<div>An Isotopic Atlas of Australia provides a convenient visual overview of age and isotopic patterns reflecting geological processes that have led to the current configuration of the Australian continent, including progressive development of continental crust from the mantle. This poster provides example maps produced from compiled data of multiple geochronology and isotopic tracer datasets from this Isotopic Atlas.&nbsp;It is also a promotion for the release of the Victorian and Tasmanian age compilation datasets (Waltenbeg et al., 2021; Jones et al., 2022).</div>

<div>The bulk oils database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the bulk properties of petroleum liquids (e.g., condensate, crude oil, bitumen) sampled from boreholes and field sites. The analyses are performed by various laboratories in service and exploration companies, Australian government institutions, and universities using a range of instruments. Petroleum is composed primarily of hydrocarbons (carbon and hydrogen) with minor quantities of heterocyclic compounds containing either nitrogen, oxygen or sulfur. Data includes the borehole or field site location, sample depth, shows and tests, stratigraphy, analytical methods, other relevant metadata, and various data types including; API gravity, elemental composition and photographs of the samples. The stable carbon (¹³C/¹²C) and hydrogen (²H/¹H) isotopic ratios of crude oil and derivative saturated and aromatic hydrocarbon fractions are presented in parts per mil (‰) and in delta notation as &delta;¹³C and &delta;²H, respectively. Results are also included from methods that separate crude oils into bulk components, such as the quantification of saturated hydrocarbon, aromatic hydrocarbon, resin, and asphaltene (SARA) fractions according to their polarity.</div><div><br></div><div>These data provide information about the petroleum fluid’s composition, source, thermal maturity, secondary alteration, and fluid migration pathways. They are also useful for enhanced oil recovery assessments, petroleum systems mapping and basin modelling. Hence, these sample-based datasets are used for the discovery and evaluation of sediment-hosted resources. Some data are generated in Geoscience Australia’s laboratory and released in Geoscience Australia records. Data are also collated from destructive analysis reports (DARs), well completion reports (WCRs), and literature. The bulk oils data are delivered in the Petroleum Bulk Properties and Stable Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div>Archean crustal evolution, and its tectonic paradigm, can be directly linked to the evolution of the mantle, the hydrosphere-atmosphere, oxygenation of the Earth, and the formation and storage of ore deposits. Hence, it is vital to understand the evolution of the early crust if we are to understand our planet’s evolution as well as transformational events in its history.</div><div> The collection of vast amounts of isotopic data, especially U-Pb, Sm-Nd, Lu-Hf, and δ18O, over the last 30 years, has significantly advanced our understanding of crustal processes and their timing. However, we rarely look at these data in a spatial context. This study aims to constrain the time-space evolution of the south-east Superior Craton, Canada, by mapping the zircon Hf-O isotopes and trace element data from 148 Archean magmatic rocks (6340 total analyses).</div><div> In Lu-Hf space, the dataset demonstrates the highly juvenile nature of this region, with the majority of values between εHfi +6 and +2. When plotted spatially, the most juvenile data (+4 to +6 εHfi) delineate an E-W oriented zone, broadly in-line and sub-parallel to the Cadillac-Larder Lake and Porcupine-Destor structures. Surrounding this juvenile region is less juvenile crust (0 to +3 εHf). Corresponding δ18O values show that light to mantle-like data (3.0-5.6‰) correlate with the most juvenile crust imaged by the εHf, with heavier δ18O (5.8-7.5‰) plotting to the south, east and west of this zone. Zircon trace element proxies for hydration (Eu/Eu*), oxidation (ΔFMQ using Ti, Ce, U), and continental vs. oceanic origin (Ui/Yb) replicate the pattern observed in the Lu-Hf and δ18O. This suggests that, broadly, the SE Superior consists of a central E-W orientated juvenile zone consisting of the most reduced, least hydrated, least continental, and most high-temperature hydrothermally-altered crust. This zone is surrounded by crust which is more hydrated, oxidised, has a greater supracrustal δ18O component, and is slightly less juvenile. The major ore systems of the Abitibi subprovince, including VMS, gold and komatiite-hosted Ni-Cu-PGE systems, fall within the E-W highly-juvenile zone.</div><div> Current tectonic models for this region of the Superior Craton range from (1) long-lived Neoarchean subduction across the whole Abitibi tectono-thermal ‘event’ (2750-<2695 Ma) – ‘horizontal’ tectonics; and (2) a variety of non-arc processes such as plume-related crustal overthickening (i.e., oceanic plateau), sagduction/drip tectonics, and subcretion, amongst others – ‘vertical’ tectonics. Models combining arc and non-arc processes have also been suggested (i.e., plume-arc interaction), and our data broadly support a combined model. We propose the E-W zone delineated by the various geochemical data represents a paleo-rift zone, driven by ambient mantle or mantle plume processes. The dry, reduced, oceanic character of the zone appears to preclude an arc or back-arc setting prior to ca. 2.7 Ga. However, temporal changes in hydration, oxidation, and the increased heavy δ18O component at ca. 2.7 Ga suggest a major geodynamic shift, potentially marking the onset of subduction and associated compression. This is contribution 2020-050 of the Mineral Exploration Research Centre (MERC) Metal Earth project.</div><div> This Abstract was submitted/presented to the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)

<div>The Yilgarn Craton of Western Australia represents one of the largest pieces of Precambrian crust on Earth, and a key repository of information on the Meso-Neoarchean period. Understanding the crustal, tectonic, thermal, and chemical evolution of the craton is critical in placing these events into an accurate geological context, as well as developing holistic tectonic models for the Archean Earth. In this study, we collected a large U-Pb (420 collated samples) and Hf isotopic (2163 analyses) dataset on zircon to investigate the evolution of the craton. These data provide strong evidence for a Hadean-Eoarchean origin for the Yilgarn Craton from mafic crust at ca. 4000 Ma. This ancient cratonic nucleus was subsequently rifted, expanded and reworked by successive crustal growth events at ca. 3700 Ma, ca. 3300 Ma, 3000-2900 Ma, 2825-2800 Ma, and ca. 2730-2620 Ma. The <3050 Ma crustal growth events correlate broadly with known komatiite events, and patterns of craton evolution, revealed by Hf isotope time-slice mapping, image the periodic break-up of the Yilgarn proto-continent and the formation of rift-zones between the older crustal blocks. Crustal growth and new magmatic pulses were focused into these zones and at craton margins, resulting in continent growth via internal (rift-enabled) expansion, and peripheral (crustal extraction at craton margins) magmatism. Consequently, we interpret these major geodynamic processes to be analogous to plume-lid tectonics, where the majority of tonalite-trondhjemite-granodiorite (TTG) felsic crust, and later granitic crust, was formed by reworking of hydrated mafic rocks and TTGs, respectively, via a combination of infracrustal and/or drip-tectonic settings. While this process of crust formation and evolution is not necessarily restricted to a specific geodynamic system, we find limited direct evidence that subduction-like processes formed a major tectonic component, aside from re-docking the Narryer Terrane to the craton at ca. 2740 Ma. Overall, these 'rift-expansion' and 'craton margin' crustal growth process led to an intra-cratonic architecture of younger, juvenile terranes located internal and external to older, long-lived, reworked crustal blocks. This framework provided pathways that localized later magmas and fluids, driving the exceptional mineral endowment of the Yilgarn Craton.</div> This Abstract/Poster was submitted to & presented at the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)

<div>The bulk source rock database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the bulk properties of sedimentary rocks that contain organic matter and fluid inclusions taken from boreholes and field sites. The analyses are performed by various laboratories in service and exploration companies, Australian government institutions, and universities, using a range of instruments. Sedimentary rocks that contain organic matter are typically referred to as source rocks (e.g., organic-rich shale, oil shale and coal) and the organic matter within the rock matrix that is insoluble in organic solvents is named kerogen. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and various data types including; elemental composition, and the stable isotopes of carbon, hydrogen, nitrogen, and sulfur. Results are also included from methods that separate the extractable organic matter (EOM) from rocks into bulk components, such as the quantification of saturated hydrocarbon, aromatic hydrocarbon, resin and asphaltene (SARA) fractions according to their polarity. The stable carbon (¹³C/¹²C) and hydrogen (²H/¹H) isotopic ratios of the EOM and derivative hydrocarbon fractions, as well as fluid inclusion oils, are presented in delta notation (i.e., &delta;¹³C and &delta;²H) in parts per mil (‰) relative to the Vienna Peedee Belemnite (VPDB) standard.</div><div><br></div><div>These data are used to determine the molecular and isotopic compositions of organic matter within rocks and associated fluid inclusions and evaluate the potential for hydrocarbon generation in a basin. Some data are generated in Geoscience Australia’s laboratory and released in Geoscience Australia records. Data are also collated from destructive analysis reports (DARs), well completion reports (WCRs), and literature. The bulk data for sedimentary rocks are delivered in the Source Rock Bulk Properties and Stable Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (NGSA; www.ga.gov.au/ngsa). The present study targeted the Yilgarn geological region in southwestern Australia. The samples were mostly taken from a depth of ~60-80 cm (Bottom Outlet Sediments, BOS) in floodplain deposits at or near the outlet of large catchments (drainage basins). A small number of surface (0-10 cm) samples (Top Outlet Sediments, TOS) were also included in the study. For all, a coarse grain-size fraction (<2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Overall, 107 NGSA BOS < 2 mm and 13 NGSA TOS < 2 mm were analysed for Sr isotopes. Given that there are ~10 % field duplicates in the NGSA, all those samples originate from within 97 NGSA catchments, which together cover 533 000 km2 of southwestern Australia. Preliminary results for the BOS samples demonstrate a wide range of strontium isotopic values (0.7152 < 87Sr/86Sr < 1.0909) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (>100 km) patterns that appear to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, catchments in the western and central Yilgarn dominated by felsic intrusive basement geology have radiogenic 87Sr/86Sr signatures in the floodplain sediments consistent with published whole-rock data. Similarly, unradiogenic signatures in sediments in the eastern Yilgarn are in agreement with published whole-rock data. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape and model derived therefrom can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations.&nbsp; The new spatial dataset is publicly available through the Geoscience Australia portal https://portal.ga.gov.au/.</div>

<div>Lithospheric and crustal architecture — the framework of major tectonic blocks, terranes and their boundaries — represents a fundamental first-order control on major geological systems, including the location of world-class mineral camps. Traditionally, lithospheric and crustal architecture are constrained using predominantly geophysical methods. However, Champion and Cassidy (2007) pioneered the use of regional Sm–Nd isotopic data from felsic igneous rocks to produce isotopic contour maps of the Yilgarn Craton, demonstrating the effectiveness of ‘isotopic mapping’, and the potential to map ‘time-constrained’ crustal architecture. Mole et al. (2013) demonstrated the association between lithospheric architecture and mineral systems, highlighting the potential of isotopic mapping as a greenfield area selection tool. Additional work, using Lu-Hf isotopes (Mole et al., 2014), demonstrated that the technique could constrain a range of temporal events via ‘time-slice mapping’, explaining how Ni-Cu-PGE mineralized komatiite systems migrated with the evolving lithospheric boundary of the Yilgarn Craton from 2.9 to 2.7 Ga. Similar studies have since been conducted in West Africa (Parra-Avila et al., 2018), Tibet (Hou et al., 2015), and Canada (Bjorkman, 2017; Mole et al., 2021; 2022). This work continues in Geoscience Australia’s $225 million Exploring for the Future program (2016-present). Isotopic mapping, which forms an integral part of a combined geology-geophysics-geochemistry approach, is currently being applied across southeast Australia, covering the eastern Gawler Craton, Delamerian Orogen, and western Lachlan Orogen, encompassing more than 3 Gyrs of Earth history with demonstrable potential for large mineral systems.</div><div> <b>Reference(s):</b></div><div> Bjorkman, K.E., 2017. 4D crust-mantle evolution of the Western Superior Craton: Implications for Archean granite-greenstone petrogenesis and geodynamics. University of Western Australia, PhD Thesis, 134 pp.</div><div> Champion, D.C. and Cassidy, K.F., 2007. An overview of the Yilgarn Craton and its crustal evolution. In: F.P. Bierlein and C.M. Knox-Robinson (Editors), Proceedings of Geoconferences (WA) Inc. Kalgoorlie '07 Conference. Geoscience Australia Record 2007/14, Kalgoorlie, Western Australia, pp. 8-13.</div><div> Hou, Z., Duan, L., Lu, Y., Zheng, Y., Zhu, D., Yang, Z., Yang, Z., Wang, B., Pei, Y., Zhao, Z. and McCuaig, T.C., 2015. Lithospheric architecture of the Lhasa terrane and its control on ore deposits in the Himalayan-Tibetan orogen. Economic Geology, 110(6): 1541-1575.</div><div> Mole, D.R., Fiorentini, M.L., Cassidy, K.F., Kirkland, C.L., Thebaud, N., McCuaig, T.C., Doublier, M.P., Duuring, P., Romano, S.S., Maas, R., Belousova, E.A., Barnes, S.J. and Miller, J., 2013. Crustal evolution, intra-cratonic architecture and the metallogeny of an Archaean craton. Geological Society, London, Special Publications, 393: pp. 23-80.</div><div> Mole, D.R., Fiorentini, M.L., Thebaud, N., Cassidy, K.F., McCuaig, T.C., Kirkland, C.L., Romano, S.S., Doublier, M.P., Belousova, E.A., Barnes, S.J. and Miller, J., 2014. Archean komatiite volcanism controlled by the evolution of early continents. Proceedings of the National Academy of Sciences, 111(28): 10083-10088.</div><div> Mole, D.R., Thurston, P.C., Marsh, J.H., Stern, R.A., Ayer, J.A., Martin, L.A.J. and Lu, Y., 2021. The formation of Neoarchean continental crust in the south-east Superior Craton by two distinct geodynamic processes. Precambrian Research, 356: 106104.</div><div> Mole, D.R., Frieman, B.M., Thurston, P.C., Marsh, J.H., Jørgensen, T.R.C., Stern, R.A., Martin, L.A.J., Lu, Y.J. and Gibson, H.L., 2022. Crustal architecture of the south-east Superior Craton and controls on mineral systems. Ore Geology Reviews, 148: 105017.</div><div> Parra-Avila, L.A., Belousova, E., Fiorentini, M.L., Eglinger, A., Block, S. and Miller, J., 2018. Zircon Hf and O-isotope constraints on the evolution of the Paleoproterozoic Baoulé-Mossi domain of the southern West African Craton. Precambrian Research, 306: 174-188.</div><div> This Abstract was submitted/presented to the Target 2023 Conference 28 July (https://6ias.org/target2023/)

<div>The Exploring for the Future program, led by Geoscience Australia, was a $225 million Australian Government investment over 8 years, focused on revealing Australia’s mineral, energy, and groundwater potential by characterising geology.&nbsp;&nbsp;This report provides an overview of activities, results, achievements and impacts from the Exploring for the Future program, with a particular focus on the last four years (2020-2024). &nbsp;</div>

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa), with a few additional Northern Australia Geochemical Survey infill samples. The present study targeted the northern parts of Western Australia, the Northern Territory and Queensland in Australia, north of 21.5 °S. The samples were taken mostly from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (&lt;2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 &lt; 87Sr/86Sr &lt; 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (&gt;100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a &gt;500 km-long northwest-southeast-trending low anomaly (87Sr/86Sr &lt; 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, conversely, high 87Sr/86Sr values (&gt; 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape and model derived therefrom can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations. &nbsp;The new spatial dataset is publicly available through the Geoscience Australia portal https://portal.ga.gov.au/.</div>

<div>The soil gas database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for gas analyses undertaken by Geoscience Australia's laboratory on soil samples taken from shallow (down to 1 m below the surface) percussion holes. Data includes the percussion hole field site location, sample depth, analytical methods and other relevant metadata, as well as the molecular and isotopic compositions of the soil gas with air included in the reported results. Acquisition of the molecular compounds are by gas chromatography (GC) and the isotopic ratios by gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). The concentrations of argon (Ar), carbon dioxide (CO₂), nitrogen (N₂) and oxygen (O₂) are given in mole percent (mol%). The concentrations of carbon monoxide (CO), helium (He), hydrogen (H₂) and methane (C₁, CH₄) are given in parts per million (ppm). Compound concentrations that are below detection limit (BDL) are reported as the value -99999. The stable carbon (¹³C/¹²C) and nitrogen (¹⁵N/¹⁴N) isotopic ratios are presented in parts per mil (‰) and in delta notation as δ¹³C and δ¹⁵N, respectively.</div><div><br></div><div>Determining the individual sources and migration pathways of the components of natural gases found in the near surface are useful in basin analysis with derived information being used to support exploration for energy resources (petroleum and hydrogen) and helium in Australian provinces. These data are collated from Geoscience Australia records with the results being delivered in the Soil Gas web services on the Geoscience Australia Data Discovery portal at https://portal.ga.gov.au which will be periodically updated.</div>