This product is a Microsoft Access database which contains the raw data, calculated biomarker ratios and reporting output forms. This product includes 120 oils from the first Oils of Western Australia study (WOZ1) and 150 oils from the second Oils of Western Australia study (WOZ2). This database is one component of "The Oils of Western Australia II" product which comprises two other components: an interpretative report documenting the petroleum geochemistry of the oils in the study and assignment of each sample to an oil family, and an ArcView GIS CD containing coverages of North West Shelf regional geology and petroleum exploration themes, and oil family maps linked to graphs of specific chemical parameters which define the families. The Oils of Western Australia II report summarises the findings of a collaborative research program between Geoscience Australia and GeoMark Research undertaken on the petroleum geochemistry of crude oils and condensates discovered within the basins of western Australia and the Papuan Basin, Papua New Guinea prior to March 2000. The interpretations documented herein build on research that Geoscience Australia and GeoMark Research undertook previously in The Oils of Western Australia (AGSO and GeoMark, 1996) and The Oils of Eastern Australia (Geoscience Australia and GeoMark, 2002) studies. To make informed decisions regarding Australia's petroleum resources, it is important to understand the relationship between the liquid hydrocarbons within and between basins. This Study has geochemically characterised the liquid hydrocarbon accumulations of western Australian basins and the Papuan Basin into genetically related families. From a total of 316 samples, 33 oil/condensate families were identified in the western Australian basins; Bonaparte (10), Browse (2), Canning (4), Carnarvon (11) and Perth (6), as well as some vagrant and contaminated samples. Three oil/condensate families were recognised in the Papuan Basin. The geographic distribution of each oil/condensate family is mapped within each basin/sub-basin. Using the geochemical characteristics of each family, the nature of their source facies, thermal maturity level and degree of preservation has been determined. This Study used a set of standardised geochemical protocols that include bulk geochemical (API gravity, elemental analysis of nickel, vanadium and sulphur), molecular (gas chromatography of the whole-oil and gas chromatography-mass spectrometry of the saturated and aromatic hydrocarbons) and bulk stable carbon isotopic analyses. n-Alkane-specific 13C isotopic analyses were carried out on only a selected set of oils and condensates. Statistical analyses were performed on these data using the software Pirouette' provided by Infometrix. In addition to this report, the geochemical data acquired for the crude oils and condensates in this Study are provided in the accompanying Microsoft Access2000 database. These data may be viewed spatially and plotted on x-y cross-plots in the charting application included in the ESRI Australia GIS ArcView3.2 georeferencing package that also accompanies this report.

This product is an ArcView GIS CD containing coverages of North West Shelf regional geology and petroleum exploration themes, and oil family maps linked to graphs of specific chemical parameters which define the families. This product includes 120 oils from the first Oils of Western Australia study (WOZ1) and 150 oils from the second Oils of Western Australia study (WOZ2). This CD is one component of "The Oils of Western Australia II" product which comprises two other components: an interpretative report documenting the petroleum geochemistry of the oils in the study and assignment of each sample to an oil family, and a Microsoft Access database which contains the raw data, calculated biomarker ratios and reporting output forms. The Oils of Western Australia II report summarises the findings of a collaborative research program between Geoscience Australia and GeoMark Research undertaken on the petroleum geochemistry of crude oils and condensates discovered within the basins of western Australia and the Papuan Basin, Papua New Guinea prior to March 2000. The interpretations documented herein build on research that Geoscience Australia and GeoMark Research undertook previously in The Oils of Western Australia (AGSO and GeoMark, 1996) and The Oils of Eastern Australia (Geoscience Australia and GeoMark, 2002) studies. To make informed decisions regarding Australia's petroleum resources, it is important to understand the relationship between the liquid hydrocarbons within and between basins. This Study has geochemically characterised the liquid hydrocarbon accumulations of western Australian basins and the Papuan Basin into genetically related families. From a total of 316 samples, 33 oil/condensate families were identified in the western Australian basins; Bonaparte (10), Browse (2), Canning (4), Carnarvon (11) and Perth (6), as well as some vagrant and contaminated samples. Three oil/condensate families were recognised in the Papuan Basin. The geographic distribution of each oil/condensate family is mapped within each basin/sub-basin. Using the geochemical characteristics of each family, the nature of their source facies, thermal maturity level and degree of preservation has been determined. This Study used a set of standardised geochemical protocols that include bulk geochemical (API gravity, elemental analysis of nickel, vanadium and sulphur), molecular (gas chromatography of the whole-oil and gas chromatography-mass spectrometry of the saturated and aromatic hydrocarbons) and bulk stable carbon isotopic analyses. n-Alkane-specific 13C isotopic analyses were carried out on only a selected set of oils and condensates. Statistical analyses were performed on these data using the software Pirouette provided by Infometrix. In addition to this report, the geochemical data acquired for the crude oils and condensates in this Study are provided in the accompanying Microsoft Access2000 database. These data may be viewed spatially and plotted on x-y cross-plots in the charting application included in the ESRI Australia GIS ArcView3.2 georeferencing package that also accompanies this report.

A laboratory study has been conducted to determine the best methods for the detection of C10 to C40 hydrocarbons at naturally occurring oil seeps in marine sediments. The results indicate that a commercially available method using hexane to extract sediments and gas chromatography to screen the resulting extract is effective at recognizing the presence of migrated hydrocarbons at concentrations between 50 to 5,000 ppm. When the oil charge is unbiodegraded the level of charge is effectively tracked by the sum of n-alkanes in the gas chromatogram. However, once the charge oil becomes biodegraded, with the loss of n-alkanes and isoprenoids, the level of charge is tracked by the quantification of the Unresolved Complex Mixture (UCM). The use of GC-MS was also found to be very effective for the recognition of petroleum related hydrocarbons and results indicate that GC-MS would be a very effective tool for screening samples at concentrations below 50 ppm oil charge.

Collation of talks and posters completed under the APCRC Program 5 during June 1999-June 2001.

The molecular composition of fluid inclusion (FI) oils from Leander Reef-1, Houtman 1 and Gage Roads-2 provide evidence of the origin of palaeo-oil accumulations in the offshore Perth Basin. These data are complemented by compound specific isotope (CSI) profiles of n-alkanes for the Leander Reef-1 and Houtman-1 samples, which were acquired on purified n-alkane fractions gained by micro-fractionation of lean FI oil samples, showing the technical feasibility of this technique. The Leander Reef-1 FI oil from the top Carynginia Formation shares many biomarker similarities with oils from the Dongara and Yardarino oilfields, which have been correlated with the Early Triassic Kockatea Shale. However, the heavier isotopic values for the C15-C25 n-alkanes in the Leander Reef-1 FI oil indicate that it is a mixture, and suggest that the main part of this oil (~90%) was sourced from the more terrestrial and isotopically heavier Early Permian Carynginia Formation or Irwin River Coal Measures. This insight would have been precluded when looking at molecular evidence alone. The Houtman-1 FI oil from the top Cattamarra Coal Measures (Middle Jurassic) was sourced from a clay-rich, low sulphur source rock with a significant input of terrestrial organic matter, deposited under oxic to suboxic conditions. Biomarkers suggest sourcing from a more prokaryotic-dominated facies than for the other FI oils, possibly a saline lagoon. The Houtman-1 FI oil ?13C CSI data are similar to data acquired on the Walyering-2 oil. Possible lacustrine sources include the Early Jurassic Eneabba Formation or the Late Jurassic Yarragadee Formation. The low maturity Gage Roads-2 FI oil from the Carnac Formation (Early Cretaceous) was derived from a strongly terrestrial, non-marine source rock containing a high proportion of Araucariacean-type conifer organic matter. It has some geochemical differences to the presently reservoired oil in Gage Roads-1, and was probably sourced from the Early Cretaceous Parmelia Formation.

Legacy product - no abstract available

Methane is present in all coals, but a number of geological factors influence the potential economic concentration of gas. The key factors are (1) depositional environment, (2) tectonic and structural setting, (3) rank and gas generation, (4) gas content, (5) permeability, and (6) hydrogeology. Commercial coal seam gas production in Queensland has been entirely from the Permian coals of the Bowen Basin, but the Jurassic coals of the Surat and Clarence-Moreton basins are poised to deliver commercial gas volumes. Depositional environments range from fluvial to delta plain to paralic and marginal marine coals in the Bowen Basin are laterally more continuous than those in the Surat and Clarence-Moreton basins. The tectonic and structural settings are important as they control the coal characteristics both in terms of deposition and burial history. The important coal seam gas seams were deposited in a foreland setting in the Bowen Basin and an intracratonic setting in the Surat and Clarence-Moreton basins. Both of these settings resulted in widespread coal deposition. The complex burial history of the Bowen Basin has resulted in a wide range of coal ranks and properties. Rank in the Bowen Basin coal seam gas fields varies from vitrinite reflectane of 0.55% to >1.1% Rv and from Rv 0.35-0.6% in the Surat and Clarence-Moreton basins in Queensland. High vitrinite coals provide optimal gas generation and cleat formation. The commercial gas fields and the prospective ones contain coals with >60% vitrinite. Gas generation in the Queensland basins is complex with isotopic studies indicating that biogenic gas, thermogenic gas and mixed gases are present. Biogenic processes occur at depths of up to a kilometre. Gas content is important, but lower gas contents can be economic if deliverability is good. Free gas is also present. Drilling and production techniques play an important role in making lower gas content coals viable. Since the Bowen and Surat basins are in a compressive regime, permeability becomes a defining parameter. Areas where the compression is offset by tensional forces provide the best chances for commercial coal seam gas production. Tensional setting such as anticline or structural hinges are important plays. Hydrodynamics control the production rate though water quality varies between the fields.

An inverted phase (polar to non-polar) column set has been compared with a non-polar to polar column set for the GC-GC separation of petroleum hydrocarbons crude oil. This is shown to provide greatly enhanced resolution for less polar compounds and makes greater use of the two-dimensional separation space. This column configuration improves resolution of a greater number of components within one analysis and offers new possibilities for crude oil fingerprinting.

We have demonstrated for the first time the application of a small angle neutron scattering (SANS) technique for the precise determination of the onset of hydrocarbon transport (primary migration) in shaly source rocks. We used a sequence of rocks pyrolysed in the laboratory under nitrogen at temperatures in the range 310-370°C. These rocks contained several percent of dispersed marine Type II organic matter. Geochemical analysis indicated a peak of the hydrocarbon generation in the middle of the temperature range (at 340°C). We observed a sharp decrease of SANS intensity in a narrow maturity range within the geochemically determined region of the onset of hydrocarbon generation. This decrease was a direct consequence of the SANS contrast variation caused by the invasion of the pore space by bitumen during the primary migration of hydrocarbons. A similar phenomenon was observed for a natural maturity sequence of source rocks originating from the same location.

A growing need to manage marine biodiversity sustainably at local, regional and global scales cannot be met by applying the limited existing biological data. Abiotic surrogates of biodiversity are thus increasingly valuable in filling the gaps in our knowledge of biodiversity patterns, especially identification of hotspots, habitats needed by endangered or commercially valuable species and systems or processes important to the sustained provision of ecosystem services. This review examines the use of abiotic variables as surrogates for patterns in benthic assemblages with particular regard to how variables are tied to processes affecting biodiversity and how easily those variables can be measured at scales relevant to resource management decisions.