Australia has been, and continues to be, a leader in isotope geochronology and geochemistry. While new isotopic data is being produced with ever increasing pace and diversity, there is also a rich legacy of existing high-quality age and isotopic data, most of which have been dispersed across a multitude of journal papers, reports and theses. Where compilations of isotopic data exist, they tend to have been undertaken at variable geographic scale, with variable purpose, format, styles, levels of detail and completeness. Consequently, it has been difficult to visualise or interrogate the collective value of age and isotopic data at continental-scale. Age and isotopic patterns at continental scale can provide intriguing insights into the temporal and chemical evolution of the continent (Fraser et al, 2020). As national custodian of geoscience data, Geoscience Australia has addressed this challenge by developing an Isotopic Atlas of Australia, which currently (as of November 2020) consists of national-scale coverages of four widely-used age and isotopic data-types: 4008 U-Pb mineral ages from magmatic, metamorphic and sedimentary rocks 2651 Sm-Nd whole-rock analyses, primarily of granites and felsic volcanics 5696 Lu-Hf (136 samples) and 553 O-isotope (24 samples) analyses of zircon 1522 Pb-Pb analyses of ores and ore-related minerals These isotopic coverages are now freely available as web-services for use and download from the GA Portal. While there is more legacy data to be added, and a never-ending stream of new data constantly emerging, the provision of these national coverages with consistent classification and attribution provides a range of benefits: vastly reduces duplication of effort in compiling bespoke datasets for specific regions or use-cases data density is sufficient to reveal meaningful temporal and spatial patterns a guide to the existence and source of data in areas of interest, and of major data gaps to be addressed in future work facilitates production of thematic maps from subsets of data. For example, a magmatic age map, or K-Ar mica cooling age map sample metadata such as lithology and stratigraphic unit is associated with each isotopic result, allowing for further filtering, subsetting and interpretation. The Isotopic Atlas of Australia will continue to develop via the addition of both new and legacy data to existing coverages, and by the addition of new data coverages from a wider range of isotopic systems and a wider range of geological sample media (e.g. soil, regolith and groundwater).

A major concern for regulators and the public with geological storage of CO2 is the potential for the migration of CO2 via a leaky fault or well into potable groundwater supplies. Given sufficient CO2, an immediate effect on groundwater would be a decrease in pH which could lead to accelerated weathering, an increase in alkalinity, release of major and minor ions and heavy metals (particularly Pd, Ni and Cr) as well as CO2 mobilisation of trace organic contaminants. These scenarios potentially occur in a high CO2 leakage event, therefore detection of a small leak, although barely perceptible, could provide an important early warning for a subsequent and more substantial impact. Different approaches are required for the detection and quantification of these low level leaks and are the subject of this paper. A 3 year groundwater survey was recently completed in the Surat Basin, which provided comprehensive water and isotopic analysis of groundwaters together with their exsolved gases. The gases were analysed for composition, -13CCO2, -13CCH4 and -2HCH4. Methane is prevalent in the major Surat Basin aquifers (e.g. Mooga, Gubberamunda and Hutton sandstones) and is invariably associated with a bacterial (methanogenic) carbonate reduction source, evident from its isotopic signature ('13CCH4 ~ -70', '2HCH4 ~ -220'). In addition to methane and low levels of CO2, trace ethane is common. Two neighbouring wells, however, were quite different to the other 85 wells surveyed. Their exsolved gases contained comparatively high ethane, but also C1-C6 hydrocarbons in addition to methane. Methane isotope systematics were significantly different from other groundwater wells completed in the same formation. The -13C of the CO2 was similar to the surrounding groundwater wells, but the relative proportion of CO2 in the gas was significantly higher. Combined, these characteristics are consistent with hydrocarbon biodegradation. There was little difference in the groundwater chemistry for these wells compared to the regional baseline. The study provides a useful analogue study for detection, at various scales, of a leaky well associated with a geological storage site. Compositional and isotopic analysis of exsolved gases from groundwater samples could be used to demonstrate non-equilibrium conditions and intrusion of exogenic CO2. Abstract for the 2013 International Association of Hydrologist Congress, Perth

Strontium isotopes (87Sr/86Sr) are useful in the earth sciences (e.g., recognising geological provinces, studying geological processes) as well in archaeological (e.g., informing on past human migrations), palaeontological/ecological (e.g., investigating extinct and extant taxa’s dietary range and migrations) and forensic (e.g., validating the origin of drinks and foodstuffs) sciences. Recently, Geoscience Australia and the University of Wollongong have teamed up to determine 87Sr/86Sr ratios in fluvial sediments selected from the low-density National Geochemical Survey of Australia (www.ga.gov.au/ngsa). The initial study targeted the northern parts of the Northern Territory and Queensland in Australia. The samples were taken from a depth of ~60-80 cm depth in floodplain deposits at or near the outlet of large catchments (drainage basins). A coarse grain-size fraction (<2 mm) was air-dried, sieved, milled then digested (hydrofluoric acid + nitric acid followed by aqua regia) to release total strontium. Preliminary results demonstrate a wide range of strontium isotopic values (0.7048 < 87Sr/86Sr < 1.0330) over the survey area, reflecting a large diversity of source rock lithologies, geological processes and bedrock ages. Spatial distribution of 87Sr/86Sr shows coherent (multi-point anomalies and gradients), large-scale (>100 km) patterns that appears to be consistent, in many places, with surface geology, regolith/soil type and/or nearby outcropping bedrock. For instance, the extensive black clay soils of the Barkly Tableland define a >500 km-long northwest-southeast trending low anomaly (87Sr/86Sr < 0.7182). Where carbonate or mafic igneous rocks dominate, a low to moderate strontium isotope signature is observed. In proximity to the outcropping Proterozoic metamorphic provinces of the Tennant, McArthur, Murphy and Mount Isa geological regions, high 87Sr/86Sr values (> 0.7655) are observed. A potential link between mineralisation and elevated 87Sr/86Sr values in these regions needs to be investigated in greater detail. Our results to-date indicate that incorporating soil/regolith strontium isotopes in regional, exploratory geoscience investigations can help identify basement rock types under (shallow) cover, constrain surface processes (e.g., weathering, dispersion), and, potentially, recognise components of mineral systems. Furthermore, the resulting strontium isoscape can also be utilised in archaeological, paleontological and ecological studies that aim to investigate past and modern animal (including humans) dietary habits and migrations.

The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Systems Section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018), Dorado 1 (2018) and Dorado 2–3 (2019) in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata (Grosjean et al., 2021; Rollet et al., 2019). As part of this program, a range of organic geochemical analyses were acquired on petroleum fluids from the Dorado 1 and Roc 2 wells with these data released in this report.

The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Systems Section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and attract exploration investment to Australia. As part of this program, molecular and isotopic analyses were undertaken by Geoscience Australia on gas samples from the well Dorado 1 and the raw data from these analyses are released in this report.

This Record presents 40Ar/39Ar chronologic results acquired in support of collaborative regional geoscientific investigations and mapping programs conducted by Geoscience Australia (GA) and the Northern Territory Geological Survey (NTGS). Argon isotopic data and interpretations from hornblende, muscovite, and biotite from seven samples collected from the Aileron Province in ALCOOTA , HUCKITTA, HALE RIVER, and ILLOGWA CREEK in the Northern Territory are presented herein. The results complement pre-existing geochronological constraints from U–Pb zircon and monazite analyses of the same or related samples, and provide new constraints on the thermal and deformation history of the Aileron Province. Three samples (2003082017, 2003082021, 2003083040) were taken from ALCOOTA in the northeastern portion of the Aileron Province. Biotite in sample 2003082017 from the ca 1.81 Ga Crooked Hole Granite records cooling below 320–280°C at 441 ± 5 Ma. Biotite in sample 2003082021 from the ca 1.73 Ga Jamaica Granite records cooling below 320–280°C at or after 414 ± 2 Ma. Muscovite in sample 2003083040 from the Delny Metamorphics, which were deposited after ca 1.82 Ga and preserve evidence for metamorphism at ca 1.72 Ga and 1.69 Ga, records cooling below 430–390°C at 399 ± 2 Ma. The fabrics preserved in the samples from the Crooked Hole Granite and Delny Metamorphics are interpreted to have formed due to dynamic metamorphism related to movement on the Waite River Shear Zone, an extension of the Delny Shear Zone, during the Palaeoproterozoic. Portions of the northeastern Aileron Province are unconformably overlain by the Neoproterozoic–Cambrian Georgina Basin, indicating these samples were likely at or near the surface by the Neoproterozoic. Together, these data indicate that rocks of the Aileron Province in ALCOOTA were subjected to heating above ~400°C during the Palaeozoic. Two samples (2003087859K, 2003087862F) of exoskarn from an indeterminate unit were taken from drillhole MDDH4 in the Molyhil tungsten–molybdenum deposit in central HUCKITTA. The rocks hosting the Molyhil tungsten–molybdenum deposit are interpreted as ca 1.79 Ga Deep Bore Metamorphics and ca 1.80 Ga Yam Gneiss. They experienced long-lived metamorphism during the Palaeoproterozoic, with supersolidus metamorphism observed until at least ca 1.72 Ga. Hornblende from sample 2003087859K indicates cooling below 520–480°C by 1702 ± 5 Ma and may closely approximate timing of skarn-related mineralisation at the Molyhil deposit; hornblende from sample 2003087862F records a phase of fluid flow at the Molyhil deposit at 1660 ± 4 Ma. The Salthole Gneiss has a granitic protolith that was emplaced at ca 1.79 Ga, and experienced alteration at ca 1.77 Ga. Muscovite from sample 2010080001 of Salthole Gneiss from the Illogwa Shear Zone in ILLOGWA CREEK records cooling of the sample below ~430–390°C at 327 ± 2 Ma. This may reflect the timing of movement of, or fluid flux along, the Illogwa Shear Zone. An unnamed quartzite in the Casey Inlier in HALE RIVER has a zircon U–Pb maximum depositional age of ca 1.24 Ga. Muscovite from sample HA05IRS071 of this unnamed quartzite yields an age of 1072 ± 8 Ma, which likely approximates, or closely post-dates, the timing of deformation in this sample; it provides the first direct evidence for a Mesoproterozoic episode of deformation in this part of the Aileron Province.

<div>Komatiites are extinct volcanic rocks that formed by partial melting of 20-50% of their mantle source – a unique feature that allows us to understand the composition of the mantle in the early Earth. Due to their high temperature, komatiites incorporate proximal rock types on their way to, and on, the Earth’s surface. In this craton-scale study, we looked to use this property of komatiite magmas to track their interaction with the crust of the Yilgarn Craton. The results yielded Hf and Nd isotope arrays (Figure 1), that potentially have three components. The first likely represents the depleted mantle source of the magmas, and most plot in the region between +2 and +6 εHfi and 0 to +3.3 εNdi. The second source represents a more unradiogenic component, most likely 3.5-3.3 Ga continental crust (minimum). This component is more notable in the 2.8 and 2.9 Ga events with values trending to CHUR and negative εNd. The 2.8 Ga dataset, and particularly the komatiitic basalts from the Marda region, appear to show the most contamination with old crust. This is likely due to this area representing the old nucleus of the craton, as shown in Hf-isotope mapping. The final component represents an ultra-depleted source. Data from Ravensthorpe, Mt Clifford, and Wiluna show trends towards this source referred to as the Early Refractory Reservoir (ERR)(Nebel et al. 2014). We suggest that the 2.7 and 2.9 Ga plumes interacted with refractory Hadean plume residues, which constitute the ERR, within the Yilgarn lithosphere. Isotopic data on crustal rocks suggests the Yilgarn may have formed in the Hadean to Eoarchean, and hence the ERR could represent the residue of the Hadean crust generation process that formed the low Lu/Hf Jack Hills zircons. If correct, this suggests that the ERR survived for much longer than previously thought, as a rare component within the Earth’s oldest cratons.</div> This Abstract was submitted/presented to the 2023 6th International Archean Symposium (6IAS) 25 - 27 July (https://6ias.org/)

The accessory mineral zircon is the most widely used geological timekeeper and tracer of crustal growth processes. Specifically, U-Pb isotopes in zircon offer a means to accurately determine the timing of magmatic events and their Hf isotopic composition provides a means to constrain magma source composition and potentially approximate source age. The high spatial resolution provided by in situ techniques such as secondary ion mass spectrometry (SIMS) and laser ablation inductively coupled mass spectrometry (LA-ICP-MS) have the advantage of being able to target different growth zones within individual zircon crystals, and unravel complex magmatic histories. However, utilising this power effectively requires calculation of accurate initial Hf compositions, which are founded on the assumption that the information obtained via the U-Pb and Lu-Hf systems are correctly integrated. A typical Hf isotope LA-ICP-MS analysis ablates a sample volume that is two orders of magnitude greater than a typical SIMS analysis. Thus, when age determination has been carried out by SIMS it is necessary to demonstrate that each subsequent Hf isotope analysis has sampled a similar isotopically homogeneous volume. Here, we use a combined SIMS and laser ablation split stream (LASS)-ICP-MS approach, whereby U-Pb isotopic measurement concurrently on the same sample volume as the Hf isotope measurement is compared to prior lower volume SIMS measurements. Using a suite of new drill core magmatic rock samples from the comparatively unexplored Coompana Province in South Australia, we demonstrate how such an approach can be used to filter Hf isotope datasets by identifying LA-ICP-MS analyses that sampled mixtures of different zircon growth domains. The robust initial 176Hf/177Hf compositions obtained from the filtered Coompana data set indicate that the province represents part of a juvenile Paleoproterozoic-Mesoproterozoic arc system formed through hyperextension of the margin of the Archean Gawler Craton, which can be correlated to the Musgrave Province and Madura Province in central and western Australia respectively. This hyperextension process is temporally similar to that on the now-adjacent Archean Yilgarn Craton margin.

<div>We present the first national-scale lead (Pb) isotope maps of Australia based on surface regolith for five isotope ratios, ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb, ²⁰⁸Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁶Pb, and ²⁰⁸Pb/²⁰⁶Pb, determined by single collector Sector Field-Inductively Coupled Plasma-Mass Spectrometry after an Ammonium Acetate leach followed by Aqua Regia digestion. The dataset is underpinned principally by the National Geochemical Survey of Australia (NGSA) archived floodplain sediment samples. We analysed 1219 ‘top coarse’ (0-10 cm depth, &lt;2 mm grain size) samples, collected near the outlet of 1098 large catchments covering 5.647 million km2 (~75% of Australia). This paper focusses on the Aqua Regia dataset. The samples consist of mixtures of the dominant soils and rocks weathering in their respective catchments (and possibly those upstream) and are therefore assumed to form a reasonable representation of the average isotopic signature of those catchments. This assumption was tested in one of the NGSA catchments, within which 12 similar ‘top coarse’ samples were also taken; results show that the Pb isotope ratios of the NGSA catchment outlet sediment sample are close to the average of the 12 sub-catchment, upstream samples. National minimum, median and maximum values reported for ²⁰⁶Pb/²⁰⁴Pb were 15.558, 18.844, 30.635; for ²⁰⁷Pb/²⁰⁴Pb 14.358, 15.687, 18.012; for ²⁰⁸Pb/²⁰⁴Pb 33.558, 38.989, 48.873; for ²⁰⁷Pb/²⁰⁶Pb 0.5880, 0.8318, 0.9847; and for ²⁰⁸Pb/²⁰⁶Pb 1.4149, 2.0665, 2.3002, respectively. The new dataset was compared with published bedrock and ore Pb isotope data, and was found to dependably represent crustal elements of various ages from Archean to Phanerozoic. This suggests that floodplain sediment samples are a suitable proxy for basement and basin geology at this scale, despite various degrees of transport, mixing, and weathering experienced in the regolith environment, locally over protracted periods of time. An example of atmospheric Pb contamination around Port Pirie, South Australia, where a Pb smelter has operated since the 1890s, is shown to illustrate potential environmental applications of this new dataset. Other applications may include elucidating detail of Australian crustal evolution and mineralisation-related investigations.&nbsp;</div> <b>Citation:</b> Desem, C. U., de Caritat, P., Woodhead, J., Maas, R., and Carr, G.: A regolith lead isoscape of Australia, <o>Earth Syst. Sci. Data</i>, 16, 1383–1393, https://doi.org/10.5194/essd-16-1383-2024, 2024.

The Roebuck Basin on Australia’s offshore north-western margin is the focus of a regional hydrocarbon prospectivity assessment being undertaken by the Offshore Energy Studies section. This offshore program is designed to produce pre-competitive information to assist with the evaluation of the hydrocarbon resource potential of the central North West Shelf and facilitate exploration investment in Australia. The recent oil and gas discoveries at Phoenix South 1 (2014), Roc 1 (2015-16), Roc 2 (2016), Phoenix South 2 (2016), Phoenix South 3 (2018), Dorado 1 (2018), Dorado 2 (2019) and Dorado 3 (2019) wells in the Bedout Sub-basin demonstrate the presence of a petroleum system in Lower Triassic strata (Thompson, 2020; Thompson et al., 2015 and 2018). The current study aims to better understand this new petroleum system and establish its extent. As part of this program, a range of organic geochemical analyses were acquired on petroleum fluids from the Roc 1 and Roc 2 wells with these data released in this report.