<div>The Australian continent comprises a broad dichotomy of crustal settings; from the Archean–Proterozoic cratonic core in the centre and west, to the accretionary margin of the Tasmanides in the east. These continental blocks meet at the Tasman Line, where successive arc systems built the eastern third of Australia in ca. 250 Myrs. This interface represents one of Australia’s most fundamental crustal boundaries and is marked by the ca. 520–490 Ma Delamerian Orogen in south-eastern Australia. Despite its first-order crustal control on tectonism, magmatism, deformation, and mineral systems in the area, the Delamerian Orogen remains poorly understood. Here, we present new zircon Hf-O isotopic and trace element data on 32 samples across the south-east Tasman Line. This initial dataset, which will grow over the next 12 months as part of Geoscience Australia’s Exploring for the Future program, will be used to constrain the time-space crustal architecture and evolution of Australia’s south-eastern Precambrian cratonic margin. These first samples include Paleoarchean to Devonian felsic magmatic rocks from the eastern Gawler Craton, across the Delamerian Orogen, to the Central Lachlan Orogen, and show that the crust of south-east Australia has a significant pre-history, with crustal reworking a major feature across the region. Delamerian arc magmatism appears to have involved significant reworking of Australia’s south-eastern Precambrian margin, as recorded by sub-chondritic Hf-isotope data. Assuming a significant mantle-component in the initial arc magmas, contamination by the ancient overlying continental rocks, some as old as ca. 3250 Ma, resulted in less juvenile compositions. This observation suggests Australia’s south-eastern Gondwanan margin may have consisted of a west-dipping continental arc, rather than an offshore island arc. The ‘heavy’ supracrustal δ18O of magmatic rocks across the area since the Paleoproterozoic is testament to the long-lived terrestrial nature of this continental margin, and its influence on magmatism across >1 billion years of Earth history.&nbsp;</div> This Abstract was submitted/presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)

The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Systems Section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. As part of this program, molecular and isotopic analyses were undertaken by Geoscience Australia on gas samples from the well Dorado 1 and the raw data from these analyses are released in this report.

Radiogenic isotopes decay at known rates and can be used to interpret ages for minerals, rocks and geologic processes. Different isotopic systems provide information related to different time periods and geologic processes, systems include: U-Pb and Ar/Ar, Sm-Nd, Pb-Pb, Lu-Hf, Rb-Sr and Re-Os isotopes. The GEOCHRON database stores full analytical U-Pb age data from Geoscience Australia's (GA) Sensitive High Resolution Ion Micro-Probe (SHRIMP) program. The ISOTOPE database is designed to expand GA's ability to deliver isotopic datasets, and stores compiled age and isotopic data from a range of published and unpublished (GA and non-GA) sources. OZCHRON is a depreciated predecessor to GEOCHRON and ISOTOPE, the information once available in OZCHRON is in the process of migration to the two current databases. The ISOTOPE compilation includes sample and bibliographic links through the A, FGDM, and GEOREF databases. The data structure currently supports summary ages (e.g., U-Pb and Ar/Ar) through the INTERPRETED_AGES tables, as well as extended system-specific tables for Sm-Nd, Pb-Pb, Lu-Hf and O- isotopes. The data structure is designed to be extensible to adapt to evolving requirements for the storage of isotopic data. ISOTOPE and the data holdings were initially developed as part of the Exploring for the Future (EFTF) program - particularly to support the delivery of an Isotopic Atlas of Australia. During development of ISOTOPE, some key considerations in compiling and storing diverse, multi-purpose isotopic datasets were developed: 1) Improved sample characterisation and bibliographic links. Often, the usefulness of an isotopic dataset is limited by the metadata available for the parent sample. Better harvesting of fundamental sample data (and better integration with related national datasets such as Australian Geological Provinces and the Australian Stratigraphic Units Database) simplifies the process of filtering an isotopic data compilation using spatial, geological and bibliographic criteria, as well as facilitating 'audits' targeting missing isotopic data. 2) Generalised, extensible structures for isotopic data. The need for system-specific tables for isotopic analyses does not preclude the development of generalised data-structures that reflect universal relationships. GA has modelled relational tables linking system-specific Sessions, Analyses, and interpreted data-Groups, which has proven adequate for all of the Isotopic Atlas layers developed thus far. 3) Dual delivery of 'derived' isotopic data. In some systems, it is critical to capture the published data (i.e. isotopic measurements and derived values, as presented by the original author) and generate an additional set of derived values from the same measurements, calculated using a single set of reference parameters (e.g. decay constant, depleted-mantle values, etc.) that permit 'normalised' portrayal of the data compilation-wide. 4) Flexibility in data delivery mode. In radiogenic isotope geochronology (e.g. U-Pb, Ar-Ar), careful compilation and attribution of 'interpreted ages' can meet the needs of much of the user-base, even without an explicit link to the constituent analyses. In contrast, isotope geochemistry (especially microbeam-based methods such as Lu-Hf via laser ablation) is usually focused on the individual measurements, without which interpreted 'sample-averages' have limited value. Data delivery should reflect key differences of this kind. <b>Value: </b>Used to provide ages and isotope geochemistry data for minerals, rocks and geologic processes. <b>Scope: </b>Australian jurisdictions and international collaborative programs involving Geoscience Australia

Newer version v1.1 available at eCat <a href="https://pid.geoscience.gov.au/dataset/ga/147720">147720</a> Isotopic data from rocks and minerals have the potential to yield unique insights into the composition and evolution of the Earth's crust and mantle. Time-integrated records of crust and mantle differentiation (as preserved by the U-Pb, Sm-Nd and Lu-Hf isotopic systems, for example) are important in a wide range of geological applications, especially when successfully integrated with other geological, geophysical, and geochemical datasets. However, such integration requires (i) compilation of comprehensive isotopic data coverages, (ii) unification of datasets in a consistent structure to facilitate inter-comparison, and (iii) easy public accessibility of the compiled and unified datasets in spatial and tabular formats useful and useable by a broad range of industry, government and academic users. This constitutes a considerable challenge, because although a wealth of isotopic information has been collected from the Australian continent over the last 40 years, the published record is fragmentary, and derived from numerous and disparate sources. Unlocking and harnessing the collective value of isotopic datasets will enable more comprehensive and powerful interpretations, and significantly broaden their applicability to Earth evolution studies and mineral exploration. As part of the Exploring for the Future (EFTF) program (https://www.ga.gov.au/eftf), we have designed a new database structure and web service system to store and deliver full Lu-Hf isotope and associated O-isotope datasets, spanning new data collected during research programs conducted by Geoscience Australia (GA), as well as compiled literature data. Our approach emphasises the links between isotopic measurements and their spatial, geological, and data provenance information in order to support the widest possible range of uses. In particular, we build and store comprehensive links to the original sources of isotopic data so that (i) users can easily track down additional context and interpretation of datasets, and (ii) generators of isotopic data are appropriately acknowledged for their contributions. This system delivers complete datasets including (i) full analytical and derived data as published by the original author, (ii) additional, normalised derived data recalculated specifically to maximise inter-comparability of data from disparate sources, (iii) metadata related to the analytical setup, (iv) a broad range of sample information including sampling location, rock type, geological province and stratigraphic unit information, and (v) descriptions of (and links to) source publications. The data is delivered through the Geoscience Australia web portal (www.portal.ga.gov.au), and can also be accessed through any web portal capable of consuming Open Geospatial Consortium (OGC)-compliant web services, or any GIS system capable of consuming Web Map Services (WMS) or Web Feature Services (WFS). This Record describes the database system and web service tables. It also contains full tabulated datasets for data compiled from the North Australian Craton as part of the EFTF program. These data are predominantly micro-analytical zircon analyses which are linked at the spot-level across Lu-Hf, O, and U-Pb measurements. This data release comprises 5974 individual analyses from 149 unique rock samples.

The accessory mineral zircon is the most widely used geological timekeeper and tracer of crustal growth processes. Specifically, U-Pb isotopes in zircon offer a means to accurately determine the timing of magmatic events and their Hf isotopic composition provides a means to constrain magma source composition and potentially approximate source age. The high spatial resolution provided by in situ techniques such as secondary ion mass spectrometry (SIMS) and laser ablation inductively coupled mass spectrometry (LA-ICP-MS) have the advantage of being able to target different growth zones within individual zircon crystals, and unravel complex magmatic histories. However, utilising this power effectively requires calculation of accurate initial Hf compositions, which are founded on the assumption that the information obtained via the U-Pb and Lu-Hf systems are correctly integrated. A typical Hf isotope LA-ICP-MS analysis ablates a sample volume that is two orders of magnitude greater than a typical SIMS analysis. Thus, when age determination has been carried out by SIMS it is necessary to demonstrate that each subsequent Hf isotope analysis has sampled a similar isotopically homogeneous volume. Here, we use a combined SIMS and laser ablation split stream (LASS)-ICP-MS approach, whereby U-Pb isotopic measurement concurrently on the same sample volume as the Hf isotope measurement is compared to prior lower volume SIMS measurements. Using a suite of new drill core magmatic rock samples from the comparatively unexplored Coompana Province in South Australia, we demonstrate how such an approach can be used to filter Hf isotope datasets by identifying LA-ICP-MS analyses that sampled mixtures of different zircon growth domains. The robust initial 176Hf/177Hf compositions obtained from the filtered Coompana data set indicate that the province represents part of a juvenile Paleoproterozoic-Mesoproterozoic arc system formed through hyperextension of the margin of the Archean Gawler Craton, which can be correlated to the Musgrave Province and Madura Province in central and western Australia respectively. This hyperextension process is temporally similar to that on the now-adjacent Archean Yilgarn Craton margin.

This report presents key results from hydrogeological investigations in the Tennant Creek region, completed as part of Exploring for the Future (EFTF)—an eight year, $225 million Australian Government funded geoscience data and information acquisition program focused on better understanding the potential mineral, energy and groundwater resources across Australia. The EFTF Southern Stuart Corridor (SSC) Project area is located in the Northern Territory and extends in a north–south corridor from Tennant Creek to Alice Springs, encompassing four water control districts and a number of remote communities. Water allocation planning and agricultural expansion in the SSC is limited by a paucity of data and information regarding the volume and extent of groundwater resources and groundwater systems more generally. Geoscience Australia, in partnership with the Northern Territory Department of Environment and Natural Resources and Power and Water Corporation, undertook an extensive program of hydrogeological investigations in the SSC Project area between 2017 and 2019. Data acquisition included; helicopter airborne electromagnetic (AEM) and magnetic data; water bore drilling; ground-based and downhole geophysical data for mapping water content and defining geological formations; hydrochemistry for characterising groundwater systems; and landscape assessment to identify potential managed aquifer recharge (MAR) targets. This report focuses on the Tennant Creek region—part of the Barkly region of the Northern Territory. Investigations in this region utilised existing geological and geophysical data and information, which were applied in the interpretation and integration of AEM and ground-based geophysical data, as well as existing and newly acquired groundwater hydrochemical and isotope data. The AEM and borehole lithological data reveal the highly weathered (decomposed) nature of the geology, which is reflected in the hydrochemistry. These data offer revised parameters, such as lower bulk electrical conductivity values and increased potential aquifer volumes, for improved modelling of local groundwater systems. In many instances the groundwater is shown to be young and of relatively good quality (salinity generally <1000 mg/L total dissolved solids), with evidence that parts of the system are rapidly recharged by large rainfall events. The exception to this is in the Wiso Basin to the west of Tennant Creek. Here lower quality groundwater occurs extensively in the upper 100 m below ground level, but this may sit above potentially potable groundwater and that possibility should be investigated further. Faults are demonstrated to have significantly influenced the occurrence and distribution of weathered rocks and of groundwater, with implications for groundwater storage and movement. Previously unrecognised faults in the existing borefield areas should be investigated for their potential role in compartmentalising groundwater. Additionally a previously unrecognised sub-basin proximal to Tennant Creek may have potential as a groundwater resource or a target for MAR. This study has improved understanding of the quantity and character of existing groundwater resources in the region and identified a managed aquifer recharge target and potential new groundwater resources. The outcomes of the study support informed water management decisions and improved water security for communities; providing a basis for future economic investment and protection of environmental and cultural values in the Tennant Creek and broader Barkly region. Data and information related to the project are summarised in the conclusions of this report and are accessible via the EFTF portal (https://portal.ga.gov.au/).

The values and distribution patterns of the strontium (Sr) isotope ratio 87Sr/86Sr in Earth surface materials is of use in the geological, environmental and social sciences. Ultimately, the 87Sr/86Sr ratio of any mineral or biological material reflects its value in the rock that is the parent material to the local soil and everything that lives in and on it. In Australia, there are few large-scale surveys of 87Sr/86Sr available, and here we report on a new, low-density dataset using 112 catchment outlet (floodplain) sediment samples covering 529,000 km2 of inland southeastern Australia (South Australia, New South Wales, Victoria). The coarse (<2 mm) fraction of bottom sediment samples (depth ~0.6-0.8 m) from the National Geochemical Survey of Australia were fully digested before Sr separation by chromatography and 87Sr/86Sr determination by multicollector-inductively coupled plasma-mass spectrometry. The results show a wide range of 87Sr/86Sr values from a minimum of 0.7089 to a maximum of 0.7511 (range 0.0422). The median 87Sr/86Sr (± robust standard deviation) is 0.7199 (± 0.0112), and the mean (± standard deviation) is 0.7220 (± 0.0106). The spatial patterns of the Sr isoscape observed are described and attributed to various geological sources and processes. Of note are the elevated (radiogenic) values (≥~0.7270; top quartile) contributed by (1) the Palaeozoic sedimentary country rock and (mostly felsic) igneous intrusions of the Lachlan geological region to the east of the study area; (2) the Palaeoproterozoic metamorphic rocks of the central Broken Hill region; both these sources contribute fluvial sediments into the study area; and (3) the Proterozoic to Palaeozoic rocks of the Kanmantoo, Adelaide, Gawler and Painter geological regions to the west of the area; these sources contribute radiogenic material to the region mostly by aeolian processes. Regions of low 87Sr/86Sr (≤~0.7130; bottom quartile) belong mainly to (1) a few central Murray Basin catchments; (2) some Darling Basin catchments in the northeast; and (3) a few Eromanga geological region-influenced catchments in the northwest of the study area. The new spatial dataset is publicly available through the Geoscience Australia portal (https://portal.ga.gov.au/restore/cd686f2d-c87b-41b8-8c4b-ca8af531ae7e).

The National Geochemical Survey of Australia (NGSA) is Australia’s first national-scale geochemical survey. It was delivered to the public on 30 June 2011, after almost five years of stakeholder engagement, strategic planning, sample collection, preparation and analysis, quality assurance/quality control, and preliminary data analytics. The project was comprehensively documented in seven initial open-file reports and six data and map sets, followed over the next decade by more than 70 well-cited scientific publications. This review compiles the body of work and knowledge that emanated from the project to-date as an indication of the impact the NGSA had over the decade 2011-2021. The geochemical fabric of Australia as never seen before has been revealed by the NGSA. This has spurred further research and stimulated the mineral exploration industry. This paper also critically looks at operational decisions taken at project time (2007-2011) that were good and perhaps – with the benefit of hindsight – not so good, with the intention of providing experiential advice for any future large-scale geochemical survey of Australia or elsewhere. Strengths of the NGSA included stakeholder engagement, holistic approach to a national survey, involvement of other geoscience agencies, collaboration on quality assurance with international partners, and targeted promotion of results. Weaknesses included gaining successful access to all parts of the nation, and management of sample processing in laboratories. <b>Citation:</b> Patrice de Caritat; The National Geochemical Survey of Australia: review and impact. <i>Geochemistry: Exploration, Environment, Analysis </i>2022;; 22 (4): geochem2022–032. doi: https://doi.org/10.1144/geochem2022-032 This article appears in multiple journals (Lyell Collection & GeoScienceWorld)

Plutonium (Pu) interactions in the environment are highly complex. Site-specific variables play an integral role in determining the chemical and physical form of Pu, and its migration, bioavailability, and immobility. This paper aims to identify the key variables that can be used to highlight regions of radioecological sensitivity and guide remediation strategies in Australia. Plutonium is present in the Australian environment as a result of global fallout and the British nuclear testing program of 1952 – 1958 in central and west Australia (Maralinga and Monte Bello islands). We report the first systematic measurements of 239+240Pu and 238Pu activity concentrations in distal (≥1,000 km from test sites) catchment outlet sediments from Queensland, Australia. The average 239+240Pu activity concentration was 0.29 mBq.g -1 (n = 73 samples) with a maximum of 4.88 mBq.g -1. 238Pu/239+240Pu isotope ratios identified a large range (0.02 – 0.29 (RSD: 74%)) which is congruent with the heterogeneous nuclear material used for the British nuclear testing programme at Maralinga and Montebello Islands. The use of a modified PCA relying on non-linear distance correlation (dCorr) provided broader insight into the impact of environmental variables on the transport and migration of Pu in this soil system. Primary key environmental indicators of Pu presence were determined to be actinide/lanthanide/heavier transition metals, elevation, electrical conductivity (EC), CaO, SiO2, SO3, landform, geomorphology, land use, and climate explaining 81.7% of the variance of the system. Overall this highlighted that trace level Pu accumulations are associated with the coarse, refractive components of Australian soils, and are more likely regulated by the climate of the region and overall soil type. <b>Citation:</b> Megan Cook, Patrice de Caritat, Ross Kleinschmidt, Joёl Brugger, Vanessa NL. Wong, Future migration: Key environmental indicators of Pu accumulation in terrestrial sediments of Queensland, Australia,<i> Journal of Environmental Radioactivity</i>, Volumes 223–224, 2020, 106398,ISSN 0265-931X, https://doi.org/10.1016/j.jenvrad.2020.106398

The first iteration of a continental-scale Isotopic Atlas of Australia was introduced by Geoscience Australia at the 2019 SGGMP conference in Devonport, Tasmania, through a talk and poster display. In the three years since, progress on this Isotopic Atlas has continued and expanded datasets are now publicly available and downloadable via Geoscience Australia’s Exploring for the Future (EFTF) <a href="https://portal.ga.gov.au/persona/geochronology">Geochronology and Isotopes Data Portal</a>. This poster provides example maps produced from the compiled data of multiple geochronology and isotopic tracer datasets, now available in the <a href="https://portal.ga.gov.au/persona/eftf">EFTF Portal</a>. Available data include Sm–Nd model ages of magmatic rocks; Lu–Hf isotopes from zircon and associated O-isotope data; Pb–Pb isotopes from ore-related minerals such as galena and pyrite; Rb–Sr isotopes from soils; U–Pb ages of magmatic, metamorphic and sedimentary rocks; and K–Ar, Ar–Ar, Re–Os, Rb–Sr and fission-track ages from minerals and whole rocks. Compiled geochronology, which commenced with coverage of northern Australia, is now much more comprehensive across Victoria and Tasmania, with New South Wales and South Australia updates well underway. This Isotopic Atlas of Australia provides a convenient visual overview of age and isotopic patterns reflecting geological processes that have led to the current configuration of the Australian continent, including progressive development of continental crust from the mantle. These datasets and maps unlock the collective value of several decades of geochronological and isotopic studies conducted across Australia, and provide an important complement to other geological maps and geophysical images—in particular, by adding a time dimension to 2D and 3D maps and models. To view the associated poster see <a href="https://pid.geoscience.gov.au/dataset/ga/147377">eCat 147377</a>. This Abstract & Poster were presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)