Fluid inclusion studies have been carried out on quartz veining from Jackson's Pit and Eva uranium mines and the Dianne and St Barb copper prospects in the Westmoreland region. Four types of inclusions have been observed. Type A, vapour-rich inclusions, contain 30 - 100 vol.% vapour with varying amounts of CO2 ± N2 ± CH4. Type B, liquid-rich inclusions, contain up to 30 vol.% vapour. Type C inclusions are liquid-only. Type D, three-phase (vapour + liquid + solid) liquid-rich inclusions, contain a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385°C. Other Type B and Type D inclusions typically homogenised between 100 and 240°C with a mode around 120°C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50°C. This may indicate three phases of fluid flow in the region with progressively cooling fluids. Eutectic melting temperatures as low as -79.8ºC in Type B and C inclusions suggest the presence of CaCl2 and other salts in the fluids. Final ice meeting temperatures for Type B and C inclusions fall into two groups. The first group has final melting temperatures below -10ºC while the second group shows final meeting above -10ºC and more typically close to 0ºC indicating the presence of low salinity fluids. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50°C.

Geoscience Australia’s Exploring for the Future (EFTF) program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to a low emissions economy, strong resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225m investment by the Australian Government. The deep stratigraphic drill hole, NDI Carrara 1 (~1751 m), was completed in December 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) recently acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1100 m of Proterozoic sedimentary rocks uncomformably overlain by 630 m of Cambrian Georgina Basin carbonates. This contractor report (FIT - Schlumberger) presents hydrocarbon and aqueous fluid inclusion petrology and data (micro-thermometry, salinities etc.) on four hydrocarbon-bearing calcite veins sampled from NDI Carrara 1 between 762.56-763.60 m depth, (under contract to, and fully funded by, Geoscience Australia as part of the Exploring for the Future program).

The Paleoproterozoic Westmoreland region is located 1250 km southeast of Darwin. The Westmoreland region is flanked on the southeast by the Paleoproterozoic Mt Isa Inlier and the Neoproterozoic South Nicholson Basin and in the northwest it is overlapped by Mesoproterozoic sediments of the McArthur Basin. The northern and southern ends of the McArthur basin share many geologic attributes including correlative stratigraphic rock types, which suggests that there is potential for unconformity-related uranium deposits in the southern McArthur basin and adjacent Westmoreland region. In fact, over fifty occurrences of uranium (some with minor gold) and copper mineralisation have been recorded in the Westmoreland region. Fluid inclusion studies have been carried out on selected uranium and copper prospects on the Northern Territory side of the Westmoreland region. Four types of inclusions have been observed, (Type A) Vapour-rich inclusions containing 30 100 vol.% vapour. Varying amounts of CO2 ± N2 ± CH4 have been detected in these inclusions, (Type B) Liquid-rich inclusions with up to 30 vol.% vapour, (Type C) Liquid-only inclusions, and (Type D) Three-phase (vapour + liquid + solid) liquid-rich inclusions containing a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385 °C and are thought to be related to early metamorphic events. Other Type B and Type D inclusions typically homogenised between 100 and 240 °C with a mode around 120 °C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50 °C. Eutectic melting temperatures indicate the presence of CaCl2 in the fluids but final melting temperatures show the presence of both high and low salinity brines. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50 °C.

The Palaeoproterozoic Westmoreland region is located 1250 km southeast of Darwin. The Westmoreland region is flanked on the southeast by the Palaeoproterozoic Mt Isa Inlier and the Neoproterozoic South Nicholson Basin and in the northwest it is overlapped by Mesoproterozoic sediments of the McArthur Basin. The northern and southern ends of the McArthur basin share many geologic attributes including correlative stratigraphic rock types, which suggests that there is potential for unconformity-related uranium deposits in the southern McArthur basin and adjacent Westmoreland region. In fact, over fifty occurrences of uranium (some with minor gold) and copper mineralisation have been recorded in the Westmoreland region. Fluid inclusion studies have been carried out on selected uranium and copper prospects on the Northern Territory side of the Westmoreland region. Four types of inclusions have been observed, (Type A) Vapour-rich inclusions containing 30 - 100 vol.% vapour. Varying amounts of CO2 ± N2 ± CH4 have been detected in these inclusions, (Type B) Liquid-rich inclusions with up to 30 vol.% vapour, (Type C) Liquid-only inclusions, and (Type D) Three-phase (vapour + liquid + solid) liquid-rich inclusions containing a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385 °C and are thought to be related to early metamorphic events. Other Type B and Type D inclusions typically homogenised between 100 and 240 °C with a mode around 120 °C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50 °C. Eutectic melting temperatures indicate the presence of CaCl2 in the fluids but final melting temperatures show the presence of both high and low salinity brines. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50 °C.

The Maldon gold deposit in central Victoria has geological, geochronological and fluid chemistry characteristics that distinguish it from typical vein-hosted, orogenic' gold deposits in this region. The deposit lies within the contact aureole of the Harcourt Granite and associated granitic dykes. The ore-bearing fluids are characterised by the presence of non-aqueous (i.e. carbonic) fluids, which exhibit complex freezing and heating behaviour, as well as mixed CO2-low-salinity aqueous fluids (mostly - 10 wt.% NaCl eq.). Raman analysis indicates that carbonic inclusions can vary from CO2-rich to CH4-rich, with N2 contents up to 38 mol.%. Higher-salinity brine inclusions, 20-22 wt.% NaCl eq., only occur locally. The Harcourt Granite is a moderately reduced, I-type granite and the reduced fluids (e.g. CH4-N2-rich) are believed to have formed within (or in close proximity to) thermal aureoles of the dykes or granites during contact metamorphism. This further supports the premise that the Maldon deposit is an 'orogenic' gold deposit that was metamorphosed and/or remobilised during the emplacement of post-orogenic intrusions/dykes. We conclude that some 'orogenic' gold deposits worldwide may have been completely overprinted by later magmatic/metamorphic events and are now only evident as reduced intrusion-related gold systems.

Raman spectroscopy has been an invaluable method for the non-destructive analysis of fluid inclusions for over 30 years1 and since then it has also been applied to the study of melt inclusions2. While the analysis of gas species in these inclusions is relatively straight forward, the identification of stable and metastable solid phases in inclusions is more challenging due to the limited availability of reference Raman spectra for some minerals. Some examples of inclusions with challenging Raman spectra are discussed below.

The Palaeoproterozoic Murphy Inlier is situated at the southern end of the McArthur Basin in northern Australia. The inlier contains over 50 uranium, copper, tin and base metal occurrences. Fluid inclusion studies were carried out on samples of quartz veining from the uranium and copper deposits as well as from the basement rocks to determine the composition of the fluids and to investigate how uranium and copper were transported in these fluids. Four types of fluid inclusions were observed in this study; Type A vapour-rich inclusions with 30 vol.% vapour, Type B two phase aqueous inclusion with - 20 vol.% vapour, Type C multiphase inclusions with one or more solid phases and, Type D liquid-only inclusions. At least three different fluids were identified in the Murphy Inlier. The first is a high temperature fluid denoted by Types A and B inclusions which homogenise over the range from 220 to 380 ºC. In the basement rocks, this fluid is enriched in N2 indicating that it may be related to metamorphic processes. In the uranium deposits this fluid is dominated by CO2 indicating that these fluids are relatively oxidized, while in the copper deposits both CO2 and CH4 are present indicating that these fluids are more reduced than in the regions of uranium mineralisation. The second fluid is a NaCl-rich with salinities ranging from 0.2 to 29.8 mass % NaCl and the third fluid is CaCl2-rich with salinities ranging from 0.1 to 24.7 mass % CaCl2. There is also evidence for fluid mixing between the NaCl-rich and CaCl2-rich end member fluids.

Abstracts from the 4th Biennial Conference on Asian Current Research on Fluid Inclusions held in Brisbane, Australia from 10 - 12 August 2012

Exploring for the Future (EFTF) is an Australian Government program led by Geoscience Australia (GA), in partnership with state and Northern Territory governments. The EFTF program (2016-2024) aims to drive industry investment in resource exploration in frontier regions of onshore Australia by providing new precompetitive data and information about their energy, mineral and groundwater resource potential. Under the EFTF program, the Onshore Energy Project undertook a study of petroleum prospectivity of the onshore Officer Basin in South Australia and Western Australia. Yowalga 3 well in Western Australia was selected based on the occurrence of gas and oil shows reported in the well completion report. Sampling of cuttings and cores was done at Geoscience Australia's Petroleum Data Repository in Canberra. Geoscience Australia commissioned a fluid inclusion stratigraphy (FIS) study on the downhole samples. Here, volatile components ostensibly trapped with fluid inclusions are released and analysed revealing the level of exposure of the well section to migrating fluids. Integration of thin section (TS) preparations reveal to extent of gas and fluid trapping within fluid inclusions while microthemometry (MT) gives an estimation of fluid inclusion trapping temperature. For Yowalga 3, FIS analysis was performed on 698 cuttings and 30 cores between 140 metres and 3526 metres base depth, together with 22 samples prepared for TS. To support this study, lithostratigraphic tops were compiled by Geoscience Australia. The results of the study are found in the accompanying documents. Note: Yowalga 3 results are in two parts, Part 1 and Part 2, since the total number of samples exceeded to maximum number of samples (575) for a Schlumberger well report. Part 1 has cuttings by increasing depth and Part 2 has the remaining cuttings then the cores.

Exploring for the Future (EFTF) is an Australian Government program led by Geoscience Australia (GA), in partnership with state and Northern Territory governments. The EFTF program (2016-2024) aims to drive industry investment in resource exploration in frontier regions of onshore Australia by providing new precompetitive data and information about their energy, mineral and groundwater resource potential. Under the EFTF program, the Basin Inventory Project undertook a study of petroleum prospectivity of the onshore Eromanga Basin in Queensland and South Australia. Gilmore 1 well in Queensland was selected based on the occurrence of gas and oil shows reported in the well completion report. Sampling of cuttings and cores was done at Geoscience Australia's Petroleum Data Repository in Canberra. Geoscience Australia commissioned a fluid inclusion stratigraphy (FIS) study on the downhole samples. Here, volatile components ostensibly trapped with fluid inclusions are released and analysed revealing the level of exposure of the well section to migrating fluids. Integration of thin section (TS) preparations reveal the extent of gas and fluid trapping within fluid inclusions while microthemometry (MT) gives an estimation of fluid inclusion trapping temperature. For Gilmore 1, FIS analysis was performed on 498 cuttings and 71 cores between 9.1 metres and 4346 metres base depth, together with 22 samples prepared for TS and 4 samples for MT. To support this study, lithostratigraphic tops were compiled by Geoscience Australia. The results of the study are found in the accompanying documents.