Geoscience Australia’s Exploring for the Future (EFTF) program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to a low emissions economy, strong resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225m investment by the Australian Government. The deep stratigraphic drill hole, NDI Carrara 1 (~1751 m), was completed in December 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) recently acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1100 m of Proterozoic sedimentary rocks uncomformably overlain by 630 m of Cambrian Georgina Basin carbonates. This contractor report (FIT - Schlumberger) presents hydrocarbon and aqueous fluid inclusion petrology and data (micro-thermometry, salinities etc.) on four hydrocarbon-bearing calcite veins sampled from NDI Carrara 1 between 762.56-763.60 m depth, (under contract to, and fully funded by, Geoscience Australia as part of the Exploring for the Future program).

The Maldon gold deposit in central Victoria has geological, geochronological and fluid chemistry characteristics that distinguish it from typical vein-hosted, orogenic' gold deposits in this region. The deposit lies within the contact aureole of the Harcourt Granite and associated granitic dykes. The ore-bearing fluids are characterised by the presence of non-aqueous (i.e. carbonic) fluids, which exhibit complex freezing and heating behaviour, as well as mixed CO2-low-salinity aqueous fluids (mostly - 10 wt.% NaCl eq.). Raman analysis indicates that carbonic inclusions can vary from CO2-rich to CH4-rich, with N2 contents up to 38 mol.%. Higher-salinity brine inclusions, 20-22 wt.% NaCl eq., only occur locally. The Harcourt Granite is a moderately reduced, I-type granite and the reduced fluids (e.g. CH4-N2-rich) are believed to have formed within (or in close proximity to) thermal aureoles of the dykes or granites during contact metamorphism. This further supports the premise that the Maldon deposit is an 'orogenic' gold deposit that was metamorphosed and/or remobilised during the emplacement of post-orogenic intrusions/dykes. We conclude that some 'orogenic' gold deposits worldwide may have been completely overprinted by later magmatic/metamorphic events and are now only evident as reduced intrusion-related gold systems.

Fluid inclusion studies have been carried out on quartz veining from Jackson's Pit and Eva uranium mines and the Dianne and St Barb copper prospects in the Westmoreland region. Four types of inclusions have been observed. Type A, vapour-rich inclusions, contain 30 - 100 vol.% vapour with varying amounts of CO2 ± N2 ± CH4. Type B, liquid-rich inclusions, contain up to 30 vol.% vapour. Type C inclusions are liquid-only. Type D, three-phase (vapour + liquid + solid) liquid-rich inclusions, contain a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385°C. Other Type B and Type D inclusions typically homogenised between 100 and 240°C with a mode around 120°C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50°C. This may indicate three phases of fluid flow in the region with progressively cooling fluids. Eutectic melting temperatures as low as -79.8ºC in Type B and C inclusions suggest the presence of CaCl2 and other salts in the fluids. Final ice meeting temperatures for Type B and C inclusions fall into two groups. The first group has final melting temperatures below -10ºC while the second group shows final meeting above -10ºC and more typically close to 0ºC indicating the presence of low salinity fluids. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50°C.

In addition to typical seafloor VHMS deposits, the ~3240 Ma Panorama district contains contemporaneous greisen- and vein-hosted Mo-Cu-Zn-Sn occurrences that hosted by the Strelley granite complex, which drove VHMS circulation. High-temperature alteration zones in volcanic rocks underlying the VHMS deposits are dominated by quartz-chlorite±albite assemblages, with lesser low-temperature quartz-sericite±K-feldspar assemblages, typical of VHMS hydrothermal systems. Alteration assemblages associated with granite-hosted greisens and veins, which do not extend into the overlying volcanc pile, include quartz-topaz-muscovite-fluorite and quartz-muscovite(sericite)-chlorite-ankerite. Fluid inclusion and stable isotope data suggest that the greisens formed from high temperature (~590C), high salinity (38-56 wt % NaCl equiv) fluids with high densities (>1.3 g/cm3) and high -18O (9.3±0.6-), which are compatible with magmatic fluids evolved from the Strelley granite complex. Fluids in the volcanic pile (including the VHMS ore-forming fluids) were of lower temperature (90-270C), lower salinity (5.0-11.2 wt % NaCl equiv), with lower densities (0.88-1.01 g/cm3) and lower -18O (-0.8±2.6), compatible with evolved Paleoarchean seawater. Fluids that formed the quartz-chalcopyrite-sphalerite-cassiterite veins, which are present within the upper granite complex, were intermediate in temperature and isotopic composition (T = 240-315C; -18O = 4.3±1.5-) and are interpreted to indicate mixing between the two end-member fluids. Evidence of mixing between evolved seawater and magmatic-hydrothermal fluid in the granite complex, along with a lack of evidence for a magmatic component in fluids from the volcanic pile, suggest partitioning of magmatic-hydrothermal from evolved seawater hydrothermal systems in the Panorama VHMS system, interpreted as a consequence swamping of the system by evolved seawater or density contrasts.

This web-enabled system allows researchers to retrieve fluid inclusion data from anywhere in the world. The concept is to build a free and widely available web-based library of fluid properties for a range of geological fluids. The database is being developed as an "open" project, which intends to bring together researchers interested in the properties of geological fluids or fluid inclusions.

The Palaeoproterozoic Westmoreland region is located 1250 km southeast of Darwin. The Westmoreland region is flanked on the southeast by the Palaeoproterozoic Mt Isa Inlier and the Neoproterozoic South Nicholson Basin and in the northwest it is overlapped by Mesoproterozoic sediments of the McArthur Basin. The northern and southern ends of the McArthur basin share many geologic attributes including correlative stratigraphic rock types, which suggests that there is potential for unconformity-related uranium deposits in the southern McArthur basin and adjacent Westmoreland region. In fact, over fifty occurrences of uranium (some with minor gold) and copper mineralisation have been recorded in the Westmoreland region. Fluid inclusion studies have been carried out on selected uranium and copper prospects on the Northern Territory side of the Westmoreland region. Four types of inclusions have been observed, (Type A) Vapour-rich inclusions containing 30 - 100 vol.% vapour. Varying amounts of CO2 ± N2 ± CH4 have been detected in these inclusions, (Type B) Liquid-rich inclusions with up to 30 vol.% vapour, (Type C) Liquid-only inclusions, and (Type D) Three-phase (vapour + liquid + solid) liquid-rich inclusions containing a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385 °C and are thought to be related to early metamorphic events. Other Type B and Type D inclusions typically homogenised between 100 and 240 °C with a mode around 120 °C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50 °C. Eutectic melting temperatures indicate the presence of CaCl2 in the fluids but final melting temperatures show the presence of both high and low salinity brines. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50 °C.

The Paleoproterozoic Westmoreland region is located 1250 km southeast of Darwin. The Westmoreland region is flanked on the southeast by the Paleoproterozoic Mt Isa Inlier and the Neoproterozoic South Nicholson Basin and in the northwest it is overlapped by Mesoproterozoic sediments of the McArthur Basin. The northern and southern ends of the McArthur basin share many geologic attributes including correlative stratigraphic rock types, which suggests that there is potential for unconformity-related uranium deposits in the southern McArthur basin and adjacent Westmoreland region. In fact, over fifty occurrences of uranium (some with minor gold) and copper mineralisation have been recorded in the Westmoreland region. Fluid inclusion studies have been carried out on selected uranium and copper prospects on the Northern Territory side of the Westmoreland region. Four types of inclusions have been observed, (Type A) Vapour-rich inclusions containing 30 100 vol.% vapour. Varying amounts of CO2 ± N2 ± CH4 have been detected in these inclusions, (Type B) Liquid-rich inclusions with up to 30 vol.% vapour, (Type C) Liquid-only inclusions, and (Type D) Three-phase (vapour + liquid + solid) liquid-rich inclusions containing a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385 °C and are thought to be related to early metamorphic events. Other Type B and Type D inclusions typically homogenised between 100 and 240 °C with a mode around 120 °C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50 °C. Eutectic melting temperatures indicate the presence of CaCl2 in the fluids but final melting temperatures show the presence of both high and low salinity brines. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50 °C.

This report is a synopsis of research compiled and carried out within the Predictive Mineral Discovery CRC F3 project "Micrometallogeny of hydrothermal fluids". The F3 project's original objectives were: (1) Geology-driven terrain and ore fluids investigations to evaluate the chemistry and fluid processes within mineral systems in order to extend the focus of fluid studies beyond direct ore deposit analysis. (2) LAICPMS and PIXE technique and methodology development were techniques utilized throughout the project and methodologies were developed for their combined application. (3) Diamond-cell autoclave experiments component of the project was a scoping-collaboration in year one of F3 with the Museum of South Australia. (4) Database development and fusion with numerical modelling resulted in development of a web-based database for fluid inclusion research has been successful and is currently accessed at http://www.ga.gov.au/minerals/research/methodology/geofluids/flincs_about.jsp

Although the Canning Basin has yielded minor gas and oil within conventional and unconventional reservoirs, the relatively limited geological data available in this under-explored basin hinder a thorough assessment of its hydrocarbon potential. Knowledge of the Paleozoic Larapintine Petroleum Supersystem is restricted by the scarcity of samples, especially recovered natural gases, which are limited to those collected from recent exploration successes in Ordovician and Permo-Carboniferous successions along the margins of the Fitzroy Trough and Broome Platform. To address this shortcoming, gases trapped within fluid inclusions were analysed from 121 Ordovician to Permian rock samples (encompassing cores, sidewall cores and cuttings) from 70 exploration wells with elevated mud gas readings. The molecular and carbon isotopic compositions of these gases have been integrated with gas compositions derived from open-file sources and recovered gases analysed by Geoscience Australia. Fluid inclusion C1–C5 hydrocarbon gases record a snapshot of the hydrocarbon generation history. Where fluid inclusion gases and recovered gases show similar carbon isotopes, a simple filling history is likely; where they differ, a multicharge history is evident. Since some fluid inclusion gases fall outside the carbon isotopic range of recovered gases, previously unidentified gas systems may have operated in the Canning Basin. Interestingly, the carbon isotopes of the fluid-inclusion heavy wet gases converge with the carbon isotopes of the light oil liquids, indicating potential for gas–oil correlation. A regional geochemical database incorporating these analyses underpins our re-evaluation of gas systems and gas–gas correlations across the basin. <b>Citation:</b> Boreham, C.J., Edwards, D.S., Sohn, J.H., Palatty, P., Chen, J.H. and Mory, A.J., 2020. Gas systems in the onshore Canning Basin as revealed by gas trapped in fluid inclusions. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

The Palaeoproterozoic Murphy Inlier is situated at the southern end of the McArthur Basin in northern Australia. The inlier contains over 50 uranium, copper, tin and base metal occurrences. Fluid inclusion studies were carried out on samples of quartz veining from the uranium and copper deposits as well as from the basement rocks to determine the composition of the fluids and to investigate how uranium and copper were transported in these fluids. Four types of fluid inclusions were observed in this study; Type A vapour-rich inclusions with 30 vol.% vapour, Type B two phase aqueous inclusion with - 20 vol.% vapour, Type C multiphase inclusions with one or more solid phases and, Type D liquid-only inclusions. At least three different fluids were identified in the Murphy Inlier. The first is a high temperature fluid denoted by Types A and B inclusions which homogenise over the range from 220 to 380 ºC. In the basement rocks, this fluid is enriched in N2 indicating that it may be related to metamorphic processes. In the uranium deposits this fluid is dominated by CO2 indicating that these fluids are relatively oxidized, while in the copper deposits both CO2 and CH4 are present indicating that these fluids are more reduced than in the regions of uranium mineralisation. The second fluid is a NaCl-rich with salinities ranging from 0.2 to 29.8 mass % NaCl and the third fluid is CaCl2-rich with salinities ranging from 0.1 to 24.7 mass % CaCl2. There is also evidence for fluid mixing between the NaCl-rich and CaCl2-rich end member fluids.