Abstracts from the 4th Biennial Conference on Asian Current Research on Fluid Inclusions held in Brisbane, Australia from 10 - 12 August 2012

The Maldon gold deposit in central Victoria lies within the contact aureole of the Harcourt Granite and associated granitic dykes. The ore-bearing fluids are characterised by the presence of CH4-rich fluids, which exhibit complex freezing and heating behaviour, as well as mixed CO2-low-salinity aqueous fluids. Raman analysis indicates that the CH4-rich inclusions from Maldon contain 30 to >70 mol.% CH4 (and <40 mol.% N2) and have highly variable ratios of CH4/CO2, ranging from 0.12 to 15.6. The presence of graphite in the CH4-rich inclusions indicates either accidental trapping of the solid phase at high temperature or post-trapping changes (i.e. incomplete reactions). Higher-salinity brine inclusions only occur locally. The Harcourt Granite is a moderately reduced, I-type granite and the reduced fluids are believed to have formed within (or in close proximity to) thermal aureoles of the dykes or granites during contact metamorphism. We conclude that the Maldon deposit is an 'orogenic' gold deposit that was metamorphosed and/or remobilised during the emplacement of post-orogenic intrusions/dykes. The late-stage magmatic fluids and retrograde metamorphic fluids have produced many of the features associated with other well documented reduced intrusion-related gold systems. This suggests that some 'orogenic' gold deposits may have been completely overprinted by later magmatic/metamorphic events and are now only evident as reduced intrusion-related gold systems.

This web-enabled system allows researchers to retrieve fluid inclusion data from anywhere in the world. The concept is to build a free and widely available web-based library of fluid properties for a range of geological fluids. The database is being developed as an "open" project, which intends to bring together researchers interested in the properties of geological fluids or fluid inclusions.

Raman spectroscopy has been an invaluable method for the non-destructive analysis of fluid inclusions for over 30 years1 and since then it has also been applied to the study of melt inclusions2. While the analysis of gas species in these inclusions is relatively straight forward, the identification of stable and metastable solid phases in inclusions is more challenging due to the limited availability of reference Raman spectra for some minerals. Some examples of inclusions with challenging Raman spectra are discussed below.

The Maldon gold deposit in central Victoria has geological, geochronological and fluid chemistry characteristics that distinguish it from typical vein-hosted, orogenic' gold deposits in this region. The deposit lies within the contact aureole of the Harcourt Granite and associated granitic dykes. The ore-bearing fluids are characterised by the presence of non-aqueous (i.e. carbonic) fluids, which exhibit complex freezing and heating behaviour, as well as mixed CO2-low-salinity aqueous fluids (mostly - 10 wt.% NaCl eq.). Raman analysis indicates that carbonic inclusions can vary from CO2-rich to CH4-rich, with N2 contents up to 38 mol.%. Higher-salinity brine inclusions, 20-22 wt.% NaCl eq., only occur locally. The Harcourt Granite is a moderately reduced, I-type granite and the reduced fluids (e.g. CH4-N2-rich) are believed to have formed within (or in close proximity to) thermal aureoles of the dykes or granites during contact metamorphism. This further supports the premise that the Maldon deposit is an 'orogenic' gold deposit that was metamorphosed and/or remobilised during the emplacement of post-orogenic intrusions/dykes. We conclude that some 'orogenic' gold deposits worldwide may have been completely overprinted by later magmatic/metamorphic events and are now only evident as reduced intrusion-related gold systems.

The Palaeoproterozoic Murphy Inlier is situated at the southern end of the McArthur Basin in northern Australia. The inlier contains over 50 uranium, copper, tin and base metal occurrences. Fluid inclusion studies were carried out on samples of quartz veining from the uranium and copper deposits as well as from the basement rocks to determine the composition of the fluids and to investigate how uranium and copper were transported in these fluids. Four types of fluid inclusions were observed in this study; Type A vapour-rich inclusions with 30 vol.% vapour, Type B two phase aqueous inclusion with - 20 vol.% vapour, Type C multiphase inclusions with one or more solid phases and, Type D liquid-only inclusions. At least three different fluids were identified in the Murphy Inlier. The first is a high temperature fluid denoted by Types A and B inclusions which homogenise over the range from 220 to 380 ºC. In the basement rocks, this fluid is enriched in N2 indicating that it may be related to metamorphic processes. In the uranium deposits this fluid is dominated by CO2 indicating that these fluids are relatively oxidized, while in the copper deposits both CO2 and CH4 are present indicating that these fluids are more reduced than in the regions of uranium mineralisation. The second fluid is a NaCl-rich with salinities ranging from 0.2 to 29.8 mass % NaCl and the third fluid is CaCl2-rich with salinities ranging from 0.1 to 24.7 mass % CaCl2. There is also evidence for fluid mixing between the NaCl-rich and CaCl2-rich end member fluids.

The Palaeoproterozoic Westmoreland region is located 1250 km southeast of Darwin. The Westmoreland region is flanked on the southeast by the Palaeoproterozoic Mt Isa Inlier and the Neoproterozoic South Nicholson Basin and in the northwest it is overlapped by Mesoproterozoic sediments of the McArthur Basin. The northern and southern ends of the McArthur basin share many geologic attributes including correlative stratigraphic rock types, which suggests that there is potential for unconformity-related uranium deposits in the southern McArthur basin and adjacent Westmoreland region. In fact, over fifty occurrences of uranium (some with minor gold) and copper mineralisation have been recorded in the Westmoreland region. Fluid inclusion studies have been carried out on selected uranium and copper prospects on the Northern Territory side of the Westmoreland region. Four types of inclusions have been observed, (Type A) Vapour-rich inclusions containing 30 - 100 vol.% vapour. Varying amounts of CO2 ± N2 ± CH4 have been detected in these inclusions, (Type B) Liquid-rich inclusions with up to 30 vol.% vapour, (Type C) Liquid-only inclusions, and (Type D) Three-phase (vapour + liquid + solid) liquid-rich inclusions containing a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385 °C and are thought to be related to early metamorphic events. Other Type B and Type D inclusions typically homogenised between 100 and 240 °C with a mode around 120 °C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50 °C. Eutectic melting temperatures indicate the presence of CaCl2 in the fluids but final melting temperatures show the presence of both high and low salinity brines. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50 °C.

Exploring for the Future (EFTF) is an Australian Government program led by Geoscience Australia (GA), in partnership with state and Northern Territory governments. The EFTF program (2016-2024) aims to drive industry investment in resource exploration in frontier regions of onshore Australia by providing new precompetitive data and information about their energy, mineral and groundwater resource potential. Under the EFTF program, the Basin Inventory Project undertook a study of petroleum prospectivity of the onshore Eromanga Basin in Queensland and South Australia. Betoota 1 well in Queensland was selected based on the occurrence of gas and oil shows reported in the well completion report. Sampling of cuttings and cores was done at Geoscience Australia's Petroleum Data Repository in Canberra. Geoscience Australia commissioned a fluid inclusion stratigraphy (FIS) study on the downhole samples. Here, volatile components ostensibly trapped with fluid inclusions are released and analysed revealing the level of exposure of the well section to migrating fluids. Integration of thin section (TS) preparations reveal the extent of gas and fluid trapping within fluid inclusions while microthemometry (MT) gives an estimation of fluid inclusion trapping temperature. For Betoota 1, FIS analysis was performed on 305 cuttings and 48 cores between 54.9 metres and 2993.3 metres base depth, together with 15 samples prepared for TS and 3 samples for MT. To support this study, lithostratigraphic tops were compiled by Geoscience Australia. The results of the study are found in the accompanying documents.

Exploring for the Future (EFTF) is an Australian Government program led by Geoscience Australia (GA), in partnership with state and Northern Territory governments. The EFTF program (2016-2024) aims to drive industry investment in resource exploration in frontier regions of onshore Australia by providing new precompetitive data and information about their energy, mineral and groundwater resource potential. Under the EFTF program, the Onshore Energy Project undertook a study of petroleum prospectivity of the onshore Officer Basin in South Australia and Western Australia. Yowalga 3 well in Western Australia was selected based on the occurrence of gas and oil shows reported in the well completion report. Sampling of cuttings and cores was done at Geoscience Australia's Petroleum Data Repository in Canberra. Geoscience Australia commissioned a fluid inclusion stratigraphy (FIS) study on the downhole samples. Here, volatile components ostensibly trapped with fluid inclusions are released and analysed revealing the level of exposure of the well section to migrating fluids. Integration of thin section (TS) preparations reveal to extent of gas and fluid trapping within fluid inclusions while microthemometry (MT) gives an estimation of fluid inclusion trapping temperature. For Yowalga 3, FIS analysis was performed on 698 cuttings and 30 cores between 140 metres and 3526 metres base depth, together with 22 samples prepared for TS. To support this study, lithostratigraphic tops were compiled by Geoscience Australia. The results of the study are found in the accompanying documents. Note: Yowalga 3 results are in two parts, Part 1 and Part 2, since the total number of samples exceeded to maximum number of samples (575) for a Schlumberger well report. Part 1 has cuttings by increasing depth and Part 2 has the remaining cuttings then the cores.

The Paleoproterozoic Westmoreland region is located 1250 km southeast of Darwin. The Westmoreland region is flanked on the southeast by the Paleoproterozoic Mt Isa Inlier and the Neoproterozoic South Nicholson Basin and in the northwest it is overlapped by Mesoproterozoic sediments of the McArthur Basin. The northern and southern ends of the McArthur basin share many geologic attributes including correlative stratigraphic rock types, which suggests that there is potential for unconformity-related uranium deposits in the southern McArthur basin and adjacent Westmoreland region. In fact, over fifty occurrences of uranium (some with minor gold) and copper mineralisation have been recorded in the Westmoreland region. Fluid inclusion studies have been carried out on selected uranium and copper prospects on the Northern Territory side of the Westmoreland region. Four types of inclusions have been observed, (Type A) Vapour-rich inclusions containing 30 100 vol.% vapour. Varying amounts of CO2 ± N2 ± CH4 have been detected in these inclusions, (Type B) Liquid-rich inclusions with up to 30 vol.% vapour, (Type C) Liquid-only inclusions, and (Type D) Three-phase (vapour + liquid + solid) liquid-rich inclusions containing a small daughter crystal. Type A, vapour-rich inclusions and some Type B, liquid-rich inclusions homogenised over the range 171 to 385 °C and are thought to be related to early metamorphic events. Other Type B and Type D inclusions typically homogenised between 100 and 240 °C with a mode around 120 °C, while the presence of liquid-only inclusions suggests trapping at temperatures below 50 °C. Eutectic melting temperatures indicate the presence of CaCl2 in the fluids but final melting temperatures show the presence of both high and low salinity brines. This suggests mixing between saline basinal fluids and low salinity meteoric fluids that continued down to temperatures below 50 °C.