Millions of data points have been acquired or compiled through both phases of the Exploring for the Future (EFTF) program at Geoscience Australia (GA). This data that graces the EFTF Portal and appears in many publications has another home within specialist databases designed and built to house the specific data that GA collects. One such database is HYDROCHEM, which was implemented as part of the Enhanced Data Delivery (EDD) and National Groundwater Systems (NGS) projects. HYDROCHEM hosts 190,097 rows of groundwater, surface water and rainfall water chemistry analyses. This data was either previously hosted in the GNDWATER database, or compiled from legacy data stores. The redevelopment of GNDWATER to HYDROCHEM saw the de-duplication and updating of sample and site-specific metadata into other GA databases, such as SAMPLES, BOREHOLES and FIELDSITES. The redevelopment also added additional constraints to the database, including minimum metadata requirements, constrained look-up tables for units of measure, laboratory, method, filter sizes, standards and uncertainty types. Other features include minimum and maximum values for particular analytes and delivery of the data in standardised GA-preferred units of measure.

<b>Legacy service retired 29/11/2022</b> This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data conforming to the GeoSciML version 4.0 specification. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.

<b>Legacy service retired 29/11/2022 IMPORTANT NOTICE:</b> This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data. This web service is intended to complement the borehole GeoSciML-Portrayal v4.0 web service, providing access to the data in a simple, non-standardised structure. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.

<b> Legacy service retired 29/11/2022</b> This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data conforming to the GeoSciML version 4.0 specification. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.

<b>IMPORTANT NOTICE:</b> This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to a subset of Australian geoscience samples data held by Geoscience Australia. The subset currently relates specifically to Australian Boreholes.

Catchment-scale hydrological and hydrogeological investigations commonly conclude by finding that particular stream reaches are either gaining or losing; they also often assume that the influence of bedrock aquifers on catchment water balances and water quality is insignificant. However, in many cases, such broad findings are likely to oversimplify the spatial and temporal complexity of the connections between the different hydrological system components, particularly in regions dominated by cycles of droughts and flooding. From a modelling perspective, such oversimplifications can have serious implications on the process of identifying the magnitude and direction of the exchange fluxes between the surface and groundwater systems. In this study, we use 3D geological modelling and historic water chemistry and hydraulic records to identify the origins of groundwater at different locations in the alluvium and along the course of streams in the Lockyer Valley (Queensland, Australia), a catchment impacted by a severe drought (‘Millennium Drought’) from 1998 to 2009, followed by extensive flooding in 2011. We also demonstrate how discharge from the sub-alluvial regional-scale volcanic and sedimentary bedrock influences the water balance and water quality of the alluvium and streams. The investigation of aquifer geometry via development of a three-dimensional geological model combined with an assessment of hydraulic data provided important insights on groundwater flow paths and helped to identify areas where bedrock aquifers interact with shallow alluvial aquifers and streams. Multivariate statistical techniques were then applied as an additional line of evidence to groundwater and surface water hydrochemical data from large historical datasets. This confirmed that most sub-catchments within the Lockyer Valley have distinct water chemistry patterns, which result from mixing of different water sources, including discharge from the sub-alluvial bedrock. Importantly, in addition to the observed spatial variability, time-series hydrochemical groundwater and surface water data further demonstrated that the hydraulic connection between alluvial aquifers, streams and sub-alluvial bedrock aquifers is temporally dynamic with very significant changes occurring at the transition from normal to drought conditions and following flooding, affecting both catchment water quality and water balances. <b>Citation:</b> M. Raiber, S. Lewis, D.I. Cendón, T. Cui, M.E. Cox, M. Gilfedder, D.W. Rassam, Significance of the connection between bedrock, alluvium and streams: A spatial and temporal hydrogeological and hydrogeochemical assessment from Queensland, Australia, <i>Journal of Hydrology</i>, Volume 569, 2019, ISSN 0022-1694, https://doi.org/10.1016/j.jhydrol.2018.12.020.

<b>Legacy service Retired 29/11/2022 IMPORTANT NOTICE: </b>This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to Australian onshore and offshore borehole data. This web service is intended to complement the borehole GeoSciML-Portrayal v4.0 web service, providing access to the data in a simple, non-standardised structure. The borehole data includes Mineral Drillholes, Petroleum Wells and Water Bores along with a variety of others types. The dataset has been restricted to onshore and offshore Australian boreholes, and bores that have the potential to support geological investigations and assessment of a variety of resources.

Geoscience Australia and its predecessors have analysed the hydrochemistry of water sampled from bores, surface features, rainwater and core samples (pore water). Samples have been collected during drilling or monitoring projects, including Exploring for the Future (EFTF). The hydrochemistry database includes physical-chemical parameters (EC, pH, redox potential, dissolved oxygen), major and minor ions, trace elements, isotopes and nutrients. The resource is accessible via the Geoscience Australia Portal <a href="https://portal.ga.gov.au/">(https://portal.ga.gov.au/)</a>

Hydrochemistry data for Australian groundwater, including field and laboratory measurements of chemical parameters (electrical conductivity (EC), potential of hydrogen (pH), redox potential, and dissolved oxygen), major and minor ions, trace elements, nutrients, pesticides, isotopes and organic chemicals. < <b>Value: </b>The chemical properties of groundwater are key parameters to understand groundwater systems and their functions. Groundwater chemistry information includes the ionic and isotopic composition of the water, representing the gases and solids that are dissolved in it. Hydrochemistry data is used to understand the source, flow, and interactions of groundwater samples with surface water and geological units, providing insight into aquifer characteristics. Hydrochemistry information is key to determining the quality of groundwater resources for societal, agricultural, industrial and environmental applications. Insights from hydrochemical analyses can be used to assess a groundwater resource, the impact of land use changes, irrigation and groundwater extraction on regional groundwater quality and quantity, assess prospective mineral exploration targets, and determine how groundwater interacts with surface water in streams and lakes. <b>Scope: </b>The database was inaugurated in 2016 with hydrochemical data collected over the Australian landmass by Geoscience Australia and its predecessors, and has expanded with regional and national data. It has been in the custodianship of the hydrochemists in Geoscience Australia's Minerals, Energy and Groundwater Division and its predecessors. Explore the <b>Geoscience Australia portal - https://portal.ga.gov.au/</b>

<b>IMPORTANT NOTICE: </b>This web service has been deprecated. The Australian Onshore and Offshore Boreholes OGC service at https://services.ga.gov.au/gis/boreholes/ows should now be used for accessing Geoscience Australia borehole data. This is an Open Geospatial Consortium (OGC) web service providing access to a subset of Australian geoscience samples data held by Geoscience Australia. The subset currently relates specifically to Australian Boreholes.