Seismic reflection mapping, geochemical analyses and petroleum systems modelling have increased our understanding of the highly prospective Mesoproterozoic and Paleoproterozoic source rocks across northern Australia, expanding the repertoire of exploration targets currently being exploited in Proterozoic petroleum systems. Data collected during the Exploring for the Future program have enabled us to redefine and increase the extent of regional petroleum systems, which will encourage additional interest and exploration activity in frontier regions. Here, we present a review of the Paleoproterozoic McArthur and Mesoproterozoic Urapungan petroleum supersystems, and the most up-to-date interpretation of burial and thermal history modelling in the greater McArthur Basin (including the Beetaloo Sub-basin), South Nicholson Basin and Isa Superbasin. We also present potential direct hydrocarbon indicators imaged in the 2017 South Nicholson Deep Crustal Seismic Survey that increase the attractiveness of this frontier region for hydrocarbon exploration activities. <b>Citation:</b> MacFarlane, S.K., Jarrett, A.J.M., Hall, L.S., Edwards, D., Palu, T.J., Close, D., Troup, A. and Henson, P., 2020. A regional perspective of the Paleo- and Mesoproterozoic petroleum systems of northern Australia. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

The Exploring for the Future program is an initiative by the Australian Government dedicated to boosting investment in resource exploration in Australia. As part of the Exploring for the Future program, this study aims to improve our understanding of the petroleum resource potential of northern Australia. The physical properties of organic matter in sedimentary rocks changes composition in an irreversible and often sequential manner after burial, diagenesis, catagenesis and metagenesis with increasing thermal maturity. Characterising these changes and identifying the thermal maturity of sedimentary rocks is essential for calculating thermal models needed in a petroleum systems analysis. This study presents organic petrology on 15 Proterozoic aged shales from the Velkerri and Barney Creek formations in the McArthur Basin and the Mullera Formation, Riversleigh Siltstone, Lawn Hill and Termite Range formations in the South Nicholson region. Qualitative maceral analysis of the 15 samples are described in addition to bitumen reflectance measurements. These samples were analysed at the Montanuniversität Leoben, Austria in June 2020. The results of this study can be used to improve our understanding of the thermal maturity and hydrocarbon prospectivity of Proterozoic aged sedimentary basins in northern Australia.

Following the publication of Geoscience Australia record 2014/09: Petroleum geology inventory of Australia's offshore frontier basins by Totterdell et. al, (2014), the onshore petroleum section embarked upon a similar project for onshore Australian basins. The purpose of this project is to provide a thorough basis for whole of basin information to advise the Australia Government and other stakeholders, such as the petroleum industry, regarding the exploration status and prospectivity of onshore Australian basins. Eight onshore Australian basins have been selected for this volume and these include: the McArthur, South Nicholson, Georgina, Amadeus, Warburton, Wiso, Galilee and Cooper basins. This record provides a comprehensive whole of basin inventory of the geology, petroleum systems, exploration status and data coverage for these eight onshore Australian basins. It draws on precompetitive work programs by Geoscience Australia as well as publicly available exploration results and geoscience literature. Furthermore, the record provides an assessment of issues and unanswered questions and recommends future work directions to meet these unknowns.

Legacy dataset from the NABRE Project, comprising multi-spectral gamma logs obtained on different drill core in the Mount Isa Province to McArthur Basin regions (Northern Territory and Queensland).

The Exploring for the Future program is an initiative by the Australian Government dedicated to boosting investment in resource exploration in Australia. As part of the Exploring for the Future program, this study aims to improve our understanding of the petroleum resource potential of northern Australia. This data release presents the bulk kerogen kinetics of 21 potential source rocks from the McArthur Basin and the Lawn Hill Platform to understand the rate of hydrocarbon conversion. Kerogen was isolated from bulk rock, and analysed by a Rock-Eval 6 (Vinci Technologies, France) using four different temperature ramps. All sample preparation and analyses were carried out in Geoscience Australia’s in-house laboratories. The results of this study can be used to improve our understanding of the hydrocarbon generative potential of Proterozoic aged source rocks in northern Australia.

<p>Northern Australia contains extensive Proterozoic-aged sedimentary basins with potential energy, mineral, and groundwater resources concealed beneath the surface. The region is remote and largely underexplored with limited data and infrastructure and therefore is considered to have high exploration risk. Exploration for hydrocarbons and basin-hosted base metals, although perceived to have very different exploration models, share a number of important similarities and key parameters. Foremost amongst these is shale geochemistry since the same reduced, organic-rich shales are both a hydrocarbon source rock and a depositional site for base metal mineralisation. Furthermore, anoxic and euxinic (anoxic with free hydrogen sulfide, H2S) water column and sediments are important for both the preservation of organic matter and as a H2S reservoir needed for precipitation of ore minerals after reaction with oxic metalliferous brines. Here we present new organic and inorganic geochemical datasets for shales in the South Nicholson Basin, Lawn Hill Platform and greater McArthur Basin, including the organic-richness of shales and the inorganic geochemistry of redox-sensitive trace metals, to demonstrate changes in water-column chemistry and favourable base metals depositional sites. Parameters such as total organic carbon (TOC) content and redox-sensitive elemental concentrations are used to identify prospective packages with hydrocarbon and base metals mineral resource potential <p>The results reveal many units in the Lawn Hill Platform, South Nicholson Basin and greater McArthur Basin contain organic-rich rocks. A cut-off value of TOC ≥ 2 wt% is used to define several shale and carbonate sequences in the region that are favourable for both hydrocarbon generation and as base metals depositional sites. Inorganic geochemistry results demonstrate a range of paleoredox conditions, from predominantly anoxic, ferruginous conditions with deviations, to sub-oxic and euxinic conditions. Future work mapping the temporal and spatial distribution of this geochemistry, in combination with other mappable geological criteria, is required to create mineral and petroleum systems models that can define prospective fairways across the basins and increase our understanding of resource potential. <p>The precompetitive data generated in this study highlight the utility of shared geochemical datasets for resource exploration in the region. More broadly, this study improves our understanding of the energy and mineral potential across northern Australia, supporting resource decision-making and investment.

Discovery of mid-Proterozoic (1.8 – 0.8 billion years ago, Ga) indigenous biomarkers is a challenge, since biologically informative molecules of such antiquity are commonly destroyed by metamorphism or overprinted by drilling fluids and other anthropogenic petroleum products. The previously oldest biomarkers were reported from the 1.64 Ga Barney Creek Formation in the McArthur Basin, northern Australian. In this study, we present the discovery of clearly indigenous biomarker molecules from carbonaceous shales of the 1.73 Ga Wollogorang Formation in the southern McArthur Basin, extending the biomarker record back in time by ~90 million years. The extracted hydrocarbons illustrate typical mid-Proterozoic signatures with a large unresolved complex mixture, high methyl-alkane/n-alkane ratios and absence of eukaryotic steranes. Also below detection limits were acyclic isoprenoids, saturated carotenoid derivatives, bacterial hopanes and aromatic hopanoids and steroids. Detected, however, were continuous homologous series (C13-C22) of 2,3,4- and 2,3,6-trimethyl aryl isoprenoids (AI). These breakdown products of aromatic carotenoids are the oldest known biogenic molecules, revealing the activity of phototrophic green (Chlorobiaceae) and purple sulphur bacteria (Chromatiaceae). The compounds provide evidence for at least temporary, very shallow (less than ~20 m) stratification of the McArthur Basin 1.73 Ga ago, supporting models of pervasive anoxic conditions in mid-Proterozoic basins.

NDI Carrara 1 is a deep stratigraphic well completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI), in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-Basin, a newly discovered depocentre in the South Nicholson region. The well intersected Proterozoic sediments with numerous hydrocarbon shows, likely to be of particular interest due to affinities with the known Proterozoic plays of the Beetaloo Sub-basin and the Lawn Hill Platform, including two organic-rich black shales and a thick sequence of interbedded black shales and silty-sandstones. Alongside an extensive suite of wireline logs, continuous core was recovered from 283.9 m to total depth at 1750.8 m, providing high-quality data to support comprehensive analysis. Presently, this includes geochronology, geochemistry, geomechanics, and petrophysics. Rock Eval pyrolysis data demonstrates the potential for several thick black shales to be a source of hydrocarbons for conventional and unconventional plays. Integration of these data with geomechanical properties highlights potential brittle zones within the fine-grained intervals where hydraulic stimulation is likely to enhance permeability, identifying prospective Carrara Sub-basin shale gas intervals. Detailed wireline log analysis further supports a high potential for unconventional shale resources. Interpretation of the L210 and L212 seismic surveys suggests that the intersected sequences are laterally extensive and continuous throughout the Carrara Sub-basin, potentially forming a significant new hydrocarbon province and continuing the Proterozoic shale play fairway across the Northern Territory and northwest Queensland. This abstract was submitted and presented at the 2022 Australian Petroleum Production and Exploration Association (APPEA), Brisbane (https://appea.eventsair.com/appea-2022/)

The Mesoproterozoic Roper Group of the McArthur Basin has excellent petroleum potential but exploration has been hampered by poor constraints on its post-depositional history that has compromised understanding of the tectonostratigraphic evolution of the basin. The Derim Derim Dolerite occupies an important position in the event chronology of the McArthur Basin, having intruded the Roper Group prior to post-Roper basin inversion, and it is also a major component of Mesoproterozoic intraplate mafic magmatism in northern Australia. Since 1997, the Derim Derim Dolerite has been assigned a magmatic crystallisation age of 1324 ± 4 Ma (all uncertainties are 95% confidence), based on unpublished Sensitive High Resolution Ion Micro Probe (SHRIMP) U–Pb analyses on baddeleyite attributed to a dolerite sample from Bureau of Mineral Resources drill-hole Urapunga 5. Herein, we establish that the SHRIMP sample originated from the type locality of the Derim Derim Dolerite in outcrop 90 km northwest of Urapunga 5 and document the 207Pb/206Pb date interpreted from the 1997 dataset. New U–Pb SHRIMP reanalysis of the same grain-mounts yielded a mean 207Pb/206Pb date of 1320.1 ± 5.3 Ma, confirming the 1997 result, and Isotope Dilution-Thermal Ionisation Mass Spectrometry (ID TIMS) analysis of baddeleyites plucked from the mounts yielded a precise mean 207Pb/206Pb date of 1327.5 ± 0.6 Ma. This date is significantly older than a baddeleyite U–Pb ID-TIMS date of ca 1313 Ma recently reported elsewhere from dolerite in the Beetaloo Sub-basin 200 km to the south, indicating that magmatism attributed to the Derim Derim Dolerite spanned at least 10–15 Ma. Previously documented geochemical variation in Mesoproterozoic intraplate mafic rocks across the Northern Territory (such as the 1325 ± 36 Ma Galiwinku Dolerite in the McArthur Basin, 1316 ± 40 Ma phonolites in the Nimbuwah Domain of the eastern Pine Creek Orogen, and 1295 ± 14 Ma gabbro in the Tomkinson Province) may reflect episodic pulses of magmatism hitherto obscured by the low precision of the available isotopic dates. The timing and geochemistry of Derim Derim-Galiwinku mafic igneous activity is strikingly similar to that of the Yanliao Large Igneous Province (LIP) in the northern North China Craton, and the global paucity of 1330–1300 Ma LIPs suggests that the North Australian Craton and the North China Craton were in relatively close proximity at that time.

The ca. 1.4 Ga Roper Group of the greater McArthur Basin in northern Australia comprises the sedimentary fill of one of the most extensive Precambrian hydrocarbon-bearing basins preserved in the geological record. It is interpreted to have been deposited in a large epeiric sea known as the Roper Seaway. Trace element data suggest that the redox structure of the basin was a shallow oxic layer overlying deeper suboxic to anoxic waters along with a prominent episode of euxinia. These anoxic and sulfidic conditions, as inferred by redox sensitive trace element (TE) abundances, (molybdenum, vanadium and uranium), developed due to high organic carbon loading consistent with models that suggest that euxinic conditions cannot develop until the flux of organic matter is significantly greater than the flux of bioavailable iron (Fe³⁺), which permits sulphate reduction to proceed. Considering the high reactive iron and molybdenum contents of these shales and the requirement for S/Fe ratios >2 for euxinia to develop, suggest sufficient atmospheric O₂ was available for oxidative scavenging of S and Mo from the continents. This is further supported by prominent negative cerium anomalies within these shales, indicative of active oxidative redox cycling of cerium. We propose that the high organic matter flux was the result of increased nutrient loading to the Roper Seaway from weathering of the continental hinterland. Data from both major and high-field strength elements (niobium, tantalum, zirconium and, hafnium) together with neodymium isotopes (¹⁴³Nd/¹⁴⁴Nd) indicate that a likely mechanism for this enhanced nutrient delivery was a shift in sedimentary provenance to a more primitive (i.e. mafic) precursor lithology. This switch in provenance would have increased phosphorus delivery to the Roper Seaway, contributing to high primary productivity and the onset of euxinia. This dataset and model serve as a basis for understanding the temporal evolution of the deepest sections of the Roper Seaway and finer scale changes in the environment at this time. <b>Citation:</b> Grant M. Cox, Amber Jarrett, Dianne Edwards, Peter W. Crockford, Galen P. Halverson, Alan S. Collins, André Poirier, Zheng-Xiang Li, Basin redox and primary productivity within the Mesoproterozoic Roper Seaway, <i>Chemical Geology</i>, Volume 440, 2016, Pages 101-114, ISSN 0009-2541, https://doi.org/10.1016/j.chemgeo.2016.06.025.