Lord Howe Island is a small, mid-ocean volcanic and carbonate island in the southwestern Pacific Ocean. Skeletal carbonate eolianite and beach calcarenite on the island are divisible into two formations based on lithostratigraphy. The Searles Point Formation comprises eolianite units bounded by clay-rich paleosols. Pore-filling sparite and microsparite are the dominant cements in these eolianite units, and recrystallised grains are common. Outcrops exhibit karst features such as dolines, caves and subaerially exposed relict speleothems. The Neds Beach Formation overlies the Searles Point Formation and consists of dune and beach units bounded by weakly developed fossil soil horizons. These younger deposits are characterised by grain-contact and meniscus cements, with patchy pore-filling micrite and mirosparite. The calcarenite comprises several disparate successions that contain a record of up to 7 discrete phases of deposition. A chronology is constructed based on U/Th ages of speleothems and corals, TL ages of dune and paleosols, AMS 14C and amino acid racemization (AAR) dating of land snails and AAR whole-rock dating of eolianite. These data indicate dune units and paleosols of the Searles Point Formation were emplaced during oxygen isotope stage (OIS) 7 and earlier in the Middle Pleistocene. Beach units of the Neds Beach Formation were deposited during OIS 5e while dune units were deposited during two major phases, the first coeval with or shortly after the beach units, the second later during OIS 5 (e.g. OIS 5a) when the older dune and beach units were buried. Large-scale exposures and morphostratigraphical features indicate much of the carbonate was emplaced as transverse and climbing dunes, with the sediment source located seaward of and several metres below the present shoreline. The lateral extent and thickness of the eolianite deposits contrast markedly with the relatively small modern dunes.

In this paper, we present a high resolution study focussed mainly on the Gorgon field and associated Rankin Trend gas fields, Carnarvon Basin, Australia (Figure 1). These gas fields are characterized by numerous stacked reservoirs with varying CO2 contents and provide a relevant natural laboratory for characterizing CO2 migration, dissolution and reaction by looking at chemical characteristics of the different reservoirs (Figure 2). The data we present reveal interesting trends for CO2 mol% and -13C both spatially and with each other as observed by Edwards et al. (2007). Our interpretation of the data suggests that mineral carbonation in certain fields can be significant and relatively rapid. The Gorgon and Rankin Trend fields natural gases may therefore be a unique natural laboratory, which give further insights into the rates and extent of carbonate mineral sequestration as applied to carbon storage operations.

The New England Orogen contains a geological record dominated by subduction-related rocks, indicating that the orogen has been part of, or adjacent to, convergent plate margins of eastern Gondwanaland from at least the Cambrian until the end of the Early Cretaceous (~95 Ma). In the late Devonian, the orogen records the change from an island arc setting to an Andean-style convergent continental plate margin (e.g., Flood & Aitchison 1992; Skilbeck and Cawood, 1994). The rock record prior to the Middle Devonian is fragmentary, but the Late Devonian to Carboniferous components of the continental margin magmatic arc, forearc basin and accretionary wedge system are well preserved in the New England Orogen, with the Lachlan Orogen, Thomson Orogen and Drummond Basin to the west being in a backarc setting at this time. This system ended in the Late Carboniferous, with the subduction zone stepping to the east (Cawood, 1984). Nevertheless, until at least the Early Cretaceous, the Australian component of the continental margin of East Gondwanaland faced the Proto-Pacific (Panthalassan) Ocean, and has been interpreted to form part of a subduction-related convergent plate margin (e.g. Powell 1984; Cawood 2005; Glen 2005). Here, we examine aspects of the southern New England Orogen from the Cambrian to the Early Permian to further document the nature of the convergent plate margin over this period of time. We are interested especially in the Tamworth Belt, where the changeover is recorded from the Cambrian-Late Devonian island arc setting, to the development of the Devonian-Carboniferous continental margin in a convergent plate setting, with its well developed forearc basin and accretionary wedge. The island arc component is referred to as the Gamilaroi Terrane by Aitchison and Flood (1995) and Offler and Gamble (2002).

This is a collection of conference program and abstracts presented at AOGC 2010, Canberra.

Metallogenic, geologic and isotopic data indicate secular changes in the character of VHMS deposits relate to changes in tectonic processes, tectonic cycles, and changes in the hydrosphere and atmosphere. The distribution of these deposits is episodic, with peaks at 2740-2680 Ma, 1910-1840 Ma, 510-460 Ma and 370-355 Ma that correspond to the assembly of Kenorland, Nuna, Gondwana and Pangea. Quiescent periods of VHMS formation correspond to periods of supercontinent stability. Large ranges in source 238U/204Pb that characterize VHMS deposits in the Archean and Proterozoic indicate early (Hadean to Paleoarchean) differentiation. A progressive decrease in - variability suggests homogenisation with time of these differentiated sources. Secular increases in the amount of lead and decreases in 100Zn/(Zn+Pb) relate to an increase in felsic-dominated sequences as hosts to deposits and an absolute increase in the abundance of lead in the crust with time. The increase in sulfate minerals in VHMS deposits from virtually absent in the Meso- to Neoarchean to relatively common in the Phanerozoic relates to oxidation of the hydrosphere. Total sulfur in the oceans increased, resulting in an increasingly important contribution of seawater sulfur to VHMS ore fluids with time. Most sulfur in Archean to Paleoproterozoic deposits was derived by leaching rocks below deposits, with little contribution from seawater, resulting in uniform, near-zero-permil values of 34Ssulfide. In contrast the more variable values of younger deposits reflect the increasing importance of seawater sulfur. Unlike Meso- to Neoarchean deposits, Paleoarchean deposits contain abundant barite, which is inferred to have been derived from photolytic decomposition of atmospheric SO2 and does not reflect overall oxidised oceans. Archean and Proterozoic seawater was more salty than Phanerozoic, particularly upper Phanerozoic, seawater. VHMS fluids ore fluids reflect this, also being saltier in Precambrian deposits.

S-type granites crop out extensively (>2500 km2) in the central and eastern parts of the Hodgkinson Province, north Queensland, Australia, forming two NW to NNW trending belts, outboard of an extensive belt of (mainly late Carboniferous) I-type granites. The S-type granites, which comprise muscovite-biotite syenogranite and monzogranite, and rare granodiorite, have been subdivided in two major supersuites: the Whypalla and Cooktown Supersuites; and a number of minor suites - including the highly differentiated Wangetti and Mount Alto Suites. The S-type granites intrude a very extensive, siliciclastic flysch sequence (late Silurian? to earliest Carboniferous) that is isotopically evolved (e.g., Nd mostly -12.0 to -15.0 at 270 Ma), and generally too mature (too CaO poor) to produce S-type granites. Isotopic and chemical modeling show that although magma-mixing is permissible, the levels permissible (<ca 20-25% basaltic input), are not large enough to explain the signature of the S-type granite. Either more complex mixing models, e.g., crustal melts with a history of mixing, or the presence of more suitable metasedimentary source rocks at depth, is required. The latter is consistent with the (uncommon) presence within the eastern parts of the Hodgkinson Province of metasediments with isotopic signatures similar to the S-type granites. These provide strong support for more extensive such rocks at depth, consistent with other local geology and accretionary tectonic models for the region.

The Victoria and Birrindudu Basins of the Victoria River region, NW Northern Territory, represent a pair of stacked unmetamorphosed Palaeoproterozoic to Neoproterozoic basins unconformably overlying low-grade metamorphic basement. SHRIMP U-Pb analysis of detrital zircons provide a basis for lithostratigraphic correlations with other Proterozoic Basins across northern Australia. The Palaeoproterozoic Stirling Sandstone (basal Limbunya Group) is tentatively correlated with the Mount Charles Formation in the Tanami region. The Jasper Gorge Sandstone (basal Auvergne Group) correlates with basal units of the lower Cryogenian Supersequence 1 of the Centralian Superbasin (Heavitree Quartzite and its correlatives). A third correlation, previously proposed elsewhere and further explored here, suggests that the Duerdin Group may correlate with the upper Cryogenian ca. 635 Ma 'Marinoan' glacigenic units of Supersequence 3 of Centralian Superbasin. In particular, the Cryogenian pre-glacigenic Black Point Sandstone Member (basal Duerdin Group) is dominated by detrital zircons with age components characteristic of the Musgrave Complex, implying significant exhumation and erosion of the Musgrave Complex occurred, at least partially, prior to the end of the Cryogenian (<ca. 635 Ma) far earlier than generally thought. The latter two correlations suggest that the Victoria Basin in the Victoria River region represents yet another relic component of the extensive former Centralian Superbasin, at least during Cryogenian time. Sm-Nd whole rock determinations overwhelmingly, and unsurprisingly, are consistent with clastic derivation from the evolved North Australian Craton and, for the Black Point Sandstone Member, from the Musgrave Complex. A relatively juvenile signature ('Ndt ' +1) is observed coincident with aerial volcanism within the Birrindudu Basin at ca. 1640 Ma as has been recently noted in other Australian Palaeoproterozoic terrains.

The oxygen isotopic record obtained from Globigerina bulloides, Globorotalia inflata, and Neogloboquadrina pachyderma (s.) was analysed for 5 sediment traps moored in the Southern Ocean and Southwest Pacific. The traps extend from Subtropical to the Polar Frontal environments, providing the first analysis of seasonal foraminiferal d18O records from these latitudes. Comparison between the foraminiferal records and various equations for predicted d18O of calcite reveals that the predicted d18O is best captured by the equations of Epstein et al. (1953) [Epstein, S., Buchsbaum, R., Lowenstam, H.A., Urey, H.C., 1953. Revised carbonate-water isotopic temperature scale. Geological Society of America Bulletin 64, 1315-1326.] and Kim and O'Neil (1997) [Kim, S.-T., O'Neil, J.R., 1997. Equilibrium and non-equilibrium oxygen isotope effects in synthetic carbonates. Geochimica et Cosmochimica Acta 61, 3461-3475.]. The Epstein equation shows a constant offset from the -18O of G. bulloides and N. pachyderma (s.) across the full range of latitudes. The seasonal range in -18O values for these two species implies a near-surface habitat across all sites, while G. inflata most likely dwells at 50 m depth. A significant finding in this study was that offsets from predicted -18O for G. bulloides do not correlate to changes in the carbonate ion concentration. This suggests that [CO32-] in and of itself may not capture the full range of carbonate chemistry conditions in the marine system. This sediment trap deployment also reveals distinct seasonal flux patterns for each species. Comparison between flux-weighted isotopic values calculated from the sediment traps and the isotopic composition of nearby surface sediments indicates that the sedimentary records retain this seasonal imprint. At the 51°S site, G. bulloides has a spring flux peak while N. pachyderma (s.) is dominated by summer production.

The Nolans Bore deposit, located in the Aileron Province of south-central Northern Territory, is an emerging Australian rare earth development. It consists of steeply northwest dipping apatite veins hosted by ~1806 Ma granite gneiss. A preliminary ~1240 Ma U-Pb age for apatite may correspond to a major global period of alkalic magmatism between 1300 and 1130 Ma, including emplacement of the Bayan Obo deposit in China. Low ?Nd and 87Sr/86Sr in the mineralisation is reminiscent of modern EM-1 ocean island basalts and may indicate a link to carbonatitic magmatism. Oxygen isotope thermometry indicates a mineralisation temperature of 410°C, with '18Ofluid of ~8.0'. Fertilisation of the mantle to produce the EM-1 source may relate to subduction associated with convergence along the southern margin of the North Australian Craton.

Natural gas is Australia's third largest energy resource after coal and uranium but despite this economic importance, the gas origin is not always recognized. To address this, isotope and geochemistry data have been collated on 850 natural gases from all of Australia's major gas provinces with proposed source ages spanning the earliest Paleozoic to the Cenozoic. Unaltered natural gases have a thermogenic origin ('13C methane ranges between -49 and -27'; 'D methane ranges between -290 and -125'). Microbially altered natural gases were identified primarily on the basis of 13C and D enrichments in propane and/or 13C depletion in methane and/or 13C enrichment in CO2. The carbon isotopic composition of the gas source has been estimated using '13C iso-butane as a surrogate for '13C kerogen while for gases where biodegradation is moderate to severe, '13C neo-pentane provides an alternative measure. The '13C kerogen of gas source rocks range from -47 to -22' with the older Paleozoic sources and marine kerogen amongst the most depleted in 13C. The '13C CO2 also provides an insight into crustal- and mantle-derived components while '15N N2 (-6.0 to 2.3' for N2 up to 47 %) distinguish between organic and inorganic (groundwater) inputs. This dataset provides a better understanding on the source and preservation history of Australian gas accumulations with direct implications on improving exploration success.