<div><strong>Output type: </strong>Exploring for the Future Extended Abstract</div><div><br></div><div><strong>Short abstract: </strong>Australian sediment-hosted mineral systems play a crucial role in providing base metals and critical minerals essential for the global low-carbon economy. The Georgina Basin has the key components for forming and preserving a sediment-hosted Zn-Pb mineral system, but historically has been considered ‘cover’ to deeper, more prospective Proterozoic basement rocks. Thus, the basin has remained relatively under-explored, with many questions yet to be resolved on its sediment-hosted Zn-Pb mineral system and prospectivity for Zn-Pb. Utilising new whole-rock and isotope geochemistry of the Georgina Basin from recently drilled holes in the Northern Territory, we demonstrate the sensitivity of local redox boundaries to detect regional mineralisation. Two geochemically enriched zones have been identified and interpreted as redox interfaces which have trapped and concentrated metals from the surrounding basin, a ‘supergene zone’ and a ‘water intercept zone’. The ‘supergene zone’ is a paleo water table horizon, while the ‘water intercept zone’ is an active redox front at the uppermost part of the Cambrian Limestone Aquifer. The enrichment of these redox zones is consistent across multiple drill holes, reaching up to 395 ppm Pb and 1550 ppm Zn. Additionally, the Pb isotopes of high-Pb and sulfidic intervals have a highly radiogenic character (206Pb/204Pb ~22.0–23.0) that is diagnostic of Georgina Basin’s Mississippi Valley-type Zn-Pb mineralisation. Taken together, these results suggest there may be buried mineralisation in this part of the Georgina Basin, as well as highlight the potential of these redox interfaces as a regional reconnaissance target for exploration.</div><div><br></div><div><strong>Citation: </strong>Schroder I.F., Huston D. & de Caritat P., 2024. The geochemistry of redox interfaces for insights into Zn-Pb prospectivity in the Georgina Basin. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, https://doi.org/10.26186/149116 </div>

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa), with a few additional Northern Australia Geochemical Survey infill samples. The present study targeted the northern parts of Western Australia, the Northern Territory and Queensland in Australia, north of 21.5 °S. The samples were taken mostly from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (&lt;2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 &lt; 87Sr/86Sr &lt; 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and smooth gradients), large-scale (&gt;100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a &gt;500 km-long northwest-southeast-trending low anomaly (87Sr/86Sr &lt; 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, conversely, high 87Sr/86Sr values (&gt; 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g. weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape and model derived therefrom can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations. &nbsp;The new spatial dataset is publicly available through the Geoscience Australia portal https://portal.ga.gov.au/.</div>

<div>The Exploring for the Future program (EFTF) is a $225M Federal Government-funded initiative spanning the period July 2016 to June 2024. This multi-disciplinary program involves aspects of method development and new pre-competitive data acquisition at a variety of scales, with the aim of building an integrated understanding of Australia’s mineral, energy and groundwater potential. Significant work has been undertaken across northern Australia within regional-scale projects and as part of national-scale data acquisition and mapping activities. Some of these activities have been largely completed, and have generated new data and products, while others are ongoing. A comprehensive overview of the EFTF program can be found via the program website (eftf.ga.gov.au). Here, we overview a range of activities with implications for resource exploration in the Northern Territory.</div><div><br></div>This Abstract was submitted & presented to the 2023 Annual Geoscience Exploration Seminar (AGES), Alice Springs (https://industry.nt.gov.au/news/2022/december/registrations-open-for-ages-2023)

The fundamental geological framework of the concealed Paleoproterozoic East Tennant area of northern Australia is very poorly understood, despite its relatively thin veneer of Phanerozoic cover and its position along strike from significant Au–Cu–Bi mineralisation of the Tennant Creek mining district within the outcropping Warramunga Province. We present 18 new U–Pb dates, obtained via Sensitive High Resolution Ion Micro Probe (SHRIMP), constraining the geological evolution of predominantly Paleoproterozoic metasedimentary and igneous rocks intersected by 10 stratigraphic holes drilled in the East Tennant area. The oldest rocks identified in the East Tennant area are two metasedimentary units with maximum depositional ages of ca. 1970 Ma and ca. 1895 Ma respectively, plus ca. 1870 Ma metagranitic gneiss. These units, which are unknown in the nearby Murphy Province and outcropping Warramunga Province, underlie widespread metasedimentary rocks of the Alroy Formation, which yield maximum depositional ages of 1873–1864 Ma. While parts of this unit appear to be correlative with the ca. 1860 Ma Warramunga Formation of the Warramunga Province, our data suggest that the bulk of the Alroy Formation in the East Tennant area is slightly older, reflecting widespread sedimentation at ca. 1870 Ma. Throughout the East Tennant area, the Alroy Formation was intruded by voluminous 1854–1845 Ma granites, contemporaneous with similar felsic magmatism in the outcropping Warramunga Province (Tennant Creek Supersuite) and Murphy Province (Nicholson Granite Complex). In contrast with the outcropping Warramunga Province, supracrustal rocks equivalent to the 1845–1810 Ma Ooradidgee Group are rare in the East Tennant area. Detrital zircon data from younger sedimentary successions corroborate seismic evidence that at least some of the thick sedimentary sequences intersected along the southern margin of the recently defined Brunette Downs rift corridor are possible age equivalents of the ca. 1670–1600 Ma Isa Superbasin. Our new results strengthen ca. 1870–1860 Ma stratigraphic and ca. 1850 Ma tectono-magmatic affinities between the East Tennant area, the Murphy Province, and the mineralised Warramunga Province around Tennant Creek, with important implications for mineral prospectivity of the East Tennant area. Appeared in Precambrian Research Volume 383, December 2022.

<div>Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g. recognising geological provinces, studying geological processes) as well as in archaeological (e.g. informing on past human migrations), palaeontological/ecological (e.g. investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g. validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected mostly from the low-density National Geochemical Survey of Australia (NGSA; www.ga.gov.au/ngsa). Three regional projects were focussed on: inland southeastern, northern, and southwestern Australia, together covering over 2.5 million km2 of catchment area. Whilst results on <em>total</em> Sr isotopic analyses have been reported previously (Caritat et al. 2022, 2023, 2024), a pilot study targeting the isotopic composition of <em>bioavailable</em> (or labile) Sr was conducted in parallel and this dataset is released here. In contrast to the total Sr isotope analyses, which were conducted mostly on NGSA Bottom Outlet Sediments (BOS; taken on average from ~60-80 cm depth), the bioavailable Sr work used Top Outlet Sediments (TOS; taken from 0-10 cm depth) to make the results more relevant to soil-, plant- and animal-focused applications. Approximately 1 g of air-dried, coarse-sieved (<2 mm) soil sample was reacted with 2.5 M ammonium acetate (buffered to pH 7) for 24 hr on a mixing table, to extract operationally defined plant-available cations (after Stewart et al. 1998). The solution was filtered at 0.45 µm and dried down to incipient dryness. The residue was re-dissolved in 2M nitric acid. The Sr was separated by chromatography and its 87Sr/86Sr ratio determined by multicollector-inductively coupled plasma-mass spectrometry. Results for 278 samples across all three regions demonstrate a wide range of bioavailable Sr isotopic values (0.7050 to 0.7812, median 0.7191) across Australia, reflecting a large diversity of source rock lithologies, geological, pedogenic and biogeochemical processes, and, ultimately, bedrock ages. Modelling and interpretation of this dataset will be presented elsewhere. The resulting bioavailable Sr isoscape for Australia, although sparse at the moment, and models to be derived therefrom, may have applications in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations.&nbsp;The new spatial dataset is publicly available through the Geoscience Australia portal (https://portal.ga.gov.au/).</div><div><br></div><div>References cited</div><div>Caritat, P. de, Dosseto, A., Dux, F., 2022. A strontium isoscape of inland southeastern Australia, Earth System Science Data, 14, 4271–4286, https://doi.org/10.5194/essd-14-4271-2022 </div><div>Caritat, P. de, Dosseto, A., Dux, F., 2023. A strontium isoscape of northern Australia, Earth System Science Data, 15, 1655–1673, https://doi.org/10.5194/essd-15-1655-2023 </div><div>Caritat, P. de, Dosseto, A., Dux, F., 2024. A strontium isoscape of southwestern Australia and progress toward a national strontium isoscape, Earth System Science Data Discussion [non peer-reviewed preprint], https://doi.org/10.5194/essd-2024-352 </div><div>Stewart, B. W., Capo, R. C., Chadwick, O. A., 1998. Quantitative strontium isotope models for weathering, pedogenesis and biogeochemical cycling, Geoderma, 82, 173–195, https://doi.org/10.1016/S0016-7061(97)00101-8 </div>

As part of Geoscience Australia's Exploring for the Future program, the East Tennant region, which is centred on the Barkly Roadhouse in the Northern Territory, was identified as having favourable geological and geophysical indicators of mineral systems potential. Potentially prospective stratigraphy in the East Tennant region is completely concealed beneath Mesoproterozoic to Quaternary cover sequences. Prior to 2020 basement rocks in the East Tennant region were only known from a handful of legacy boreholes, supported by geophysical interpretation. In order to test geophysical interpretations and obtain additional samples of basement rocks for detailed analysis, a stratigraphic drilling campaign was undertaken in the East Tennant region as part of the MinEx CRC’s National Drilling Initiative. Ten stratigraphic boreholes were drilled through the cover sequences and into basement for a total of nearly 4000 m, including over 1500 m of diamond cored basement rocks to be used for scientific purposes. Inorganic geochemical samples from East Tennant National Drilling Initiative boreholes were taken to characterise cover and basement rocks intersected during drilling. Two sampling approaches were implemented based on the rocks intersected: 1) Borehole NDIBK04 contained localised sulphide mineralisation and elevated concentrations of several economically-significant elements in portable X-ray fluorescence data. In order to understand the geochemical variability and distribution of elements important for mineral system characterisation, the entire basement interval was sampled at nominal one metre intervals. This spacing was reduced to between 0.5 and 0.25 m from 237 m to 263 m to better understand a more intense zone of mineralisation, and 2) Samples from boreholes NDIBK01, NDIBK02, NDIBK03, NDIBK05, NDIBK06, NDIBK07, NDIBK08, NDIBK09 and NDIBK10 were selected to capture lithological and geochemical variability to establish bulk rock geochemical compositions for further interpretation. Attempts were made to sample representative, lithologically consistent intervals. A total of 402 samples were selected for analysis. Sample preparation was completed at Geoscience Australia and Bureau Veritas, with all analyses performed by Bureau Veritas in Perth. All samples were submitted for X-ray fluorescence (XRF), laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS), FeO determination, and loss on ignition (LOI). Samples from borehole NDIBK04 also underwent total combustion C and S, and Pb collection fire assay by ICP-MS for determination of Au, Pt and Pd concentrations. This data release presents inorganic geochemistry data acquired on rock samples from the ten East Tennant National Drilling Initiative boreholes.

NDI Carrara 1 is a deep stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-basin, a newly discovered Proterozoic depocentre in the South Nicholson region, based on interpretation from new seismic surveys (L210 in 2017 and L212 in 2019) acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1120 m of Proterozoic sedimentary rocks unconformably overlain by 630 m of Cambrian Georgina Basin carbonates. Continuous cores recovered from 283 m to a total depth of 1751 m. Geoscience Australia conducted an extensive post-drilling analytical program that generated over 30 datasets which the interested reader can find under the EFTF webpage (under the "Data and publications" drop down menu) at https://www.eftf.ga.gov.au/south-nicholson-national-drilling-initiative This record links to the Exploring for the Future 'borehole completion report' for NDI Carrara 1 and access to all on-site downhole geophysical datasets.

<div>New SHRIMP U-Pb detrital zircon geochronology on Mesoproterozoic and Paleoproterozoic siliciclastic rocks from the South Nicholson region, in concert with recently acquired complementary regional geophysical datasets, has enabled comprehensive revision of the regional Proterozoic tectono-stratigraphy. The identification of analogous detrital zircon spectra between units deposited in half-graben hanging walls of major ENE-WSW trending extensional faults, the Benmara, Bauhinia, and Maloney-Mitchiebo faults, offers compelling evidence for regional tectono-stratigraphic correlation. Units sampled from the hanging walls of these faults are characterised by immature proximal lithofacies and host a small yet persistent population of <em>ca</em> 1640–1650 Ma aged zircon and lack Mesoproterozoic detritus, consistent with deposition coincident with extension during the River Extension event at <em>ca</em> 1640 Ma, an event previously identified from the Lawn Hill Platform in western Queensland. This finding suggests the hanging wall sequences are chrono-stratigraphically equivalent to the highly prospective sedimentary rocks of the Isa Superbasin, host to world-class sediment-hosted base metal deposits across western Queensland and north-eastern Northern Territory. Subsequent inversion of the extensional faults, resulted in development of south-verging thrusts, and exhumation of late Paleoproterozoic hanging wall siliciclastic rocks through overlying Mesoproterozoic South Nicholson Group rocks as fault propagated roll-over anticlines. These geochronology data and interpretations necessitate revision of the stratigraphy and the renaming of a number of stratigraphic units in the South Nicholson region. Accordingly, the distribution of the highly prospective late Paleoproterozoic units of the McArthur Basin, Lawn Hill Platform and Mount Isa Province is greatly expanded across the South Nicholson region. These findings imply that the previously underexplored South Nicholson region is a highly prospective greenfield for energy and mineral resources.</div> <b>Citation:</b> C. J. Carson, N. Kositcin, J. R. Anderson & P. A. Henson (2023) A revised Proterozoic tectono-stratigraphy of the South Nicholson region, Northern Territory, Australia—insights from SHRIMP U–Pb detrital zircon geochronology, <i>Australian Journal of Earth Sciences,</i> DOI: 10.1080/08120099.2023.2264355

Australia remains underexplored or unexplored, boasting discovery potential in the mineral, groundwater, and energy resources hidden beneath the surface. These “greenfield” areas are key to Australia’s future prosperity and sustainability. Led by Geoscience Australia, Australia’s national government geoscience organisation, the Exploring for the Future program was a groundbreaking mission to map Australia’s mineral, energy, and groundwater systems in unparalleled scale and detail. The program has advanced our understanding of Australia’s untapped potential. Over the course of 8 years, the Exploring for the Future program provided a significant expansion of public, precompetitive geoscience data and information, equipping decision-makers with the knowledge and tools to tackle urgent challenges related to Australia’s resource prosperity, energy security, and groundwater supply.

<div>The National Geochemical Survey of Australia (NGSA) is Australia’s only internally consistent, continental-scale geochemical atlas and dataset. The present dataset contains additional mineralogical data obtained on NGSA samples selected from the Barkly-Isa-Georgetown (BIG) region of northeastern Australia for the second partial data release of the Heavy Mineral Map of Australia (HMMA) project. The HMMA project, a collaborative project between Geoscience Australia and Curtin University underpinned by a pilot project establishing its feasibility, is part of the Australian Government-funded Exploring for the Future (EFTF) program.</div><div>One-hundred and eighty eight NGSA sediment samples were selected from the HMMA project within the EFTF’s BIG polygon plus an approximately one-degree buffer. The samples were taken on average from 60 to 80 cm depth in floodplain landforms, dried and sieved to a 75-430 µm grainsize fraction, and the contained heavy minerals (HMs; i.e., those with a specific gravity > 2.9 g/cm3) were separated by dense fluids and mounted on cylindrical epoxy mounts. After polishing and carbon-coating, the mounts were subjected to automated mineralogical analysis on a TESCAN® Integrated Mineral Analyzer (TIMA). Using scanning electron microscopy and backscatter electron imaging integrated with energy dispersive X-ray analysis, the TIMA identified 151 different HMs in the BIG area. The dataset, consisting of over 18 million individual mineral grains, was quality controlled and validated by an expert team. The data released here can be visualised, explored and downloaded using an online, bespoke mineral network analysis (MNA) tool built on a cloud-based platform. Preliminary analysis suggests that copper minerals cuprite and chalcopyrite may be indicative of base-metal/copper mineralisation in the area. Accompanying this report are two data files of TIMA results, and a minerals vocabulary file. </div><div>When completed in 2023, it is hoped the HMMA project will positively impact mineral exploration and prospectivity modelling around Australia, as well as have other applications in earth and environmental sciences.</div>