Few published studies have demonstrated that coals have sourced significant volumes of oil, while none have clearly implicated coals in the Australian context. This paper presents strong geochemical evidence for coals being the source for the sub-economic oil accumulations in the Bass Basin. Oils in the Bass Basin form a single oil population. Biodegradation of Cormorant oil results in a separate oil family compared to Pelican and Yolla crudes. Oil-to-source correlation based on biomarkers and carbon isotopes shows that the Early Eocene to Palaeocene coals are effective source rocks in the Bass Basin. This is in contrast to previous work which favoured disseminated organic matter in claystone as the sole source (Miyazaki, 1995). Potential oil-prone source rocks in the Bass Basin are the early Tertiary coals, mainly concentrated in the Middle to Early Eocene succession. These coals have hydrogen indices (HI) up to 500 mg HC/gTOC) and are associated with disseminated organic matter in claystones that are mainly gas prone. Maturity is sufficient for oil and gas generation with vitrinite reflectance (VR) up to 1.8 % at base of Pelican-5. Igneous intrusions, mainly within Palaeocene, Oligocene and Miocene sediments, produce localised elevated maturity to 5 % VR. The key events in the process of petroleum generation and migration from the effective coaly source rocks in the Bass Basin are: (i) the onset of oil generation at a VR of 0.65 % (2450m in Pelican-5); (ii) the onset of expulsion (primary migration) at a VR of 0.75 % (2700 to 3200m in Bass Basin; 2850m in Pelican-5); (iii) the main oil window between VR of 0.75 % and 0.95 % (2850-3300m in Pelican-5); and, (iv) the main gas window at VR >1.2 % (>3650m in Pelican-5).

D/H ratios of terrestrially-sourced whole oils and their respective saturated, aromatic, and polar fractions, individual n-alkanes, formation waters and non-exchangeable hydrogen in kerogen were measured from source rocks from seven Australian petroleum basins. Data for 75 oils and condensates, their sub-fractions, and 52 kerogens indicate that oil sub-fractions have deltaD values comparable to deltaDoil, with a deltadeltaD offset (deltaDkerogen - deltaDoil) averaging ca. 23?. The weighted-average deltaD of individual n-alkanes is usually identical to deltaDoil and deltaDsaturate. A trend of increasing deltaD with n-alkane chain length in most oils causes individual n-alkanes from an oil to vary in deltaD by 30? or more. A modest correlation between deltaD for aromatic sub-fractions and formation waters indicates that about 50% of aromatic C-bound H has exchanged with water. In contrast, deltaDoil and deltaDsaturated show no evidence for H-exchange with formation water under reservoir conditions at temperatures up to 150 oC. Acyclic isoprenoids and n-alkanes show essentially indistinguishable deltaD, indicating that primary isotopic differences from biosynthesis have been erased. Overall, extensive exchange of C-bound H in petroleum with other hydrogen is apparent, but seems to have affected most hydrocarbons only during their chemical genesis from precursor molecules. Our isotopic findings from terrestrial-sourced oils should be qualitatively relevant for marine oils as well.

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The molecular composition of fluid inclusion (FI) oils from Leander Reef-1, Houtman 1 and Gage Roads-2 provide evidence of the origin of palaeo-oil accumulations in the offshore Perth Basin. These data are complemented by compound specific isotope (CSI) profiles of n-alkanes for the Leander Reef-1 and Houtman-1 samples, which were acquired on purified n-alkane fractions gained by micro-fractionation of lean FI oil samples, showing the technical feasibility of this technique. The Leander Reef-1 FI oil from the top Carynginia Formation shares many biomarker similarities with oils from the Dongara and Yardarino oilfields, which have been correlated with the Early Triassic Kockatea Shale. However, the heavier isotopic values for the C15-C25 n-alkanes in the Leander Reef-1 FI oil indicate that it is a mixture, and suggest that the main part of this oil (~90%) was sourced from the more terrestrial and isotopically heavier Early Permian Carynginia Formation or Irwin River Coal Measures. This insight would have been precluded when looking at molecular evidence alone. The Houtman-1 FI oil from the top Cattamarra Coal Measures (Middle Jurassic) was sourced from a clay-rich, low sulphur source rock with a significant input of terrestrial organic matter, deposited under oxic to suboxic conditions. Biomarkers suggest sourcing from a more prokaryotic-dominated facies than for the other FI oils, possibly a saline lagoon. The Houtman-1 FI oil ?13C CSI data are similar to data acquired on the Walyering-2 oil. Possible lacustrine sources include the Early Jurassic Eneabba Formation or the Late Jurassic Yarragadee Formation. The low maturity Gage Roads-2 FI oil from the Carnac Formation (Early Cretaceous) was derived from a strongly terrestrial, non-marine source rock containing a high proportion of Araucariacean-type conifer organic matter. It has some geochemical differences to the presently reservoired oil in Gage Roads-1, and was probably sourced from the Early Cretaceous Parmelia Formation.

Petroleum accumulations have been discovered in the Bonaparte, Browse and Carnarvon basins over the last fifty years. However, a regional synthesis of the geochemistry of these North West Shelf hydrocarbons has not been published. To address this, this study documents the biomarker and isotopic analyses of ~300 North West Shelf oils/condensate samples that have been statistically characterised into genetically related families. Carbon and hydrogen isotopic signatures of ~50 gas samples, together with existing molecular data for ~1000 gas samples, show regional trends in wetness and abundance of non-combustible gases. These petroleum accumulations can be attributed to source rocks of Early Carboniferous, Permian, Triassic, Jurassic and Early Cretaceous age; however, most economic oil and gas accumulations are sourced from Mesozoic (Triassic Jurassic) sediments. The oils produced from the Bonaparte (Vulcan Sub-basin, northern Bonaparte) and Carnarvon (Dampier, Barrow and Exmouth sub-basins) basins are geochemically similar, being sourced from Late Jurassic marine rift-fill sediments (lower Vulcan Formation/Dingo Claystone) that contain variable amounts of terrigenous (particularly gymnosperm-derived) organic matter. Variations in their biomarker signatures can be explained by maturity differences, multiple charging and secondary alteration processes. Gas produced from the northern Rankin Platform is predominantly sourced from Triassic Jurassic fluvio-deltaic sediments. Proven and potential supergiant and giant gas accumulations occur in the deepwater areas of the North West Shelf. Case studies focussing on the geochemistry of the outer Browse (Scott Reef trend) and Carnarvon (deepwater Exmouth Plateau and Rankin Platform) gas accumulations will be presented with emphasis on d13C and d2H isotopic data.

An inverted phase (polar to non-polar) column set has been compared with a non-polar to polar column set for the GC-GC separation of petroleum hydrocarbons crude oil. This is shown to provide greatly enhanced resolution for less polar compounds and makes greater use of the two-dimensional separation space. This column configuration improves resolution of a greater number of components within one analysis and offers new possibilities for crude oil fingerprinting.

Exploration for Unconventional Hydrocarbons in Australia reached a new milestone when Beach Energy announced the first successful flow test of a shale gas target in the Cooper Basin. The ever expanding coal seam gas industry on Australia's east coast in addition to the large resource potential of shale and tight gas in Australia's eastern basins has put Australia firmly on the radar of many local and international exploration companies. Over the next 12 months Geoscience Australia in collaboration with its counterparts in the State and Territory resource and energy departments will begin an assessment of Australia's coal seam gas, shale gas and oil and tight gas resource potential. Capitalising on decades of high quality geological data held by the Commonwealth and the States and Territories, the aim of this collaboration is to develop nationally consistent assessment methodologies and provide robust national resource estimates in an internationally accepted standard. Overall, the programme aims to answer the 'where' and 'how much' questions for government, as well as provide this new industry with pre-competitive data and tools for comparing exploration opportunities. The immediate goal is to provide a first-pass, high level estimate of the likely resource volumes, which will be reported in the second edition of the Australian Energy Resource Assessment (published by RET). The longer term work program aims to assess Australia's onshore basins in terms of their resource potential and provide pre-competitive data to industry. To achieve this, several geological techniques will be applied including, but not limited to, geochemical screening, mapping of source rock occurrences and their distributions as well as physical rock property studies.

This report is a post-drill assessment of wells drilled in the Neoproterozoic to Palaeozoic Arafura Basin and the overlying Mesozoic to Cenozoic Money Shoal Basin. The Arafura Basin is located offshore northern Australia and extends from the onshore Northern Territory to beyond the Australian-Indonesian border. The region is under-explored with only 9 wells drilled, all of which are located in the central Goulburn Graben, a complexly structured feature. They include: Arafura-1, Chameleon-1, Cobra-1A, Kulka-1, Goulburn-1, Money Shoal-1, Tasman-1, Torres-1 and Tuatara-1. These wells have been analysed based on well completion reports, information from Geoscience Australia databases and published reports.

A wide variety of studies have been carried out around the Australian margin to infer or detect natural hydrocarbon seepage. Hydrocarbon seepage can, in selected geological settings, delineate subsurface petroleum accumulations and provide information on hydrocarbon charge type. However, the relationship between near-surface hydrocarbon seepage and subsurface petroleum generation and entrapment is often complex. Rates and volume of hydrocarbon seepage to the surface produce a variety of near-surface geological and biological responses, which require a range of sampling techniques to detect the seepage effectively. Interpreters must firmly grasp these issues to understand the significance of migrated hydrocarbons within near-surface sediments. Thus, it is important to understand the data types that have been used to infer seepage in Australia and the results of these studies, if natural hydrocarbon seepage is to be assumed in this region. Furthermore, the strengths and weaknesses of different approaches need to be understood and the data often need to be set in a global context to appreciate the significance of results obtained. This report is aimed at providing an overview of natural hydrocarbon seepage studies that have been carried out around Australia and to provide information on techniques and approaches that have proved to be successful during studies carried out by Geoscience Australian between 2004 and 2007. ... This investigation provides an increased understanding of seepage detection technologies and techniques, particularly in relation to the Australian environment, and appropriate interpretation of potential seepage indicators in a global context. Consequently, seepage studies can be undertaken with greater confidence in Australia's offshore jurisdiction, in locations and at times that are optimal for effective seepage detection.

This report contains data on the 68 petroleum accumulations discovered in the Bonaparte Basin to December 2002. It provides summaries of the regional setting, evolution and stratigraphy of the basin and discusses the hydrocarbon habitat and development of the producing accumulations. For the purpose of this report, a discrete, measured recovery of petroleum on test from an exploration well qualifies as a `discovery?. Petroleum accumulations inferred from wireline log interpretations (and where petroleum has not been recovered on test) are referred to as `shows?. Small quantities of gas recovered on test in three wells included in this report may represent `solution gas? - indicating these wells may not have intersected a petroleum pool.