<p>Northern Australia contains extensive Proterozoic-aged sedimentary basins with potential energy, mineral, and groundwater resources concealed beneath the surface. The region is remote and largely underexplored with limited data and infrastructure and therefore is considered to have high exploration risk. Exploration for hydrocarbons and basin-hosted base metals, although perceived to have very different exploration models, share a number of important similarities and key parameters. Foremost amongst these is shale geochemistry since the same reduced, organic-rich shales are both a hydrocarbon source rock and a depositional site for base metal mineralisation. Furthermore, anoxic and euxinic (anoxic with free hydrogen sulfide, H2S) water column and sediments are important for both the preservation of organic matter and as a H2S reservoir needed for precipitation of ore minerals after reaction with oxic metalliferous brines. Here we present new organic and inorganic geochemical datasets for shales in the South Nicholson Basin, Lawn Hill Platform and greater McArthur Basin, including the organic-richness of shales and the inorganic geochemistry of redox-sensitive trace metals, to demonstrate changes in water-column chemistry and favourable base metals depositional sites. Parameters such as total organic carbon (TOC) content and redox-sensitive elemental concentrations are used to identify prospective packages with hydrocarbon and base metals mineral resource potential <p>The results reveal many units in the Lawn Hill Platform, South Nicholson Basin and greater McArthur Basin contain organic-rich rocks. A cut-off value of TOC ≥ 2 wt% is used to define several shale and carbonate sequences in the region that are favourable for both hydrocarbon generation and as base metals depositional sites. Inorganic geochemistry results demonstrate a range of paleoredox conditions, from predominantly anoxic, ferruginous conditions with deviations, to sub-oxic and euxinic conditions. Future work mapping the temporal and spatial distribution of this geochemistry, in combination with other mappable geological criteria, is required to create mineral and petroleum systems models that can define prospective fairways across the basins and increase our understanding of resource potential. <p>The precompetitive data generated in this study highlight the utility of shared geochemical datasets for resource exploration in the region. More broadly, this study improves our understanding of the energy and mineral potential across northern Australia, supporting resource decision-making and investment.

The Exploring for the Future program is an initiative by the Australian Government dedicated to boosting investment in resource exploration in Australia. As part of the Exploring for the Future program, this study aims to improve our understanding of the petroleum resource potential of northern Australia. This data release presents the bulk kerogen kinetics of 21 potential source rocks from the McArthur Basin and the Lawn Hill Platform to understand the rate of hydrocarbon conversion. Kerogen was isolated from bulk rock, and analysed by a Rock-Eval 6 (Vinci Technologies, France) using four different temperature ramps. All sample preparation and analyses were carried out in Geoscience Australia’s in-house laboratories. The results of this study can be used to improve our understanding of the hydrocarbon generative potential of Proterozoic aged source rocks in northern Australia.

The Mesoproterozoic Roper Group of the McArthur Basin has excellent petroleum potential but exploration has been hampered by poor constraints on its post-depositional history that has compromised understanding of the tectonostratigraphic evolution of the basin. The Derim Derim Dolerite occupies an important position in the event chronology of the McArthur Basin, having intruded the Roper Group prior to post-Roper basin inversion, and it is also a major component of Mesoproterozoic intraplate mafic magmatism in northern Australia. Since 1997, the Derim Derim Dolerite has been assigned a magmatic crystallisation age of 1324 ± 4 Ma (all uncertainties are 95% confidence), based on unpublished Sensitive High Resolution Ion Micro Probe (SHRIMP) U–Pb analyses on baddeleyite attributed to a dolerite sample from Bureau of Mineral Resources drill-hole Urapunga 5. Herein, we establish that the SHRIMP sample originated from the type locality of the Derim Derim Dolerite in outcrop 90 km northwest of Urapunga 5 and document the 207Pb/206Pb date interpreted from the 1997 dataset. New U–Pb SHRIMP reanalysis of the same grain-mounts yielded a mean 207Pb/206Pb date of 1320.1 ± 5.3 Ma, confirming the 1997 result, and Isotope Dilution-Thermal Ionisation Mass Spectrometry (ID TIMS) analysis of baddeleyites plucked from the mounts yielded a precise mean 207Pb/206Pb date of 1327.5 ± 0.6 Ma. This date is significantly older than a baddeleyite U–Pb ID-TIMS date of ca 1313 Ma recently reported elsewhere from dolerite in the Beetaloo Sub-basin 200 km to the south, indicating that magmatism attributed to the Derim Derim Dolerite spanned at least 10–15 Ma. Previously documented geochemical variation in Mesoproterozoic intraplate mafic rocks across the Northern Territory (such as the 1325 ± 36 Ma Galiwinku Dolerite in the McArthur Basin, 1316 ± 40 Ma phonolites in the Nimbuwah Domain of the eastern Pine Creek Orogen, and 1295 ± 14 Ma gabbro in the Tomkinson Province) may reflect episodic pulses of magmatism hitherto obscured by the low precision of the available isotopic dates. The timing and geochemistry of Derim Derim-Galiwinku mafic igneous activity is strikingly similar to that of the Yanliao Large Igneous Province (LIP) in the northern North China Craton, and the global paucity of 1330–1300 Ma LIPs suggests that the North Australian Craton and the North China Craton were in relatively close proximity at that time.

Mineral exploration in Australia faces the challenge of declining discovery rates despite continued exploration investment. The UNCOVER roadmap, developed by stakeholders from industry, government and academia, has highlighted the need for discovering mineral resources in areas of cover. In these areas, potentially prospective basement is covered by regolith, including transported sediment, challenging many traditional exploration methods designed to probe outcrop or shallow subcrop. Groundwater-mineral interaction in the subsurface has the potential to give the water geochemical and isotopic characteristics that may persist over time and space. Geoscience Australia’s hydrogeochemistry for mineral exploration project, part of the Exploring for the Future Programme, aims to use groundwater chemistry to better understand the bedrock-regolith system and develop new methods for recognising mineral system footprints within and below cover. During the 2017 dry season (May to September), ~150 groundwater samples (including QC samples) were collected from pastoral and water supply bores in the regions of Tennant Creek and McArthur River, Northern Territory. The Tennant Creek region has a demonstrated iron oxide-hosted copper-gold-iron(-bismuth) mineral potential in the Paleoproterozoic and Mesoproterozoic basement and vast areas of regolith cover. Among the critical elements of this mineral system, the presence/absence of redox contrasts, iron enrichment, presence of sulfide minerals, and carbonaceous intervals can potentially be diagnosed by the elemental and isotopic composition of groundwater. The McArthur River region, in contrast, has demonstrated sediment-hosted stratiform lead-zinc-silver mineral potential in the Paleoproterozoic to Neoproterozoic basement and also vast areas of regolith cover. Here, critical mineral system elements that have the potential to be identified using groundwater geochemistry include the presence of felsic rocks (lead source), carbonate rocks (zinc source), basinal brines, dolomitic black shales (traps), and evaporite-rich sequences. Preliminary results will be presented and interpreted in the context of these mineral systems.

The ca. 1.4 billion years (Ga) old Roper Group of the McArthur Basin, northern Australia, is one of the most extensive Proterozoic hydrocarbon-bearing basins deposited in a large epeiric sea known as the Roper Seaway. Black shales from the Velkerri Formation were deposited in a deep water shoaling sequence and are well preserved in the Altree 2 drillcore in the Beetaloo Sub-basin. These shales were analysed to determine their organic geochemical (biomarker) signatures which were used to interpret the microbial diversity and palaeoenvironment of the Roper Seaway. The results were integrated with published inorganic geochemistry and microfossil distributions. The indigenous hydrocarbon biomarker assemblages describe a water column dominated by bacteria with large scale heterotrophic reworking of the organic matter in the water column or bottom sediment. Evidence for microbial reworking includes a large unresolved complex mixture (UCM) and high ratios of monomethyl alkanes relative to n-alkanes—features characteristic of indigenous Proterozoic bitumen. Steranes, biomarkers for single-celled and multicellular eukaryotes, were below detection limits in all extracts analysed, despite eukaryotic microfossils having been previously identified in the Roper Group. These data suggest that eukaryotes, while present in the Roper Seaway, were ecologically restricted and contributed little to the net biomass. The combination of increased dibenzothiophene in the middle Velkerri Formation and low concentrations of 2,3,6-trimethyl aryl isoprenoids throughout the Velkerri Formation suggest that the water column at the time of deposition was transiently euxinic. As a comparison we reanalysed extracts from the 1.64 Ga Barney Creek Formation of the McArthur Basin. The biomarker assemblages differ between the Velkerri and Barney Creek Formations between is a biomarkers and water column chemistry, demonstrating that the microbial environments and water column geochemistry were variable in the Proterozoic.

The Exploring for the Future program is an initiative by the Australian Government dedicated to boosting investment in resource exploration in Australia. As part of the Exploring for the Future program, this study aims to improve our understanding of the petroleum resource potential of northern Australia. The physical properties of organic matter in sedimentary rocks changes composition in an irreversible and often sequential manner after burial, diagenesis, catagenesis and metagenesis with increasing thermal maturity. Characterising these changes and identifying the thermal maturity of sedimentary rocks is essential for calculating thermal models needed in a petroleum systems analysis. This study presents organic petrology on 15 Proterozoic aged shales from the Velkerri and Barney Creek formations in the McArthur Basin and the Mullera Formation, Riversleigh Siltstone, Lawn Hill and Termite Range formations in the South Nicholson region. Qualitative maceral analysis of the 15 samples are described in addition to bitumen reflectance measurements. These samples were analysed at the Montanuniversität Leoben, Austria in June 2020. The results of this study can be used to improve our understanding of the thermal maturity and hydrocarbon prospectivity of Proterozoic aged sedimentary basins in northern Australia.

The ca. 1.4 Ga Roper Group of the greater McArthur Basin in northern Australia comprises the sedimentary fill of one of the most extensive Precambrian hydrocarbon-bearing basins preserved in the geological record. It is interpreted to have been deposited in a large epeiric sea known as the Roper Seaway. Trace element data suggest that the redox structure of the basin was a shallow oxic layer overlying deeper suboxic to anoxic waters along with a prominent episode of euxinia. These anoxic and sulfidic conditions, as inferred by redox sensitive trace element (TE) abundances, (molybdenum, vanadium and uranium), developed due to high organic carbon loading consistent with models that suggest that euxinic conditions cannot develop until the flux of organic matter is significantly greater than the flux of bioavailable iron (Fe³⁺), which permits sulphate reduction to proceed. Considering the high reactive iron and molybdenum contents of these shales and the requirement for S/Fe ratios >2 for euxinia to develop, suggest sufficient atmospheric O₂ was available for oxidative scavenging of S and Mo from the continents. This is further supported by prominent negative cerium anomalies within these shales, indicative of active oxidative redox cycling of cerium. We propose that the high organic matter flux was the result of increased nutrient loading to the Roper Seaway from weathering of the continental hinterland. Data from both major and high-field strength elements (niobium, tantalum, zirconium and, hafnium) together with neodymium isotopes (¹⁴³Nd/¹⁴⁴Nd) indicate that a likely mechanism for this enhanced nutrient delivery was a shift in sedimentary provenance to a more primitive (i.e. mafic) precursor lithology. This switch in provenance would have increased phosphorus delivery to the Roper Seaway, contributing to high primary productivity and the onset of euxinia. This dataset and model serve as a basis for understanding the temporal evolution of the deepest sections of the Roper Seaway and finer scale changes in the environment at this time. <b>Citation:</b> Grant M. Cox, Amber Jarrett, Dianne Edwards, Peter W. Crockford, Galen P. Halverson, Alan S. Collins, André Poirier, Zheng-Xiang Li, Basin redox and primary productivity within the Mesoproterozoic Roper Seaway, <i>Chemical Geology</i>, Volume 440, 2016, Pages 101-114, ISSN 0009-2541, https://doi.org/10.1016/j.chemgeo.2016.06.025.

Following the publication of Geoscience Australia record 2014/09: Petroleum geology inventory of Australia's offshore frontier basins by Totterdell et. al, (2014), the onshore petroleum section embarked upon a similar project for onshore Australian basins. The purpose of this project is to provide a thorough basis for whole of basin information to advise the Australia Government and other stakeholders, such as the petroleum industry, regarding the exploration status and prospectivity of onshore Australian basins. Eight onshore Australian basins have been selected for this volume and these include: the McArthur, South Nicholson, Georgina, Amadeus, Warburton, Wiso, Galilee and Cooper basins. This record provides a comprehensive whole of basin inventory of the geology, petroleum systems, exploration status and data coverage for these eight onshore Australian basins. It draws on precompetitive work programs by Geoscience Australia as well as publicly available exploration results and geoscience literature. Furthermore, the record provides an assessment of issues and unanswered questions and recommends future work directions to meet these unknowns.

<p>The Mesoproterozoic Roper Group of the McArthur Basin has excellent petroleum potential, but its poorly constrained post-depositional history has hampered resource exploration and management. The Derim Derim Dolerite occupies an important position in the regional event chronology, having intruded the Roper Group prior to deformation associated with the ‘Post-Roper Inversion’ event. It was assigned a magmatic crystallisation age of 1324 ± 4 Ma (uncertainties are 95% confidence unless otherwise indicated) in 1997, based on unpublished Sensitive High Resolution Ion Micro Probe (SHRIMP) U-Pb analyses of dolerite-hosted baddeleyite from sample 97106010, collected from the Derim Derim Dolerite type locality in outcrop within the northwestern McArthur Basin. Herein, we refine these data via Isotope Dilution-Thermal Ionisation Mass Spectrometry (ID-TIMS) analysis of baddeleyites plucked from the SHRIMP grain-mounts, which yielded a precise mean 207Pb/206Pb date of 1327.5 ± 0.6 Ma. This date is significantly older than a baddeleyite U-Pb ID-TIMS date of 1313.8 ± 1.3 Ma recently obtained from dolerite ALT-05, sampled in Pacific Oil and Gas Ltd drillhole Altree 2, near the northern margin of the Beetaloo Sub-basin, and 200 km south of 97106010. This pair of results indicates that Derim Derim Dolerite magmatism spanned at least 10-15 Ma. Previously documented geochemical variation in Mesoproterozoic mafic rocks across the Northern Territory (such as the 1325 ± 36 Ma (2σ) Galiwinku Dolerite in the northern McArthur Basin, 1316 ± 40 Ma phonolites intruding the eastern Pine Creek Orogen, and 1295 ± 14 Ma gabbro in the Tomkinson Province) may reflect episodic pulses of magmatism hitherto obscured by the low precision of the available isotopic dates. <p><b>Citation:</b> Bodorkos, S., Yang, B., Collins, A.S., Crowley, J., Denyszyn, S.W., Claoue-Long, J.C., Anderson, J.R. and Magee, C., 2020 Precise U–Pb baddeleyite dating of the Derim Derim Dolerite: evidence for episodic mafic magmatism in the greater McArthur Basin. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

Legacy dataset from the NABRE Project, comprising multi-spectral gamma logs obtained on different drill core in the Mount Isa Province to McArthur Basin regions (Northern Territory and Queensland).