into five northwest-prograding clinoformal sequences and 19 sub-sequences. Clinoform fronts progress from smooth to highly dissected, with intense gullying apparent only after the mid Miocene optimum. Once initiated, gullies become the focus for sediment distribution across the front. Bottomsets remain relatively sediment-starved without the development of aprons on the lower slope and basin. Small-scale variability suggests heterogeneous sediment dispersal through the slope conduits. Along-strike sediment transport superimposed on progradation changes from south-directed in the late Oligocene to north-directed in the late mid-Miocene suggesting a major reorganization of circulation in the southeastern Indian Ocean. Prominent seismic discontinuity surfaces represent both intervals of shallow paleo-water depth and flooding of the shelf. Partial exposure of the shelf indicated by karst morphology is coeval with middle to outer neritic paleo-water depths on the outer shelf. Rather than build to sea-level, progradation occurs with shelf paleo-water depths at the clinoform rollover >100 m. Therefore, in the Northern Carnarvon Basin onlap onto the clinoform front is not coastal and the sensitivity of the clinoforms to sea-level changes is muted.