Discovery of mid-Proterozoic (1.8 – 0.8 billion years ago, Ga) indigenous biomarkers is a challenge, since biologically informative molecules of such antiquity are commonly destroyed by metamorphism or overprinted by drilling fluids and other anthropogenic petroleum products. The previously oldest biomarkers were reported from the 1.64 Ga Barney Creek Formation in the McArthur Basin, northern Australian. In this study, we present the discovery of clearly indigenous biomarker molecules from carbonaceous shales of the 1.73 Ga Wollogorang Formation in the southern McArthur Basin, extending the biomarker record back in time by ~90 million years. The extracted hydrocarbons illustrate typical mid-Proterozoic signatures with a large unresolved complex mixture, high methyl-alkane/n-alkane ratios and absence of eukaryotic steranes. Also below detection limits were acyclic isoprenoids, saturated carotenoid derivatives, bacterial hopanes and aromatic hopanoids and steroids. Detected, however, were continuous homologous series (C13-C22) of 2,3,4- and 2,3,6-trimethyl aryl isoprenoids (AI). These breakdown products of aromatic carotenoids are the oldest known biogenic molecules, revealing the activity of phototrophic green (Chlorobiaceae) and purple sulphur bacteria (Chromatiaceae). The compounds provide evidence for at least temporary, very shallow (less than ~20 m) stratification of the McArthur Basin 1.73 Ga ago, supporting models of pervasive anoxic conditions in mid-Proterozoic basins.

Exploring for the Future (EFTF) is a four-year $100.5 million initiative by the Australian Government conducted by Geoscience Australia in partnership with state and Northern Territory government agencies, CSIRO and universities to provide new geoscientific datasets for frontier regions. As part of this program, Geoscience Australia acquired two new seismic surveys that collectively extend across the South Nicholson Basin (L120 South Nicholson seismic line) and into the Beetaloo Sub-basin of the McArthur Basin (L212 Barkly seismic line). Interpretation of the seismic has resulted in the discovery of new basins that both contain a significant section of presumed Proterozoic strata. Integration of the seismic results with petroleum and mineral systems geochemistry, structural analyses, geochronology, rock properties and a petroleum systems model has expanded the knowledge of the region for energy and mineral resources exploration. These datasets are available through Geoscience Australia’s newly developed Data Discovery Portal, an online platform delivering digital geoscientific information, including seismic locations and cross-section images, and field site and well-based sample data. Specifically for the EFTF Energy project, a petroleum systems framework with supporting organic geochemical data has been built to access source rock, crude oil and natural gas datasets via interactive maps, graphs and analytical tools that enable the user to gain a better and faster understanding of a basin’s petroleum prospectivity. <b>Citation:</b> Henson Paul, Robinson David, Carr Lidena, Edwards Dianne S., MacFarlane Susannah K., Jarrett Amber J. M., Bailey Adam H. E. (2020) Exploring for the Future—a new oil and gas frontier in northern Australia. <i>The APPEA Journal</i><b> 60</b>, 703-711. https://doi.org/10.1071/AJ19080

This presentation comprises information for the Minister to answer the following questions: The minister is looking to build his understanding of the different types of hydrocarbons that come out of the ground (e.g. dry gas, wet gas, condensate, etc.), how are they different and what does that mean for value, ease of production, transport?   Provide some simple diagrams demonstrating the spectrum of hydrocarbon types (e.g. oil to gas), as well as figures demonstrating source rock to hydrocarbon type relationships. Give examples of the molecular structures and difference in composition between condensate, light and mediums oils etc. Use examples from northern Australian basins with a focus on the Beetaloo Sub-basin and the Canning Basin. 25 October 2019

<p>The Mesoproterozoic Roper Group of the McArthur Basin has excellent petroleum potential, but its poorly constrained post-depositional history has hampered resource exploration and management. The Derim Derim Dolerite occupies an important position in the regional event chronology, having intruded the Roper Group prior to deformation associated with the ‘Post-Roper Inversion’ event. It was assigned a magmatic crystallisation age of 1324 ± 4 Ma (uncertainties are 95% confidence unless otherwise indicated) in 1997, based on unpublished Sensitive High Resolution Ion Micro Probe (SHRIMP) U-Pb analyses of dolerite-hosted baddeleyite from sample 97106010, collected from the Derim Derim Dolerite type locality in outcrop within the northwestern McArthur Basin. Herein, we refine these data via Isotope Dilution-Thermal Ionisation Mass Spectrometry (ID-TIMS) analysis of baddeleyites plucked from the SHRIMP grain-mounts, which yielded a precise mean 207Pb/206Pb date of 1327.5 ± 0.6 Ma. This date is significantly older than a baddeleyite U-Pb ID-TIMS date of 1313.8 ± 1.3 Ma recently obtained from dolerite ALT-05, sampled in Pacific Oil and Gas Ltd drillhole Altree 2, near the northern margin of the Beetaloo Sub-basin, and 200 km south of 97106010. This pair of results indicates that Derim Derim Dolerite magmatism spanned at least 10-15 Ma. Previously documented geochemical variation in Mesoproterozoic mafic rocks across the Northern Territory (such as the 1325 ± 36 Ma (2σ) Galiwinku Dolerite in the northern McArthur Basin, 1316 ± 40 Ma phonolites intruding the eastern Pine Creek Orogen, and 1295 ± 14 Ma gabbro in the Tomkinson Province) may reflect episodic pulses of magmatism hitherto obscured by the low precision of the available isotopic dates. <p><b>Citation:</b> Bodorkos, S., Yang, B., Collins, A.S., Crowley, J., Denyszyn, S.W., Claoue-Long, J.C., Anderson, J.R. and Magee, C., 2020 Precise U–Pb baddeleyite dating of the Derim Derim Dolerite: evidence for episodic mafic magmatism in the greater McArthur Basin. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

The Exploring for the Future program is an initiative by the Australian Government dedicated to boosting investment in resource exploration in Australia. As part of the Exploring for the Future program, this study aims to improve our understanding of the petroleum resource potential of northern Australia. The physical properties of organic matter in sedimentary rocks changes composition in an irreversible and often sequential manner after burial, diagenesis, catagenesis and metagenesis with increasing thermal maturity. Characterising these changes and identifying the thermal maturity of sedimentary rocks is essential for calculating thermal models needed in a petroleum systems analysis. This study presents organic petrology on 15 Proterozoic aged shales from the Velkerri and Barney Creek formations in the McArthur Basin and the Mullera Formation, Riversleigh Siltstone, Lawn Hill and Termite Range formations in the South Nicholson region. Qualitative maceral analysis of the 15 samples are described in addition to bitumen reflectance measurements. These samples were analysed at the Montanuniversität Leoben, Austria in June 2020. The results of this study can be used to improve our understanding of the thermal maturity and hydrocarbon prospectivity of Proterozoic aged sedimentary basins in northern Australia.

<div>This report presents new data from X-ray Computerised Tomography (XCT) scanning, gas porosity and permeability testing, and grain density measurements of 79 of 82 samples from the Birrindudu and McArthur basins. Three plugs could not be recovered from the whole core section. Plugs were taken from depths of interest from drill holes Manbulloo S1, Hidden Valley S2, Broughton 1, ANT003, 99VRNTGSDD1, 99VRNTGSDD2, Lamont Pass 3 and WLMB001B.</div><div><br></div><div>These tests were performed in 2023 by CSIRO in Perth. The full results as provided by CSIRO to Geoscience Australia are provided as an attachment to this document.&nbsp;This work was conducted as part of the Exploring for the Future Program (Officer–Musgrave–Birrindudu module).</div><div><br></div>

<div>This dataset presents results of a first iteration of a 3D geological model across the Georgina Basin, Beetaloo Sub-basin of the greater McArthur Basin and South Nicholson Basin (Figure 1), completed as part of Geoscience Australia’s Exploring for the Future Program National Groundwater Systems (NGS) Project. These basins are located in a poorly exposed area between the prospective Mt Isa Province in western Queensland, the Warramunga Province in the Northern Territory, and the southern McArthur Basin to the north. These surrounding regions host major base metal or gold deposits, contain units prospective for energy resources, and hold significant groundwater resources. The Georgina Basin has the greatest potential for groundwater.</div><div>&nbsp;</div><div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to net zero emissions, strong, sustainable resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225m investment by the Australian Government. More information is available at http://www.ga.gov.au/eftf and https://www.eftf.ga.gov.au/national-groundwater-systems.</div><div>&nbsp;</div><div>This model builds on the work undertaken in regional projects across energy, minerals and groundwater aspects in a collection of data and interpretation completed from the first and second phases of the EFTF program. The geological and geophysical knowledge gathered for energy and minerals projects is used to refine understanding of groundwater systems in the region.</div><div>&nbsp;</div><div>In this study, we integrated interpretation of a subset of new regional-scale data, which include ~1,900 km of deep seismic reflection data and 60,000 line kilometres of AusAEM1 airborne electromagnetic survey, supplemented with stratigraphic interpretation from new drill holes undertaken as part of the National Drilling Initiative and review of legacy borehole information (Figure 2). A consistent chronostratigraphic framework (Figure 3) is used to collate the information in a 3D model allowing visualisation of stacked Cenozoic Karumba Basin, Mesozoic Carpentaria Basin, Neoproterozoic to Paleozoic Georgina Basin, Mesoproterozoic Roper Superbasin (including South Nicholson Basin and Beetaloo Sub-basin of the southern McArthur Basin), Paleoproterozoic Isa, Calvert and Leichhardt superbasins (including the pre-Mesoproterozoic stratigraphy of the southern McArthur Basin) and their potential connectivity. The 3D geological model (Figure 4) is used to inform the basin architecture that underpins groundwater conceptual models in the region, constrain aquifer attribution and groundwater flow divides. This interpretation refines a semi-continental geological framework, as input to national coverage databases and informs decision-making for exploration, groundwater resource management and resource impact assessments.</div><div><br></div><div>This metadata document is associated with a data package including:</div><div>·&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;Nine surfaces (Table 1): 1-Digital elevation Model (Whiteway, 2009), 2-Base Cenozoic, 3-Base Mesozoic, 4-Base Neoproterozoic, 5-Base Roper Superbasin, 6-Base Isa Superbasin, 7-Base Calvert Superbasin, 8-Base Leichhardt Superbasin and 9-Basement.</div><div>·&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;Eight isochores (Table 4): 1-Cenozoic sediments (Karumba Basin), 2-Mesozoic sediments (Carpentaria and Eromanga basins), 3-Paleozoic and Neoproterozoic sediments (Georgina Basin), 4-Mesoproterozoic sediments (Roper Superbasin including South Nicholson Basin and Beetaloo Sub-basin), 5-Paleoproterozoic Isa Superbasin, 6-Paleoproterozoic Calvert Superbasin, 7-Paleoproterozoic Leichhardt Superbasin and 8-Undifferentiated Paleoproterozoic above basement.</div><div>·&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;Five confidence maps (Table 5) on the following stratigraphic surfaces: 1-Base Cenozoic sediments, 2-Base Mesozoic, 3-Base Neoproterozoic, 4-Base Roper Superbasin and 5-Combination of Base Isa Superbasin/Base Calvert Superbasin/Base Leichhardt Superbasin/Basement.</div><div>·&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;Three section examples (Figure 4) with associated locations.</div><div>Two videos showing section profiles through the model in E-W and N-S orientation.</div>

NDI Carrara 1 is a deep stratigraphic well completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI), in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-Basin, a newly discovered depocentre in the South Nicholson region. The well intersected Proterozoic sediments with numerous hydrocarbon shows, likely to be of particular interest due to affinities with the known Proterozoic plays of the Beetaloo Sub-basin and the Lawn Hill Platform, including two organic-rich black shales and a thick sequence of interbedded black shales and silty-sandstones. Alongside an extensive suite of wireline logs, continuous core was recovered from 283.9 m to total depth at 1750.8 m, providing high-quality data to support comprehensive analysis. Presently, this includes geochronology, geochemistry, geomechanics, and petrophysics. Rock Eval pyrolysis data demonstrates the potential for several thick black shales to be a source of hydrocarbons for conventional and unconventional plays. Integration of these data with geomechanical properties highlights potential brittle zones within the fine-grained intervals where hydraulic stimulation is likely to enhance permeability, identifying prospective Carrara Sub-basin shale gas intervals. Detailed wireline log analysis further supports a high potential for unconventional shale resources. Interpretation of the L210 and L212 seismic surveys suggests that the intersected sequences are laterally extensive and continuous throughout the Carrara Sub-basin, potentially forming a significant new hydrocarbon province and continuing the Proterozoic shale play fairway across the Northern Territory and northwest Queensland. This abstract was submitted and presented at the 2022 Australian Petroleum Production and Exploration Association (APPEA), Brisbane (https://appea.eventsair.com/appea-2022/)

The ca. 1.4 billion years (Ga) old Roper Group of the McArthur Basin, northern Australia, is one of the most extensive Proterozoic hydrocarbon-bearing basins deposited in a large epeiric sea known as the Roper Seaway. Black shales from the Velkerri Formation were deposited in a deep water shoaling sequence and are well preserved in the Altree 2 drillcore in the Beetaloo Sub-basin. These shales were analysed to determine their organic geochemical (biomarker) signatures which were used to interpret the microbial diversity and palaeoenvironment of the Roper Seaway. The results were integrated with published inorganic geochemistry and microfossil distributions. The indigenous hydrocarbon biomarker assemblages describe a water column dominated by bacteria with large scale heterotrophic reworking of the organic matter in the water column or bottom sediment. Evidence for microbial reworking includes a large unresolved complex mixture (UCM) and high ratios of monomethyl alkanes relative to n-alkanes—features characteristic of indigenous Proterozoic bitumen. Steranes, biomarkers for single-celled and multicellular eukaryotes, were below detection limits in all extracts analysed, despite eukaryotic microfossils having been previously identified in the Roper Group. These data suggest that eukaryotes, while present in the Roper Seaway, were ecologically restricted and contributed little to the net biomass. The combination of increased dibenzothiophene in the middle Velkerri Formation and low concentrations of 2,3,6-trimethyl aryl isoprenoids throughout the Velkerri Formation suggest that the water column at the time of deposition was transiently euxinic. As a comparison we reanalysed extracts from the 1.64 Ga Barney Creek Formation of the McArthur Basin. The biomarker assemblages differ between the Velkerri and Barney Creek Formations between is a biomarkers and water column chemistry, demonstrating that the microbial environments and water column geochemistry were variable in the Proterozoic.

Exploring for the Future (EFTF) is a four-year (2016-20) geoscience data and information acquisition program that aims to better understand on a regional scale the potential mineral, energy and groundwater resources concealed under cover in northern Australia and parts of South Australia. Hydrogeochemical surveys utilise groundwater as a passive sampling medium to reveal the chemistry of the underlying geology including hidden mineralisation. These surveys also potentially provide input into regional baseline groundwater datasets that can inform environmental monitoring and decision making. Geoscience Australia, as part of the Australian Government’s EFTF program, undertook an extensive groundwater sampling survey in collaboration with the Northern Territory Geological Survey and the Geological Survey of Queensland. During the 2017, 2018 and 2019 dry season, 224 groundwater samples (including field duplicate samples) were collected from 203 pastoral and water supply bores in the Tennant Creek-Mt Isa EFTF focus area of the Northern Territory and Queensland. An additional 38 groundwater samples collected during the 2013 dry season in the Lake Woods region from 35 bores are included in this release as they originate from within the focus area. The area was targeted to evaluate its mineral potential with respect to iron oxide copper-gold, sediment-hosted lead-zinc-silver and Cu-Co, and/or lithium-boron-potash mineral systems, among others. The 2017-2019 surveys were conducted across 21 weeks of fieldwork and sampled groundwater for a comprehensive suite of hydrogeochemical parameters, including isotopes, analysed over subsequent months. The present data release includes information and atlas maps of: 1) sampling sites; 2) physicochemical parameters (EC, pH, Eh, DO and T) of groundwater measured in the field; 3) field measurements of total alkalinity (HCO3-), dissolved sulfide (S2-), and ferrous iron (Fe2+); 4) major cation and anion results; 5) trace element concentrations; 6) isotopic results of water (δ18O and δ2H), DIC (δ13C), dissolved sulfate (δ34S and δ18O), dissolved strontium (87Sr/86Sr), and dissolved lead (204Pb, 206Pb, 207Pb, and 208Pb) isotopes; 7) dissolved hydrocarbon VFAs, BTEX, and methane concentrations, as well as methane isotopes (δ13C and δ2H); and 8) atlas of hydrogeochemical maps representing the spatial distribution of these parameters. Pending analyses include: CFCs and SF6; tritium; Cu isotopes; and noble gas concentrations (Ar, Kr, Xe, Ne, and 4He) and 3He/4He ratio. This data release (current as of July 2021) is the second in a series of staged releases and interpretations from the Northern Australia Hydrogeochemical Survey. It augments and revises the first data release, which it therefore supersedes. Relevant data, information and images are available through the GA website (https://pid.geoscience.gov.au/dataset/ga/133388) and GA’s EFTF portal (https://portal.ga.gov.au/).