This Record contains new zircon and monazite U-Pb geochronological data obtained via Sensitive High-Resolution Ion Micro Probe (SHRIMP) from nine samples of volcanic, volcaniclastic and plutonic igneous rocks of the central Lachlan Orogen and the New England Orogen, New South Wales. These data were obtained during the reporting period July 2014-June 2015, under the auspices of the collaborative Geochronology Project between the Geological Survey of New South Wales (GSNSW) and Geoscience Australia (GA), which is part of the National Collaboration Framework (NCF).

Geoscience Australia has compiled U-Pb datasets from disparate sources into a single, standardised and publicly-available U–Pb geochronology compilation for all Australia. The national maps presented in this poster expand upon the data coverage previously compiled by Anderson et al. (2017) and Jones et al. (2018), which covered northern and western Australia only. This extension of a national coverage has been achieved through the development of Geoscience Australia’s Interpreted Ages database. In this database, there are now >4000 U–Pb sample points compiled from across Australia, with significant datasets to come from the southern Australia regions. These will be available to the public in the coming months through the Exploring for the Future Data Discovery Portal (eftf.ga.gov.au).

Plutonium (Pu) interactions in the environment are highly complex. Site-specific variables play an integral role in determining the chemical and physical form of Pu, and its migration, bioavailability, and immobility. This paper aims to identify the key variables that can be used to highlight regions of radioecological sensitivity and guide remediation strategies in Australia. Plutonium is present in the Australian environment as a result of global fallout and the British nuclear testing program of 1952 – 1958 in central and west Australia (Maralinga and Monte Bello islands). We report the first systematic measurements of 239+240Pu and 238Pu activity concentrations in distal (≥1,000 km from test sites) catchment outlet sediments from Queensland, Australia. The average 239+240Pu activity concentration was 0.29 mBq.g -1 (n = 73 samples) with a maximum of 4.88 mBq.g -1. 238Pu/239+240Pu isotope ratios identified a large range (0.02 – 0.29 (RSD: 74%)) which is congruent with the heterogeneous nuclear material used for the British nuclear testing programme at Maralinga and Montebello Islands. The use of a modified PCA relying on non-linear distance correlation (dCorr) provided broader insight into the impact of environmental variables on the transport and migration of Pu in this soil system. Primary key environmental indicators of Pu presence were determined to be actinide/lanthanide/heavier transition metals, elevation, electrical conductivity (EC), CaO, SiO2, SO3, landform, geomorphology, land use, and climate explaining 81.7% of the variance of the system. Overall this highlighted that trace level Pu accumulations are associated with the coarse, refractive components of Australian soils, and are more likely regulated by the climate of the region and overall soil type. <b>Citation:</b> Megan Cook, Patrice de Caritat, Ross Kleinschmidt, Joёl Brugger, Vanessa NL. Wong, Future migration: Key environmental indicators of Pu accumulation in terrestrial sediments of Queensland, Australia,<i> Journal of Environmental Radioactivity</i>, Volumes 223–224, 2020, 106398,ISSN 0265-931X, https://doi.org/10.1016/j.jenvrad.2020.106398

The National Geochemical Survey of Australia (NGSA) is Australia’s first national-scale geochemical survey. It was delivered to the public on 30 June 2011, after almost five years of stakeholder engagement, strategic planning, sample collection, preparation and analysis, quality assurance/quality control, and preliminary data analytics. The project was comprehensively documented in seven initial open-file reports and six data and map sets, followed over the next decade by more than 70 well-cited scientific publications. This review compiles the body of work and knowledge that emanated from the project to-date as an indication of the impact the NGSA had over the decade 2011-2021. The geochemical fabric of Australia as never seen before has been revealed by the NGSA. This has spurred further research and stimulated the mineral exploration industry. This paper also critically looks at operational decisions taken at project time (2007-2011) that were good and perhaps – with the benefit of hindsight – not so good, with the intention of providing experiential advice for any future large-scale geochemical survey of Australia or elsewhere. Strengths of the NGSA included stakeholder engagement, holistic approach to a national survey, involvement of other geoscience agencies, collaboration on quality assurance with international partners, and targeted promotion of results. Weaknesses included gaining successful access to all parts of the nation, and management of sample processing in laboratories. <b>Citation:</b> Patrice de Caritat; The National Geochemical Survey of Australia: review and impact. <i>Geochemistry: Exploration, Environment, Analysis </i>2022;; 22 (4): geochem2022–032. doi: https://doi.org/10.1144/geochem2022-032 This article appears in multiple journals (Lyell Collection & GeoScienceWorld)

This study assesses the effect of chemical abrasion on in-situ mass spectrometric isotopic and elemental analyses in zircon. Chemical abrasion improves the U-Pb systematics of SIMS (Secondary Ion Mass Spectrometry) analyses of reference zircons, while leaving other isotopic systems largely unchanged. SIMS ²⁰⁶Pb/²³⁸U ages of chemically abraded reference materials TEMORA-2, 91500, QGNG, and OG1 are precise to within 0.25 to 0.4%, and are within uncertainty of chemically abraded TIMS reference ages, while SIMS ²⁰⁶Pb/²³⁸U ages of untreated zircons are within uncertainty of TIMS reference ages where chemical abrasion was not used. Chemically abraded and untreated zircons appear to cross-calibrate within uncertainty using all but one possible permutations of reference materials, provided that the corresponding chemically abraded or untreated reference age is used for the appropriate material. In the case of reference zircons QGNG and OG1, which are slightly discordant, the SIMS U-Pb ages of chemically abraded and untreated material differ beyond their respective 95% confidence intervals. SIMS U-Pb analysis of chemically abraded zircon with multiple growth stages are more difficult to interpret. Treated igneous rims on zircon crystals from the S-type Mount Painter Volcanics are much lower in common Pb than the rims on untreated zircon grains. However, the analyses of chemically abraded material show excess scatter. Chemical abrasion also changes the relative abundance of the ages of zircon cores inherited from the sedimentary protolith, presumably due to some populations being more likely to survive the chemical abrasion process than others. We consider these results from inherited S-type zircon cores to be indicative of results for detrital zircon grains from unmelted sediments. Trace element, &delta;¹⁸O, and εHf analyses were also performed on these zircons. None of these systems showed substantial changes as a result of chemical abrasion. The most discordant reference material, OG1, showed a loss of OH as a result of chemical abrasion, presumably due to dissolution of hydrous metamict domains, or thermal dehydration during the annealing step of chemical abrasion. In no case did zircon gain fluorine due to exchange of lattice-bound substituted OH or other anions with fluorine during the HF partial dissolution phase of the chemical abrasion process. As the OG1, QGNG, and TEMORA-2 zircon samples are known to be compositionally inhomogenous in trace element composition, spot-to-spot differences dominated the trace element results. Even the 91500 megacrystic zircon pieces exhibited substantial chip-to-chip variation. The LREE in chemically abraded OG1 and TEMORA-2 were lower than in the untreated samples. Ti concentration and phosphorus saturation ((Y+REE)/P) were generally unchanged in all samples. <b>Citation:</b> Kooymans, C., Magee Jr., C. W., Waltenberg, K., Evans, N. J., Bodorkos, S., Amelin, Y., Kamo, S. L., and Ireland, T.: Effect of chemical abrasion of zircon on SIMS U–Pb, &delta;¹⁸O, trace element, and LA-ICPMS trace element and Lu–Hf isotopic analyses, Geochronology, 6, 337–363, https://doi.org/10.5194/gchron-6-337-2024, 2024.

<div>Lead isotopic data implies that Th and U were fractionated from one another in Earth's early history, however, the origin of this fractionation is poorly understood. We report new <em>in-situ</em> Pb isotope data from orthoclase in 144 granites, sampled across the Archean Yilgarn Craton to characterize its Pb isotope variability and evolution. Granite Pb isotope compositions reveal three Pb sources, a mantle derived Pb reservoir and two crustal Pb reservoirs, distinguished by their implied source 232Th/238U (κPb). High-κPb granites reflect sources with high 232Th/238U (~4.7) and are largely co-located with Eoarchean–Paleoarchean crust. The Pb isotope compositions of most granites, and those of VHMS and gold ores, define a mixing array between a mantle Pb source and a Th-rich Eoarchean-Paleoarchean source. Pb isotope modelling indicates that the high-κPb source rocks experienced Th/U fractionation at ~3.3 Ga. As Th/U fractionation in the Yilgarn Craton must have occurred before Earth’s atmosphere was oxygenated, subaerial weathering cannot explain the apparent differences in their geochemical behavior. Instead, the high Th/U source reflects Eoarchean–Paleoarchean rocks that experienced prior high-temperature metamorphism, partial melting, and melt loss in the presence of a Th-sequestering mineral like monazite. Archean Pb isotope variability thus has its origins in open-system high-temperature metamorphic processes responsible for the differentiation and stabilization of Earth’s continental crust.</div> <b>Citation:</b> M.I.H. Hartnady, C.L. Kirkand, S.P. Johnson, R.H. Smithies, L.S. Doucet, D.R. Mole; <i>Origin of Archean Pb isotope variability through open-system Paleoarchean crustal anatexis</i>. Geology 2023; doi: https://doi.org/10.1130/G51507.1

<div>The first ca. 2.2 billion years of Earth history saw significant change; from a water-world dominated by an anoxic atmosphere and tonalitic continents, to the exposed landmasses, oxygenated atmosphere, and granitic crust of the Paleoproterozoic. Precisely when, and how, these major changes occurred, remain some of the most important and controversial questions in modern geoscience. Here, we present an extensive new zircon U-Pb-Hf-O isotopic and trace element dataset from Earth’s largest preserved Archean continent, the Superior Craton, Canada. These data record a number of fundamental geochemical changes through time and indicate a major geological and geodynamic transition occurred toward the end of Archean, at ca. 2.7 Ga. Our data show that, at&nbsp;&gt;2704–2695&nbsp;Ma, the southern Superior Craton had juvenile εHf, light to mantle-like δ18O, low (Eu/Eu*)/Y (drier/shallower crust), reduced ΔFMQ, less continental initial-U (Ui)/Yb, and more mantle-like Ui/Nb. At ca. 2704–2695&nbsp;Ma, there is a marked transition in multiple datasets, including increases in δ18O, (Eu/Eu*)/Y, ΔFMQ, Ui/Yb and Ui/Nb data, together with more distinct arc-like trace element trends. These data reveal that at 2.7 Ga there was an increase in: (1) continental surface weathering, supported by increased sedimentation at &lt;2.68 Ga, (2) oxidized and hydrous magmatism, and (3) surface material in magma sources. Together, these observations suggest a major geodynamic transition from ‘vertical’ tectonics (sagduction, drips) to north-dipping subduction at 2.7 Ga. The increase in δ18O suggests that proximal continental crust, probably in the northern Superior Craton, became emergent at this time, an inference supported by detrital zircon geochronology. Hence, this dataset links major geodynamic change to the emergence of continental crust and the rise of more oxidized magmatism. These fundamental changes to the Earth’s surface environment, tectonics, and atmosphere at 2.7 Ga, provide evidence for an Earth systems turning-point at the end of the Neoarchean.</div> This Abstract was submitted/presented to the 2022 Specialist Group in Geochemistry, Mineralogy and Petrology (SGGMP) Conference 7-11 November (https://gsasggmp.wixsite.com/home/biennial-conference-2021)

<div>Exploring for the Future (EFTF) is an Australian Government program led by Geoscience Australia, in partnership with state and Northern Territory governments, and aimed at stimulating exploration now to ensure a sustainable, long-term future for Australia through an improved understanding of the nation’s minerals, energy and groundwater resource potential. </div><div>The EFTF program is currently focused on eight interrelated projects, united in growing our understanding of subsurface geology. One of these projects, the Barkly–Isa–Georgetown project, will deliver new data and knowledge to assess the mineral and energy potential in undercover regions between Tennant Creek, Mount Isa and Georgetown. Building on the work completed in the first four years of the Exploring for the Future program (2016-2020), the project undertook stratigraphic drilling in the East Tennant and South Nicholson regions, in collaboration with MinEx CRC and the Northern Territory Geological Survey (NTGS). This work tests geological interpretations and the inferred mineral and energy potential of these covered regions. Geoscience Australia is undertaking a range of analyses on physical samples from these drill holes including geochemistry and geochronology. </div><div>The South Nicholson National Drilling Initiative (NDI) Carrara 1 drill hole is the first drillhole to intersect the Proterozoic rocks of the Carrara Sub-Basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys acquired as part of the EFTF. It is located on the western flanks of the Carrara Sub-basin on the South Nicholson Seismic line 17GA-SN1, reaching a total depth of 1751 m, intersecting ca. 630 m of Cambrian Georgina Basin overlying ca. 1100 m of Proterozoic carbonates, black shales and minor siliciclastics.</div><div>The NDI BK10 drill hole is the tenth drill hole drilled as part of the East Tennant project aimed to constrain the East Tennant basement geology and calibrate predictive mineral potential maps to further our understanding of the prospectivity of this region. NDI BK10 reached a depth of 766 m and intersected basement at 734 m. Overlying these basement metasediments of the Alroy Formation, the drillhole intersected about 440 m of Proterozoic rocks underlain by ca. 300 m rocks of Cambrian age from the Georgina Basin.</div><div>During coring of NDI Carrara 1 and NDI BK10, cores containing oil stains were identified and sent for geochemical analysis to Geoscience Australia. This report presents the geochemical data from these oil stains including biomarker and isotopic data.</div>

An Isotopic Atlas of Australia (Fraser et al., 2020) provides a convenient visual overview of age and isotopic patterns reflecting geological processes that have led to the current configuration of the Australian continent, including progressive development of continental crust from the mantle. This poster provides example maps produced from compiled data of multiple geochronology and isotopic tracer datasets from this Isotopic Atlas, now publicly available and downloadable via Geoscience Australia’s (GA) Exploring for the Future (EFTF) <a href="https://portal.ga.gov.au/persona/geochronology">Geochronology and Isotopes Data Portal</a> and Mineral Resources Tasmania’s <a href="https://www.mrt.tas.gov.au/mrt_maps/app/list/map">Listmap</a>. These datasets and maps unlock the collective value of several decades of geochronological and isotopic studies conducted across Australia. Compiled geochronology, which commenced with coverage of northern Australia (Jones et al., 2018), is now much more comprehensive across Victoria (Waltenberg et al., 2021) and Tasmania (Jones et al., in press), with New South Wales and South Australia updates well underway. Available data include: Sm–Nd model ages of magmatic rocks; Lu–Hf isotopes from zircon and associated O-isotope data; Pb–Pb isotopes from ore-related minerals such as galena and pyrite; Rb–Sr isotopes from soils; U–Pb ages of magmatic, metamorphic and sedimentary rocks; and K–Ar, Ar–Ar, Re–Os, Rb–Sr and fission-track ages from minerals and whole rocks. <b>To view the associated poster see <a href="https://dx.doi.org/10.26186/147420">eCat 147420</a>. This Abstract & Poster were presented to the 2022 Specialist Group in Tectonics & Structural Geology(SGTSG) Conference 22-24 November (https://www.sgtsg.org/). </b> <i>Fraser, G.L., Waltenberg, K., Jones, S.L., Champion, D.C., Huston, D.L., Lewis, C.J., Bodorkos, S., Forster, M., Vasegh, D., Ware, B., Tessalina, S. 2020. An Isotopic Atlas of Australia. Geoscience Australia, Canberra. https://doi.org/10.11636/133772. Geoscience Australia. 2021. Geoscience Australia Exploring for the Future portal, viewed 13 September 2022. https://portal.ga.gov.au/persona/geochronology. Jones, S.L., Anderson, J.R., Fraser, G.L., Lewis, C.J., McLennan, S.M. 2018. A U-Pb Geochronology Compilation for Northern Australia: Version 2, 2018. Geoscience Australia Record 2018/49. https://doi.org/10.11636/Record.2018.049. Jones, S.L., Waltenberg, K., Ramesh, R., Cumming, G., Everard, J.L., Vicary, M.J., Bottrill, R.S., Knight, K., McNeill, A.W., Bodorkos, S., Meffre, S. in press. Isotopic Atlas of Australia: Geochronology compilation for Tasmania Version 1.0. Geoscience Australia Record. Mineral Resources Tasmania. 2022. Mineral Resources Tasmania Listmap, viewed 19 September 2022. https://www.mrt.tas.gov.au/mrt_maps/app/list/map. Waltenberg, K., Jones, S.L., Duncan, R.J., Waugh, S., Lane, J. 2021. Isotopic Atlas of Australia: Geochronology compilation for Victoria Version 1.0. Geoscience Australia Record 2021/24. https://doi.org/10.11636/Record.2021.024. </i>

Preamble: The 'National Geochemical Survey of Australia: The Geochemical Atlas of Australia' was published in July 2011 along with a digital copy of the NGSA geochemical dataset (http://dx.doi.org/10.11636/Record.2011.020). The NGSA project is described here: www.ga.gov.au/ngsa. The present dataset contains additional geochemical data obtained on NGSA samples: the Lead Isotopes Dataset. Abstract: Over 1200 new lead (Pb) isotope analyses were obtained on catchment outlet sediment samples from the NGSA regolith archive to document the range and patterns of Pb isotope ratios in the surface regolith and their relationships to geology and anthropogenic activity. The selected samples included 1204 NGSA Top Outlet Sediment (TOS) samples taken from 0 to 10 cm depth and sieved to <2 mm (or ‘coarse’ fraction); three of these were analysed in duplicate for a total of 1207 Pb isotope analyses. Further, 12 Northern Australia Geochemical Survey (NAGS; http://dx.doi.org/10.11636/Record.2019.002) TOS samples from within a single NGSA catchment, also sieved to <2 mm, were analysed to provide an indication of smaller scale variability. Combined, we thus present 1219 new TOS coarse, internally comparable data points, which underpin new national regolith Pb isoscapes. Additionally, 16 NGSA Bottom Outlet Sediment (BOS; ~60 to 80 cm depth) samples, also sieved to <2 mm, and 16 NGSA TOS samples sieved to a finer grainsize (<75 um, or ‘fine’) fraction from selected NGSA catchments were also included to inform on Pb mobility and residence. Lead isotope analyses were performed by Candan Desem as part of her PhD research at the School of Geography, Earth and Atmospheric Sciences, University of Melbourne. After an initial ammonium acetate (AmAc) leach, the samples were digested in aqua regia (AR). Although a small number of samples were analysed after the AmAc leach, all samples were analysed after the second, AR digestion, preparation step. The analyses were performed without prior matrix removal using a Nu Instruments Attom single collector Sector Field-Inductively Coupled Plasma-Mass Spectrometer (SF-ICP-MS). The dried soil digests were redissolved in 2% HNO3 run solutions containing high-purity thallium (1 ppb Tl) and diluted to provide ~1 ppb Pb in solution. Admixture of natural, Pb-free Tl (with a nominal 205Tl/203Tl of 2.3871) allowed for correction of instrumental mass bias effects. Concentrations of matrix elements in the diluted AR digests are estimated to be in the range of 1–2 ppm. The SF-ICP-MS was operated in wet plasma mode using a Glass Expansion cyclonic spray chamber and glass nebuliser with an uptake rate of 0.33 mL/min. The instrument was tuned for maximum sensitivity and provided ~1 million counts per second/ppb Pb while maintaining flat-topped peaks. Each analysis, performed in the Attom’s ‘deflector peak jump’ mode, consists of 30 sets of 2000 sweeps of masses 202Hg, 203Tl, 204Pb, 205Tl, 206Pb, 207Pb and 208Pb, with dwell times of 500 μs and a total analysis time of 4.5 min. Each sample acquisition was preceded by a blank determination. All corrections for baseline, sample Hg interference (202Hg/204Pb ratios were always <0.043) and mass bias were performed online, producing typical in-run precisions (2 standard errors) of ±0.047 for 206Pb/204Pb, ±0.038 for 207Pb/204Pb, ±0.095 for 208Pb/204Pb, ±0.0012 for 207Pb/206Pb and ±0.0026 for 208Pb/206Pb. A small number of samples with low Pb concentrations exhibited very low signal sizes during analysis resulting in correspondingly high analytical uncertainties. Samples producing within-run uncertainties of >1% relative (measured on the 207Pb/204Pb ratio) were discarded as being insufficiently precise to contribute meaningfully to the dataset. Data quality was monitored using interspersed analyses of Tl-doped ~1 ppb solutions of the National Institute of Standards and Technology (NIST) SRM981 Pb standard, and several silicate reference materials: United States Geological Survey ‘BCR-2’ and ‘AGV-2’, Centre de Recherches Pétrographiques et Géochimiques ‘BR’ and Japan Geological Survey ‘JB-2’. In a typical session, up to 50 unknowns plus 15 standards were analysed using an ESI SC-2 DX autosampler. Although previous studies using the Attom SF-ICP-MS used sample-standard-bracketing techniques to correct for instrumental Pb mass bias, Tl doping was found to produce precise, accurate and reproducible results. Based upon the data for the BCR-2 and AGV-2 secondary reference materials, for which we have the most analyses, deviations from accepted values (accuracy) were typically <0.17%. Data for the remaining silicate standards appear slightly less accurate but these results may, to some extent, reflect uncertainty in the assigned literature values for these materials. Replicate runs of selected AR digests yielded similar reproducibility estimates. The results show a wide range of Pb isotope ratios in the NGSA (and NAGS) TOS <2 mm fraction samples across the continent (N = 1219): 206Pb/204Pb: Min = 15.558; Med ± Robust SD = 18.844 ± 0.454; Mean ± SD = 19.047 ± 1.073; Max = 30.635 207Pb/204Pb; Min = 14.358; Med ± Robust SD = 15.687 ± 0.091; Mean ± SD = 15.720 ± 0.221; Max = 18.012 208Pb/204Pb; Min = 33.558; Med ± Robust SD = 38.989 ± 0.586; Mean ± SD = 39.116 ± 1.094; Max = 48.873 207Pb/206Pb; Min = 0.5880; Med ± Robust SD = 0.8318 ± 0.0155; Mean ± SD = 0.8270 ± 0.0314; Max = 0.9847 208Pb/206Pb; Min = 1.4149; Med ± Robust SD = 2.0665 ± 0.0263; Mean ± SD = 2.0568 ± 0.0675; Max = 2.3002 These data allow the construction of the first continental-scale regolith Pb isotope maps (206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb, 207Pb/206Pb, and 208Pb/206Pb isoscapes) of Australia and can be used to understand contributions of Pb from underlying bedrock (including Pb-rich mineralisation), wind-blown dust and possibly from anthropogenic sources (industrial, transport, agriculture, residential, waste handling). The complete dataset is available to download as a comma separated values (CSV) file from Geoscience Australia's website (http://dx.doi.org/10.26186/5ea8f6fd3de64). Isoscape grids (inverse distance weighting interpolated grids with a power coefficient of 2 prepared in QGis using GDAL gridding tool based on nearest neighbours) are also provided for the five Pb isotope ratios (IDW2NN.TIF files in zipped folder). Alternatively, the new Pb isotope data can be downloaded from and viewed on the GA Portal (https://portal.ga.gov.au/).