The main aim of this study is to use petroleum systems analysis to improve the understanding of the petroleum systems present on the Lawn Hill Platform of the Isa Superbasin. Part A of this report series reported the results of burial and thermal modelling of two wells (Desert Creek 1 and Egilabria 1). Results from the 1-D modelling help other aspects of interest such as the hydrocarbon generation potential and distribution of hydrocarbons by source rock which this publication presents. Modelling uncertainties are reported and described, highlighting knowledge gaps and areas for further work.

The Browse Basin is located offshore on Australia's North West Shelf and is a proven hydrocarbon province hosting gas with associated condensate and where oil reserves are typically small. The assessment of a basin's oil potential traditionally focuses on the presence or absence of oil-prone source rocks. However, light oil can be found in basins where source rocks are gas-prone and the primary hydrocarbon type is gas-condensate. Oil rims form whenever such fluids migrate into reservoirs at pressures less than their dew point (saturation) pressure. By combining petroleum systems analysis with geochemical studies of source rocks and fluids (gases and liquids), four Mesozoic petroleum systems have been identified in the basin. This study applies petroleum systems analysis to understand the source of fluids and their phase behaviour in the Browse Basin. Source rock richness, thickness and quality are mapped from well control. Petroleum systems modelling that integrates source rock property maps, basin-specific kinetics, 1D burial history models and regional 3D surfaces, provides new insights into source rock maturity, generation and expelled fluid composition. The principal source rocks are Early-Middle Jurassic fluvio-deltaic coaly shales and shales within the J10-J20 supersequences (Plover Formation), Middle-Late Jurassic to Early Cretaceous sub-oxic marine shales within the J30-K10 supersequences (Vulcan and Montara formations) and K20-K30 supersequences (Echuca Shoals Formation). All of these source rocks contain significant contributions of land-plant derived organic matter and within the Caswell Sub-basin have reached sufficient maturities to have transformed most of the kerogen into hydrocarbons, with the majority of expulsion occurring from the Late Cretaceous until present.

The Browse Basin hosts considerable gas and condensate resources, including the Ichthys and Prelude fields that are being developed for liquefied natural gas (LNG) production. Oil discoveries are sub-economic. This multi-disciplinary study integrating sequence stratigraphy, palaeogeography and geochemical data has mapped the spatial and temporal distribution of Jurassic to earliest Cretaceous source rocks. This study allows a better understanding of the source rocks contribution to the known hydrocarbon accumulations and charge history in the basin, including in underexplored areas. The Jurassic to earliest Cretaceous source rocks have been identified as being the primary sources of the gases and condensates recovered from accumulations in the Browse Basin as follows: - The Lower–Middle Jurassic J10–J20 (Plover Formation) organic-rich source rocks have been deposited along the northeast-southwest trending fluvial-deltaic system associated with a phase of pre-breakup extension. They have charged gas reservoired within J10–J20 accumulations on the Scott Reef Trend and in the central Caswell Sub-basin at Ichthys/Prelude, and in the Lower Cretaceous K40 supersequence on the Yampi Shelf. - Late Jurassic–earliest Cretaceous J30–K10 source rocks are interpreted to have been deposited in a rift, north of the Scott Reef Trend and along the Heywood Fault System (e.g. Callovian–Tithonian J30–J50 supersequences, lower Vulcan Formation). The J30–K10 shales are believed to have sourced wet gas reservoired in the K10 sandstone (Brewster Member) in the Ichthys/Prelude and Burnside accumulations, and potentially similar plays in the southern Caswell Sub-basin. - The organic-rich source rocks observed in the Heywood Graben may be associated with deeper water marine shales with higher plant input into the isolated inboard rift. They are the potential source of fluids reservoired within the Crux accumulation, which has a geochemical composition more closely resembling a petroleum system in the southern Bonaparte Basin.

<p>Northern Australia contains extensive Proterozoic-aged sedimentary basins with potential energy, mineral, and groundwater resources concealed beneath the surface. The region is remote and largely underexplored with limited data and infrastructure and therefore is considered to have high exploration risk. Exploration for hydrocarbons and basin-hosted base metals, although perceived to have very different exploration models, share a number of important similarities and key parameters. Foremost amongst these is shale geochemistry since the same reduced, organic-rich shales are both a hydrocarbon source rock and a depositional site for base metal mineralisation. Furthermore, anoxic and euxinic (anoxic with free hydrogen sulfide, H2S) water column and sediments are important for both the preservation of organic matter and as a H2S reservoir needed for precipitation of ore minerals after reaction with oxic metalliferous brines. Here we present new organic and inorganic geochemical datasets for shales in the South Nicholson Basin, Lawn Hill Platform and greater McArthur Basin, including the organic-richness of shales and the inorganic geochemistry of redox-sensitive trace metals, to demonstrate changes in water-column chemistry and favourable base metals depositional sites. Parameters such as total organic carbon (TOC) content and redox-sensitive elemental concentrations are used to identify prospective packages with hydrocarbon and base metals mineral resource potential <p>The results reveal many units in the Lawn Hill Platform, South Nicholson Basin and greater McArthur Basin contain organic-rich rocks. A cut-off value of TOC ≥ 2 wt% is used to define several shale and carbonate sequences in the region that are favourable for both hydrocarbon generation and as base metals depositional sites. Inorganic geochemistry results demonstrate a range of paleoredox conditions, from predominantly anoxic, ferruginous conditions with deviations, to sub-oxic and euxinic conditions. Future work mapping the temporal and spatial distribution of this geochemistry, in combination with other mappable geological criteria, is required to create mineral and petroleum systems models that can define prospective fairways across the basins and increase our understanding of resource potential. <p>The precompetitive data generated in this study highlight the utility of shared geochemical datasets for resource exploration in the region. More broadly, this study improves our understanding of the energy and mineral potential across northern Australia, supporting resource decision-making and investment.

Petroleum geochemical datasets and information are essential to government for evidence-based decision making on natural resources, and to the petroleum industry for de-risking exploration. Geoscience Australia’s newly built Data Discovery Portal (https://portal.ga.gov.au/) enables digital discoverability and accessibility to key petroleum geochemical datasets. The portal’s web map services and web feature services allow download and visualisation of geochemical data for source rocks and petroleum fluids, and deliver a petroleum systems framework for northern Australian basins. The Petroleum Source Rock Analytics Tool enables interrogation of source rock data within boreholes and field sites, and facilitates correlation of these elements of the petroleum system within and between basins. The Petroleum Systems Summary Assessment Tool assists the user to search and query components of the petroleum system(s) identified within a basin. The portal functionality includes customised data searches, and visualisation of data via interactive maps, graphs and geoscientific tools. Integration of the petroleum systems framework with the supporting geochemical data enables the Data Discovery Portal to unlock the value of these datasets by affording the user a one-stop access to interrogate the data. This allows greater efficiency and performance in evaluating the petroleum prospectivity of Australia’s sedimentary basins, facilitating and accelerating decision making around exploration investment to ensure Australia’s future resource wealth <b>Citation:</b> Edwards, D.S., MacFarlane, S.K., Grosjean, E., Buckler, T., Boreham, C.J., Henson, P., Cherukoori, R., Tracey-Patte, T., van der Wielen, S., Ray, J. and Raymond, O., 2020. Australian source rocks, fluids and petroleum systems – a new integrated geoscience data discovery portal for maximising data potential. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.

Pyrolysis and bulk kinetic studies were used to investigate the hydrocarbon generation potential and source rock facies variability of the marine organic-rich rocks from the Middle Ordovician (Darriwilian) Goldwyer Formation in the Canning Basin, Western Australia. Rock Eval pyrolysis results for the analysed immature to mid-mature calcareous mudstones imply that the upper Goldwyer Sequence I samples contain oil-prone Type I kerogen, while the lower Goldwyer Sequence III samples comprise on average Type II/III oil- and gas-prone kerogen. This is supported by the pyrolysis gas chromatography (Py-GC) results that show the presence of homogenous organofacies in the Goldwyer Sequence I that comprise aliphatic molecular signatures, possibly attributed to the selective preservation of the lipid fraction derived from <i>Gloeocapsomorpha prisca</i> (<i>G. prisca</i>). The heterogeneous organofacies of the Goldwyer Sequence III contains aromatic moieties that are present in similar abundance as the aliphatic compounds. The calcareous claystones of the Goldwyer Sequence I have the capacity to generate paraffinic oil with low wax contents, whereas those of the Goldwyer Sequence III have generative potential for paraffinic-naphthenic-aromatic (P-N-A) low wax oils and gas and condensate. The temperature for hydrocarbon generation for the Type I kerogen, assuming a constant geological heating rate of 3^oC/Ma, is estimated to occur over a narrow interval between 145^oC and 170^oC for the Goldwyer Sequence I samples. Generation from the Type II/III kerogen occurs from 100°C to 160°C in the Goldwyer Sequence III samples which are significantly thermally less stable than observed for the Goldwyer Sequence I samples. The kinetics results for both sequences were used in standard thermal and burial history plots to evaluate their transformation ratio and hydrocarbon generative potential. This provided a basin-specific kinetic input for burial history modelling and a better constraint for kerogen transformation and hydrocarbon generation on the Broome Platform. <b>Citation:</b> Lukman M. Johnson, Reza Rezaee, Gregory C. Smith, Nicolaj Mahlstedt, Dianne S. Edwards, Ali Kadkhodaie, Hongyan Yu,; Kinetics of hydrocarbon generation from the marine Ordovician Goldwyer Formation, Canning Basin, Western Australia,<i> International Journal of Coal Geology</i>, Volume 232, <b>2020</b>, 103623, ISSN 0166-5162, https://doi.org/10.1016/j.coal.2020.103623.

<div>Geoscience Australia’s Onshore Basin Inventories project delivers a single point of reference and creates a standardised national basin inventory that provides a whole-of-basin catalogue of geology, petroleum systems, exploration status and data coverage of hydrocarbon-prone onshore Australian sedimentary basins. In addition to summarising the current state of knowledge within each basin, the onshore basin inventory reports identify critical science questions and key exploration uncertainties that may help inform future work program planning and decision making for both government and industry. Volume 1 of the inventory covers the McArthur, South Nicholson, Georgina, Wiso, Amadeus, Warburton, Cooper and Galilee basins and Volume 2 expands this list to include the Officer, Perth and onshore Canning basins. Under Geoscience Australia’s Exploring for the Future (EFTF) program, several new onshore basin inventory reports are being delivered. Upcoming releases include the Adavale Basin of southern Queensland, and a compilation report addressing Australia’s poorly understood Mesoproterozoic basins. These are supported by value-add products that address identified data gaps and evolve regional understanding of basin evolution and prospectivity, including petroleum systems modelling, seismic reprocessing and regional geochemical studies. The Onshore Basin Inventories project continues to provide scientific and strategic direction for pre-competitive data acquisition under the EFTF work program, guiding program planning and shaping post-acquisition analysis programs.</div>

The greater Phoenix area in the Bedout Sub-basin has experienced recent exploration success on Australia’s North West Shelf (NWS). Oil and gas discoveries in the Triassic reservoirs of the Keraudren Formation and Locker Shale have revived interest in mapping the distribution and lateral facies variation of the Triassic succession from the Bedout Sub-basin into the adjacent underexplored Beagle and Rowley sub-basins. This multi-disciplinary study integrating structural architecture, sequence stratigraphy, palaeogeography and geochemistry has mapped the spatial and temporal distributions of Triassic source rocks on the central NWS. The Lower‒Middle Triassic palaeogeography is dominated by a deltaic system building from the Bedout Sub-basin into the Beagle Sub-basin. The oil sourced and reservoired within the Lower‒Middle Triassic sequences at Phoenix South 1 is unique to the Bedout Sub-basin, compared to other oils along the NWS. Its mixed land-plant and algal biomarker signature is most likely sourced locally by fluvial-deltaic mudstones within the TR10‒TR14 or TR15 sequences and represents a new petroleum system on the NWS. A Middle Triassic marine incursion is recorded in the Bedout Sub-basin with the development of a carbonate platform while in the Rowley Sub-basin, volcanics have been penetrated at the top of the thick Lower‒Middle Triassic sediment package. The Late Triassic palaeogeographic map suggests a carbonate environment in the Rowley Sub-basin distinct to the clastic-dominated fluvial-deltaic environment in the Beagle Sub-basin. This information combined with results of well-based geochemical analyses highlights the potential for hydrocarbon generation within the Upper Triassic in these sub-basins. This extended abstract was presented at the Australasian Exploration Geoscience Conference (AECG) 2019

<div>NDI Carrara 1 is a 1750 m stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia under the Exploring for the Future program and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-basin, a recently discovered depocentre in the South Nicholson region. The drill hole intersected Cambrian and Proterozoic sediments consisting of organic-rich black shales and a thick sequence of interbedded black shales and silty sandstones with hydrocarbon shows. A comprehensive analytical program carried out by Geoscience Australia on the recovered core samples from 283 m to total depth at 1751&nbsp;m provides critical data for calibration of burial and thermal history modelling.</div><div>Using data from this drilling campaign, burial and thermal history modelling was undertaken to provide an estimate of the time-temperature maxima that the sub-basin has experienced, contributing to an understanding of hydrocarbon maturity. Proxy kerogen kinetics are assessed to estimate the petroleum prospectivity of the sub-basin and attempt to understand the timing and nature of hydrocarbon generation. Combined, these newly modelled data provide insights into the resource potential of this frontier Proterozoic hydrocarbon province, delivering foundational data to support explorers across the eastern Northern Territory and northwest Queensland.</div> <b>Citation:</b> Palu Tehani J., Grosjean Emmanuelle, Wang Liuqi, Boreham Christopher J., Bailey Adam H. E. (2023) Thermal history of the Carrara Sub-basin: insights from modelling of the NDI Carrara 1 drill hole. <i>The APPEA Journal</i><b> 63</b>, S263-S268. https://doi.org/10.1071/AJ22048

Although the Canning Basin has yielded minor gas and oil within conventional and unconventional reservoirs, the relatively limited geological data available in this under-explored basin hinder a thorough assessment of its hydrocarbon potential. Knowledge of the Paleozoic Larapintine Petroleum Supersystem is restricted by the scarcity of samples, especially recovered natural gases, which are limited to those collected from recent exploration successes in Ordovician and Permo-Carboniferous successions along the margins of the Fitzroy Trough and Broome Platform. To address this shortcoming, gases trapped within fluid inclusions were analysed from 121 Ordovician to Permian rock samples (encompassing cores, sidewall cores and cuttings) from 70 exploration wells with elevated mud gas readings. The molecular and carbon isotopic compositions of these gases have been integrated with gas compositions derived from open-file sources and recovered gases analysed by Geoscience Australia. Fluid inclusion C1–C5 hydrocarbon gases record a snapshot of the hydrocarbon generation history. Where fluid inclusion gases and recovered gases show similar carbon isotopes, a simple filling history is likely; where they differ, a multicharge history is evident. Since some fluid inclusion gases fall outside the carbon isotopic range of recovered gases, previously unidentified gas systems may have operated in the Canning Basin. Interestingly, the carbon isotopes of the fluid-inclusion heavy wet gases converge with the carbon isotopes of the light oil liquids, indicating potential for gas–oil correlation. A regional geochemical database incorporating these analyses underpins our re-evaluation of gas systems and gas–gas correlations across the basin. <b>Citation:</b> Boreham, C.J., Edwards, D.S., Sohn, J.H., Palatty, P., Chen, J.H. and Mory, A.J., 2020. Gas systems in the onshore Canning Basin as revealed by gas trapped in fluid inclusions. In: Czarnota, K., Roach, I., Abbott, S., Haynes, M., Kositcin, N., Ray, A. and Slatter, E. (eds.) Exploring for the Future: Extended Abstracts, Geoscience Australia, Canberra, 1–4.