The Paleoproterozoic Westmoreland region is located 1250 km southeast of Darwin. The Westmoreland region is flanked on the southeast by the Paleoproterozoic Mt Isa Inlier and the Neoproterozoic South Nicholson Basin and in the northwest it is overlapped by Mesoproterozoic sediments of the McArthur Basin. The northern and southern ends of the McArthur basin share many geologic attributes including correlative stratigraphic rock types, which suggests that there is potential for unconformity-related uranium deposits in the southern McArthur basin and adjacent Westmoreland region. In fact, over fifty occurrences of uranium (some with minor gold) and copper mineralisation have been recorded in the Westmoreland region. Fluid inclusion studies have been carried out on selected uranium and copper prospects on the Northern Territory side of the Westmoreland region. Four types of inclusions have been observed, (Type A) Vapour-rich inclusions containing 30 100 vol.% vapour. Varying amounts of CO2 ± N2 ± CH4 have been detected in these inclusions, (Type B) Liquid-rich inclusions with up to 30 vol.% vapour, (Type C) Liquid-only inclusions, and (Type D) Three-phase (vapour + liquid + solid) liquid-rich inclusions containing a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385 °C and are thought to be related to early metamorphic events. Other Type B and Type D inclusions typically homogenised between 100 and 240 °C with a mode around 120 °C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50 °C. Eutectic melting temperatures indicate the presence of CaCl2 in the fluids but final melting temperatures show the presence of both high and low salinity brines. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50 °C.

This report is a synopsis of research compiled and carried out within the Predictive Mineral Discovery CRC F3 project "Micrometallogeny of hydrothermal fluids". The F3 project's original objectives were: (1) Geology-driven terrain and ore fluids investigations to evaluate the chemistry and fluid processes within mineral systems in order to extend the focus of fluid studies beyond direct ore deposit analysis. (2) LAICPMS and PIXE technique and methodology development were techniques utilized throughout the project and methodologies were developed for their combined application. (3) Diamond-cell autoclave experiments component of the project was a scoping-collaboration in year one of F3 with the Museum of South Australia. (4) Database development and fusion with numerical modelling resulted in development of a web-based database for fluid inclusion research has been successful and is currently accessed at http://www.ga.gov.au/minerals/research/methodology/geofluids/flincs_about.jsp

Raman spectroscopy has been an invaluable method for the non-destructive analysis of fluid inclusions for over 30 years1 and since then it has also been applied to the study of melt inclusions2. While the analysis of gas species in these inclusions is relatively straight forward, the identification of stable and metastable solid phases in inclusions is more challenging due to the limited availability of reference Raman spectra for some minerals. Some examples of inclusions with challenging Raman spectra are discussed below.

This web-enabled system allows researchers to retrieve fluid inclusion data from anywhere in the world. The concept is to build a free and widely available web-based library of fluid properties for a range of geological fluids. The database is being developed as an "open" project, which intends to bring together researchers interested in the properties of geological fluids or fluid inclusions.

Geoscience Australia’s Exploring for the Future (EFTF) program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to a low emissions economy, strong resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225m investment by the Australian Government. The deep stratigraphic drill hole, NDI Carrara 1 (~1751 m), was completed in December 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) recently acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1100 m of Proterozoic sedimentary rocks uncomformably overlain by 630 m of Cambrian Georgina Basin carbonates. This contractor report (FIT - Schlumberger) presents hydrocarbon and aqueous fluid inclusion petrology and data (micro-thermometry, salinities etc.) on four hydrocarbon-bearing calcite veins sampled from NDI Carrara 1 between 762.56-763.60 m depth, (under contract to, and fully funded by, Geoscience Australia as part of the Exploring for the Future program).

Exploring for the Future (EFTF) is an Australian Government program led by Geoscience Australia (GA), in partnership with state and Northern Territory governments. The EFTF program (2016-2024) aims to drive industry investment in resource exploration in frontier regions of onshore Australia by providing new precompetitive data and information about their energy, mineral and groundwater resource potential. Under the EFTF program, the Basin Inventory Project undertook a study of petroleum prospectivity of the onshore Eromanga Basin in Queensland and South Australia. Yongala 1 well in Queensland was selected based on the occurrence of gas and oil shows reported in the well completion report. Sampling of cuttings and cores was done at Geoscience Australia's Petroleum Data Repository in Canberra. Geoscience Australia commissioned a fluid inclusion stratigraphy (FIS) study on the downhole samples. Here, volatile components ostensibly trapped with fluid inclusions are released and analysed revealing the level of exposure of the well section to migrating fluids. Integration of thin section (TS) preparations reveal the extent of gas and fluid trapping within fluid inclusions while microthemometry (MT) gives an estimation of fluid inclusion trapping temperature. For Yongala 1, FIS analysis was performed on 418 cuttings and 52 cores between 15.2 metres and 3104.5 metres base depth, together with 22 samples prepared for TS and 3 samples for MT. To support this study, lithostratigraphic tops were compiled by Geoscience Australia. The results of the study are found in the accompanying documents.

<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential.</div><div><br></div><div>The Paleo to Mesoproterozoic Birrindudu Basin is an underexplored frontier basin located in northwestern Northern Territory and northeastern Western Australia. The Birrindudu Basin is a region of focus for the second phase of the EFTF program (2020–2024) as it contains strata of similar age to the prospective McArthur Basin, South Nicholson region and Mount Isa Province, but remains comparatively poorly understood.</div><div><br></div><div>Geoscience Australia have undertaken (via the service provider, FIT, Schlumberger) Fluid Inclusion Petrography and Microthermometry analysis of samples for the drillhole 99VRNTGSDD1, Birrindudu Basin, located in the northwest Northern Territory (Company reference number MT#F1230005c).</div><div><br></div><div>This eCat Record accompanies the report containing the results of fluid inclusion stratigraphy on this drillhole (eCat record 148973).</div>

<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential.</div><div><br></div><div>The Paleo to Mesoproterozoic Birrindudu Basin is an underexplored frontier basin located in northwestern Northern Territory and northeastern Western Australia. The Birrindudu Basin is a region of focus for the second phase of the EFTF program (2020–2024) as it contains strata of similar age to the prospective McArthur Basin, South Nicholson region and Mount Isa Province, but remains comparatively poorly understood.</div><div><br></div><div>Geoscience Australia have undertaken (via the service provider, FIT, Schlumberger) Fluid Inclusion Petrography and Microthermometry analysis of samples for the drillhole WLMB001B, Birrindudu Basin, located in the northwest Northern Territory (Company reference number MT#FI230004a).</div><div><br></div><div>This eCat Record accompanies the report containing the results of fluid inclusion stratigraphy on this drillhole (eCat record 149178)</div>

<div>Geoscience Australia’s Exploring for the Future (EFTF) program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential.</div><div><br></div><div>The Stansbury Basin is a relatively underexplored basin in southern South Australia. Stansbury West 1 was drilled on the east coast of Yorke Peninsula to test the basal Permian sands and Paleozoic carbonate known to contain traces of hydrocarbon gas and residual oil. The well encountered no significant hydrocarbons and was abandoned as dry. A known occurrence of hydrogen-rich natural gas was discovered nearly a century ago in a well to the north of Stansbury West 1. Also potential hydrogen gas enrichment in the near-surface in the surrounds of the Stansbury West 1 drillhole has been proposed using satellite imagery and land surface features.</div><div><br></div><div>The study of natural hydrogen gas occurrences is a focus for the second phase of the EFTF program (2020–2024) and the fluid inclusion stratigraphy (FIS) technique of Fluid Inclusion Technology (Schlumberger) provides a convenient method to measure the well's complete downhole section for both hydrocarbon non-hydrocarbon gases that have been geologically trapped in fluid inclusions and then mechanically released in the laboratory.</div><div><br></div><div>Geoscience Australia have undertaken (via the service provider, FIT Schlumberger) stratigraphic reconstructions of bulk volatile chemistry from fluid inclusions from the drillhole Stansbury West 1, Stansbury Basin. FIS analysis was performed on 270 cuttings and core samples from 15.24 to 1743.53 metres, including 4.9 metres of Archean gneiss and granitic basement at the base of the drillhole.</div><div><br></div><div>This ecat record releases the final report containing the results of fluid inclusion stratigraphy and thin section analyses, raw data files (*.LAS) and rock descriptions by FIT Schlumberger (Company reference number FI220025a).</div>

Although the Canning Basin has yielded minor gas and oil within conventional and unconventional reservoirs, the relatively limited geological data available in this under-explored basin hinder a thorough assessment of its hydrocarbon potential. Knowledge of the Paleozoic Larapintine Petroleum Supersystem is restricted by the scarcity of samples, especially recovered natural gases, which are limited to those collected from recent exploration successes in Ordovician and Permo-Carboniferous successions along the margins of the Fitzroy Trough and Broome Platform. To address this shortcoming, gases trapped within fluid inclusions were analysed from 121 Ordovician to Permian rock samples (encompassing cores, sidewall cores and cuttings) from 70 exploration wells with elevated mud gas readings. The molecular and carbon isotopic compositions of these gases have been integrated with gas compositions derived from open-file sources and recovered gases analysed by Geoscience Australia. Fluid inclusion C1–C5 hydrocarbon gases record a snapshot of the hydrocarbon generation history. Where fluid inclusion gases and recovered gases show similar carbon isotopes, a simple filling history is likely; where they differ, a multicharge history is evident. Since some fluid inclusion gases fall outside the carbon isotopic range of recovered gases, previously unidentified gas systems may have operated in the Canning Basin. Interestingly, the carbon isotopes of the fluid-inclusion heavy wet gases converge with the carbon isotopes of the light oil liquids, indicating potential for gas–oil correlation. A regional geochemical database incorporating these analyses underpins our re-evaluation of gas systems and gas–gas correlations across the basin. <b>Citation:</b> Boreham, C.J., Edwards, D.S., Sohn, J.H., Palatty, P., Chen, J.H. and Mory, A.J., 2020. Gas systems in the onshore Canning Basin as revealed by gas trapped in fluid inclusions. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.