<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources.&nbsp;&nbsp;By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential.&nbsp;</div><div><br></div><div>The Paleo to Mesoproterozoic Birrindudu Basin is an underexplored frontier basin located in northwestern Northern Territory and northeastern Western Australia. The Birrindudu Basin is a region of focus for the second phase of the EFTF program (2020–2024) as it contains strata of similar age to the prospective McArthur Basin, South Nicholson region and Mount Isa Province, but remains comparatively poorly understood.&nbsp;Geoscience Australia, in collaboration with the Northern Territory Geological Survey is acquiring isotopic, geochronological, geochemical and geomechanical data from drillholes intersecting the Birrindudu Basin as part of phase two of EFTF. </div><div><br></div><div>This report presents results on selected rock samples from the Birrindudu Basin, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include:</div><div>1.&nbsp;&nbsp;&nbsp;&nbsp;Carbon (δ13C), oxygen (δ18O) and strontium (87Sr/86Sr) isotopes on carbonate-bearing samples, and</div><div>2.&nbsp;&nbsp;&nbsp;&nbsp;Trace element data on the leachates prepared for 87Sr/86Sr ratio analyses.</div>

<div>The bulk rock stable isotopes database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the stable isotopic composition of sedimentary rocks with an emphasis on calcareous rocks and minerals sampled from boreholes and field sites. The stable isotopes of carbon, oxygen, strontium, hydrogen, nitrogen, and sulfur are measured by various laboratories in service and exploration companies, Australian government institutions, and universities, using a range of instruments. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and the stable isotopes ratios. The carbon (¹³C/¹²C) and oxygen (¹⁸O/¹⁶O) isotope ratios of calcareous rocks are expressed in delta notation (i.e., &delta;¹³C and &delta;¹⁸O) in parts per mil (‰) relative to the Vienna Peedee Belemnite (VPDB) standard, with the &delta;¹⁸O values also reported relative to the Vienna Standard Mean Ocean Water (VSMOW) standard. Likewise, the stable isotope ratio of hydrogen (²H/¹H) is presented in delta notation (&delta;²H) in parts per mil (‰) relative to the VSMOW standard, the stable isotope ratio of nitrogen (¹⁵N/¹⁴N) is presented in delta notation (&delta;¹⁵N) in parts per mil (‰) relative to the atmospheric air (AIR) standard, and the stable isotope ratio of sulfur (³⁴S/³²S) is presented in delta notation (&delta;³⁴S) relative to the Vienna Canyon Diablo Troilite (VCDT) standard. For carbonates, the strontium (⁸⁷Sr/⁸⁶Sr) isotope ratios are also provided.</div><div><br></div><div>These data are used to determine the isotopic compositions of sedimentary rock with emphasis on the carbonate within rocks, either as minerals, the mineral matrix or cements. The results for the carbonate rocks are used to determine paleotemperature, paleoenvironment and paleoclimate, and establish regional- and global-scale stratigraphic correlations. These data are collated from Geoscience Australia records, destructive analysis reports (DARs), well completion reports (WCRs), and literature. The stable isotope data for sedimentary rocks are delivered in the Stable Isotopes of Carbonates web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>

<div>NDI Carrara&nbsp;1 is a 1751 m stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI). This campaign was a collaboration between Geoscience Australia under the Exploring for the Future program, together with MinEx CRC and the Northern Territory Geological Survey. It is the first drillhole to intersect Proterozoic rocks of the Carrara Sub-basin, a recently discovered depocentre in the South Nicholson region. The drill hole intersected ~625 m of the Paleozoic Georgina Basin, which overlies ~1120 m of Proterozoic carbonates, black shales and siliciclastic rocks, with hydrocarbon shows encountered in both the Paleozoic and Proterozoic sections. Following the completion of the drillhole, a comprehensive analytical program was carried out by Geoscience Australia to better understand the geology of the Carrara Sub-basin and its resource potential.</div><div><br></div><div>Here we present new high-resolution strontium (87Sr/86Sr), carbon (δ13C) and oxygen (δ18O) isotope data from carbonate bearing samples of the Paleozoic Georgina Basin and the Proterozoic Lawn Hill Formation intersected in NDI Carrara&nbsp;1. The aim of this data acquisition was to provide an improved understanding of the paleo-depositional environments and local/global chemostratigraphy trends recorded in the Carrara Sub-basin. </div><div><br></div><div>The majority of samples show significant alteration and thus caution should be exercised when using this data for assessing primary depositional conditions and contemporary sea-water chemistry. Despite the altered nature of most samples, samples belonging to undifferentiated Georgina Basin preserve 87Sr/86Sr ratios close to that of mid-Cambrian seawater, indicating the sampled intervals of Georgina Basin were likely connected to the global Cambrian ocean.&nbsp;Two small positive δ13C excursions (with positive shift in δ18O) within Georgina Basin samples may coincide with reported mid-Cambrian positive δ13C global marine excursions. </div><div><br></div><div>The least altered samples from the Proterozoic Lawn Hill Formation show more radiogenic 87Sr/86Sr values than the expected value of coeval mid-Proterozoic ocean at ~1600 Ma. These radiogenic 87Sr/86Sr values may reflect (i) influx of terrigenous material into a restricted basin with reduced interaction with the global ocean, or (ii) secondary overprinting by more radiogenic diagenetic fluids.</div> Abstract/Poster submitted and presented at 2023 Australian Earth Science Convention (AESC), Perth WA (https://2023.aegc.com.au/)

<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources.</div><div><br></div><div>In order to gain insights into the resource potential of the South Nicholson region, a key region of focus for EFTF, National Drilling Initiative (NDI) Carrara&nbsp;1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS), and the MinEx CRC. NDI Carrara&nbsp;1 is the first drill hole to intersect the, as yet, undifferentiated Proterozoic rocks of the newly defined Carrara Sub-Basin within the South Nicholson region. NDI Carrara&nbsp;1 is located on the western flank of the Carrara Sub-basin, reaching a total depth of 1751&nbsp;m, intersecting ca. 630&nbsp;m of Cambrian Georgina Basin overlying ca. 1100&nbsp;m of Proterozoic carbonates, black shales and minor siliciclastics.</div><div><br></div><div>Geoscience Australia is undertaking a range of investigations on the lithology, stratigraphy and geotechnical properties of NDI Carrara&nbsp;1 based on wireline data, as well as undertaking a range of analyses of over 400 physical samples recovered through the entire core. These analyses include geochronology, isotopic studies, mineralogy, inorganic and organic geochemistry, petrophysics, geomechanics, thermal maturity, and petroleum systems investigations. Hylogger™ data is available at the NTGS Geoscience Exploration and Mining Information System (GEMIS) webpage.</div><div><br></div><div>This data release presents results for analyses on selected rock samples from NDI Carrara 1, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include:</div><div><br></div><div>1.&nbsp;&nbsp;&nbsp;&nbsp;Carbon (δ13C), oxygen (δ18O) and strontium (87Sr/86Sr) isotopes on carbonate bearing samples, and</div><div>2.&nbsp;&nbsp;&nbsp;&nbsp;Trace element data on the leachates prepared for 87Sr/86Sr ratio analyses.</div><div><br></div>

<div>A minor update to Version 1.0: Lu Hf and O isotope data structure and delivery.</div><div><br></div><div>Isotopic data from rocks and minerals have the potential to yield unique insights into the composition and evolution of the Earth's crust and mantle. Time-integrated records of crust and mantle differentiation (as preserved by the U-Pb, Sm-Nd and Lu-Hf isotopic systems, for example) are important in a wide range of geological applications, especially when successfully integrated with other geological, geophysical, and geochemical datasets. However, such integration requires (i) compilation of comprehensive isotopic data coverages, (ii) unification of datasets in a consistent structure to facilitate inter-comparison, and (iii) easy public accessibility of the compiled and unified datasets in spatial and tabular formats useful and useable by a broad range of industry, government and academic users. This constitutes a considerable challenge, because although a wealth of isotopic information has been collected from the Australian continent over the last 40 years, the published record is fragmentary, and derived from numerous and disparate sources. Unlocking and harnessing the collective value of isotopic datasets will enable more comprehensive and powerful interpretations, and significantly broaden their applicability to Earth evolution studies and mineral exploration.</div><div><br></div><div>As part of the Exploring for the Future (EFTF) program (https://www.ga.gov.au/eftf), we have designed a new database structure and web service system to store and deliver full Lu-Hf isotope and associated O-isotope datasets, spanning new data collected during research programs conducted by Geoscience Australia (GA), as well as compiled literature data. Our approach emphasises the links between isotopic measurements and their spatial, geological, and data provenance information in order to support the widest possible range of uses. In particular, we build and store comprehensive links to the original sources of isotopic data so that (i) users can easily track down additional context and interpretation of datasets, and (ii) generators of isotopic data are appropriately acknowledged for their contributions.</div><div><br></div><div>This system delivers complete datasets including (i) full analytical and derived data as published by the original author, (ii) additional, normalised derived data recalculated specifically to maximise inter-comparability of data from disparate sources, (iii) metadata related to the analytical setup, (iv) a broad range of sample information including sampling location, rock type, geological province and stratigraphic unit information, and (v) descriptions of (and links to) source publications. The data is delivered through the Geoscience Australia web portal (www.portal.ga.gov.au), and can also be accessed through any web portal capable of consuming Open Geospatial Consortium (OGC)-compliant web services, or any GIS system capable of consuming Web Map Services (WMS) or Web Feature Services (WFS).</div><div><br></div><div>Version 1.0 of this Record (Waltenberg et al., 2021) described the database system and web service tables, and featured normalised Lu-Hf data that utilised CHondritic Uniform Reservoir (CHUR) parameters from Blichert-Toft and Albarède (1997). It also presented full tabulated datasets compiled from the North Australian Craton as part of the initial EFTF (2016–2020) program, comprising 5974 individual analyses from 149 unique rock samples. This update (version 1.1) enacts minor changes to some field names within the web services tables to ensure consistency with other web services offered by GA, and for normalised Lu-Hf data, it applies the CHUR parameters of Bouvier et al. (2008) to the entire dataset. The digital datasets presented by Waltenberg et al. (2021) have also been supplemented by more recent analyses collected as part of GA projects in Queensland and New South Wales, in collaboration with the relevant State geological surveys. Version 1.1 does not include an updated tabular data release; the digital dataset available via the web portal now comprises 7630 individual analyses from 180 unique rock samples.</div>