<div>This study was commissioned by Geoscience Australia (GA) to produce a report on methane adsorption and desorption of select samples from the deep stratigraphic drill hole NDI Carrara 1, located in the Proterozoic Carrara Sub-basin in the Northern Territory. Plugs were taken from depths of interest and analysed via adsorption and desorption isotherm testing at the CSIRO laboratories in Clayton, Victoria. </div>

The recently drilled deep stratigraphic drill hole NDI Carrara 1 penetrates the carbonate formations of the Cambrian Georgina Basin as well as the underlying Proterozoic successions of the Carrara Sub-basin. The Proterozoic section consists predominantly of tight shales, siltstones, and calcareous clastic rocks. This study aims to assess the petrophysical properties of the Proterozoic shales using conventional wireline logs. Gamma ray and neutron-density crossplots were used to calculate shale volume fraction, and neutron-density crossplots were applied to compute the total and effective porosity of non-shale rocks. Total organic carbon (TOC) content was interpreted using artificial neural networks, and was used to derive the volume of organic matter was converted from TOC content. Bulk density logs were corrected by removing the kerogen effect in the organic-rich shales. Matrix and kerogen densities were obtained by correlating the reciprocal of grain density with TOC content. Total shale porosity was calculated from kerogen-corrected density porosity and organic porosity. Effective porosity was estimated by removing the shaliness effect. Water saturation was derived using the Simandoux equation. The Proterozoic Lawn Hill Formation in NDI Carrara 1 exhibits petrophysical properties that indicate a favourable potential for shale gas resources. Herein, we define three informal intervals within the intersected Lawn Hill Formation; the upper Lawn Hill, the Lawn Hill shale, and the lower Lawn Hill. The net shale thickness of the upper Lawn Hill and Lawn Hill shale intervals are 165 m and 149 m, respectively. The increased TOC content and organic porosity of the upper Lawn Hill and Lawn Hill shale implies higher adsorbed gas content potential. The Lawn Hill shale has the highest gas saturation (average of 31.1%) and the highest potential for free gas content, corresponding to the highest methane responses in logged mud gas profiles. This extended Abstract was submitted to/presented at the Australasian Exploration Geoscience Conference (AEGC) 2023, Brisbane (https://2023.aegc.com.au/)

<div>Geoscience Australia’s Exploring for the Future program provides precompetitive information to inform decision-making by government, community and industry on the sustainable development of Australia's mineral, energy and groundwater resources. By gathering, analysing and interpreting new and existing precompetitive geoscience data and knowledge, we are building a national picture of Australia’s geology and resource potential. This leads to a strong economy, resilient society and sustainable environment for the benefit of all Australians. This includes supporting Australia’s transition to a low emissions economy, strong resources and agriculture sectors, and economic opportunities and social benefits for Australia’s regional and remote communities. The Exploring for the Future program, which commenced in 2016, is an eight year, $225 m investment by the Australian Government. </div><div>As part of this program, Geoscience Australia led two deep crustal reflection seismic surveys in the South Nicholson region, revealing the existence of the Carrara Sub-basin, a large sedimentary depocentre up to 8 km deep, beneath the Georgina Basin (Carr et al., 2019; 2020). The depocentre is believed to contain thick sequences of highly prospective Proterozoic rocks for base metals and unconventional hydrocarbons. To confirm geological interpretations and assess resource potential, the National Drilling Initiative, NDI Carrara 1 stratigraphic drill hole was completed in late 2020, as a collaboration between Geoscience Australia, the Northern Territory Geological Survey (NTGS) and the MinEx CRC (Geoscience Australia, 2021). NDI Carrara 1 is located on the western flank of the Carrara Sub-basin on the South Nicholson seismic line (17GA-SN1) (Figure 1.1; Figure 1.2), reaching a total depth of 1751 m, intersecting sedimentary rocks comprising ca. 630 m of Cambrian calcareous shales of the Georgina Basin and ca. 1100 m of Proterozoic carbonates and siliciclastics that include black shales of the Carrara Sub-basin.</div><div>This report presents data on selected rock samples from NDI Carrara&nbsp;1, conducted by the Mawson Analytical Spectrometry Services, University of Adelaide, under contract to Geoscience Australia. These results include bulk carbon isotope ratios (δ13C) of bitumens and isolated kerogens. In addition, a selection of 10 samples was analysed at Geoscience Australia for comparison purposes.</div><div><br></div>

NDI Carrara 1 is a deep stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-Basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) recently acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1120 m of Proterozoic sedimentary rocks unconformably overlain by 630 m of Cambrian Georgina Basin carbonates. Continuous cores recovered from 283 m to a total depth of 1750 m provide samples of the highest quality for a comprehensive geochemical program designed to inform on the energy and mineral prospectivity of the Carrara Sub-basin. Total Organic Carbon (TOC) contents from Rock-Eval pyrolysis of the Cambrian and Proterozoic sections demonstrate the potential for several thick black shales as source rocks and unconventional plays. Evidence for retained hydrocarbons included bituminous oil stains in centimetre-scale vugs within the Cambrian Georgina Basin and several oil bleeds within the Proterozoic section. The latter also contains surface gas with up to 2% methane concentrations measured within carbonaceous mudstones. Geochemical analyses of hydrocarbon shows highlight the occurrence of several petroleum systems operating in this frontier region. The results at NDI Carrara 1 offer the promise of a new exciting resource province in northern Australia.

<div>NDI Carrara 1 is a deep stratigraphic borehole that was drilled in 2020 under the MinEx CRC’s National Drilling Initiative (NDI) program in collaboration with Geoscience Australia and the Northern Territory Geological Survey. NDI Carrara 1 is the first stratigraphic test of the recently described Carrara Sub-basin, a Proterozoic aged depocentre located in the South Nicholson region of northwest Queensland and the Northern Territory. The borehole was drilled to a total depth of 1751 m and penetrated a succession of Cambrian aged Georgina Basin carbonate and siliciclastic rocks that unconformably overly a thick succession of Proterozoic age siliciclastic and carbonate-rich sediments. Although drilled on the western flank of the Carrara Sub-basin, NDI Carrara 1 did not penetrate to basement. Interpretation of the L210 deep-crustal seismic survey suggests that further Proterozoic sedimentary packages known from the northern Lawn Hill Platform in northwest Queensland are likely to be found underlying the succession intersected in NDI Carrara 1. The borehole was continuously cored from 283 m to total depth, and an extensive suite of wireline logs was acquired. Geoscience Australia and partners have undertaken an extensive analytical program to understand the depositional, structural, and diagenetic history of the sediments intersected in NDI Carrara 1. This program includes a targeted petrophysical study that aims to characterise the physical properties of these Proterozoic rocks through laboratory analysis of core samples, the results of which are summarised in this data release.</div><div><br></div><div>This data release provides data from new X-ray Computerised Tomography (XCT) scanning and gas porosity and permeability testing for 32 samples from NDI Carrara 1. Additional low permeability tests were undertaken on select samples that were identified as being ultra-tight (permeability <1 μD). These tests were performed at the CSIRO Geomechanics and Geophysics Laboratory in Perth, during January to June 2022. The full results as provided by CSIRO to Geoscience Australia are provided as an attachment to this document.&nbsp;</div>

The NDI Carrara 1 sedimentology, microstructural analysis and sequence stratigraphy program was a joint undertaking between Geoscience Australia (GA) and CSIRO (Perth) as part of the Exploring for the Future program to examine the sedimentology, sequence stratigraphy and paleogeography of the Carrara Sub-basin. The program was based on recovered core from the National Drilling Initiative (NDI) deep stratigraphic drill hole, NDI Carrara 1. NDI Carrara 1 is the first drill hole to intersect the Proterozoic rocks of the Carrara Sub-Basin, a large depocentre discovered during seismic acquisition conducted during the first phase of the EFTF program in 2017. NDI Carrara 1 is located on the western flanks of the Carrara Sub-basin, reaching a total depth of 1751 m, intersecting ca. 630 m of Cambrian Georgina Basin overlying ca. 1100 m of Proterozoic carbonates, black shales and siliciclastics. This final report, and associated appendices, compiles the findings of three milestone deliverables. The first component of the report addresses the sedimentology of the Proterozoic section of NDI Carrara 1 with an accompanying Appendix (core log, from HyLogger data). The second component is a detailed microstructural analysis based on selected thin sections in intervals of interest. The final component completed a 1D sequence stratigraphic assessment, enabling regional stratigraphic correlations to be established and an interpretive paleogeographic map generated for the Proterozoic sequences of interest across the region .

As part of Geoscience Australia’s Exploring for the Future program, this study aims to analyse the hydrocarbon prospectivity in the Carrra Sub-basin through wireline log interpretation and shale gas reservoir characterisation. NDI Carrara 1 is the first stratigraphic test of the Carrara Sub-basin, a recently uncovered depocentre located within the South Nicholson region of the eastern Northern Territory and northwestern Queensland. Four chemostratigraphic packages were defined according to the informal sub-division of stratigraphy and inorganic geochemical properties. Wireline log interpretation has been conducted to derive the clay mineral compositions, porosity, gas saturation and gas contents for the unconventional shale gas reservoirs in the Proterozoic succession in NDI Carrara 1. The predominant clay minerals include illite/muscovite, mixed-layer clay, smectite, kaolinite, and minor contents of glauconite and chlorite. The average geothermal gradient is estimated to be 35.04 °C/km with a surface temperature of 29.4 °C. The average formation pressure gradient is calculated to be < 10.7 MPa/km from mud weight records. Artificial neural network technology is used to interpret the TOC content from wireline logs for unconventional shale gas reservoirs. TOC content is positively correlated with methane and ethane concentrations in mudlog gas profiles, shale porosity, formation resistivity and gas content for NDI Carrara 1. The organic-rich shales in P2 have favourable adsorbed, free and total gas contents. The organic-rich micrites within P3 have the potential in adsorbed gas, but with very low average gas saturation (< 0.01 m3/m3). Our interpretation has identified potential shale gas reservoirs, as well as tight non-organic-rich shales and siltstones with potential as gas reservoirs. These occur throughout several of the identified chemostratigraphic packages within the Proterozoic section of NDI Carrara 1.

NDI Carrara 1 is a deep stratigraphic drill hole (~1751m) completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first test of the Carrara Sub-basin, a depocentre newly discovered in the South Nicholson region based on interpretation from seismic surveys (L210 in 2017 and L212 in 2019) recently acquired as part of the Exploring for the Future program. The drill hole intersected approximately 1100 m of Proterozoic sedimentary rocks uncomformably overlain by 630 m of Cambrian Georgina Basin carbonates. This report presents the petrology conducted on 50 selected thin sections of NDI Carrara 1 undertaken by Microanalysis Australia (under contract to Geoscience Australia as part of the Exploring for the Future program).

A comprehensive geochemical program was carried out on rock samples collected in the NDI Carrara 1 drill hole, the first stratigraphic test of the newly discovered Carrara Sub-basin located in the South Nicholson region of northern Australia. The drill hole recovered continuous core from 284 m to total depth at 1750 m and intersected approximately 1120 m of Proterozoic sedimentary rocks, unconformably overlain by 630 m of Cambrian Georgina Basin carbonate-rich rocks. Total organic carbon (TOC) contents from Rock-Eval pyrolysis highlight the potential for several thick black shales to be a source of petroleum for conventional and unconventional plays. Cambrian rocks contain an organic-rich section with TOC contents of up to 4.7 wt.% and excellent oil-generating potential. The Proterozoic section is overmature for oil generation but mature for gas generation, with potential for generating gas in carbonaceous mudstones showing TOC contents up to 5.5 wt.% between 680 and 725 m depth. A sustained release of methane (up to 2%) recorded during drilling from 1150 to 1500 m suggests potential for an unconventional gas system in the Proterozoic rocks from 950 to 1415 m depth, which exhibit favourable organic richness and thermal maturity. The Proterozoic rocks, which are comparable in age to the sediment-hosted deposits of the Century Mine, contain local occurrences of lead, zinc and copper sulfide minerals providing hints of mineralisation. The combined geochemical results offer the promise of a potential new resource province in northern Australia. <b>Citation:</b> E. Grosjean, A.J.M. Jarrett, C.J. Boreham, L. Wang, L. Johnson, J.M. Hope, P. Ranasinghe, J.J. Brocks, A.H.E. Bailey, G.A. Butcher, C.J. Carson, Resource potential of the Proterozoic–Paleozoic Carrara depocentre, South Nicholson region, Australia: Insights from stratigraphic drilling, <i>Organic Geochemistry</i>, Volume 186, 2023, 104688, ISSN 0146-6380, DOI: https://doi.org/10.1016/j.orggeochem.2023.104688.

<div>NDI Carrara 1 is a 1750 m stratigraphic drill hole completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI) in collaboration with Geoscience Australia under the Exploring for the Future program and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-basin, a recently discovered depocentre in the South Nicholson region. The drill hole intersected Cambrian and Proterozoic sediments consisting of organic-rich black shales and a thick sequence of interbedded black shales and silty sandstones with hydrocarbon shows. A comprehensive analytical program carried out by Geoscience Australia on the recovered core samples from 283 m to total depth at 1751&nbsp;m provides critical data for calibration of burial and thermal history modelling.</div><div>Using data from this drilling campaign, burial and thermal history modelling was undertaken to provide an estimate of the time-temperature maxima that the sub-basin has experienced, contributing to an understanding of hydrocarbon maturity. Proxy kerogen kinetics are assessed to estimate the petroleum prospectivity of the sub-basin and attempt to understand the timing and nature of hydrocarbon generation. Combined, these newly modelled data provide insights into the resource potential of this frontier Proterozoic hydrocarbon province, delivering foundational data to support explorers across the eastern Northern Territory and northwest Queensland.</div> <b>Citation:</b> Palu Tehani J., Grosjean Emmanuelle, Wang Liuqi, Boreham Christopher J., Bailey Adam H. E. (2023) Thermal history of the Carrara Sub-basin: insights from modelling of the NDI Carrara 1 drill hole. <i>The APPEA Journal</i><b> 63</b>, S263-S268. https://doi.org/10.1071/AJ22048