This report provides an initial summary of the hydrogeochemistry of the McBride Basalt Province (MBP) and Nulla Basalt Province (NBP) of the Upper Burdekin Region of North Queensland, completed as part of Exploring for the Future (EFTF)—an eight year, $225 million Australian Government funded geoscience data and information acquisition program focused on better understanding the potential mineral, energy and groundwater resources across Australia. Groundwater hydrogeochemistry studies can improve system understanding by reflecting host formation compositions and groundwater processes. These studies also provide regional baseline groundwater datasets that can inform environmental monitoring, resource use and decision making. During 2017 and 2018 Geoscience Australia collected 38 groundwater samples and 80 surface water samples (including quality control samples) to evaluate groundwater system processes including potential flow paths, recharge and groundwater-surface water-interactions. These surveys were conducted across three months of fieldwork, sampling water for a comprehensive suite of hydrogeochemical parameters. The present report includes surface water and groundwater data and information on: 1) sampling sites; 2) field physicochemical parameters (EC, pH, Eh, DO and T); 3) field measurements of total alkalinity (HCO3-); 4) laboratory results of major anion and cation results; 5) laboratory results for isotopes of water (δ18O and δD), DIC (δ13C), and dissolved strontium (87Sr/86Sr); and 6) hydrogeochemical maps representing the spatial distribution of these parameters. Pending analyses include: CFCs, SF6 and radiogenic isotopes δ14C and δ36Cl. Analysis that were largely below detection limit include: trace element concentrations, dissolved sulfide (S2-), ferrous iron (Fe2+), and dissolved sulfate (affecting sampling of δ34S and δ18O). This study demonstrates that hydrogeochemistry surveys, with full suites of chemical parameters including isotopes, can reveal fundamental groundwater system processes such as groundwater flow paths, groundwater recharge and groundwater-surface water interactions. The chemical ‘fingerprints’ identified here indicate groundwater flow paths are largely restricted to within the MBP and NBP aquifers, which have little interaction with adjacent and underlying non-basaltic rocks. The results also indicate groundwater is largely recharged from rainfall in higher elevations of the basalt provinces, with variable rainfall inputs to groundwater from lower elevation and rivers along flow paths. Groundwater-surface water interactions show several chemical signatures linking groundwater to springs, tributary rivers and the Burdekin River. Results from the Upper Burdekin Hydrogeochemistry Survey for the MBP and NBP have been plotted and mapped with initial interpretations presented below. Further detailed interpretation of this hydrogeochemistry data will be the focus of future publications. This data release is part in a series of staged outputs from the EFTF program. Relevant data, information and images are available through the Geoscience Australia website.

July 2020: The data in this product has been superseded, with the new dataset available here: <a href="https://pid.geoscience.gov.au/dataset/ga/133388">https://pid.geoscience.gov.au/dataset/ga/133388</a> However, the report in this product still presents valuable insights e.g., into the relationship between copper in the regolith and groundwater. The mineral resources of Tennant Creek and Mt Isa have contributed tremendously to the economic development the Northern Territory and Queensland. Vast areas of poorly known mineral potential remain under explored between and around these two mining centres, with prospective solid geology covered by a relatively thin layer of transported sediments. Hydrogeochemical surveys utilise groundwater as a passive sampling medium to reveal the chemistry of the underlying geology including hidden mineralisation. These surveys also provide regional baseline groundwater datasets that can inform environmental monitoring and decision making.

Exploring for the Future (EFTF) is a four-year (2016-20) geoscience data and information acquisition program that aims to better understand on a regional scale the potential mineral, energy and groundwater resources concealed under cover in northern Australia and parts of South Australia. Hydrogeochemical surveys utilise groundwater as a passive sampling medium to reveal the chemistry of the underlying geology including hidden mineralisation. These surveys also potentially provide input into regional baseline groundwater datasets that can inform environmental monitoring and decision making. Geoscience Australia, as part of the Australian Government’s EFTF program, undertook an extensive groundwater sampling survey in collaboration with the Northern Territory Geological Survey and the Geological Survey of Queensland. During the 2017, 2018 and 2019 dry season, 224 groundwater samples (including field duplicate samples) were collected from 203 pastoral and water supply bores in the Tennant Creek-Mt Isa EFTF focus area of the Northern Territory and Queensland. An additional 38 groundwater samples collected during the 2013 dry season in the Lake Woods region from 35 bores are included in this release as they originate from within the focus area. The area was targeted to evaluate its mineral potential with respect to iron oxide copper-gold, sediment-hosted lead-zinc-silver and Cu-Co, and/or lithium-boron-potash mineral systems, among others. The 2017-2019 surveys were conducted across 21 weeks of fieldwork and sampled groundwater for a comprehensive suite of hydrogeochemical parameters, including isotopes, analysed over subsequent months. The present data release includes information and atlas maps of: 1) sampling sites; 2) physicochemical parameters (EC, pH, Eh, DO and T) of groundwater measured in the field; 3) field measurements of total alkalinity (HCO3-), dissolved sulfide (S2-), and ferrous iron (Fe2+); 4) major cation and anion results; 5) trace element concentrations; 6) isotopic results of water (δ18O and δ2H), DIC (δ13C), dissolved sulfate (δ34S and δ18O), dissolved strontium (87Sr/86Sr), and dissolved lead (204Pb, 206Pb, 207Pb, and 208Pb) isotopes; 7) dissolved hydrocarbon VFAs, BTEX, and methane concentrations, as well as methane isotopes (δ13C and δ2H); and 8) atlas of hydrogeochemical maps representing the spatial distribution of these parameters. Pending analyses include: CFCs and SF6; tritium; Cu isotopes; and noble gas concentrations (Ar, Kr, Xe, Ne, and 4He) and 3He/4He ratio. This data release (current as of July 2021) is the second in a series of staged releases and interpretations from the Northern Australia Hydrogeochemical Survey. It augments and revises the first data release, which it therefore supersedes. Relevant data, information and images are available through the GA website (https://pid.geoscience.gov.au/dataset/ga/133388) and GA’s EFTF portal (https://portal.ga.gov.au/).

Geoscience Australia and its predecessors have analysed the hydrochemistry of water sampled from bores, surface features, rainwater and core samples (pore water). Samples have been collected during drilling or monitoring projects, including Exploring for the Future (EFTF). The hydrochemistry database includes physical-chemical parameters (EC, pH, redox potential, dissolved oxygen), major and minor ions, trace elements, isotopes and nutrients. The resource is accessible via the Geoscience Australia Portal <a href="https://portal.ga.gov.au/">(https://portal.ga.gov.au/)</a>

Millions of data points have been acquired or compiled through both phases of the Exploring for the Future (EFTF) program at Geoscience Australia (GA). This data that graces the EFTF Portal and appears in many publications has another home within specialist databases designed and built to house the specific data that GA collects. One such database is HYDROCHEM, which was implemented as part of the Enhanced Data Delivery (EDD) and National Groundwater Systems (NGS) projects. HYDROCHEM hosts 190,097 rows of groundwater, surface water and rainfall water chemistry analyses. This data was either previously hosted in the GNDWATER database, or compiled from legacy data stores. The redevelopment of GNDWATER to HYDROCHEM saw the de-duplication and updating of sample and site-specific metadata into other GA databases, such as SAMPLES, BOREHOLES and FIELDSITES. The redevelopment also added additional constraints to the database, including minimum metadata requirements, constrained look-up tables for units of measure, laboratory, method, filter sizes, standards and uncertainty types. Other features include minimum and maximum values for particular analytes and delivery of the data in standardised GA-preferred units of measure.

With the increasing need to extend mineral exploration undercover, new approaches are required to better constrain concealed geology, thereby reducing exploration risk and search space. Hydrogeochemistry is an under-utilised tool that can identify subsurface geology and buried mineral system components, while also providing valuable insights into environmental baselines, energy systems and groundwater resources. With this aim, 238 water bores spanning seven geological provinces in the Northern Territory and Queensland were sampled and analysed for major cations and anions, trace elements, stable and radiogenic isotopes, organic species, and dissolved gases. Here, we demonstrate the utility of this dataset for identifying carbonate-rich aquifers and mineral system components therein. First, we use trends in major element ratios (Ca+Mg)/Cl– and SiO2/HCO–3, then strontium isotope ratios (87Sr/86Sr), to define subpopulations that reflect both spatial and compositional differences. We then apply mafic-to-felsic trace element ratios (V/Cs and Cu/Rb) to reveal elevated base metal concentrations near Lake Woods caused by water–rock interaction with dolerite intrusions. Correlated Sr concentrations between groundwater and surface sediments suggest that the geochemical evolution of these mediums in carbonate-dominated terrains is coupled. Our work develops an approach to guide mineral exploration undercover via the characterisation and differentiation of groundwaters from different aquifers, resulting in improved identification of geochemical anomalies. <b>Citation:</b> Schroder, I., de Caritat, P. and Wallace, L., 2020. The Northern Australia Hydrogeochemical Survey: aquifer lithologies, local backgrounds and undercover processes. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.