Australia has embarked on a process of potential commitment through the Kyoto Protocol to contain growth in greenhouse gas emissions to 8% between 1990 and the reporting period of 2008 - 2012. The target is well below the estimated growth of about 28% under the `business as usual' condition. Australia's greenhouse gas inventory estimates that 502 million tonnes of carbon dioxide equivalents were emitted in the base year of 1990. This report examines over 175 candidate options for reducing greenhouse gas emissions to identify their technical feasibility, cost per tonne of carbon dioxide avoided and capability to reduce emissions under Australian conditions. The candidate options were not intended to represent an exhaustive list but they encompass major and some lesser options being canvassed in Australia and overseas. Preferred options were selected on their performance towards the criteria of technical feasibility, cost and capability.

Australia has been making major progress towards early deployment of carbon capture and storage from natural gas processing and power generation sources. This paper will review, from the perspective of a government agency, the current state of various Australian initiatives and the advances in technical knowledge up until the 2010 GHGT conference. In November 2008, the Offshore Petroleum and Greenhouse Gas Storage Bill 2006 was passed by the Australian Parliament and established a legal framework to allow interested parties to explore for and evaluate storage potential in offshore sedimentary basins that lie in Australian Commonwealth waters. As a result of this Act, Australia became the first country in the world, in March 2009, to open exploration acreage for storage of greenhouse gases under a system that closely mirrors the well-established Offshore Petroleum Acreage Release. The ten offshore areas offered for geological storage assessment are significantly larger than their offshore petroleum counterparts to account for, and fully contain, the expected migration pathways of the injected GHG substances. The co-incidence of the 2009 Global Financial Crisis may have reduced the number of prospective CCS projects that were reported to be in the 'pipe-line' and the paper examines the implications of this apparent outcome. The Carbon Storage Taskforce has brought together both Australian governments technical experts to build a detailed assessment of the perceived storage potential of Australia's sedimentary basins. This evaluation has been based on existing data, both on and offshore. A pre-competitive exploration programme has also been compiled to address the identified data gaps and to acquire, with state funding, critical geological data which will be made freely available to encourage industrial participation in the search for commercial storage sites.

Hot Rocks in Australia - National Outlook Hill, A.J.1, Goldstein, B.A1 and Budd, A.R.2 goldstein.barry@saugov.sa.gov.au hill.tonyj@saugov.sa.gov.au Petroleum & Geothermal Group, PIRSA Level 6, 101 Grenfell St.Adelaide SA 50001 Anthony.Budd@ga.gov.au Onshore Energy & Minerals Division, Geoscience Australia, GPO Box 378 Canberra ACT 26012 Abstract: Evidence of climate change and knowledge of enormous hot rock resources are factors stimulating growth in geothermal energy research, including exploration, proof-of-concept appraisals, and development of demonstration pilot plant projects in Australia. In the six years since the grant of the first Geothermal Exploration Licence (GEL) in Australia, 16 companies have joined the hunt for renewable and emissions-free geothermal energy resources in 120 licence application areas covering ~ 67,000 km2 in Australia. The associated work programs correspond to an investment of $570 million, and that tally excludes deployment projects assumed in the Energy Supply Association of Australia's scenario for 6.8% (~ 5.5 GWe) of Australia's base-load power coming from geothermal resources by 2030. Australia's geothermal resources fall into two categories: hydrothermal (from relatively hot groundwater) and the hot fractured rock i.e. Enhanced Geothermal Systems (EGS). Large-scale base-load electricity generation in Australia is expected to come predominantly from Enhanced Geothermal systems. Geologic factors that determine the extent of EGS plays can be generalised as: - source rock availability, in the form of radiogenic, high heat-flow basement rocks (mostly granites); - low thermal-conductivity insulating rocks overlying the source rocks, to provide thermal traps; - the presence of permeable fabrics within insulating and basement rocks, that can be enhanced to create heat-exchange reservoirs; and - a practical depth-range, limited by drilling and completion technologies (defining a base) and necessary heat exchange efficiency (defining a top). A national EGS resource assessment and a road-map for the commercialisation of Australia's EGSs are expected to be published in 2008. The poster will provide a synopsis of investment frameworks and geothermal energy projects underway and planned in Australia.

Covering an area of approximately 247 000km2, the Galilee Basin is a significant feature of central Queensland. Three main depocentres contain several hundred metres of Late Carboniferous to Middle Triassic sediments. Sedimentation in the Galilee Basin was dominated by fluvial to lacustrine depositional systems. This resulted in a sequence of sandstones, mudstones, siltstones, coals and minor tuff in what was a relatively shallow intracratonic basin with little topographic relief. Forty years or more of exploration in the Galilee Basin has failed to discover any economic accumulations of hydrocarbons, despite the presence of apparently fair to very good reservoirs and seals in both the Permian and Triassic sequence. Despite some relatively large distances (upwards of 500km) between sources and sinks, previous and ongoing work on the Galilee Basin suggests that it has potential to sequester a significant amount of Queensland's carbon dioxide emissions. Potential reservoirs include the Early Permian Aramac Coal Measures, the Late Permian Colinlea Sandstone and the Middle Triassic Clematis Sandstone. These are sealed by several intraformational and local seals as well as the regional Triassic Moolayember Formation. With few suitable structural traps and little faulting throughout the Galilee sequence, residual trapping within saline reservoir is the most likely mechanism for storing CO2. The current study is aimed at building a sound geological model of the basin through activities such as detailed mapping, well correlation, and reservoir and seal analysis leading to reservoir simulations to gain a better understanding of the basin.

Having techniques available for the accurate quantification of potential CO2 surface leaks from geological storage sites is critical for regulators, public assurance and for underpinning carbon pricing mechanisms. Currently, there are few options available that enable accurate CO2 quantification of potential leaks at the soil-atmosphere interface. Integrated soil flux measurements can be used to quantify CO2 emission rates from the soil and atmospheric techniques such as eddy covariance or Lagrangian stochastic modelling have been used with some success to quantify CO2 emissions into the atmosphere from simulated surface leaks. The error for all of these techniques for determining the emission rate is not less than 10%. A new technique to quantify CO2 emissions was trialled at the CO2CRC Ginninderra controlled release site in Canberra. The technique, termed atmospheric tomography, used an array of sampling sites and a Bayesian inversion technique to simultaneously solve for the location and magnitude of a simulated CO2 leak. The technique requires knowledge of concentration enhancement downwind of the source and the normalized, three-dimensional distribution (shape) of concentration in the dispersion plume. Continuous measurements of turbulent wind and temperature statistics were used to model the dispersion plume.

The first large-scale projects for geological storage of carbon dioxide on the Australian mainland are likely to occur within sedimentary sequences that underlie or are within the Triassic-Cretaceous, Great Artesian Basin (GAB) aquifer sequence. Recent national1 and state2 assessments have concluded that certain deep formations within the GAB show considerable geological suitability for the storage of greenhouse gases. These same formations contain trapped methane and naturally generated CO2 stored for millions of years. In July 2010, the Queensland government released exploration permits for Greenhouse Gas Storage in the Surat and Galilee basins.An important consideration in assessing the potential economic, environmental, health and safety risks of such projects is the potential impact CO2 migrating out of storage reservoirs could have on overlying groundwater resources. The risk and impact of CO2 migrating from a greenhouse gas storage reservoir into groundwater cannot be objectively assessed without knowledge of the natural baseline characteristics of the groundwater within these systems. Due to the phase behaviour of CO2, geological storage of carbon dioxide in the supercritical state requires depths greater than 800m, but there are few hydrogeochemical studies of these deeper aquifers in the prospective storage areas. Historical hydrogeochemical data are compiled from various State and Federal Government agencies. In addition, hydrogeochemical information is compiled from thousands of petroleum well completion reports in order to obtain more information on the deeper aquifers, not typically used for agriculture or human consumption. The data are passed through a QC procedure to check for mud contamination and to ascertain whether a representative sample had been collected. The large majority of the samples proved to be contaminated but a small selection passed the QC criteria. The full dataset is available for download from GA's Virtual Dataroom. Oral presentation at "Groundwater 2010" Conference, 31 October - 4 November 2010, Canberra

In July 2010 Geoscience Australia and CSIRO Marine & Atmospheric Research jointly commissioned a new atmospheric composition monitoring station (' Arcturus') in central Queensland. The facility is designed as a proto-type remotely operated `baseline monitoring station' such as could be deployed in areas that are likely targets for commercial scale carbon capture and geological storage (CCS). It is envisaged that such a station could act as a high quality reference point for later in-fill, site based, atmospheric monitoring associated with geological storage of CO2. The station uses two wavelength scanned cavity ringdown instruments to measure concentrations of carbon dioxide (CO2), methane (CH4), water vapour and the isotopic signature (?13C) of CO2. Meteorological parameters such as wind speed and wind direction are also measured. In combination with CSIRO's TAPM (The Air Pollution Model), data will be used to understand the local variations in CO2 and CH4 and the contributions of natural and anthropogenic sources in the area to this variability. The site is located in a region that supports cropping, grazing, cattle feedlotting, coal mining and gas production activities, which may be associated with fluxes of CO2 and CH4. We present in this paper some of the challenges found during the installation and operation of the station in a remote, sub-tropical environment and how these were resolved. We will also present the first results from the site coupled with preliminary modelling of the relative contribution of large point source anthropogenic emissions and their contribution to the background.

A Bayesian inversion technique to determine the location and strength of trace gas emissions from a point source in open air is presented. It was tested using atmospheric measurements of nitrous oxide (N2O) and carbon dioxide (CO2) released at known rates from a source located within an array of eight evenly spaced sampling points on a 20 m radius circle. The analysis requires knowledge of concentration enhancement downwind of the source and the normalized, three-dimensional distribution (shape) of concentration in the dispersion plume. The influence of varying background concentrations of ~1% for N2O and ~10% for CO2 was removed by subtracting upwind concentrations from those downwind of the source to yield only concentration enhancements. Continuous measurements of turbulent wind and temperature statistics were used to model the dispersion plume. The analysis localized the source to within 0.8 m of the true position and the emission rates were determined to better than 3% accuracy. This technique will be useful in assurance monitoring for geological storage of CO2 and for applications requiring knowledge of the location and rate of fugitive emissions.

CO2CRC Project 1 - Site Specific Studies for Geological Storage of carbon Dioxide Part 1: Southeast Queensland CO2 Storage Sites - Basin Desk-top, Geological Interpretation and Reservoir Simulation of Regional Model

<p>Geoscience Australia in collaboration with the CO2CRC hosted three controlled subsurface release experiments of CO2 during 2012 to 2013 at an agricultural research station managed by CSIRO Plant Industry Canberra. The facility was designed to simulate surface emissions of CO2 and other greenhouse gases from the soil into the atmosphere, and has deployed a range of near-surface monitoring techniques in the pursuit of improving detection and quantification methods and technologies. This product, which encompasses 4 geodatabases, a metadata report and a data dictionary, presents all the data collected during the experiments from over 10 research organisations, and is made to use with GIS software. The intention of this data release is make the data available for comparison with measurements taken at other controlled release experiments, CO2 storage projects and natural analogues. This will hopefully facilitate the further development of greenhouse gas monitoring technologies, methods and monitoring strategies and increase our understanding of the migration behaviour and impact of near surface CO2 leakage. <p>The contents of each geodatabase/experiment is summarised below: <p>Release 1 (Feb-May 2012): <p>- Soil microbial data <p>- Soil chemistry <p>- Free air CO2 concentration <p>- Eddy covariance <p>- Groundwater chemistry <p>- Soil gas <p>- Krypton tracers <p>- EM31 <p>- Soil flux <p>Release 2 (Oct-Dec 2012): <p>- Groundwater chemistry <p>- EM31 <p>- EM38 <p>- Soil gas <p>- Soil flux <p>- Airborne hyperspectral <p>- Ground hyperspectral <p>Release 3 (Oct-Dec 2013): <p>- Mobile CO2 surveys <p>- Groundwater depth <p>- Eddy covariance <p>- Plant physiology and chemistry <p>- EM31 <p>- EM38 <p>- Soil gas <p>- Soil flux <p>- Airborne hyperspectral <p>All Releases: <p>- Aerial images <p>- Groundwater depths <p>- Meteorological data <p>Bibliographic reference: <p>Feitz, A.J., Schroder, I.F., Jenkins, C.J., Schacht, U., Zegelin, S., Berko, H., McGrath, A., Noble, R., Palu, T.J., George, S., Heath, C., Zhang, H., Sirault, X. and Jimenez-Berni, J. 2016. Ginninderra Controlled CO2 Release Facility Dataset 2012-2013. eCat 90078, Geoscience Australia and CO2CRC, Canberra. https://pid.geoscience.gov.au/dataset/ga/90078. <p>Digital Object Identifier: http://dx.doi.org/10.4225/25/5823c37333f9d