Geoscience Australia and CO2CRC have constructed a greenhouse gas controlled release facility to simulate surface emissions of CO2 (and other greenhouse gases) from the soil into the atmosphere under controlled conditions. The facility is located at an experimental agricultural station maintained by CSIRO Plant Industry at Ginninderra, Canberra. The design of the facility is modelled on the ZERT controlled release facility in Montana. The facility is equipped with a 2.5 tonne liquid CO2 storage vessel, vaporiser and mass flow controller unit with a capacity for 6 individual metered CO2 gas streams (up to 600 kg/d capacity in total). Injection of CO2 into the soil is via a 120m long slotted HDPE pipe installed horizontally 2m underground. This is equipped with a packer system to partition the well into six CO2 injection chambers. The site is characterised by the presence of deep red and yellow podsolic soils with the subsoil containing mainly kaolinite and subdominant illite. Injection is above the water table. The choice of well orientation based upon the effects of various factors such as topography, wind direction, soil properties and ground water depth will be discussed. An above ground release experiment was conducted from July - October 2010 leading to the development of an atmospheric tomography technique for quantifying and locating CO2 emissions1. An overview of monitoring experiments conducted during the first subsurface release (January-March 2012), including application of the atmospheric tomography technique, soil flux surveys, microbiological surveys, and tracer studies, will be presented. Additional CO2 release experiments are planned for late 2012 and 2013. Poster presented at 11th Annual Conference on Carbon Capture Utilization & Sequestration, April 30 - May 3, 2012, Pittsburgh, Pennsylvania

Abstract: The extent to which fluids may leak from sedimentary basins to the seabed is a critical issue for assessing the potential of a basin for carbon capture and storage. The Petrel Sub-basin, located beneath central and eastern Joseph Bonaparte Gulf in tropical northern Australia, is identified as potentially suitable for the geological storage of CO2 because of its geological characteristics and proximity to offshore gas and petroleum resources. In May 2012, a multidisciplinary marine survey was undertaken to collect data in two targeted areas of the Petrel Sub-basin to facilitate an assessment of CO2 storage potential. Multibeam bathymetry and backscatter mapping (650 km2 over 5,300 line km), combined with acoustic sub-bottom profiling (650 line km) and geomorphological and sediment characterisation of the seabed was undertaken above the CO2 supercritical seal boundary of the sub-basin. Features identified in the high resolution (2 m) bathymetry data include carbonate banks, ridges, pockmark fields and fields of low amplitude hummocks located directly adjacent to banks. Unit and composite pockmarks and clusters of pockmarks are present on plains and adjacent to, and on, carbonate ridges. It is postulated that there are three possible sources for fluids and fluidised gas involved in pockmark formation: deep fluids from the basin, post-Cretaceous intra-formational, layer-bound fluids, and shallow-sourced fluidised gas from the breakdown of organic matter following the Holocene marine transgression of Joseph Bonaparte Gulf.

The middle to lower Jurassic sequence in Australia's Surat Basin has been identified as a potential reservoir system for geological CO2 storage. The sequence comprises three major formations with distinctly different mineral compositions, and generally low salinity formation water (TDS<3000 mg/L). Differing geochemical responses between the formations are expected during geological CO2 storage. However, given the prevailing use of saline reservoirs in CCS projects elsewhere, limited data are available on CO2-water-rock dynamics during CO2 storage in such low-salinity formations. Here, a combined batch experiment and numerical modelling approach is used to characterise reaction pathways and to identify geochemical tracers of CO2 migration in the low-salinity Jurassic sandstone units. Reservoir system mineralogy was characterized for 66 core samples from stratigraphic well GSQ Chinchilla 4, and six representative samples were reacted with synthetic formation water and high-purity CO2 for up to 27 days at a range of pressures. Low formation water salinity, temperature, and mineralization yield high solubility trapping capacity (1.18 mol/L at 45°C, 100 bar), while the paucity of divalent cations in groundwater and the silicate reservoir matrix results in very low mineral trapping capacity under storage conditions. Formation water alkalinity buffers pH at elevated CO2 pressures and exerts control on mineral dissolution rates. Non-radiogenic, regional groundwater-like 87Sr/86Sr values (0.7048-0.7066) indicate carbonate and authigenic clay dissolution as the primary reaction pathways regulating solution composition, with limited dissolution of the clastic matrix during the incubations. Several geochemical tracers are mobilised in concentrations greater than found in regional groundwater, most notably cobalt, concentrations of which are significantly elevated regardless of CO2 pressure or sample mineralogy.

Underground gas storage (UGS) facilities provide a wealth of information, which can be used to better understand various aspects of CO2 storage in depleted reservoirs. In some cases UGS facilities can provide important site specific information for carbon storage projects that are planned in similar formations in close proximity. In this paper, we discuss the various ways in which UGS facilities can be used to extract important information, and when possible we draw upon information from the Iona gas storage facility in Australia's Otway basin. The Iona facility is located 20 km away from the CO2CRC Otway Project, in which CO2 65445 tonnes of 77 mole% carbon dioxide, 20 mole% methane and 3 mole% other gas components (containing about 58000 tonnes of carbon dioxide) was injected into the Waarre C formation over a 17 month period. In this paper, we compare the factors that control CO2 seal capacity and discuss how UGS facilities can provide information on sustainable column heights either limited by faults or by cap rocks. We also present dynamic modeling results in which information is gained regarding injectivity, pressure evolution of the reservoir, storage capacity and maximum fluid pressures sustained by the faults. Understanding such parameters is important for the safe operation of any carbon storage project, be it on a demonstration or industrial scale.

Quantification of leakage into the atmosphere from geologically stored CO2 is achievable by means of atmospheric monitoring techniques if the position of the leak can be located and the perturbation above the background concentration is sufficiently large for discrimination. Geoscience Australia and the CO2CRC have recently constructed a site in northern Canberra for the controlled release of greenhouse gases. This facility enables the simulation of leak events and provides an opportunity to investigate techniques for the detection and quantification of emissions of CO2 (and other greenhouse gases) into the atmosphere under controlled conditions. The facility is modelled on the ZERT controlled release facility in Montana. The first phase of the installation is complete and has supported an above ground, point source, release experiment (e.g. simulating leakage from a compromised well). Phase 2 involves the installation of a shallow underground horizontal well for line source CO2 release experiments and this will be installed during the first half of 2011. A release experiment was conducted at the site to explore the application of a technique, termed atmospheric tomography, to simultaneously determine the location and emission rate of a leak when both are unknown. The technique was applied to the release of two gas species, N2O and CO2, with continuous sampling of atmospheric trace gas concentrations from 8 locations 20m distant from a central release point and measurement of atmospheric turbulence and dispersive conditions. The release rate was 1.10 ± 0.02 g min-1 for N2O and 58.5 ± 0.4 g min-1 for CO2 (equivalent to 30.7 ± 0.2 tonnes CO2 yr-1). Localisation using both release species occurred within 0.5 m (2% error) of the known location. Determination of emission rate was possible to within 7% for CO2 and 5% for N2O.

Carbon capture and storage is a mitigation strategy that could rapidly reduce CO2 emissions from high emission sources. However, the exploration and assessment of reservoirs for the geological storage of CO2 is a complicated science commonly hampered by large uncertainties. The major hurdles lie in correctly assessing the prospectivity of basin plays, and ultimately of play fairways suitable for CO2 storage. On the North West Shelf of Australia, turbidite deposits are a common depositional system and many are considered prospective for CO2 storage in this emission intensive part of Australia. Using an integrated reservoir modelling approach, this study assessed the storage potential of the Caswell Fan turbidite in the Browse Basin, Western Australia. A detailed seismic interpretation utilising both 2D and 3D seismic and four previously drilled wells, provided the sequence stratigraphic framework for a detailed reservoir evaluation. The Fan was deposited in a basin floor fan setting within a lowstand systems tract, which provided optimal conditions for sequestration due to the sandstone's extended geometry, sorting, and high net-to-gross ratios, all overlain by a regional marine claystone seal. Through 3D static geological modelling it was determined that the Caswell Fan had an estimated storage capacity of approximately 300 million tonnes of CO2. This largely unconfined basin floor fan represents one of several plays along the North West Shelf of Australia, which could provide suitable CO2 storage formations for the carbon capture and storage industry.

Between 2009 and 2012, Australia and China successfully completed the first phase of a bilateral project that aimed to build capacity in the area of geological storage of carbon dioxide among Chinese researchers, students, policy makers and professionals from academia, government and industry. This paper details the activities and results of the International CCS CAGS project, Phase I.

The Early Cretaceous Gage Sandstone and South Perth Shale formations are one of the most prospective reservoir-seal pairs in the Vlaming Sub-basin. Plays include post-breakup pinch-outs with the South Perth Shale forming a top seal. The Gage reservoir has porosities of 23-30% and permeabilities of 200-1800 mD and was deposited in palaeotopographic lows of the Valanginian breakup unconformity. This is overlain by the thick deltaic South Perth (SP) Supersequence. To characterise the reservoir-seal pair, a detailed sequence stratigraphic analysis was conducted by integrating 2D seismic interpretation, well log analysis and new biostratigraphic data. The palaeogeographic reconstructions for the Gage reservoir are based predominantly on the seismic facies mapping, whereas SP Sequence reconstructions are derived from mapping higher-order prograding sequences and establishing changes in sea level and sediment supply. The Gage reservoir forms part of a sand-rich submarine fan system and was deposited in water depths of > 400 m. It ranges from confined canyon fill to fan deposits on a basin plain. Directions of sediment supply are complex, with major sediment contributions from a northern and southern canyon adjacent to the Badaminna Fault Zone. The characteristics of the SP Supersequence differ markedly between the northern and southern parts of the sub-basin due to variations in palaeotopography and sediment supply. Palaeogeographic reconstructions reveal a series of regressions and transgressions leading to infilling of the palaeo-depression. Seven palaeogeographic reconstructions for the SP Supersequence portray a complex early post-rift depositional history in the central Vlaming Sub-basin. The developed approach could be applicable for detailed studies of other sedimentary basins

Geoscience Australia and CO2CRC have constructed a greenhouse gas controlled release reference facility to simulate surface emissions of CO2 (and other GHG gases) from an underground slotted horizontal well into the atmosphere under controlled conditions. The facility is located at an experimental agricultural station maintained by CSIRO Plant Industry at Ginninderra, Canberra. The design of the facility is modelled on the ZERT controlled release facility in Montana. The facility is equipped with a 2.5 tonne liquid CO2 storage vessel, vaporiser and mass flow controller unit with a capacity for 6 individual metered CO2 gas streams (up to 600 kg/d capacity). Injection of CO2 into soil is via a shallow (2m depth) underground 120m horizontally drilled slotted HDPE pipe. This is equipped with a packer system to partition the well into six CO2 injection chambers. The site is characterised by the presence of deep red and yellow podsolic soils with the subsoil containing mainly kaolinite and subdominant illite. Injection is above the water table. The choice of well orientation based upon the effects of various factors such as topography, wind direction, soil properties and ground water depth will be discussed. An above ground release experiment was conducted from July - October 2010 leading to the development of an atmospheric tomography technique for quantifying and locating CO2 emissions1. This technique will be applied to the first sub-surface experiment held in January-March 2012 in addition to soil flux surveys, microbiological surveys, and tracer studies. An overview of monitoring experiments conducted during the subsurface release and preliminary results will be presented. Additional CO2 releases are planned for late 2012 and 2013. Abstract for "11th Annual Conference on Carbon Capture Utilization & Sequestration" April 30 - May 3, 2012, Pittsburgh, Pennsylvania

The 2011 United Nations climate change meeting in Durban provided an historic moment for CCS. After five years without progress, the Cancun Decision (2010) put in place a work program to address issues of concern before CCS could be included under the Kyoto Protocol's Clean Development Mechanism (CDM) and so allow projects in developing countries to earn Certified Emission Reductions (CERs). The program - consisting submissions, a synthesis report and workshop - concluded with the UNFCCC Secretariat producing draft 'modalities and procedures describing requirements for CCS projects under the CDM. The twenty page 'rulebook' provided the basis for negotiations in Durban. The challenging negotiations, lasting over 32 hours, concluded on 9th December with Parties agreeing to adopt final modalities and procedures for CCS under the CDM. These include provisions for participation requirements (including host country regulations), site selection and characterisation, risk and safety assessment, monitoring, liabilities, financial provision, environmental and social impact assessments, responsibilities for long term non-permanence, and timing of the CDM-project end. A key issue was the responsibility for any seepage of CO2 emissions in the long-term (non-permanence). The modalities and procedures separate responsibility for non-permanence from the liability for any local damages resulting from operation of the storage site. In relation to the former, they allow for the host country to determine the responsible entity, either the host country or the country purchasing the CERs. Note that a CER which incorporates responsibility for seepage will be less attractive to buyers. Thus a standard is established for managing CCS projects in developing countries, which will ensure a high level of environmental protection and is workable for projects. It sets an important precedent for the inclusion of CCS into other support mechanisms.