carbon isotopes
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<div>NDI Carrara 1 is a 1751 m stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI). This campaign was a collaboration between Geoscience Australia under the Exploring for the Future program, together with MinEx CRC and the Northern Territory Geological Survey. It is the first drillhole to intersect Proterozoic rocks of the Carrara Sub-basin, a recently discovered depocentre in the South Nicholson region. The drill hole intersected ~625 m of the Paleozoic Georgina Basin, which overlies ~1120 m of Proterozoic carbonates, black shales and siliciclastic rocks, with hydrocarbon shows encountered in both the Paleozoic and Proterozoic sections. Following the completion of the drillhole, a comprehensive analytical program was carried out by Geoscience Australia to better understand the geology of the Carrara Sub-basin and its resource potential.</div><div><br></div><div>Here we present new high-resolution strontium (87Sr/86Sr), carbon (δ13C) and oxygen (δ18O) isotope data from carbonate bearing samples of the Paleozoic Georgina Basin and the Proterozoic Lawn Hill Formation intersected in NDI Carrara 1. The aim of this data acquisition was to provide an improved understanding of the paleo-depositional environments and local/global chemostratigraphy trends recorded in the Carrara Sub-basin. </div><div><br></div><div>The majority of samples show significant alteration and thus caution should be exercised when using this data for assessing primary depositional conditions and contemporary sea-water chemistry. Despite the altered nature of most samples, samples belonging to undifferentiated Georgina Basin preserve 87Sr/86Sr ratios close to that of mid-Cambrian seawater, indicating the sampled intervals of Georgina Basin were likely connected to the global Cambrian ocean. Two small positive δ13C excursions (with positive shift in δ18O) within Georgina Basin samples may coincide with reported mid-Cambrian positive δ13C global marine excursions. </div><div><br></div><div>The least altered samples from the Proterozoic Lawn Hill Formation show more radiogenic 87Sr/86Sr values than the expected value of coeval mid-Proterozoic ocean at ~1600 Ma. These radiogenic 87Sr/86Sr values may reflect (i) influx of terrigenous material into a restricted basin with reduced interaction with the global ocean, or (ii) secondary overprinting by more radiogenic diagenetic fluids.</div> Abstract/Poster submitted and presented at 2023 Australian Earth Science Convention (AESC), Perth WA (https://2023.aegc.com.au/)
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<div>The bulk rock stable isotopes database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the stable isotopic composition of sedimentary rocks with an emphasis on calcareous rocks and minerals sampled from boreholes and field sites. The stable isotopes of carbon, oxygen, strontium, hydrogen, nitrogen, and sulfur are measured by various laboratories in service and exploration companies, Australian government institutions, and universities, using a range of instruments. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and the stable isotopes ratios. The carbon (<sup>13</sup>C/<sup>12</sup>C) and oxygen (<sup>18</sup>O/<sup>16</sup>O) isotope ratios of calcareous rocks are expressed in delta notation (i.e., δ<sup>13</sup>C and δ<sup>18</sup>O) in parts per mil (‰) relative to the Vienna Peedee Belemnite (VPDB) standard, with the δ<sup>18</sup>O values also reported relative to the Vienna Standard Mean Ocean Water (VSMOW) standard. Likewise, the stable isotope ratio of hydrogen (<sup> 2</sup>H/<sup> 1</sup>H) is presented in delta notation (δ<sup> 2</sup>H) in parts per mil (‰) relative to the VSMOW standard, the stable isotope ratio of nitrogen (<sup> 15</sup>N/<sup>14</sup>N) is presented in delta notation (δ<sup>15</sup>N) in parts per mil (‰) relative to the atmospheric air (AIR) standard, and the stable isotope ratio of sulfur (<sup> 34</sup>S/<sup> 32</sup>S) is presented in delta notation (δ<sup> 34</sup>S) relative to the Vienna Canyon Diablo Troilite (VCDT) standard. For carbonates, the strontium (<sup>87</sup>Sr/<sup>86</sup>Sr) isotope ratios are also provided.</div><div><br></div><div>These data are used to determine the isotopic compositions of sedimentary rock with emphasis on the carbonate within rocks, either as minerals, the mineral matrix or cements. The results for the carbonate rocks are used to determine paleotemperature, paleoenvironment and paleoclimate, and establish regional- and global-scale stratigraphic correlations. These data are collated from Geoscience Australia records, destructive analysis reports (DARs), well completion reports (WCRs), and literature. The stable isotope data for sedimentary rocks are delivered in the Stable Isotopes of Carbonates web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>
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<div>The Proterozoic basins of northern Australia have been the focus of regional hydrocarbon prospectivity studies undertaken by the Exploring for the Future program dedicated to increasing investment in resource exploration in northern Australia. As part of this program, a compilation of the compound-specific isotopic compositions of linear alkanes in source extracts, oils and oil stains from 21 boreholes of the greater McArthur Basin has been completed. The samples were analysed in Geoscience Australia’s Isotope and Organic Geochemistry Laboratory and the stable carbon and hydrogen isotopic data of individual alkanes are released in this report. </div>
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<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources.</div><div><br></div><div>In order to gain insights into the resource potential of the South Nicholson region, a key region of focus for EFTF, National Drilling Initiative (NDI) Carrara 1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS), and the MinEx CRC. NDI Carrara 1 is the first drill hole to intersect the, as yet, undifferentiated Proterozoic rocks of the newly defined Carrara Sub-Basin within the South Nicholson region. NDI Carrara 1 is located on the western flank of the Carrara Sub-basin, reaching a total depth of 1751 m, intersecting ca. 630 m of Cambrian Georgina Basin overlying ca. 1100 m of Proterozoic carbonates, black shales and minor siliciclastics.</div><div><br></div><div>Geoscience Australia is undertaking a range of investigations on the lithology, stratigraphy and geotechnical properties of NDI Carrara 1 based on wireline data, as well as undertaking a range of analyses of over 400 physical samples recovered through the entire core. These analyses include geochronology, isotopic studies, mineralogy, inorganic and organic geochemistry, petrophysics, geomechanics, thermal maturity, and petroleum systems investigations. Hylogger™ data is available at the NTGS Geoscience Exploration and Mining Information System (GEMIS) webpage.</div><div><br></div><div>This data release presents results for analyses on selected rock samples from NDI Carrara 1, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include:</div><div><br></div><div>1. Carbon (δ13C), oxygen (δ18O) and strontium (87Sr/86Sr) isotopes on carbonate bearing samples, and</div><div>2. Trace element data on the leachates prepared for 87Sr/86Sr ratio analyses.</div><div><br></div>
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<div>The bulk source rock database table contains publicly available results from Geoscience Australia's organic geochemistry (ORGCHEM) schema and supporting oracle databases for the bulk properties of sedimentary rocks that contain organic matter and fluid inclusions taken from boreholes and field sites. The analyses are performed by various laboratories in service and exploration companies, Australian government institutions, and universities, using a range of instruments. Sedimentary rocks that contain organic matter are typically referred to as source rocks (e.g., organic-rich shale, oil shale and coal) and the organic matter within the rock matrix that is insoluble in organic solvents is named kerogen. Data includes the borehole or field site location, sample depth, stratigraphy, analytical methods, other relevant metadata, and various data types including; elemental composition, and the stable isotopes of carbon, hydrogen, nitrogen, and sulfur. Results are also included from methods that separate the extractable organic matter (EOM) from rocks into bulk components, such as the quantification of saturated hydrocarbon, aromatic hydrocarbon, resin and asphaltene (SARA) fractions according to their polarity. The stable carbon (<sup>13</sup>C/<sup>12</sup>C) and hydrogen (<sup>2</sup>H/<sup>1</sup>H) isotopic ratios of the EOM and derivative hydrocarbon fractions, as well as fluid inclusion oils, are presented in delta notation (i.e., δ<sup>13</sup>C and δ<sup>2</sup>H) in parts per mil (‰) relative to the Vienna Peedee Belemnite (VPDB) standard.</div><div><br></div><div>These data are used to determine the molecular and isotopic compositions of organic matter within rocks and associated fluid inclusions and evaluate the potential for hydrocarbon generation in a basin. Some data are generated in Geoscience Australia’s laboratory and released in Geoscience Australia records. Data are also collated from destructive analysis reports (DARs), well completion reports (WCRs), and literature. The bulk data for sedimentary rocks are delivered in the Source Rock Bulk Properties and Stable Isotopes web services on the Geoscience Australia Data Discovery Portal at https://portal.ga.gov.au which will be periodically updated.</div>
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<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to a low emissions economy, strong resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225 m investment by the Australian Government. </div><div>As part of this program, Geoscience Australia led two deep crustal reflection seismic surveys in the South Nicholson region, revealing the existence of the Carrara Sub-basin, a large sedimentary depocentre up to 8 km deep, beneath the Georgina Basin (Carr et al., 2019; 2020). The depocentre is believed to contain thick sequences of highly prospective Proterozoic rocks for base metals and unconventional hydrocarbons. To confirm geological interpretations and assess resource potential, the National Drilling Initiative, NDI Carrara 1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS) and the MinEx CRC (Geoscience Australia, 2021). NDI Carrara 1 is located on the western flank of the Carrara Sub-basin on the South Nicholson seismic line (17GA-SN1) (Figure 1.1; Figure 1.2), reaching a total depth of 1751 m, intersecting sedimentary rocks comprising ca. 630 m of Cambrian calcareous shales of the Georgina Basin and ca. 1100 m of Proterozoic carbonates and siliciclastics that include black shales of the Carrara Sub-basin.</div><div>This report presents data on selected rock samples from NDI Carrara 1, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include bulk carbon isotope ratios (δ13C) of bitumens and isolated kerogens. In addition, a selection of 10 samples was analysed at Geoscience Australia for comparison purposes.</div><div><br></div>
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Well and seismic correlation schemes exist for the Western Australian and South Australian parts of the Officer Basin but there are inconsistencies between the western and eastern regions. Hence, as part of the Exploring for the Future Officer-Musgrave Project, a chemostratigraphic correlation has been determined for the sedimentary fill of the Officer Basin with emphasis on Neoproterozoic to Cambrian rocks. The correlations have been developed on whole rock inorganic geochemical data obtained from the analysis of 10 study wells which span the basin from Western Australia and into South Australia. A total of 8 chemostratigraphic mega-sequences (MS) are recognised across the basin, that in turn are subdivided into a total of 24 chemostratigraphic sequences. MS1 to MS6 include the Neoproterozoic to Cambrian sedimentary rocks and are the focus of this study. The Neoproterozoic–Cambrian mega-sequences MS1 to MS4 broadly correspond to the previously defined Centralian supersequences CS1 to CS4 and provide robust well-control to the regional seismic correlations. Confidence in the correlation of these old rocks are important since they contain both potential source and reservoir rocks for petroleum generation and accumulation. MS7 is equivalent to the Permian Paterson Formation, while MS8 is equivalent to the Mesozoic section. The elemental data has also been used to elucidate aspects of the petroleum system by characterising reservoirs and identifying fine-grained siliciclastics deposited in anoxic environments which may have source potential. This work is expected to further improve geological knowledge and reduce the energy exploration risk of the Officer Basin, a key focus of this program. <b>Citation:</b> Edwards D.S., Munday S., Wang L., Riley D. & Khider K., 2022. Neoproterozoic and Cambrian chemostratigraphic mega-sequences of the Officer Basin; a regional framework to assist petroleum and mineral exploration. In: Czarnota, K. (ed.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, https://dx.doi.org/10.26186/146285
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Exploring for the Future, Strontium, Oxygen and Carbon Isotopes from the Birrindudu Basin, Australia
<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. </div><div><br></div><div>The Paleo to Mesoproterozoic Birrindudu Basin is an underexplored frontier basin located in northwestern Northern Territory and northeastern Western Australia. The Birrindudu Basin is a region of focus for the second phase of the EFTF program (2020–2024) as it contains strata of similar age to the prospective McArthur Basin, South Nicholson region and Mount Isa Province, but remains comparatively poorly understood. Geoscience Australia, in collaboration with the Northern Territory Geological Survey is acquiring isotopic, geochronological, geochemical and geomechanical data from drillholes intersecting the Birrindudu Basin as part of phase two of EFTF. </div><div><br></div><div>This report presents results on selected rock samples from the Birrindudu Basin, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include:</div><div>1. Carbon (δ13C), oxygen (δ18O) and strontium (87Sr/86Sr) isotopes on carbonate-bearing samples, and</div><div>2. Trace element data on the leachates prepared for 87Sr/86Sr ratio analyses.</div>